EP 2534117 A2 20121219 - METHOD FOR ALLYLATING AND VINYLATING ARYL, HETEROARYL, ALKYL, AND ALKENE HALOGENIDES USING TRANSITION METAL CATALYSIS
Title (en)
METHOD FOR ALLYLATING AND VINYLATING ARYL, HETEROARYL, ALKYL, AND ALKENE HALOGENIDES USING TRANSITION METAL CATALYSIS
Title (de)
VERFAHREN ZUR ALLYLIERUNG UND VINYLIERUNG VON ARYL-, HETEROARYL-, ALKYL- UND ALKENYLHALOGENIDEN UNTER ÜBERGANGSMETALLKATALYSE
Title (fr)
PROCÉDÉ D'ALKYLATION ET DE VINYLATION D'HALOGÉNURES D'ARYLE, D'HÉTÉROARYLE, D'ALKYLE ET ALCÉNYLE PAR CATALYSE PAR LES MÉTAUX DE TRANSITION
Publication
Application
Priority
- DE 102010007226 A 20100209
- EP 2011051390 W 20110201
Abstract (en)
[origin: WO2011098375A2] The invention relates to a method for producing organic compounds of the general formula (I) R-R' (I), by reacting a corresponding compound of the general formula (II) R-X (H), where X stands for fluorine, chlorine, bromine, or iodine, forming a magnesium organic compound of the general formula (III) [M+]n [RmMgXkY1] (III), compounds of the formula (III) being reacted with a compound of the general formula (IV), characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic quantities of an iron compound, relative to the compound of the general formula (II), and optionally in the presence b) of an additive comprising nitrogen, oxygen, and/or phosphorous in a catalytic or stoichiometric quantity relative to the compound of the general formula (II).
IPC 8 full level
C07B 49/00 (2006.01); C07B 37/04 (2006.01); C07C 1/30 (2006.01); C07C 1/32 (2006.01); C07C 15/44 (2006.01); C07C 17/26 (2006.01); C07C 17/263 (2006.01); C07C 41/24 (2006.01); C07C 41/30 (2006.01); C07C 43/205 (2006.01); C07C 67/343 (2006.01); C07C 209/68 (2006.01); C07C 209/74 (2006.01); C07C 253/04 (2006.01); C07C 253/30 (2006.01)
CPC (source: EP US)
C07B 37/04 (2013.01 - EP US); C07B 49/00 (2013.01 - EP US); C07C 1/30 (2013.01 - US); C07C 1/326 (2013.01 - EP US); C07C 17/26 (2013.01 - US); C07C 17/2632 (2013.01 - EP US); C07C 41/24 (2013.01 - US); C07C 41/30 (2013.01 - EP US); C07C 67/343 (2013.01 - EP US); C07C 209/68 (2013.01 - EP US); C07C 209/74 (2013.01 - US); C07C 253/04 (2013.01 - US); C07C 253/30 (2013.01 - EP US); C07C 2527/128 (2013.01 - EP US); C07C 2531/22 (2013.01 - EP US); C07C 2603/26 (2017.04 - EP US)
Citation (search report)
See references of WO 2011098375A2
Designated contracting state (EPC)
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
DOCDB simple family (publication)
WO 2011098375 A2 20110818; WO 2011098375 A3 20111013; AU 2011214483 A1 20120920; BR 112012019976 A2 20160503; CA 2789079 A1 20110818; EP 2534117 A2 20121219; JP 2013518919 A 20130523; JP 5540117 B2 20140702; KR 101536041 B1 20150710; KR 20120115577 A 20121018; MX 2012009238 A 20121205; US 2013184485 A1 20130718; US 9309188 B2 20160412
DOCDB simple family (application)
EP 2011051390 W 20110201; AU 2011214483 A 20110201; BR 112012019976 A 20110201; CA 2789079 A 20110201; EP 11702820 A 20110201; JP 2012552337 A 20110201; KR 20127023324 A 20110201; MX 2012009238 A 20110201; US 201113577278 A 20110201