EP 0315247 B1 19920415 - PROCESS FOR THE PRODUCTION OF EPOXY DERIVATIVES WITH CIS-CONFIGURATION, BY STARTING FROM MIXTURES OF THE CORRESPONDING OLEFINIC STEREOISOMERS
Title (en)
PROCESS FOR THE PRODUCTION OF EPOXY DERIVATIVES WITH CIS-CONFIGURATION, BY STARTING FROM MIXTURES OF THE CORRESPONDING OLEFINIC STEREOISOMERS
Publication
Application
Priority
IT 2248487 A 19871102
Abstract (en)
[origin: EP0315247A1] Process for producing epoxy derivatives with cis-configuration by starting from mixtures of cis- and trans-isomers of the corresponding olefinic compounds by means of the oxidation of the corresponding olefinic compounds with hydrogen peroxide, or with compounds capable of producing hydrogen peroxide under the reaction conditions, in the presence of synthetic zeolites containing titanium atoms, wherein the process is carried out by operating with hydrogen peroxide in an amount lower than, or equal to, the amount, by mol, of the olefinic compound with cis-configuration which is present in the mixture, the so-obtained epoxy compound of substantially cis-configuration is separated from the unreacted olefinic compounds, essentially constituted by isomers with trans-configuration, the olefinic compound with substantially trans-configuration is submitted to low temperature isomerization, in order to reach the equilibrium composition, and the so-isomerized olefinic compound is recycled to the oxidation area.
IPC 1-7
IPC 8 full level
C07D 301/12 (2006.01); C07D 303/04 (2006.01)
CPC (source: EP)
C07D 301/12 (2013.01); C07D 303/04 (2013.01)
Designated contracting state (EPC)
AT BE CH DE ES FR GB GR LI LU NL SE
DOCDB simple family (publication)
EP 0315247 A1 19890510; EP 0315247 B1 19920415; AT E74916 T1 19920515; DE 3870152 D1 19920521; IT 1223337 B 19900919; IT 8722484 A0 19871102
DOCDB simple family (application)
EP 88202369 A 19881025; AT 88202369 T 19881025; DE 3870152 T 19881025; IT 2248487 A 19871102