Global Patent Index - EP 0673381 A1

EP 0673381 A1 19950927 - HOMOGENEOUS BIMETALLIC HYDROFORMYLATION CATALYSTS AND PROCESSES UTILIZING THESE CATALYSTS FOR CONDUCTING HYDROFORMYLATION REACTIONS.

Title (en)

HOMOGENEOUS BIMETALLIC HYDROFORMYLATION CATALYSTS AND PROCESSES UTILIZING THESE CATALYSTS FOR CONDUCTING HYDROFORMYLATION REACTIONS.

Title (de)

HOMOGENE BIMETALLISCHE HYDROFORMYLIERUNGSKATALYSATOREN UND HYDROFORMYLIERUNGSVERFAHREN, WELCHE SOLCHE KATALYSATOREN GEBRAUCHEN.

Title (fr)

CATALYSEURS HOMOGENES BIMETALLIQUES D'HYDROFORMYLATION, ET PROCEDES UTILISANT CES CATALYSEURS POUR MENER DES REACTIONS D'HYDROFORMYLATION.

Publication

EP 0673381 A1 19950927 (EN)

Application

EP 94907166 A 19940107

Priority

  • US 9400262 W 19940107
  • US 2841593 A 19930309

Abstract (en)

[origin: WO9420510A1] Novel homogeneous bimetallic hydroformylation catalysts, and processes utilizing these catalysts to convert alkenes, particularly alpha olefins, under mild conditions to a product rich in aldehydes, particularly a product containing a high ratio of linear: branched chain aldehydes. The catalysts can be produced from a binucleating tetratertiaryphosphine ligand capable of strongly coordinating two metal centers and holding them in general proximity to one another. Bimetallic catalyst precursors are produced which, on reaction with carbon monoxide and hydrogen, forms the active bimetallic hydroformylation catalyst system. This invention also relates to asymmetric synthesis in which a prochiral or chiral compound is contacted in the presence of an optically pure metal-ligand complex catalyst, in enantiomeric form, to produce an optically active product.

IPC 1-7

C07F 15/00; C07C 45/50; C07C 27/04; C07C 29/14; C07C 29/143

IPC 8 full level

B01J 31/24 (2006.01); C07C 29/141 (2006.01); C07C 45/49 (2006.01); C07C 45/50 (2006.01); C07C 51/14 (2006.01); C07C 67/293 (2006.01); C07C 253/10 (2006.01); C07F 15/00 (2006.01)

CPC (source: EP)

B01J 31/1845 (2013.01); B01J 31/20 (2013.01); B01J 31/24 (2013.01); B01J 31/2409 (2013.01); C07C 29/14 (2013.01); C07C 29/141 (2013.01); C07C 45/505 (2013.01); C07C 51/36 (2013.01); C07C 67/293 (2013.01); C07C 253/10 (2013.01); C07F 15/008 (2013.01); B01J 2231/32 (2013.01); B01J 2231/321 (2013.01); B01J 2231/323 (2013.01); B01J 2231/325 (2013.01); B01J 2231/342 (2013.01); B01J 2231/44 (2013.01); B01J 2231/643 (2013.01); B01J 2231/645 (2013.01); B01J 2531/10 (2013.01); B01J 2531/80 (2013.01); B01J 2531/822 (2013.01); C07B 2200/07 (2013.01); C07C 2602/42 (2017.04); Y02P 20/582 (2015.11)

Designated contracting state (EPC)

AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

DOCDB simple family (publication)

WO 9420510 A1 19940915; AU 6084794 A 19940926; EP 0673381 A1 19950927; EP 0673381 A4 19970910

DOCDB simple family (application)

US 9400262 W 19940107; AU 6084794 A 19940107; EP 94907166 A 19940107