EP 1404444 A2 20040407 - METHOD FOR THE PRODUCTION OF CYCLOALIPHATIC COMPOUNDS (1) HAVING SIDE CHAINS WITH EPOXY GROUPS
Title (en)
METHOD FOR THE PRODUCTION OF CYCLOALIPHATIC COMPOUNDS (1) HAVING SIDE CHAINS WITH EPOXY GROUPS
Title (de)
VERFAHREN ZUR HERSTELLUNG VON CYCLOALIPHATISCHEN VERBINDUNGEN, DIE SEITENKETTEN MIT EPOXIDGRUPPEN AUFWEISEN, DURCH HYDRIERUNG AN RU/SIO2 KATALYSATOREN
Title (fr)
PROCEDE DE FABRICATION DE COMPOSES CYCLOALIPHATIQUES (I) PRESENTANT DES CHAINES LATERALES COMPORTANT DES GROUPES EPOXY
Publication
Application
Priority
- DE 10128204 A 20010611
- EP 0206348 W 20020610
Abstract (en)
[origin: DE10128204A1] A method for the production of cycloaliphatic compounds (I) having side chains with expoxy groups by heterogenous-catalytic hydrogenation of a compound (II) having at least one carbocyclic, aromatic group and at least one side chain with at least one epoxy group, on a ruthenium catalyst, characterized in that the ruthenium catalyst is obtained by i) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200 DEG C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350 DEG C, wherein step ii) is carried out directly after step i).
[origin: DE10128204A1] Production of cycloaliphatic compounds that have side chains containing epoxy groups is claimed. A process for the production of cycloaliphatic compounds (I) that have side chains containing epoxy groups comprises heterogeneously catalyzed hydrogenation of a compound (II), having at least one carbocyclic aromatic group and at least one side chain having at least one epoxy group, at a ruthenium catalyst whereby the catalyst is prepared by: (A) a single or multiple treatment of an amorphous silicon dioxide support material with a halogen free solution of a low mol. wt. ruthenium compound followed by drying at below 200 deg C; (B) reduction of the resulting solid with hydrogen at 100-350 deg C such that step (B) is carried out immediately after step (A).
IPC 1-7
IPC 8 full level
B01J 23/46 (2006.01); B01J 37/18 (2006.01); C07B 61/00 (2006.01); C07D 303/30 (2006.01); C08G 59/14 (2006.01); C08G 59/24 (2006.01); B01J 21/08 (2006.01)
CPC (source: EP KR US)
B01J 23/462 (2013.01 - EP US); B01J 37/18 (2013.01 - EP US); C07D 303/28 (2013.01 - KR); C07D 303/30 (2013.01 - EP US); C08G 59/1405 (2013.01 - EP US); C08G 59/24 (2013.01 - EP US); B01J 21/08 (2013.01 - EP US)
Citation (search report)
See references of WO 02100538A2
Designated contracting state (EPC)
AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR
DOCDB simple family (publication)
DE 10128204 A1 20021212; AU 2002325235 A1 20021223; AU 2002325235 A8 20051013; CN 1239488 C 20060201; CN 1535175 A 20041006; EP 1404444 A2 20040407; JP 2004529200 A 20040924; KR 20040030664 A 20040409; US 2004176549 A1 20040909; WO 02100538 A2 20021219; WO 02100538 A3 20030327; WO 02100538 A8 20031120
DOCDB simple family (application)
DE 10128204 A 20010611; AU 2002325235 A 20020610; CN 02813277 A 20020610; EP 0206348 W 20020610; EP 02758224 A 20020610; JP 2003503350 A 20020610; KR 20037016145 A 20031210; US 48023903 A 20031210