EP 1187801 A4 20020918 - A METHOD OF PREPARING CYCLOHEXANECARABOXYLIC ACID USING [2+4] DIELS-ALDER REACTION
Title (en)
A METHOD OF PREPARING CYCLOHEXANECARABOXYLIC ACID USING [2+4] DIELS-ALDER REACTION
Title (de)
VERFAHREN ZUR HERSTELLUNG VON CYCLOHEXANCARBONSÄURE MIT HILFE DER [2+4]-DIELS-ALDER-REAKTION
Title (fr)
PROCEDE DE PREPARATION D'ACIDE CYCLOHEXANECARBOXYLIQUE FAISANT APPEL A UNE REACTION [2+4] DIELS-ALDER
Publication
Application
Priority
- KR 9900739 W 19991204
- KR 19990004025 A 19990205
- KR 19990037508 A 19990903
Abstract (en)
[origin: WO0046174A1] Disclosed herein is a method of preparing cyclohexanecarboxylic acid in which 1,3-butadiene and acrylic acid are subjected to [2+4] Diels-Alder reaction to produce 3-cyclohexene-1-carboxylic acid which is then hydrogenated. The [2+4] Diels-Alder reaction is carried out at a temperature of room temperature to 200 DEG C in an aromatic hydrocarbon solvent, such as toluene or xylene. The hydrogenation is carried out at a temperature of room temperature to 150 DEG C under a hydrogen pressure of 10 psi to 150 psi in the presence of the platinum of palladium catalyst. The disclosed method is featured in that it enables the use of 1,3-butadiene as the raw material for fine chemicals, unlike the prior methods. Moreover, the method disclosed is advantageous in that the reaction can be carried out in a relatively simple and easy manner and also the reaction by-products can be conveniently treated after the reaction.
IPC 1-7
IPC 8 full level
C07B 61/00 (2006.01); C07C 51/00 (2006.01); C07C 51/353 (2006.01); C07C 51/36 (2006.01); C07C 61/08 (2006.01)
CPC (source: EP KR)
C07C 51/00 (2013.01 - KR); C07C 51/353 (2013.01 - EP); C07C 51/36 (2013.01 - EP)
C-Set (source: EP)
Citation (search report)
No further relevant documents disclosed
Designated contracting state (EPC)
AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE
DOCDB simple family (publication)
WO 0046174 A1 20000810; AU 1513800 A 20000825; BR 9917235 A 20011127; CA 2361682 A1 20000810; CN 1348437 A 20020508; EP 1187801 A1 20020320; EP 1187801 A4 20020918; HU P0200112 A2 20020529; HU P0200112 A3 20030228; JP 2002539083 A 20021119; KR 20000056975 A 20000915; PL 350029 A1 20021021
DOCDB simple family (application)
KR 9900739 W 19991204; AU 1513800 A 19991204; BR 9917235 A 19991004; CA 2361682 A 19991204; CN 99816019 A 19991204; EP 99957434 A 19991204; HU P0200112 A 19991204; JP 2000597247 A 19991204; KR 19990037508 A 19990903; PL 35002999 A 19991204