EP 1438575 A4 20090513 - SYSTEM AND METHOD FOR DETERMINING RADIUS OF GYRATION, MOLECULAR WEIGHT, AND INTRINSIC VISCOSITY OF A POLYMERIC DISTRIBUTION USING GEL PERMEATION CHROMATOGRAPHY AND LIGHT-SCATTERING DETECTION
Title (en)
SYSTEM AND METHOD FOR DETERMINING RADIUS OF GYRATION, MOLECULAR WEIGHT, AND INTRINSIC VISCOSITY OF A POLYMERIC DISTRIBUTION USING GEL PERMEATION CHROMATOGRAPHY AND LIGHT-SCATTERING DETECTION
Title (de)
SYSTEM UND VERFAHREN ZUR BESTIMMUNG DES GYRATIONSRADIUS, DES MOLEKULARGEWICHTS UND DER INTRINSISCHEN VISKOSITÄT EINER POLYMERVERTEILUNG UNTER VERWENDUNG VON GELPERMEATIONSCHROMATOGRAPHIE UND LICHTSTREUUNGSNACHWEIS
Title (fr)
SYSTEME ET PROCEDE PERMETTANT DE DETERMINER LE RAYON DE GIRATION, LA MASSE MOLECULAIRE ET LA VISCOSITE INTRINSEQUE D'UNE DISTRIBUTION DE POLYMERE, AU MOYEN DE LA CHROMATOGRAPHIE D'EXCLUSION DIFFUSION ET DE LA DETECTION A DIFFUSION DE LUMIERE
Publication
Application
Priority
- US 0233945 W 20021023
- US 33525401 P 20011023
Abstract (en)
[origin: WO03036258A2] A system and method for analyzing data from a gel permeation chromatography (GPC) or size exclusion chromatography (SEC) system for determining a polymeric sample's radius of gyration. Data from two or more detectors (18) is used with a least-squares minimization fit (20). A novel method includes the simultaneous determination of a sample's radius of gyration using data from a light scattering detector that collects data from at least two incident angles. Detectors within the inventive method include a multi-angle light scattering (LS) detector, viscometer (V) and a refractive index (RI) detector.
IPC 1-7
IPC 8 full level
G01N 30/88 (2006.01); G01N 15/02 (2006.01); G01N 30/42 (2006.01); G01N 30/62 (2006.01); G01N 30/74 (2006.01); G01N 30/78 (2006.01); G01N 30/86 (2006.01); G01N 11/00 (2006.01); G01N 30/02 (2006.01); G01N 33/44 (2006.01)
CPC (source: EP)
G01N 15/0205 (2013.01); G01N 30/8693 (2013.01); G01N 30/88 (2013.01); G01N 30/02 (2013.01); G01N 30/78 (2013.01); G01N 30/8651 (2013.01); G01N 33/442 (2013.01); G01N 2011/0026 (2013.01); G01N 2030/885 (2013.01)
Citation (search report)
- [XY] US 6265226 B1 20010724 - PETRO MIROSLAV [US], et al
- [DXAY] WO 9942489 A2 19990826 - WATERS INVESTMENTS LTD [US], et al
- [XY] LAGUNA M. T. R., MEDRANO R., PLANA M. P. AND M. P. TARAZONA: "Polymer characterization by size-exclusion chromatography with multiple detection", JOURNAL OF CHROMATOGRAPHY A, vol. 919, no. 1, 1 June 2001 (2001-06-01), pages 13 - 19, XP002520892
- [XY] BURDALO J., MEDRANO R., SAIZ E. AND M. P. TARAZONA: "A simple method to determine unperturbed dimensions of polymers using size exclusion chromatography and multiangle light scattering", POLYMER, vol. 41, no. 4, February 2000 (2000-02-01), pages 1615 - 1620, XP002520893
- [XA] BRUN Y ET AL: "New approach to model fitting in multi-detector GPC", JOURNAL OF LIQUID CHROMATOGRAPHY AND RELATED TECHNOLOGIES, MONTICELLO, NY, US, vol. 23, no. 17, 1 January 2000 (2000-01-01), pages 2615 - 2639, XP009114353, ISSN: 1082-6076
- [A] P. J. WYATT: "Light scattering and the absolute characterization of macromolecules", ANALYTICA CHIMICA ACTA, vol. 272, no. 1, 1 February 1993 (1993-02-01), Amsterdam, pages 1 - 40, XP002520894
- See references of WO 03036258A2
Designated contracting state (EPC)
DE FR GB
DOCDB simple family (publication)
WO 03036258 A2 20030501; WO 03036258 A3 20030605; AU 2002348395 A1 20030506; EP 1438575 A2 20040721; EP 1438575 A4 20090513; JP 2005507077 A 20050310
DOCDB simple family (application)
US 0233945 W 20021023; AU 2002348395 A 20021023; EP 02782217 A 20021023; JP 2003538708 A 20021023