Global Patent Index - EP 3260498 B1

EP 3260498 B1 20190918 - BIODEGRADABLE POLYESTER COMPOSITION

Title (en)

BIODEGRADABLE POLYESTER COMPOSITION

Title (de)

BIOLOGISCH ABBAUBARE POLYESTERZUSAMMENSETZUNG

Title (fr)

COMPOSITION DE POLYESTER BIODÉGRADABLE

Publication

EP 3260498 B1 20190918 (EN)

Application

EP 17762460 A 20170224

Priority

  • CN 201610126866 A 20160307
  • CN 2017074676 W 20170224

Abstract (en)

[origin: EP3260498A1] The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of a cyclic ester compound having a structure shown as formula (I) is 100ppm-950ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5ppm-85ppm. In the present invention, by adding the cyclic ester compound and cyclopentanone into the composition and controlling the content of the cyclic ester compound and the content of cyclopentanone in a certain range in the composition, an anti-thermal oxidative aging property of the biodegradable polyester composition can be greatly improved. Besides, after being digested with 95% ethanol at 40°C for 240 hours, a film prepared by blow molding or a part prepared by injection molding has little precipitate separating out of the surface and has an excellent surface appearance property. In addition, the lubrication degree of film during the blow molding process of the biodegradable polyester can be improved. When the velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2µm and a relative deviation of the film thickness is less than 1%. Bubble stability and continuity of film blowing are guaranteed.

IPC 8 full level

C08L 67/02 (2006.01); C08J 5/18 (2006.01); C08K 5/00 (2006.01); C08K 5/07 (2006.01); C08K 5/156 (2006.01); C08K 13/02 (2006.01); C08L 3/02 (2006.01); C08L 67/04 (2006.01)

CPC (source: CN EP KR US)

C08G 59/1466 (2013.01 - US); C08K 3/013 (2017.12 - KR); C08K 5/07 (2013.01 - CN EP US); C08K 5/12 (2013.01 - KR); C08K 5/156 (2013.01 - CN EP KR US); C08K 13/02 (2013.01 - KR US); C08L 3/02 (2013.01 - EP KR US); C08L 25/14 (2013.01 - KR); C08L 67/02 (2013.01 - CN EP KR US); C08L 67/04 (2013.01 - EP KR US); C08J 5/18 (2013.01 - EP US); C08J 2367/02 (2013.01 - EP US); C08K 5/0016 (2013.01 - EP US); C08K 5/0075 (2013.01 - EP US); C08L 2201/06 (2013.01 - CN KR US); C08L 2201/08 (2013.01 - CN US); C08L 2203/16 (2013.01 - CN); C08L 2205/03 (2013.01 - CN)

Citation (opposition)

Opponent : BASF SE

Opponent : Novamont S.p.A.

  • US 2004019178 A1 20040129 - GROSS RICHARD A [US], et al
  • CN 103044226 A 20130417 - HUAIAN WANBANG AROMATIC CHEMICALS INDUSTRY CO LTD
  • CN 105195063 A 20151230 - SHANDONG GREEN BIO PHARMACEUTICAL CO LTD
  • CN 1284761 C 20061115 - UNIV SHENYANG TECHNOLOGY [CN]
  • CN 101864068 A 20101020 - PETROCHINA CO LTD
  • EP 3260496 B1 20190925 - KINGFA SCIENCE & TECHNOLOGY CO [CN]
  • EP 3260497 B1 20190925 - KINGFA SCIENCE & TECHNOLOGY CO [CN]
  • WO 2011054896 A1 20110512 - NOVAMONT SPA [IT], et al
  • ELENA CANELLAS, PAULA VERA, CRISTINA NERÍN: "UPLC–ESI-Q-TOF-MSE and GC–MS identification and quantification of non-intentionally added substances coming from biodegradable food packaging", ANALYTICAL AND BIOANALYTICAL CHEMISTRY, SPRINGER BERLIN HEIDELBERG, DE, vol. 407, no. 22, 1 September 2015 (2015-09-01), DE, pages 6781 - 6790, XP055759585, ISSN: 1618-2642, DOI: 10.1007/s00216-015-8848-2
  • ANONYMOUS: "Cyclopentanon", WIKIPEDIA, 11 June 2020 (2020-06-11), pages 1 - 3, XP055759589, Retrieved from the Internet <URL:https://de.wikipedia.org/wiki/Cyclopentanon> [retrieved on 20201214]
  • JAN DEVROEDE, ROBBERT DUCHATEAU, COR E. KONING: "The synthesis of poly(butylene terephthalate) from terephthalic acid, part II: Assessment of the first stage of the polymerization process", JOURNAL OF APPLIED POLYMER SCIENCE, JOHN WILEY & SONS, INC., US, vol. 114, no. 4, 15 November 2009 (2009-11-15), US, pages 2427 - 2434, XP055759619, ISSN: 0021-8995, DOI: 10.1002/app.30781
  • ANONYMOUS: "TETRAHYDROFURAN", THF, 1 June 1999 (1999-06-01), pages 1 - 2, XP055645827, Retrieved from the Internet <URL:https://cameochemicals.noaa.gov> [retrieved on 20191122]

Designated contracting state (EPC)

AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DOCDB simple family (publication)

EP 3260498 A1 20171227; EP 3260498 A4 20190102; EP 3260498 B1 20190918; AU 2017230352 A1 20180118; AU 2017230352 B2 20180906; CN 105585827 A 20160518; DE 202017007332 U1 20201028; DE 202017007335 U1 20201028; DE 202017007336 U1 20201028; ES 2761049 T3 20200518; JP 2018515684 A 20180614; JP 6469931 B2 20190213; KR 102024492 B1 20190923; KR 20180054720 A 20180524; US 10494521 B2 20191203; US 2018163044 A1 20180614; WO 2017152774 A1 20170914

DOCDB simple family (application)

EP 17762460 A 20170224; AU 2017230352 A 20170224; CN 201610126866 A 20160307; CN 2017074676 W 20170224; DE 202017007332 U 20170224; DE 202017007335 U 20170224; DE 202017007336 U 20170224; ES 17762460 T 20170224; JP 2018511329 A 20170224; KR 20187010585 A 20170224; US 201715578683 A 20170224