EP 1673324 A1 20060628 - PROCESS FOR THE PREPARATION OF 1,1,1,3,3,3-HEXAFLUOROPROPANE AND AT LEAST ONE OF 1,1,1,2,3,3-HEXAFLUOROPROPANE AND 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE
Title (en)
PROCESS FOR THE PREPARATION OF 1,1,1,3,3,3-HEXAFLUOROPROPANE AND AT LEAST ONE OF 1,1,1,2,3,3-HEXAFLUOROPROPANE AND 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE
Title (de)
VERFAHREN ZUR HERSTELLUNG VON 1,1,1,3,3,3-HEXAFLUORPROPAN UND WENIGSTENS EINER VERBINDUNG AUSGEWÄHLT AUS 1,1,1,2,3,3-HEXAFLUORPROPAN UND 1,1,1,2,3,3,3-HEPTAFLUORPROPAN
Title (fr)
PROCEDE POUR PREPARER DU 1,1,1,3,3,3-HEXAFLUOROPROPANE, DU 1,1,1,2,3,3-HEXAFLUOROPROPANE ET/OU DU 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE
Publication
Application
Priority
- US 2004034447 W 20041013
- US 51135503 P 20031014
Abstract (en)
[origin: WO2005037742A1] A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and at least one 1,1,1,2,3,3-hexafluoropropane (HFC-236ea) and 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea). The process involves (a) reacting HF, Cl2, and at least one halopropene of the formula CX3CCl=CX2 (where each X is independently F or Cl) to produce a product including both CF3CCl2CF3 and CF3CClFCClF2; (b) reacting CF3CCl2CF3 and CF3CClFCClF2 produced in (a) with hydrogen to produce a product comprising CF3CH2CF3 and at least one compound selected from the group consisting of CHF2CHFCF3, and CF3CHFCF3; and (c) recovering from the product produced in (b), CF3CH2CF3 and at least one compound selected from the group consisting of CHF2CHFCF3 and CF3CHFCF3. In (a), the CF3CCl2CF3 and CF3CClFCClF2 are produced in the presence of a chlorofluorination catalyst including a ZnCr2O4/crystalline alpha-chromium oxide composition, a ZnCr2O4/crystalline alpha-chromium oxide composition which has been treated with a fluorinating agent, a zinc halide/alpha-chromium oxide composition and/or a zinc halide/alpha-chromium oxide composition which has been treated with a fluorinating agent.
IPC 1-7
IPC 8 full level
B01J 23/00 (2006.01); B01J 23/26 (2006.01); B01J 27/12 (2006.01); B01J 37/26 (2006.01); C07C 17/04 (2006.01); C07C 17/21 (2006.01); C07C 17/23 (2006.01); C07C 19/08 (2006.01)
CPC (source: EP KR US)
B01J 23/002 (2013.01 - EP US); B01J 23/26 (2013.01 - EP US); B01J 27/12 (2013.01 - EP US); B01J 37/26 (2013.01 - EP US); C07C 17/04 (2013.01 - KR); C07C 17/21 (2013.01 - EP KR US); C07C 17/23 (2013.01 - EP KR US); C07C 19/08 (2013.01 - EP KR US); B01J 2523/00 (2013.01 - EP US)
C-Set (source: EP US)
Citation (search report)
See references of WO 2005037742A1
Designated contracting state (EPC)
AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR
DOCDB simple family (publication)
WO 2005037742 A1 20050428; AU 2004281279 A1 20050428; CA 2539933 A1 20050428; CN 100393679 C 20080611; CN 1867530 A 20061122; EP 1673324 A1 20060628; HK 1099273 A1 20070810; JP 2007508375 A 20070405; KR 101125343 B1 20120327; KR 20060132821 A 20061222; US 2006258890 A1 20061116; US 7285691 B2 20071023
DOCDB simple family (application)
US 2004034447 W 20041013; AU 2004281279 A 20041013; CA 2539933 A 20041013; CN 200480030357 A 20041013; EP 04795589 A 20041013; HK 07105340 A 20070521; JP 2006535419 A 20041013; KR 20067007079 A 20041013; US 57262506 A 20060317