EP 0998442 A1 20000510 - HYDROFORMYLATION WITH UNMODIFIED RHODIUM CATALYSTS IN SUPERCRITICAL CARBON DIOXIDE
Title (en)
HYDROFORMYLATION WITH UNMODIFIED RHODIUM CATALYSTS IN SUPERCRITICAL CARBON DIOXIDE
Title (de)
HYDROFORMYLIERUNG MIT UNMODIFIZIERTEN RHODIUMKATALYSATOREN IN ÜBERKRITISCHEM KOHLENDIOXID
Title (fr)
HYDROFORMYLATION AVEC DES CATALYSEURS DE RHODIUM NON MODIFIES DANS DU DIOXYDE DE CARBONE SURCRITIQUE
Publication
Application
Priority
- DE 19730783 A 19970718
- EP 9804319 W 19980711
Abstract (en)
[origin: DE19730783A1] The invention relates to a method for producing oxo products by hydroformylation of substrates with C=C double bonds, using unmodified rhodium catalysts in a reaction mixture consisting essentially of the substrates, the catalyst and carbon dioxide in a supercritical state (scCO2). The invention especially relates to methods of this kind for producing products containing substantial parts of branched i-oxo products. The invention further relates to methods of this kind for the hydroformylation of substrates not corresponding to the general formula C2H2n. The invention also relates to said methods in which the product and catalyst are separated using the special solubilizing properties of scCO2.
IPC 1-7
C07C 45/50; C07B 41/06; C07C 45/80; C07C 47/02; C07C 403/08; C07C 57/30
IPC 8 full level
B01J 23/46 (2006.01); B01J 31/16 (2006.01); B01J 31/20 (2006.01); B01J 31/22 (2006.01); C07B 41/06 (2006.01); C07B 61/00 (2006.01); C07C 45/50 (2006.01); C07C 45/80 (2006.01); C07C 47/02 (2006.01); C07C 47/52 (2006.01); C07C 51/265 (2006.01); C07C 57/30 (2006.01); C07C 63/00 (2006.01); C07C 67/29 (2006.01); C07C 67/293 (2006.01); C07C 67/343 (2006.01); C07C 67/38 (2006.01); C07C 69/12 (2006.01); C07C 69/716 (2006.01); C07C 403/08 (2006.01)
CPC (source: EP US)
B01J 31/20 (2013.01 - EP US); B01J 31/2226 (2013.01 - EP US); B01J 31/2234 (2013.01 - EP US); B01J 31/2282 (2013.01 - EP US); B01J 31/2295 (2013.01 - EP US); C07C 45/50 (2013.01 - EP US); C07C 67/293 (2013.01 - EP US); C07C 67/343 (2013.01 - EP US); C07C 403/14 (2013.01 - EP US); B01J 2231/321 (2013.01 - EP US); B01J 2531/0205 (2013.01 - EP US); B01J 2531/822 (2013.01 - EP US); B01J 2531/922 (2013.01 - EP US); C07C 2601/16 (2017.04 - EP US); Y02P 20/54 (2015.11 - EP US)
Citation (search report)
See references of WO 9903810A1
Designated contracting state (EPC)
AT BE CH DE DK ES FR GB IE IT LI LU NL SE
DOCDB simple family (publication)
DE 19730783 A1 19990121; CA 2297455 A1 19990128; EP 0998442 A1 20000510; JP 2001510176 A 20010731; US 6388141 B1 20020514; WO 9903810 A1 19990128
DOCDB simple family (application)
DE 19730783 A 19970718; CA 2297455 A 19980711; EP 9804319 W 19980711; EP 98942539 A 19980711; JP 2000503043 A 19980711; US 46285500 A 20000113