EP 1042377 A1 20001011 - SLURRY POLYMERIZATION PROCESS WITH ALKYL-SUBSTITUTED BISCYCLOPENTADIENYL METALLOCENES
Title (en)
SLURRY POLYMERIZATION PROCESS WITH ALKYL-SUBSTITUTED BISCYCLOPENTADIENYL METALLOCENES
Title (de)
VERFAHREN ZUR SUSPENSIONSPOLYMERISATION MIT ALKYLSUBSTITUIERTEN BISCYCLOPENTADIENLYMETALLOCENEN
Title (fr)
PROCEDE DE POLYMERISATION DE BOUES AVEC DES METALLOCENES DE BIS-CYCLOPENTADIENYLE A SUBSTITUTION ALKYLE
Publication
Application
Priority
- US 9827361 W 19981223
- US 6864097 P 19971223
Abstract (en)
[origin: WO9932531A1] The invention describes a slurry process for producing ethylene polymers and copolymers with high productivity capability that will be particularly suitable for industrial practice. This process relates to contacting ethylene, optionally with one or more copolymerizable monomers, under slurry conditions with a supported zirconium biscyclopentadienyl metallocene wherein at least one cyclopentadienyl group contains a hydrocarbyl or hydrocarbylsilyl group that is a C4-C20 branched-alkyl or -silylalkyl substituent with said branch occurring at the second or third atom removed from the cyclopentadienyl rings thereof. Examples of poly(ethylene-hexene) made with bis(isobutylcyclopentadienyl) zirconium dichloride and bis((trimethylsilylmethyl)cyclopentadienyl) zirconium dichloride are presented with suitable comparisons of similar catalysts.
IPC 1-7
IPC 8 full level
C08F 2/06 (2006.01); C08F 2/14 (2006.01); C08F 4/642 (2006.01); C08F 4/6592 (2006.01); C08F 10/00 (2006.01); C08F 10/02 (2006.01); C08F 4/659 (2006.01)
CPC (source: EP)
C08F 10/00 (2013.01); C08F 10/02 (2013.01); C08F 4/65908 (2013.01); C08F 4/65912 (2013.01); C08F 4/65916 (2013.01); C08F 4/65927 (2013.01); C08F 110/02 (2013.01)
Citation (search report)
See references of WO 9932531A1
Designated contracting state (EPC)
BE DE ES FR GB IT NL SE
DOCDB simple family (publication)
WO 9932531 A1 19990701; CA 2304491 A1 19990701; CA 2314502 A1 19990701; DE 69814920 D1 20030626; DE 69814920 T2 20031224; EP 1042376 A1 20001011; EP 1042376 B1 20030521; EP 1042377 A1 20001011; ES 2195443 T3 20031201; JP 2001527097 A 20011225; JP 2001527098 A 20011225; WO 9932530 A1 19990701
DOCDB simple family (application)
US 9827361 W 19981223; CA 2304491 A 19981223; CA 2314502 A 19981223; DE 69814920 T 19981223; EP 98964875 A 19981223; EP 98964876 A 19981223; ES 98964875 T 19981223; JP 2000525465 A 19981223; JP 2000525466 A 19981223; US 9827360 W 19981223