EP 1093479 A1 20010425 - POLYMERIC COMPOSITIONS FOR SOIL RELEASE ON FABRICS
Title (en)
POLYMERIC COMPOSITIONS FOR SOIL RELEASE ON FABRICS
Title (de)
POLYMERZUSAMMENSETZUNG ZUR SCHMUTZLÖSUNG IN GEWEBE
Title (fr)
Compositions de polymères antisalissures pour tissus
Publication
Application
Priority
- US 9913535 W 19990616
- US 8987198 P 19980619
- US 31226499 A 19990514
Abstract (en)
[origin: WO9965959A1] A copolymer composition and its use as a soil release agent for fabrics comprising monomers copolymerized in the following percentages by weight: (a) from about 30 % to about 49 % of at least one monomer of formula (I): Rf-Q-A-C(O)-C(R)=CH2, wherein Rf is a straight or branched-chain perfluoroalkyl group of from 2 to about 20 carbon atoms, R is H or CH3, A is O, S or N(R'), wherein R' is H or an alkyl from 1 to about 4 carbon atoms, Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 3 to about 15 carbon atoms, -(CnH2n)(OCqH2q)m-, -SO2-NR'(CnH2n)-, or -CONR'(CnH2n)-, wherein R' is H or an alkyl of from 1 to about 4 carbon atoms, n is 1 to about 15, q is 2 to about 4, and m is 1 to about 15; (b) from about 10 % to about 70 % of at least one monomer or a mixture of monomers selected from the formulae (IIA): (R1)2N-(CH2)r-Z-C(O)-C(R2)=CH2, (IIB): (O)(R3)(R4)N-(CH2)r-Z-C(O)-C(R2)=CH2, (IIC): X<->(R5)(R4)(R3)N<+>-(CH2)r-Z-C(O)-C(R2)=CH2, wherein Z is -O- or -NR5-; R1 is an alkyl group of from 1 to about 3 carbon atoms; R2 is H or an alkyl radical of 1 to about 4 carbon atoms; R3 and R4 are each an alkyl of 1 to 4 carbon atoms, hydroxyethyl, benzyl, or R3 and R4 together with the nitrogen atom form a morpholine, pyrrolidine, or piperadine ring; R5 is H or an alkyl of 1 to 4 carbon atoms, or R3, R4 and R5 together with the nitrogen atom form a pyridine ring; r is 2 to 4; and wherein for formula (IIA) the nitrogen is from about 40 % to 100 % salinized; and (c) eventually other monomers.
IPC 1-7
C08F 220/24; C08F 220/34; C08L 33/14; C08L 33/16; D06M 15/277; D06M 15/263; D06M 15/273; D06M 15/267
IPC 8 full level
C08F 220/24 (2006.01); C08F 220/34 (2006.01); C08L 33/16 (2006.01); D06M 15/263 (2006.01); D06M 15/267 (2006.01); D06M 15/273 (2006.01); D06M 15/277 (2006.01)
CPC (source: EP KR US)
C08F 214/08 (2013.01 - KR); C08F 220/24 (2013.01 - EP KR US); C08F 220/325 (2020.02 - KR); C08F 220/34 (2013.01 - EP KR US); C08F 220/382 (2020.02 - KR); C08F 220/56 (2013.01 - KR); C08L 33/16 (2013.01 - EP US); D06M 15/263 (2013.01 - EP US); D06M 15/267 (2013.01 - EP KR US); D06M 15/273 (2013.01 - EP KR US); D06M 15/277 (2013.01 - EP KR US)
Citation (search report)
See references of WO 9965959A1
Designated contracting state (EPC)
BE CH DE FR GB IT LI NL
DOCDB simple family (publication)
WO 9965959 A1 19991223; AU 4569099 A 20000105; BR 9911848 A 20010403; CA 2330051 A1 19991223; CN 1130400 C 20031210; CN 1309673 A 20010822; DE 69932931 D1 20061005; DE 69932931 T2 20070510; EP 1093479 A1 20010425; EP 1093479 B1 20060823; ID 27010 A 20010222; KR 100577672 B1 20060510; KR 20010052977 A 20010625; TW 466259 B 20011201; US 2002052457 A1 20020502; US 6326447 B1 20011204; US 6478981 B2 20021112
DOCDB simple family (application)
US 9913535 W 19990616; AU 4569099 A 19990616; BR 9911848 A 19990616; CA 2330051 A 19990616; CN 99807526 A 19990616; DE 69932931 T 19990616; EP 99928687 A 19990616; ID 20002645 A 19990616; KR 20007014369 A 20001218; TW 88110229 A 19990707; US 31226499 A 19990514; US 97090701 A 20011004