EP 2333031 A1 20110615 - Process to produce high quality kerosine and diesel fuels and hydrogen coproduction from light saturated fractions
Title (en)
Process to produce high quality kerosine and diesel fuels and hydrogen coproduction from light saturated fractions
Title (de)
Verfahren zur Herstellung von Kerosin- und Dieselkraftstoffen sowie zur gleichzeitigen Herstellung von Wasserstoff aus gesättigten leichten Fraktionen
Title (fr)
Procédé de production de carburants kérosène et diesel de haute qualité et de coproduction d'hydrogène à partir de coupes saturées légères
Publication
Application
Priority
FR 0905465 A 20091113
Abstract (en)
Producing kerosene and diesel fuel and co-production of hydrogen from a light saturated charge (F1) having (a) light naphtha cut (NL), and (b) 3C/4C (LPG) cut, comprises: dehydrogenation (2) of the charge using a dehydrogenation catalyst having e.g. a noble metal group VIII e.g. platinum, to obtain olefinic effluent (F2); oligomerization (3) of all/part of the effluent in an oligomerization unit using oligomerization catalyst e.g. ion exchange resins, to obtain an effluent (F4); and entirely/partly hydrogenating (4) the effluent (F3) in liquid phase in one or more fixed bed reactors. Producing kerosene and diesel fuel and co-production of hydrogen from light saturated charge (F1) of a carbon number of 3-7C comprising (a) light naphtha cut (NL) having number of carbon atoms of 5-7 obtained from primary distillation units, hydrocracking unit or Fischer Tropsch unit, from interval of distillation of 30-120[deg] C, where the light naphtha cut is previously hydrotreated to be freed from oxygen nitrogen and sulfur compound, and (b) 3C/4C (LPG) cut in any proportion, freed from oxygenated and sulfur compound, comprises: dehydrogenation (2) of the charge operating at pressure of 1.3-5 absolute bars and at a temperature of 400-700[deg] C, preferably 500-600[deg] C, using a dehydrogenation catalyst consisting of a noble metal group VIII comprising platinum, iridium or rhodium, and at least one promoter comprising tin, germanium, lead, gallium, indium, and thallium, where the noble metal and the promoter is deposited on an inert support comprising silica, alumina, titania oxide, and/or magnesia silica and the dehydrogenation step to recover an effluent (F2) mainly comprises olefins having number of carbon atoms of 3-7, called olefinic effluent (F2); oligomerization (3) of all or part of the obtained olefin effluent (F2) in an oligomerization unit using oligomerization catalyst comprising solid phosphoric acid, ion exchange resins, alumina silica or silico aluminates such as pure zeolites or supported on alumina, where the oligomerization for recovering an effluent (F3) mainly comprises olefins of 10-25C, and an effluent essence (F4) mainly comprises paraffins of 5-10C which is separated from the effluent (F3) by distillation and recycled at the inlet of the oligomerization unit; and entirely or partly hydrogenating (4) the obtained olefinic effluent (F3) carried out in liquid phase in one or more fixed bed reactors, at temperatures of 50-350[deg] C, preferably 100-200[deg] C and under pressures of 5-50 bars, preferably 10-30 bars, and using a hydrogenation catalyst containing a metal comprising platinum, palladium or nickel, deposited on an inert support such as silica and/or alumina, where the hydrogenation step for recovering an effluent (F6) is a kerosene or diesel cut mainly paraffinic.
Abstract (fr)
Procédé de production majoritaire de carburants kérosène et diesel de haute qualité et de coproduction d'hydrogène à partir d'une coupe dite naphta léger à laquelle on peut ajouter une quantité quelconque de coupe LPG, faisant appel à l'enchaînement d'étapes suivant : déshydrogénation des paraffines, oligomerisation des oléfines et hydrogénation des oléfines oligomérisées, ledit procédé permettant la production de carburants kérosène et diesel aux spécifications du marché, voire améliorées par rapport à ces dernières.
IPC 8 full level
C10G 69/12 (2006.01); C07C 2/08 (2006.01); C10G 35/09 (2006.01); C10G 50/00 (2006.01); C10L 1/06 (2006.01); C10L 1/08 (2006.01)
CPC (source: EP US)
C10G 35/09 (2013.01 - EP US); C10G 50/00 (2013.01 - EP US); C10G 69/126 (2013.01 - EP US); C10G 2300/1022 (2013.01 - EP US); C10G 2300/1044 (2013.01 - EP US); C10G 2300/202 (2013.01 - EP US); C10G 2300/301 (2013.01 - EP US); C10G 2300/4006 (2013.01 - EP US); C10G 2300/4012 (2013.01 - EP US); C10G 2400/04 (2013.01 - EP US); C10G 2400/08 (2013.01 - EP US)
Citation (applicant)
- GB 2186287 A 19870812 - INST FRANCAIS DU PETROLE
- US 2003073875 A1 20030417 - RYU J YONG [US], et al
Citation (search report)
- [A] GB 2186287 A 19870812 - INST FRANCAIS DU PETROLE
- [A] WO 9303116 A1 19930218 - MOBIL OIL CORP [US]
- [A] US 5998685 A 19991207 - NIERLICH FRANZ [DE], et al
- [A] US 3909451 A 19750930 - WILHELM FREDERICK C
- [A] US 2003073875 A1 20030417 - RYU J YONG [US], et al
- [A] STOCKLE MIKE AND KNIGHT TINA: "Dealing with Dieselisation", ERTC 14TH ANNUAL MEETING-BERLIN-NOVEMBER 2009, 11 November 2009 (2009-11-11), XP002587070, Retrieved from the Internet <URL:http://www.fwc.com/publications/tech_papers/files/Dealing%20with%20dieselisation%20ERTC%202009.pdf> [retrieved on 20100611]
Designated contracting state (EPC)
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
Designated extension state (EPC)
BA ME
DOCDB simple family (publication)
EP 2333031 A1 20110615; EP 2333031 B1 20120822; CN 102061195 A 20110518; FR 2952646 A1 20110520; FR 2952646 B1 20120928; US 2011114538 A1 20110519; US 8470165 B2 20130625; ZA 201007637 B 20110831
DOCDB simple family (application)
EP 10290586 A 20101028; CN 201010548630 A 20101112; FR 0905465 A 20091113; US 94498110 A 20101112; ZA 201007637 A 20101026