EP 1297034 A2 20030402 - HEAT-SENSITIVE WATER SOLUBLE COPOLYMERS BASED ON (POLY)ETHOXYLATED (METH)ACRYLATE, METHOD FOR MAKING SAME AND USE FOR PREPARING ADHESIVE FILMS AND BINDERS FOR TEXTILE WEBS
Title (en)
HEAT-SENSITIVE WATER SOLUBLE COPOLYMERS BASED ON (POLY)ETHOXYLATED (METH)ACRYLATE, METHOD FOR MAKING SAME AND USE FOR PREPARING ADHESIVE FILMS AND BINDERS FOR TEXTILE WEBS
Title (de)
WASSERLÖSLICHE COPOLYMERISATE AUS POLYETHYLENOXID METHACRYLATEN, IHRE HERSTELLUNG UND IHRE VERWENDUNG ZUR HERSTELLUNG VON FOLIEN
Title (fr)
COPOLYMERES HYDROSOLUBLES THERMOSENSIBLES A BASE DE (METH)ACRYLATE (POLY)ETHOXYLE, LEUR FABRICATION ET LEUR UTILISATION POUR LA PREPARATION DE FILMS, ADHESIFS ET LIANTS POUR NAPPES FIBREUSES
Publication
Application
Priority
- FR 0102015 W 20010626
- FR 0008229 A 20000627
Abstract (en)
[origin: FR2810669A1] A copolymer of thermosensitive solubility comprising hydrophobic units obtained from a specified monomer composition The polymer has a LCST of 6-95 deg C and the monomer composition comprises (all hydrosoluble): (A) a compound of formula (I) or (II) (10-69 pts.mol.); (B) an ethylenically unsaturated sulfonic acid (30-75 pts.mol.); (C) a compound of formula (III) or (IV) (0-50 pts.mol.) (D) a compound of formula (V) or (VI) (0-30 pts.mol.); (E) compounds of formula (VII) or (VIII) or ethylenically unsaturated monomers which are sulfonated, silanated or phosphonated or have phosphate groups, or monomers having N-vinyl groups, or compounds of formula (IX), acrylonitrile, allyl alcohol, vinylpyridine, N-(meth)acryloyltris(hydroxymethyl) methylamine, 2-sulfoethyl (meth)acrylate, 2-(acetoacetoxy)ethyl (meth)acrylate (0-30 pts.mol.); and (F) at least one hydrophobic monomer (0.001-50 pts.mol.). Independent claims are also included for: (1) preparation by radical polymerization in an aqueous or organic or mixed solvent medium; (2) a mixture in aqueous medium of one or more of the claimed polymers with a hydrophobic (co)polymer; (3) use of the claimed polymers for the fabrication of hydrodispersible or hydrodisintegrable films, especially those forming part of hydrodisintegrable hygiene articles, for such films; and (4) use of the polymers as binders for fiber tissues or as components of adhesives, especially those forming part of hydrodisintegrable hygiene articles and for hygiene articles, especially disposable comprising in any form the claimed copolymer or a mixture with at least 50 wt.% of hydrophobic polymer. CH2=C(R<1>)-C(O)-O-(R<2>-O)n-R<3> (I) H-C(R<4>)=C(R<5>)-Y<1>-O-(R<6>-O)o-R<7> (II) CH2-C(R<8>)-C(O)-O-(R<9>-O)p-(R<10>-O)q-R<11> (III) H-C(R<12>)=C(R<13>-Y<2>-O-(R<14>-O)r-(R<15>-O)S-R16 (IV) CH2=C(R<17>)-C(O)-O-(R<18>-O)t-R<19> (V) H-C(R<20>)=C(R<21>)-Y<3>-O-(R<22>-O)u-R<23> (VI) CH2=C(R<24>)C(O)A<1>B<1>N<+>(R<27>)(R<25>)(R<26>)X<-> (VII) CH2=C(R<28>)-C(O)-A<2>B<2>N(R<29>)(R<30>) (VIII) CH2=C(R<31>)-C(O)-N(R<32>)(R<33>) (IX) R<1>, R<3>, R<7>, R<8>, R<11>, R<16>, R<17>, R<24>, R<28>, R<31> = H or CH3; R<2>, R<6>, R<9>, R<10>, R<14>, R<15>, R<18>, R<22> = 2-4C alkylene optionally bearing one or more OH groups; n, o, p, r, t, u = integer 1-70; R<4>, R<5>, R<12>, R<13>, R<20>, R<21> = H or 2-4C alkyl; Y<1>, Y<2>, Y<3> = null or 1-4C alkyl; q, s = integer 1-40; R<19>, R<23> = 2-40C alkyl chain, 6-60C aryl or aralkyl; A<1>, A<2> = -O- or -NH-; B<1>, B<2> = -CH2CH2-, - CH2CH2CH2-, CH2CHOHCH2-; R<27> = H, CH3 or 2-16C alkyl chain; X<+> = monovalent anion; R<29>, R<30> = CH3 or 2-16C alkyl chain; and R<32>, R<33> = H, 1-5C alkyl optionally bearing one or more OH groups, alkoxy(1-5C)alkyl(1-5C).
IPC 1-7
IPC 8 full level
A61F 13/53 (2006.01); A61F 13/15 (2006.01); A61F 13/472 (2006.01); A61F 13/49 (2006.01); A61F 13/514 (2006.01); A61F 13/551 (2006.01); A61L 15/62 (2006.01); C08F 4/00 (2006.01); C08F 220/28 (2006.01); C08F 220/58 (2006.01); C08F 290/06 (2006.01)
CPC (source: EP KR US)
A61L 15/62 (2013.01 - EP KR US); C08F 220/282 (2020.02 - KR); C08F 220/286 (2020.02 - EP KR US); C08F 220/288 (2020.02 - KR); C08F 220/34 (2013.01 - KR); C08F 220/58 (2013.01 - KR); C08F 220/585 (2020.02 - EP US); C08F 220/60 (2013.01 - KR)
Citation (search report)
See references of WO 0200743A2
Designated contracting state (EPC)
AT BE CH CY DE ES FR GB LI
DOCDB simple family (publication)
FR 2810669 A1 20011228; FR 2810669 B1 20020830; AU 7066201 A 20020108; CN 1449415 A 20031015; EP 1297034 A2 20030402; JP 2004501993 A 20040122; KR 20030014284 A 20030215; US 2003220459 A1 20031127; WO 0200743 A2 20020103; WO 0200743 A3 20020314
DOCDB simple family (application)
FR 0008229 A 20000627; AU 7066201 A 20010626; CN 01814819 A 20010626; EP 01949527 A 20010626; FR 0102015 W 20010626; JP 2002505865 A 20010626; KR 20027017884 A 20021227; US 31186203 A 20030321