EP 0826792 B1 20000412 - Bath and process for phosphating metal substrates, concentrates for preparing the bath and metal substrates treated according to the process
Title (en)
Bath and process for phosphating metal substrates, concentrates for preparing the bath and metal substrates treated according to the process
Title (de)
Bad und Verfahren zum Phosphatieren von Metallgegenständen, Konzentrate zur Herstellung des Bades und Metallgegenstanden behandelt nach dem Verfahren
Title (fr)
Bain et procédé de phosphatation de substrats métalliques, concentré pour la préparation de ce bain et substrats métalliques traités à l'aide de ce procédé
Publication
Application
Priority
FR 9610684 A 19960902
Abstract (en)
[origin: EP0826792A1] A new composition for a phosphating bath for the treatment of metallic substrates based on steel, possibly coated with Zn or Zn alloyed with Fe, Ni, Al or Mn, or Al-based (possibly alloyed), at a pH of 1 - 5.5.The composition contains classical components comprising :- 0.3 - 25(preferably 0.5 - 10) g/l of Zn ions ; 5 - 50(preferably 8 - 30) g/l of phosphate ions ; and about 0.01 - 10(preferably 0.03 - 3) g/l of a trivalent Co complex represented by one or other of the formulae :- ÄCo(Ligand)nÜc (I) ÄCo(Ligand)nZpÜc (II) -n, p = 1 - 6, with(formula II) n+p ≤ 6 ; -c = charge on the complex, positive or negative according to the charge of the ligand and of Z ; -the Ligand is chosen from the ions of a group comprising NO2, CN, CO3 and SO3, a group comprising oxalate, acetate, citrate, gluconate, tartrate and acetylacetonate, and compounds of formula N (R1, R2, R3), in which R1, R2 and R3 are (independently) H, 1 - 6C alkyl, hydroxyalkyl, hydroxy, alkylamine, hydroxyalkylamine, carboxylic acids or aminocarboxylic acids and their salts ; and -Z is chosen from Cl, Br, F, I, OH, NO3, SCN, PO4, S2O3, MoO4, SeO4 and H2O, given that a given complex may comprise one or more ligands and one or more Z different from one another. Also claimed, is the phosphating process, a concentrate for the preparation of a phosphating bath, the use of the Co complex as an accelerator and metallic substrates treated by the process.
IPC 1-7
IPC 8 full level
C23C 22/10 (2006.01); C23C 22/12 (2006.01)
CPC (source: EP US)
C23C 22/10 (2013.01 - EP US); C23C 22/12 (2013.01 - EP US)
Designated contracting state (EPC)
AT BE CH DE ES FR GB IT LI NL PT SE
DOCDB simple family (publication)
EP 0826792 A1 19980304; EP 0826792 B1 20000412; AT E191754 T1 20000415; CA 2214398 A1 19980302; DE 69701659 D1 20000518; DE 69701659 T2 20010201; ES 2146069 T3 20000716; FR 2752851 A1 19980306; FR 2752851 B1 19981113; JP 3993280 B2 20071017; JP H10183365 A 19980714; PT 826792 E 20000929; US 6068709 A 20000530
DOCDB simple family (application)
EP 97402032 A 19970901; AT 97402032 T 19970901; CA 2214398 A 19970902; DE 69701659 T 19970901; ES 97402032 T 19970901; FR 9610684 A 19960902; JP 23686097 A 19970902; PT 97402032 T 19970901; US 92187797 A 19970902