EP 2222726 B1 20170607 - USE OF A ZIEGLER-NATTA PROCATALYST CONTAINING A TRANSESTERIFICATION PRODUCT OF A LOWER ALCOHOL AND A PHTHALIC ESTER FOR THE PRODUCTION OF REACTOR GRADE THERMOPLASTIC POLYOLEFINS WITH IMPROVED PAINTABILITY
Title (en)
USE OF A ZIEGLER-NATTA PROCATALYST CONTAINING A TRANSESTERIFICATION PRODUCT OF A LOWER ALCOHOL AND A PHTHALIC ESTER FOR THE PRODUCTION OF REACTOR GRADE THERMOPLASTIC POLYOLEFINS WITH IMPROVED PAINTABILITY
Title (de)
VERWENDUNG EINES EIN UMESTERUNGSPRODUKT EINES NIEDEREN ALKOHOLS UND EINES PHTHALSÄUREESTERS ENTHALTENDEN ZIEGLER-NATTA-PROKATALYSATORS ZUR HERSTELLUNG VON THERMOPLASTISCHEN POLYOLEFINEN VON REAKTORQUALITÄT MIT VERBESSERTER ANSTREICHBARKEIT
Title (fr)
UTILISATION D'UN PROCATALYSEUR DE ZIEGLER-NATTA CONTENANT UN PRODUIT DE TRANSESTÉRIFICATION D'UN ALCOOL INFÉRIEUR ET D'UN ESTER PHTALIQUE POUR LA FABRICATION DE POLYOLÉFINES THERMOPLASTIQUES DE GRADE RÉACTEUR AYANT UNE PEIGNABILITÉ AMÉLIORÉE
Publication
Application
Priority
- EP 2008066088 W 20081124
- EP 07122450 A 20071206
- EP 08858103 A 20081124
Abstract (en)
[origin: EP2067794A1] Use of a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester for the production of reactor grade thermoplastic polyolefins with improved paintability, characterized in that the procatalyst used has been prepared by a) reacting a spray crystallized or emulsion solidified adduct of MgCl 2 and a C 1 -C 2 alcohol with TiCl 4 b) reacting the product of stage a) with a dialkylphthalate of formula (I) wherein R 1 ' and R 2 ' are independently at least a C 5 alkyl under conditions where a transesterification between said C 1 to C 2 alcohol and said dialkylphthalate of formula (I) takes place to form the internal donor c) washing the product of stage b) or d) optionally reacting the product of step c) with TiCl 4 ., as well as reactor grade thermoplastic polyolefins prepared by using the above described Ziegler-Natta procatalyst, use of these reactor grade thermoplastic polyolefins, molded articles produced from them and a method to improve paintability and/or surface quality of reactor grade thermoplastic polyolefin resin articles.
IPC 8 full level
C08F 4/651 (2006.01); C08F 10/06 (2006.01)
CPC (source: EP)
C08F 10/06 (2013.01); C08F 210/16 (2013.01)
Citation (examination)
- US 6107404 A 20000822 - RYNTZ ROSE ANN [US]
- US 6686433 B1 20040203 - MIRO NEMESIO DELGADO [US], et al
Designated contracting state (EPC)
AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR
DOCDB simple family (publication)
EP 2067794 A1 20090610; BR PI0820682 A2 20150616; CN 101889033 A 20101117; EP 2222726 A1 20100901; EP 2222726 B1 20170607; WO 2009071461 A1 20090611
DOCDB simple family (application)
EP 07122450 A 20071206; BR PI0820682 A 20081124; CN 200880120040 A 20081124; EP 08858103 A 20081124; EP 2008066088 W 20081124