EP 0975559 A1 20000202 - METHOD FOR CATALYTIC AND SELECTIVE OXIDATION OF AROMATIC COMPOUNDS
Title (en)
METHOD FOR CATALYTIC AND SELECTIVE OXIDATION OF AROMATIC COMPOUNDS
Title (de)
VERFAHREN ZUR KATALYTISCHEN UND SELEKTIVEN OXIDATION AROMATISCHER VERBINDUNGEN
Title (fr)
PROCEDE D'OXYDATION CATALYTIQUE ET SELECTIVE DE COMPOSES AROMATIQUES
Publication
Application
Priority
- DE 19717176 A 19970424
- EP 9801864 W 19980331
Abstract (en)
[origin: DE19717176A1] The invention relates to the use of compounds of formula (I): R<1>aRebOc. Ld as catalysts for the oxidation of aromatic compounds rich in electrons and of derivatives of such compounds, whereby the catalysts are used in a solution containing peroxide and in the presence of an anhydride, a carboxylic acid and/or a dehydrating agent. In said formula (I) a = 0 or an integer between 0 and 6, b = an integer between 1 and 4, c = an integer between 1 and 12, d = an integer between 0 and 4, and L = Lewis base. The sum of a, b and c is such that it ensures the pentavalence or heptavalence of the rhenium, provided that c is not greater than 3 . b. R<1> can either not be present, or represent the same group or represent a different group and is an aliphatic hydrocarbon rest having between 1 and 10 C-atoms, an aromatic hydrocarbon rest having between 6 and 10 C-atoms or an aryl alkyl rest having between 7 and 9 C-atoms, whereby said R<1> rests independently of each other may possibly be substituted identically or differently.
IPC 1-7
IPC 8 full level
C07B 33/00 (2006.01); C07C 37/60 (2006.01); C07C 41/26 (2006.01); C07C 46/04 (2006.01)
CPC (source: EP US)
C07B 33/00 (2013.01 - EP US); C07C 37/60 (2013.01 - EP US); C07C 41/26 (2013.01 - EP US); C07C 46/04 (2013.01 - EP US)
Citation (search report)
See references of WO 9847837A1
Designated contracting state (EPC)
AT BE CH DE ES FR GB IT LI LU NL PT SE
DOCDB simple family (publication)
DE 19717176 A1 19981029; AU 7213198 A 19981113; EP 0975559 A1 20000202; US 6365762 B1 20020402; WO 9847837 A1 19981029
DOCDB simple family (application)
DE 19717176 A 19970424; AU 7213198 A 19980331; EP 9801864 W 19980331; EP 98919195 A 19980331; US 40346100 A 20000314