EP 1622967 A1 20060208 - METHOD FOR THE PRODUCTION OF POWDER-TYPE ETHYLENE VINYL ALCOHOL MIXED POLYMERS
Title (en)
METHOD FOR THE PRODUCTION OF POWDER-TYPE ETHYLENE VINYL ALCOHOL MIXED POLYMERS
Title (de)
VERFAHREN ZUR HERSTELLUNG VON PULVERFÖRMIGEN ETHYLEN-VINYLAL KOHOL-MISCHPOLYMERISATEN
Title (fr)
PROCEDE POUR PRODUIRE DES COPOLYMERES PULVERULENTS D'ETHYLENE ET D'ALCOOL VINYLIQUE
Publication
Application
Priority
- EP 2004004564 W 20040429
- DE 10321942 A 20030515
Abstract (en)
[origin: WO2004101655A1] The invention relates to a method for the production of powder-type ethylene vinyl alcohol mixed polymers by radical polymerisation of ethylene and one or several vinyl esters, and optionally other monomers which can be copolymerised therewith, subsequently saponification of the thus obtained ethylene vinyl ester polymer mixture in order to form ethylene vinyl alcohol mixed polymers. The invention is characterised in that the ethylene vinyl alcohol mixed polymer is precipitated, after saponification, from the alcoholic solution by cooling according to a temperature gradient, and optionally, by the addition of water. In ethylene vinyl alcohol mixed polymers which are derived from low molecular ethylene vinyl ester mixed polymers, the average molecular weight Mw varies between 2000 - 100000 g/mol and the temperature gradient is between -0.1 DEG C/min to -10 DEG C/min. In ethylene vinyl alcohol mixed polymers which are derived from high molecular ethylene vinyl ester mixed polymers, the average molecular weight Mw is > 100000 g/mol and the temperature gradient is between -0.1 DEG C/min to -1 DEG C/min.
IPC 1-7
IPC 8 full level
CPC (source: EP US)
C08F 8/12 (2013.01 - EP US); C08J 3/14 (2013.01 - EP US); C08F 2800/10 (2013.01 - EP US); C08F 2810/50 (2013.01 - EP US); C08J 2329/04 (2013.01 - EP US)
C-Set (source: EP US)
Citation (search report)
See references of WO 2004101655A1
Designated contracting state (EPC)
AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR
DOCDB simple family (publication)
WO 2004101655 A1 20041125; CN 1832983 A 20060913; DE 10321942 A1 20041209; EP 1622967 A1 20060208; JP 2006526050 A 20061116; US 2006258803 A1 20061116
DOCDB simple family (application)
EP 2004004564 W 20040429; CN 200480013254 A 20040429; DE 10321942 A 20030515; EP 04730227 A 20040429; JP 2006508157 A 20040429; US 55600005 A 20051108