(19)
(11)EP 3 209 496 B1

(12)EUROPEAN PATENT SPECIFICATION

(45)Mention of the grant of the patent:
30.12.2020 Bulletin 2020/53

(21)Application number: 15781276.9

(22)Date of filing:  05.10.2015
(51)International Patent Classification (IPC): 
B32B 7/00(2019.01)
B32B 7/04(2019.01)
B32B 7/12(2006.01)
B32B 27/06(2006.01)
B32B 27/28(2006.01)
B32B 27/32(2006.01)
B32B 1/00(2006.01)
B32B 3/00(2006.01)
B32B 3/06(2006.01)
B32B 7/02(2019.01)
B32B 7/06(2019.01)
B32B 27/00(2006.01)
B32B 27/08(2006.01)
B32B 27/30(2006.01)
B32B 27/34(2006.01)
B32B 1/02(2006.01)
B32B 3/02(2006.01)
B32B 3/30(2006.01)
(86)International application number:
PCT/US2015/053920
(87)International publication number:
WO 2016/064557 (28.04.2016 Gazette  2016/17)

(54)

A MULTILAYER STRUCTURE, A FILM MADE THEREFROM AND A PACKAGE FORMED THEREFROM

MEHRSCHICHTIGE STRUKTUR, DARAUS HERGESTELLTE FOLIE UND DARAUS HERGESTELLTE PACKUNG

STRUCTURE MULTICOUCHE, FILM RÉALISÉ À PARTIR DE CETTE DERNIÈRE ET EMBALLAGE RÉALISÉ À PARTIR DE CES DERNIERS


(84)Designated Contracting States:
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

(30)Priority: 20.10.2014 US 201414519070

(43)Date of publication of application:
30.08.2017 Bulletin 2017/35

(73)Proprietor: Dow Global Technologies LLC
Midland, MI 48674 (US)

(72)Inventors:
  • MAZZOLA, Nicolas C.
    13209-460 Jundiai (BR)
  • GARGALAKA, JUNIOR, João,
    03187-060 Sao Paulo (BR)
  • GOMES, Jorge, Caminero
    04601-040 Sao Paulo (BR)
  • BUASZCZYK, Gianna
    95320-000 Nova Praia (BR)

(74)Representative: Boult Wade Tennant LLP 
Salisbury Square House 8 Salisbury Square
London EC4Y 8AP
London EC4Y 8AP (GB)


(56)References cited: : 
WO-A1-2013/101931
US-A1- 2004 151 932
US-A- 5 874 139
  
      
    Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).


    Description

    Field of Invention



    [0001] The disclosure relates to a multilayer structure, a film made therefrom and a package formed therefrom.

    Background of the Invention



    [0002] Reliable and reproducible easy open packages are generally hard to find as it such properties depend upon the sealant layer composition, sealing conditions and/or aging time. Variability in these properties is particularly pronounced in packages with different package and lid compositions (e.g. rigid containers and lids, flexible containers and lids). There remains a need for multilayer structures allowing easy open sealing areas and which may be used in a variety of applications and with a wide variety of processing conditions.

    [0003] WO2013/101931 A1 discloses a multilayer film used in retort applications comprising a first outer layer which is heat sealable, said first outer layer comprising from 95 to 100 percent by weight of the first outer layer of a first polymer, said first polymer being derived from propylene and optionally one or more comonomers selected from the group consisting of ethylene and C4-C8 alpha olefins, said first polymer having a melting point of at least 125°C; an inner portion adjacent to the first outer layer, said inner portion comprising an elastomeric propylene based polymer ("EPBP") and a second polymer, wherein the second polymer is selected from the group consisting of high pressure LDPE, HDPE, EAA, EMA and combinations thereof; optionally one or more additional layers; and a second outer layer arranged so that the inner portion is encapsulated between the first outer layer and the second outer layer, said second outer layer comprising a third polymer, wherein said third polymer is selected from the group consisting of homopolymer polypropylene, random copolymer polypropylene and impact copolymer polypropylene and blends thereof.

    Summary of the Invention



    [0004] The disclosure is for a multilayer structure, a film made therefrom and a package formed therefrom.

    [0005] In one embodiment, the disclosure provides a multilayer structure comprising a first layer; a sealant layer formed from one or more ethylene-based polymers, wherein the ethylene-based polymer comprises a majority amount of polymerized ethylene monomer, based on the weight of the polymer; and a cohesive delamination layer adjacent to the sealant layer and formed from a polymer blend which comprises an elastomeric propylene based polymer and a second polymer, wherein the second polymer is selected from the group consisting of high pressure low density polyethylene, high density polyethylene, ethylene acrylic acid copolymers, ethylene (meth) acrylic acid copolymers and combinations thereof.

    [0006] In alternative embodiments, the disclosure provides a film made from the multilayer structure, and a package made therefrom.

    Brief Description of the Drawings



    [0007] 

    Fig. 1A is a schematic illustrating two multilayer structures according to an embodiment of the invention prior to sealing;

    Fig. 1B is a schematic illustrating the two multilayer structures following sealing of the two structures;

    Fig. 1C is a schematic illustrating the sealing area following application of force to open the seal;

    Fig. 2 is a graph illustrating the peak seal strength as a function of temperature for Comp. Ex. 1-6 and Inv. Ex. 1-3;

    Fig. 3A is a schematic illustrating the equipment used to measure peak seal strength for the examples;

    Fig. 3B is a schematic illustrating the sealing bars pressing against multilayer structures to form a seal;

    Fig. 3C is a schematic illustrating the process of opening the seal to measure the seal strength.

    Fig. 4 is a graph illustrating the peak seal force as a function of temperature for Comp. Ex. 8 and Inv. Ex. 5-8;

    Fig. 5 is a graph illustrating the peak seal force as a function of temperature for Comp. Ex. 9 (plus bottom films 1 and 2) and Inv. Ex. 9 (plus bottom films 1 and 2);

    Fig. 6 is a graph illustrating the peak seal force as a function of temperature for Comp. Ex. 10 (plus bottom films 1 and 2) and Inv. Ex. 10 (plus bottom films 1 and 2); and

    Fig. 7 is a graph illustrating the peak seal force as a function of temperature for Inv. Ex. 11-14.


    Detailed Description of the Invention



    [0008] The disclosure provides a multilayer structure, a film made therefrom and a package formed therefrom.

    [0009] The term "polymer," as used herein, refers to a polymeric compound prepared by polymerizing monomers, whether of the same or a different type. The generic term polymer thus embraces the term homopolymer (employed to refer to polymers prepared from only one type of monomer, with the understanding that trace amounts of impurities can be incorporated into the polymer structure), and the term interpolymer as defined hereinafter. Trace amounts of impurities (for example, catalyst residues) may be incorporated into and/or within the polymer.

    [0010] The term "interpolymer," as used herein, refers to polymers prepared by the polymerization of at least two different types of monomers. The generic term interpolymer includes copolymers (employed to refer to polymers prepared from two different types of monomers), and polymers prepared from more than two different types of monomers.

    [0011] The term "olefin-based polymer," as used herein, refers to a polymer that comprises a majority amount of polymerized olefin monomer, for example ethylene or propylene (based on weight of the polymer) and, optionally, may contain at least one comonomer.

    [0012] The term "ethylene-based polymer," as used herein, refers to a polymer that comprises a majority amount of polymerized ethylene monomer (based on weight of the polymer) and, optionally, may contain at least one comonomer.

    [0013] The term "ethylene/α-olefin interpolymer," as used herein, refers to an interpolymer that comprises a majority amount of polymerized ethylene monomer (based on the weight of the interpolymer) and at least one α-olefin.

    [0014] The term, "ethylene/α-olefin copolymer," as used herein, refers to a copolymer that comprises a majority amount of polymerized ethylene monomer (based on the weight of the copolymer), and an α-olefin, as the only two monomer types.

    [0015] The term "propylene-based polymer," as used herein, refers to a polymer that comprises a majority amount of polymerized propylene monomer (based on weight of the polymer) and, optionally, may comprise at least one comonomer.

    [0016] The term "composition," as used herein, includes a mixture of materials which comprise the composition, as well as reaction products and decomposition products formed from the materials of the composition.

    [0017] The terms "blend" or "polymer blend," as used herein, refers to a mixture of two or more polymers. A blend may or may not be miscible (not phase separated at the molecular level). A blend may or may not be phase separated. A blend may or may not contain one or more domain configurations, as determined from transmission electron spectroscopy, light scattering, x-ray scattering, and other methods known in the art. The blend may be effected by physically mixing the two or more polymers on the macro level (for example, melt blending resins or compounding) or the micro level (for example, simultaneous forming within the same reactor).

    [0018] The term "ionomer," as used herein means (or includes) polyethylene based copolymers modified with cations to provide ionic links. These copolymers are well known and described at The Wiley Encyclopedia of Packaging Technology or Handbook of Engineering and Specialty Thermoplastics, Polyolefins and Styrenics.

    [0019] The terms "cyclic olefin copolymers" and "COC," are known and described, for example, in EP-A-0 407 870, EP-A-0 485 893, EP-A-0 503 422, and DE-A-40 36 264.

    [0020] The multilayer structure according to a first embodiment of the invention provides a multilayer structure comprising a first layer; a sealant layer formed from one or more ethylene-based polymers, wherein the ethylene-based polymer comprises a majority amount of polymerized ethylene monomer, based on the weight of the polymer; and a cohesive failure layer adjacent to the sealant layer and formed from a polymer blend which comprises an elastomeric propylene based polymer and a second polymer, wherein the second polymer is selected from the group consisting of high pressure low density polyethylene, high density polyethylene, ethylene acrylic acid copolymers, ethylene (meth) acrylic acid copolymers and combinations thereof.

    [0021] The film according to another embodiment of the invention comprises one or more multilayer structures according to any embodiment described herein.

    [0022] The package according to yet another embodiment of the invention comprises one or more components formed from the multilayer structure according to any embodiment described herein.

    [0023] In embodiments of the multilayer structure, the cohesive failure layer is adjacent to the sealant layer. As used in this context, adjacent means that the cohesive failure layer abuts the sealing layer over at least a portion of a surface of the sealing layer. The polymer blend from which the cohesive failure layer is formed may include any one or more polymer blends, each of which comprises an elastomeric propylene based polymer and a second polymer, wherein the second polymer is selected from the group consisting of high pressure low density polyethylene, high density polyethylene, ethylene acrylic acid copolymers, ethylene (meth) acrylic acid copolymers and combinations thereof. Various combinations of such polymer blends are described, for example, in U.S. Patent 7,863,383 and PCT Publication WO2013101931. Commercial polymer blends are available under the name SEALUTION, from The Dow Chemical Company (Midland, MI, USA).

    [0024] In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that a seal force of the multilayer structure with any olefin-based layer does not substantially increase with increasing sealing temperature. As used in this context, "substantially increase" means an increase of 50% with an increase of 40 °C in sealing temperature.

    [0025] In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that the sealing layer is made from one or more materials selected from the group consisting of polar ethylene based copolymers, and ionomers.

    [0026] In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that the sealing layer has a thickness equal to or less than 50 microns. All individual values and subranges from equal to or less than 50 microns are included and disclosed herein. For example, the sealing layer may have a thickness equal to or less than 50 microns, or in the alternative, equal to or less than 20 microns, or in the alternative, equal to or less than 10 microns. In a particular embodiment, the lower limit of the sealing layer thickness is 0.5 micron. A skilled artisan would understand that the lower thickness limit is generally defined by the extrusion equipment limitations and may range from 0.5 to 5 microns, with all individual values therebetween disclosed herein. In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that the multilayer structure has 3 or more layers. All individual values from at least 3 layers are included and disclosed herein. For example, the multilayer structure may have 3, 4, 5, 6, or 7 layers.

    [0027] In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that the sealant layer consists of low density polyethylene. Any low density polyethylene may be used. Exemplary LDPE include 640i, LDPE 219M, LDPE 132i, LDPE 515E, LDPE 301E, all commercially available from The Dow Chemical Company.

    [0028] In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that the sealant layer is formed from 1 to 100 wt% one or more polymers selected from LLDPE and ionomers and, optionally, from 1 to 50 wt% of HDPE. All individual values and subranges from 1 to 100 wt% one or more polymers selected from LLDPE and ionomers are included and disclosed herein; for example, the amount of such components may range from a lower limit of 1, 15, 30, 45, 60, 75 or 90 wt% to an upper limit of 10, 25, 40, 55, 70, 85 or 100 wt%. For example, the amount of one or more polymers selected from LLDPE and ionomers can be from 1 to 100 wt%, or in the alternative, from 50 to 100 wt%, or in the alternative, from 1 to 50 wt%, or in the alternative, from 25 to 75 wt%, or in the alternative, from 40 to 80 wt%. When present, the amount HDPE can range from 1 to 50 wt%. All individual values and subranges from 1 to 50 wt% are included and disclosed herein; for example, the amount of such components can range from a lower limit of 1, 10, 20, 30 or 40 wt% to an upper limit of 5, 15, 25, 35, 45 or 50 wt%. For example, the amount of HDPE can range from 1 to 50 wt%, or in the alternative, from 1 to 25 wt%, or in the alternative, from 25 to 50 wt%, or in the alternative, from 10 to 25 wt%.

    [0029] In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that the sealant layer is formed from 1 to 100 wt% one or more polymers selected from LLDPE and ionomers and, optionally, from 20 to 99 wt% one or more materials selected from LDPE. All individual values and subranges from 1 to 100 wt% one or more polymers selected from LLDPE and ionomers are included and disclosed herein; for example, the amount of such components may range from a lower limit of 1, 15, 30, 45, 60, 75 or 90 wt% to an upper limit of 10, 25, 40, 55, 70, 85 or 100 wt%. For example, the amount of one or more polymers selected from LLDPE and ionomers can be from 1 to 100 wt%, or in the alternative, from 50 to 100 wt%, or in the alternative, from 1 to 50 wt%, or in the alternative, from 25 to 75 wt%, or in the alternative, from 40 to 80 wt%. All individual values and subranges from 20 to 99 wt% one or more materials selected from LDPE are included and disclosed herein; for example, when present, the amount of one or more materials selected from LDPE may range from a lower limit of 20, 30, 40, 50, 60, 70, 80 or 90 wt% to an upper limit of 25, 35, 45, 55, 5, 75, 85, 95 or 99 wt%. For example, when present, the amount of one or more materials selected from LDPE may range from 20 to 99 wt%, or in the alternative, from 50 to 99 wt%, or in the alternative, from 20 to 50 wt%.

    [0030] In yet another embodiment, the disclosure provides a multilayer structure, film or package in accordance with any embodiment described herein, except that the multilayer structure further comprises one or more additional layers selected from the group consisting of barrier layers and tie layers. In a particular embodiment, the multilayer structure comprises one or more barrier layers. In a specific embodiment, the one or more barrier layers is formed from one or more of polyamide, ethylene vinylalcohol and polyvinylidene chloride.

    [0031] In another embodiment, the disclosure provides a film formed by adhesion of any embodiment of the multilayer structure disclosed herein to a substrate selected from the group consisting of monolayer and multilayer films. Lamination substrates includes OPET, BOPP, PA, BOPA, PVOH and other substrates.

    [0032] In yet another embodiment, the disclosure provides a package in accordance with any embodiment described herein, except that the package is a pouch.

    [0033] In yet another embodiment, the disclosure provides a package in accordance with any embodiment described herein, except that the package is a food or beverage container.

    [0034] Fig. 1 illustrates a seal formed using one embodiment of the inventive multilayer structure. As shown in Fig. 1a, a first film 10 includes an external layer 11, a cohesive failure layer 12 and a sealant layer 13. Likewise, a second film 20 includes an external layer 21, a cohesive failure layer 22 and a sealant layer 23. In Fig. 1a, the sealant layers of each of the first and second films are facing each other. In Fig. 1b, the two sealant layers are fused in a sealing area 30. Fig. 1c illustrates the sealing area 39 following application of a force to pull the first and second films apart. As can be seen in Fig. 1c, the first and second films are separated by cohesive failure within the cohesive failure layer 12 of the first film. Alternatively, cohesive failure could occur in the cohesive failure layer 22 of the second film 20 or in both of layers 12 and 22.

    Examples



    [0035] The following examples illustrate the present invention but are not intended to limit the scope of the invention.

    [0036] Resins used in forming the comparative and inventive examples are described in Table 1.
    Table 1
    ResinCommercial Name/SupplierTypeI2 or MFR (g/10min)Density (g/cm3)
    Resin 1 RP 240 / Braskem (São Paulo, Brasil) rPP 1.50* 0.900
    Resin 2 VERSIFY 2200 / The Dow Chemical Co. (TDCC) (Midland, MI, USA) propylene/ethylene plastomer 2.00* 0.888
    Resin 3 LDPE 301 / TDCC LDPE 2.00** 0.920
    Resin 4 DOWLEX TG2085B / TDCC LLDPE 0.95** 0.919
    Resin 5 ELITE 5960G / TDCC HDPE 0.85** 0.965
    * MFR @ 2.16kg, 230°C
    ** I2 @ 2.16kg, 190 °C


    [0037] Five layer structures, having a layer structure designated as A/B/C/D/E. were prepared to illustrate comparative and inventive multilayer structures. Layer A is a sealing layer, Layer B is a cohesive failure layer, and Layers C, D, and E are additional layers with Layer E being the outermost layer. Table 2 provides the structure and layer composition of Comparative multilayer structures 1-6 (Comp. Ex. 1-6) and Inventive multilayer structures 1-3 (Inv. Ex. 1-3). For example, as illustrated in Table 2, Resin 1 is used to make layer A of Comp. Ex. 1 and 50 wt% Resin 2 and 50 wt% Resin 3 is used to make layer B of Comp. Ex. 1.
    Table 2
    FilmComp Ex. 1Comp Ex. 2Comp Ex. 3Comp Ex. 4Comp Ex. 5Inv. Ex. 1Inv. Ex. 2Inv. Ex. 3Comp. Ex. 6
    Thickness 60 60 60 60 60 60 60 60 60
    % A 10 20 30 10 10 10 10 10 10
    B 30 30 30 20 10 30 30 30 30
    c 20 20 20 30 30 20 20 20 30
    D 20 15 10 20 30 20 20 20 20
    E 20 15 10 20 20 20 20 20 20
    Resin A 1 1 1 1 1 5 4 4 50% 2 / 50% 3
    B 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 5
    C 5 5 5 5 5 1 5 1 5
    D 5 5 5 5 5 1 5 1 5
    E 5 5 5 5 5 1 5 1 5


    [0038] The films were sealed using conventional heat seal conditions (layer A being sealed onto layer E) and were tested to measure sealing force. The sealing force results are illustrated in Fig. 2. Referring to Fig. 2, it is seen that the seal force is dependent upon the sealing layer thickness and the heat seal initiation temperature (HSIT) is dependent on seal layer composition. The thickness of the cohesive failure layer also has an impact on sealing strength, the lower the sealing layer thickness the lower the seal strength. Inventive examples 1 to 3 exhibit a broad seal window; that is, the films can be used in a wide range of sealing temperatures, with heat seal temperatures from 120 °C to 180 °C.

    [0039] Additional examples were produced to illustrate the sealing of two different film structures. Inv. Ex. 1 was sealed to a commercial thermoforming bottom film having the following structure: Resin 4/Tie Layer/Barrier Layer/Tie Layer/ External Layer, to form Inv. Ex. 4. Specifically, Layer A of Inv. Ex. 1 was sealed to the Resin 4 Layer of the commercial film using a Multivac R145 with a seal time of 1 second and a sealing temperature of 150 °C.

    [0040] Using the same conditions, Comp. Ex. 6 was sealed to the same commercial thermoforming bottom film to form Comp. Ex. 7.

    [0041] Each of Inv. Ex. 4 and Comp. Ex. 7 were cut to form a specimen with 25.4mm width and were opened in a standard universal testing machine using the procedure described in ASTM F88. The results are shown in Table 3.
    Table 3
     Seal Temperature (°C)Seal Strength (N)
    Comp. Ex. 7 150 72.08
    Inv. Ex. 4 150 14.3


    [0042] Additional inventive and comparative examples were formed utilizing the resins listed and described in Tables 2 and 4.
    Table 4
    ResinCommercial Name / SupplierTypeI2 or MFR (g/10min)Density (g/cm3)
    Resin 6 DOWLEX 2050B / TDCC HDPE 0.95** 0.950
    Resin 7 DOWLEX NG 2038.11B / TDCC MDPE 1.00** 0.935
    Resin 8 DOWLEX 2049B/ TDCC LLDPE 1.00** 0.926


    [0043] Table 5 describes the structure of Comp. Ex.8 and Inv. Ex. 5-8.
    Table 5
    FilmComp Ex. 8Inv Ex. 5Inv Ex. 6Inv Ex. 7Inv Ex. 8
    Thickness 90 90 90 90 90
    % A 35 10 10 10 10
    B 10 35 35 35 35
    C 10 10 10 10 10
    D 22.5 22.5 22.5 22.5 22.5
    E 22.5 22.5 22.5 22.5 22.5
    Resin A 50% 2 / 50% 3 80% 6 / 20% 3 80% 7 / 20% 3 80% 8 / 20% 3 80% 4 / 20% 3
    B 4 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3
    C 4 4 4 4 4
    D 4 4 4 4 4
    E 4 4 4 4 4


    [0044] Each of Comp. Ex. 8 and Inv. Ex. 5-8 were sealed to the commercial thermoforming bottom film (with a thickness of 160 microns) described above according to ASTM F88. However, the seals were opened using the procedure shown in Fig. 3. Fig. 4 illustrates the peak seal force as a function of temperature for each of Comp. Ex. 8 and Inv. Ex. 5-8. As can be seen in Fig. 4, the Inv. Ex. 5-8 exhibit more stable values in a broader range of temperatures.

    [0045] Comparative Examples 9 and 10 and Inventive Examples 9 and 10 were produced having the composition and structure described in Table 6. In this set, 2 different bottom films were used; both with 160 microns thickness and composed of 100% resin 4 (bottom film 1) or 100% resin 3 (bottom film 2).
    Table 6
    FilmComp Ex. 9Inv Ex. 9Comp Ex. 10Inv Ex. 10
    Thickness 90 90 90 90
    % A 35 10 35 10
    B 10 35 10 35
    C 10 10 10 10
    D 22.5 22.5 22.5 22.5
    E 22.5 22.5 22.5 22.5
    Resin A 50% 2 / 50% 3 80% 6 / 20% 3 75% 2/ 25% 3 80% 8 / 20% 3
    B 4 50% 2 / 50% 3 4 75% 2 / 25% 3
    C 4 4 4 4
    D 4 4 4 4
    E 4 4 4 4


    [0046] The seal forces are illustrated in Figs. 5 and 6, with the combinations of the 4 different top films with the 2 different bottom films. These results illustrate the consistency of seal force achieved when the compositions of the cohesive failure layer are used adjacent to the sealing layer (Inv. Ex. 9 ad 10) versus using such cohesive failure compositions as the sealing layer (Comp. Ex. 9 and 10).

    [0047] Additional examples were prepared using the resins described in Tables 2, 4 and 7.
    Table 7
    ResinCommercial Name / SupplierTypeI2@2.16kg, 190°C (g/10min)Density (g/cm3)
    Resin 9 AMPLIFY TY 1352/ TDCC MAH graft 1.00 -
    Resin 4 DOWLEX TG 2085B/ TDCC LLDPE 0.95 0.919
    Resin 10 SURLYN 1650/E. I. du Pont de Nemours and Company (Wilmington, DE, USA) Ionomer 1.80 0.940
    Resin 11 UBE 5034B/ UBE Corporation Europe SA (Spain) Polyamide Not available Not available
    * MFR @ 2.16kg, 230 °C
    The films were produced in a blown film Collin line, and tested using standard heat seal methods (ASTM F88). The film structures are described in Table 8 and heat seal results are shown Fig. 7.
    Table 8
    FilmInv. Ex. 11Inv. Ex. 12Inv. Ex. 13Inv. Ex. 14
    Thickness 70 70 70 70
    % A 10 10 10 10
    B 29 29 29 29
    C 28 28 28 28
    D 7 7 7 7
    E 26 26 26 26
    Resin A 6 4 4 10
    B 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3 50% 2 / 50% 3
    C 6 6 9 6
    D 9 9 9 9
    E 11 11 11 11

    Test Methods



    [0048] Test methods include the following:

    Density was measured according to ASTM-D 792.

    Melt index, I2, is measured according to ASTM D-1238 at 190°C and at 2.16 kg.

    Melt Flow Rate, MFR, is measured according to ASTM D1238.



    [0049] Peak seal strength/force was measured according to ASTM F88 and using the equipment schematically illustrated in Fig. 3. As can be seen in Fig. 3a, a film having a top layer 40 and a bottom layer 45 is provided as well as two sealing bars 50. The sealing bars are heated and pressed against opposite sides of the film to form a sealed area 55, as seen in Fig. 3b. Fig. 3c illustrates the process of opening the sealed area 55 using pulling mechanisms 60 one each on the top layer 40 and bottom layer 45.

    [0050] The present invention may be embodied in other forms without departing from the scope thereof, and, accordingly, reference should be made to the appended claims, rather than to the foregoing specification, as defining the scope of the invention.


    Claims

    1. A multilayer structure comprising:

    a first layer;

    a sealant layer formed from one or more ethylene-based polymers, wherein the ethylene-based polymer comprises a majority amount of polymerized ethylene monomer, based on the weight of the polymer; and

    a cohesive failure layer adjacent to the sealant layer and formed from a polymer blend which comprises an elastomeric propylene based polymer and a second polymer, wherein the second polymer is selected from the group consisting of high pressure low density polyethylene, high density polyethylene, ethylene acrylic acid copolymers, ethylene (meth) acrylic acid copolymers and combinations thereof.


     
    2. The multilayer structure according to claim 1, wherein the seal force, as measured by ASTM F88, of the multilayer structure with any olefin-based layer does not increase by 50% or more with an increase of 40 °C in sealing temperature.
     
    3. The multilayer structure according to any one of the preceding claims, wherein the one or more ethylene-based polymers are selected from the group consisting of polar ethylene based copolymers and ionomers.
     
    4. The multilayer structure according to any one of the preceding claims, wherein the sealant layer has a thickness equal to or less than 50 microns.
     
    5. The multilayer structure according to any one of the preceding claims, wherein the multilayer structure has 3 or more layers.
     
    6. The multilayer structure according to any one of the preceding claims, wherein the sealant layer consists of low density polyethylene.
     
    7. The multilayer structure according to any one of claims 1-5, wherein the sealant layer is formed from 1 to 100 wt% one or more polymers selected from LLDPE and ionomers and, optionally, from 1 to 50 wt% of o HDPE.
     
    8. The multilayer structure according to any one of claims 1-5, wherein the sealant layer is formed from 1 to 100 wt% one or more polymers selected from LLDPE and ionomers and, optionally, from 20 to 99 wt% one or more materials selected from LDPE.
     
    9. The multilayer structure according to any one of the preceding claims wherein the multilayer structure further comprises one or more additional layers selected from the group consisting of barrier layers and tie layers.
     
    10. The multilayer structure according to claim 9 wherein the barrier layer is formed from one or more of polyamide, ethylene vinylalcohol and polyvinylidene chloride.
     
    11. A first film comprising the multilayer structure according to any one of the preceding claims.
     
    12. The first film of claim 11 laminated onto a substrate selected from the group consisting of monolayer and multilayer films using one or more adhesives.
     
    13. A package comprising one or more components formed from the multilayer structure according to any one of the preceding claims.
     
    14. The package according to claim 13 wherein the package is a pouch.
     
    15. The package according to claim 13, wherein the package is a food or beverage container.
     


    Ansprüche

    1. Eine mehrschichtige Struktur, die Folgendes beinhaltet:

    eine erste Schicht;

    eine Versiegelungsschicht, die aus einem oder mehreren Polymeren auf Ethylenbasis gebildet ist, wobei das Polymer auf Ethylenbasis bezogen auf das Gewicht des Polymers eine mehrheitliche Menge an polymerisiertem Ethylenmonomer beinhaltet; und

    eine an die Versiegelungsschicht angrenzende Kohäsionsbruchschicht, die aus einer Polymermischung gebildet ist, die ein elastomeres Polymer auf Propylenbasis und ein zweites Polymer beinhaltet, wobei das zweite Polymer ausgewählt ist aus der Gruppe, bestehend aus Hochdruck-Polyethylen niederer Dichte, Polyethylen hoher Dichte, Ethylen-Acrylsäurecopolymeren, Ethylen-(Meth)acrylsäurecopolymeren und Kombinationen davon.


     
    2. Mehrschichtige Struktur gemäß Anspruch 1, wobei sich die Versiegelungskraft, wie gemäß ASTM F88 gemessen, der mehrschichtigen Struktur mit irgendeiner Schicht auf Olefinbasis bei einer Erhöhung der Versiegelungstemperatur um 40 °C nicht um 50 % oder mehr erhöht.
     
    3. Mehrschichtige Struktur gemäß einem der vorhergehenden Ansprüche, wobei das eine oder die mehreren Polymere auf Ethylenbasis aus der Gruppe ausgewählt sind, die aus polaren Copolymeren auf Ethylenbasis und lonomeren besteht.
     
    4. Mehrschichtige Struktur gemäß einem der vorhergehenden Ansprüche, wobei die Versiegelungsschicht eine Dicke aufweist, die gleich oder weniger als 50 Mikrometer ist.
     
    5. Mehrschichtige Struktur gemäß einem der vorhergehenden Ansprüche, wobei die mehrschichtige Struktur 3 oder mehr Schichten aufweist.
     
    6. Mehrschichtige Struktur gemäß einem der vorhergehenden Ansprüche, wobei die Versiegelungsschicht aus Polyethylen niederer Dichte besteht.
     
    7. Mehrschichtige Struktur gemäß einem der Ansprüche 1-5, wobei die Versiegelungsschicht zu 1 bis 100 Gew.-% aus einem oder mehreren Polymeren, die aus LLDPE und lonomeren ausgewählt sind, und gegebenenfalls zu 1 bis 50 Gew.-% aus HDPE gebildet ist.
     
    8. Mehrschichtige Struktur gemäß einem der Ansprüche 1-5, wobei die Versiegelungsschicht zu 1 bis 100 Gew.-% aus einem oder mehreren Polymeren, die aus LLDPE und lonomeren ausgewählt sind, und gegebenenfalls zu 20 bis 99 Gew.-% aus einem oder mehreren Materialien, die aus LDPE ausgewählt sind, gebildet ist.
     
    9. Mehrschichtige Struktur gemäß einem der vorhergehenden Ansprüche, wobei die mehrschichtige Struktur ferner eine oder mehrere zusätzliche Schichten beinhaltet, die aus der Gruppe, bestehend aus Barriereschichten und Verbindungsschichten, ausgewählt sind.
     
    10. Mehrschichtige Struktur gemäß Anspruch 9, wobei die Barriereschicht aus einem oder mehreren von Polyamid, Ethylenvinylalkohol und Polyvinylidenchlorid gebildet ist.
     
    11. Eine erste Folie, die die mehrschichtige Struktur gemäß einem der vorhergehenden Ansprüche beinhaltet.
     
    12. Erste Folie gemäß Anspruch 11, die unter Verwendung eines oder mehrerer Haftmittel auf ein Substrat laminiert ist, das aus der Gruppe, bestehend aus Monoschicht- und Mehrschichtenfolien, ausgewählt ist.
     
    13. Eine Packung, die einen oder mehrere Bestandteile beinhaltet, die aus der mehrschichtigen Struktur gemäß einem der vorhergehenden Ansprüche gebildet sind.
     
    14. Packung gemäß Anspruch 13, wobei die Packung ein Beutel ist.
     
    15. Packung gemäß Anspruch 13, wobei die Packung ein Nahrungsmittel- oder Getränkebehälter ist.
     


    Revendications

    1. Une structure multicouche comprenant :

    une première couche ;

    une couche de matériau d'étanchéité formée à partir d'un ou de plusieurs polymères à base d'éthylène, le polymère à base d'éthylène comprenant une quantité majoritaire de monomère d'éthylène polymérisé, rapporté au poids du polymère ; et

    une couche de rupture de cohésion adjacente à la couche de matériau d'étanchéité et formée à partir d'un mélange homogène de polymères qui comprend un polymère à base de propylène élastomère et un deuxième polymère, le deuxième polymère étant sélectionné dans le groupe constitué de polyéthylène basse densité haute pression, de polyéthylène haute densité, de copolymères d'éthylène-acide acrylique, de copolymères d'éthylène-acide (méth)acrylique et de combinaisons de ceux-ci.


     
    2. La structure multicouche selon la revendication 1, dans laquelle la force d'étanchéité, telle que mesurée par l'ASTM F88, de la structure multicouche avec toute couche à base d'oléfine n'augmente pas de 50 % ou plus avec une augmentation de la température d'étanchéité de 40 °C.
     
    3. La structure multicouche selon n'importe laquelle des revendications précédentes, dans laquelle les un ou plusieurs polymères à base d'éthylène sont sélectionnés dans le groupe constitué d'ionomères et de copolymères à base d'éthylène polaires.
     
    4. La structure multicouche selon n'importe laquelle des revendications précédentes, dans laquelle la couche de matériau d'étanchéité a une épaisseur égale ou inférieure à 50 micromètres.
     
    5. La structure multicouche selon n'importe laquelle des revendications précédentes, dans laquelle la structure multicouche a 3 couches ou plus.
     
    6. La structure multicouche selon n'importe laquelle des revendications précédentes, dans laquelle la couche de matériau d'étanchéité est constituée de polyéthylène basse densité.
     
    7. La structure multicouche selon n'importe laquelle des revendications 1 à 5, dans laquelle la couche de matériau d'étanchéité est formée à partir de 1 à 100 % en poids d'un ou de plusieurs polymères sélectionnés parmi le PEBDL et des ionomères et, facultativement, à partir de 1 à 50 % en poids de PEHD.
     
    8. La structure multicouche selon n'importe laquelle des revendications 1 à 5, dans laquelle la couche de matériau d'étanchéité est formée à partir de 1 à 100 % en poids d'un ou de plusieurs polymères sélectionnés parmi le PEBDL et des ionomères et, facultativement, à partir de 20 à 99 % en poids d'un ou de plusieurs matériaux sélectionnés parmi le PEBD.
     
    9. La structure multicouche selon n'importe laquelle des revendications précédentes, la structure multicouche comprenant en outre une ou plusieurs couches supplémentaires sélectionnées dans le groupe constitué de couches barrières et de couches de liaison.
     
    10. La structure multicouche selon la revendication 9 dans laquelle la couche barrière est formée à partir d'un ou de plusieurs éléments parmi le polyamide, l'éthylène-alcool vinylique et le polychlorure de vinylidène.
     
    11. Un premier film comprenant la structure multicouche selon n'importe laquelle des revendications précédentes.
     
    12. Le premier film de la revendication 11 stratifié sur un substrat sélectionné dans le groupe constitué de films monocouche et multicouche à l'aide d'un ou de plusieurs adhésifs.
     
    13. Un emballage comprenant un ou plusieurs constituants formés à partir de la structure multicouche selon n'importe laquelle des revendications précédentes.
     
    14. L'emballage selon la revendication 13, l'emballage étant un sachet.
     
    15. L'emballage selon la revendication 13, l'emballage étant un récipient pour aliments ou boissons.
     




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    Cited references

    REFERENCES CITED IN THE DESCRIPTION



    This list of references cited by the applicant is for the reader's convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.

    Patent documents cited in the description