(19)
(11)EP 3 387 232 B1

(12)EUROPEAN PATENT SPECIFICATION

(45)Mention of the grant of the patent:
20.11.2019 Bulletin 2019/47

(21)Application number: 16810448.7

(22)Date of filing:  06.12.2016
(51)International Patent Classification (IPC): 
F01N 13/00(2010.01)
B01D 53/94(2006.01)
F01N 3/28(2006.01)
B01J 35/04(2006.01)
(86)International application number:
PCT/GB2016/053833
(87)International publication number:
WO 2017/098224 (15.06.2017 Gazette  2017/24)

(54)

IMPROVED FRAME ELEMENTS FOR CONTAINING MONOLITHS

VERBESSERTE RAHMENELEMENTE ZUR AUFNAHME VON MONOLITHEN

ELEMENTS DE CADRE AMÉLIORÉS POUR RECEVOIR DES MONOLITHES


(84)Designated Contracting States:
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

(30)Priority: 07.12.2015 US 201562263901 P

(43)Date of publication of application:
17.10.2018 Bulletin 2018/42

(60)Divisional application:
19182176.8 / 3567230

(73)Proprietor: Johnson Matthey Catalysts (Germany) GmbH
96257 Redwitz an der Rodach (DE)

(72)Inventors:
  • KLEUDERLEIN, Robert
    D-96257 Redwitz (DE)
  • REICHERT, Dirk
    D-96257 Redwitz (DE)
  • SCHERBEL, Harald
    D-96257 Redwitz (DE)

(74)Representative: Wilson, Nicola Ann 
Patent Attorney@Johnson Matthey Publ.Ltd Comp. Intell. Property Dept.@Johnson Matthey Techn. Ctr. Blount's Court Road
Sonning Common Reading Berkshire RG4 9NH
Sonning Common Reading Berkshire RG4 9NH (GB)


(56)References cited: : 
EP-A1- 2 902 601
JP-A- H1 133 409
JP-A- 2002 239 345
KR-A- 20150 107 385
US-A1- 2011 030 355
DE-U1- 8 605 649
JP-A- H07 213 865
JP-U- S53 128 345
US-A1- 2009 293 464
  
      
    Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).


    Description

    FIELD OF THE INVENTION



    [0001] The invention relates to an improved element frame that holds monoliths containing catalysts within the frame, where the element frame with the catalyst is configured to be placed in the flow of exhaust gas from an engine.

    BACKGROUND OF THE INVENTION



    [0002] The invention relates to element frames used in catalyst modules for treating exhaust gases from a stationary combustion source having an exhaust system passing exhaust gases through a support structure containing one or more monoliths, each containing one or more catalysts. A stationary combustion system can be any system that combusts a hydrocarbon-based fuel that is not used in an on-road operated car, truck or aircraft. They can be, for example, coal-fired systems, oil-fired (petroleum) systems or gas turbines. Stationary combustion systems can also be used in marine applications, where combustion systems such as diesel engines, as used for large container or cruise ships. Stationary combustion systems are usually operated continuously under a constant, stationary load while mobile combustion systems are usually operated under varying loads.

    [0003] Hydrocarbon combustion in these systems, and in engines used in mobile applications, generates exhaust gas that must be treated to remove pollutants like nitrogen oxides (NOx), carbon monoxide (CO) or hydrocarbons (HC) that are formed. NOx is known to cause a number of health issues for humans and animals as well as causing a number of detrimental environmental effects including the formation of smog and acid rain. CO is toxic to humans and animals and HC can cause adverse health effects. To mitigate both the human and environmental impact from these pollutants, especially NOx, in exhaust gas, it is desirable to eliminate these undesirable components, preferably by a process that does not generate other noxious or toxic substances.

    [0004] Stationary combustion systems can be equipped with an emission control system, which is provided with catalyst modules. Figure 1 is a depiction of a catalyst module known in the art. Catalyst modules are structures comprising a plurality of element frames, where each element frame can contain a plurality of monoliths each comprising a catalyst support and one or more catalysts. The catalyst modules are installed in a flue gas duct of the emission control system and the flue gas, which is to be purified, flows through the monoliths during operation. The flue gas duct can typically have a cross-sectional area of a few square meters and can be in the tens to hundreds of square meters. The dimensions of the flue duct can vary widely depending upon many factors, including the size of the engine, the conditions under which the engine is operated, permissible back pressure, etc. In some cases, the flue gas duct can have a rectangular cross-section with the width and the height of the duct each being several meters, for example, of 10 m x 10 m. The entire cross-sectional area of the flue gas duct is covered by one or more catalyst modules. The catalyst modules are arranged next to one another so that all the flue gas passes through the monoliths, contacts the catalyst(s) on or in the monoliths and becomes purified. Several catalyst modules, for example, two to five, can be placed next to one another in rows and columns, often connected in a supporting framework, within the flue gas duct (Figure 2). The catalyst modules themselves typically have a rectangular cross-section with an edge length of several meters.

    [0005] In the direction of flow of the flue gas, catalyst modules frequently are located in several planes positioned one behind the other. In some applications, the catalyst modules can extend for several meters, and even as much as 10-15 meters in the direction of flow (Figure 3). For some applications, such as marine or gas turbines, relatively harsh ambient conditions in terms of mechanical stress can be present for the catalyst modules. For example, on marine vessels, forces several times gravity can be experienced. In addition, especially for large cross-sections of catalyst modules used with gas turbines, mechanical stresses due to earthquakes have to be considered.

    [0006] Catalyst modules can be constructed using a stacking frame in which several element frame units are inserted, where the element frame units contain monoliths comprising one or more catalysts. Flue gas flows through the individual monoliths in the direction of the flue gas flow. The monoliths are also known as honeycomb type catalysts. These honeycomb type catalysts are generally made of a ceramic material and have a plurality of flow channels through the monolith in the direction of the gas flow. In the installed, operating state, flue gas flows through the flow channels in the monolith where it interacts with catalyst in the monolith or in a coating on the surface of the monolith and becomes purified.

    [0007] A typical problem encountered in the use of these treatment systems is that material placed between the monoliths and the element frame elements to provide a seal and therefore, gas-tightness i.e. no bypass flow around the catalyst, as well as, to act as a cushion against vibrations, is not able to stay in place during normal use except for when the material is specially designed and provided as a special type of mat that has a relatively high cost. The mat between element frame and a monolith containing one or more catalysts is placed in the element frame just before the element frame is welded together. In situations where there is periodical mechanical stress, which is typical in exhaust system conditions where engine pulsation leads to shock and vibrations, the mat can move against the frame and monolith. This movement can cause the destruction of the monolith because of the relatively low mechanical stability of the system to shock and vibrations.

    [0008] Current element frames have metal flaps or lips that overlap the inlet and/or outlet faces of the monolith so that approximately 15 % of the catalyst cells are not directly exposed to the exhaust flow.

    [0009] Current element frames also have locking elements in the center of the inlet and outlet face. One of the functions of the locking element is to shield gaps between the monoliths from direct exhaust gas flow. The locking element is welded without prestress, which leads to relatively low mechanical stability against shock and vibrations.

    [0010] The current designs of element frames do not provide a mechanism to attach the element frames directly to each other. The ability to join element frames together can avoid the need for a catalyst module when only a small number of element frames are needed.

    [0011] JP 11 033409 describes a catalyst module with a housing body formed from a prismatic housing frame consisting of four connected side plates and upper and lower grids arranged at the upper and lower ends of the frame. A cushioning material is attached to the inner faces of the respective side plates. A connecting part is opened between at least two adjacent side plates, and a specified number of catalyst elements are put into the housing body therefrom. Both upper and lower ends of at least one side plate are fastened to the side faces of the grids with a bolt and a nut. A spring is provided to the bolt to press the side plate against a group of the elements.

    [0012] It would be desirable to have a catalyst module that allows for a cost-effective material to be placed between the monoliths and the metal frame of the element frame to provide a seal and to act as a cushion against vibrations that can stay in place during normal use and also provide for the largest possible catalyst cross-section to be utilized, all under harsh mechanical stress conditions.

    SUMMARY OF THE INVENTION



    [0013] In a first aspect, the invention relates to an element frame for holding monoliths containing catalysts in the flow of exhaust gases from a combustion source, the element frame comprising two pairs of opposing walls where the walls form a rectangular or square shape, an interior formed by the walls, an inlet end, an outlet end, at least one locking element, at least one mat and at least one monolith comprising an inlet, an outlet, four sides and at least one catalyst effective in reducing the concentration of one or more gases in the exhaust gas, where the at least one mat and the at least one monolith is positioned in the interior of the element frame with at least one mat between the monolith and each adjacent wall, each locking element extending across the inlet end or outlet end of the element frame and being connected to two opposite sides of the element frame, characterized in that one or more of the walls comprises a plurality of protrusions extending into the interior.

    [0014] In a second aspect, the invention relates to a catalyst module comprising a plurality of element frames of the first aspect of the invention.

    [0015] In another aspect, the invention relates to an exhaust system comprising an element frame of the first aspect of the invention.

    [0016] In yet another aspect, the invention relates to an exhaust system comprising a catalyst module of the second aspect of the invention.

    [0017] In still another aspect, the invention relates to a method of making an element frame of the first aspect of the invention.

    [0018] In another aspect, the invention relates to a method of making a catalyst module of the second aspect of the invention.

    [0019] In yet another aspect, the invention relates to a method of treating an exhaust gas, the method comprising passing an exhaust gas through monoliths in an element frame of the first aspect of the invention, where the monoliths comprise one or more catalysts effective in reducing the concentration of one or more gases in the exhaust gas.

    [0020] In still another aspect, the invention relates to a method of increasing the amount of catalyst contacted with an exhaust gas, the method comprising passing an exhaust gas through a catalyst module of the second aspect of the invention.

    BRIEF DESCRIPTION OF THE DRAWINGS



    [0021] 

    Figure 1 is a three-dimensional depiction of a catalyst module.

    Figure 2 is a diagram showing the placement of modules across the cross section of an exhaust duct.

    Figure 3 is a diagram showing an overhead view of the placement of five groups of modules placed one after another in the direction of the gas flow within an exhaust duct.

    Figure 4 is a three-dimensional depiction of a frame element.

    Figure 5 is a three-dimensional depiction of a frame element with four monoliths in the frame element.

    Figure 6 is a depiction of part of an element frame shown from the inlet and/or outlet side showing two pieces each with adjacent wall and cut-outs in the inlet and/or outlet face.

    Figure 7 depicts an end view of a frame element with a locking element attached.

    Figure 8 depicts a side view of a frame element.

    Figure 9 depicts a cross-sectional view of a frame element with two monoliths within the cross-section of the frame element.

    Figure 10 depicts a cross sectional view of a protrusion on the frame element.

    Figure 11 depicts a side view of a frame element comprising four monoliths.

    Figure 12 depicts a side view of a frame element comprising six monoliths.

    Figure 13 is a three-dimensional depiction of a frame element with each of the sides having an extension for connecting the frame element to other frame elements.

    Figure 14 is a depiction of two connected locking elements with cut-outs.

    Figure 15 is a three-dimensional depiction of three frame elements with the sides having extension for connecting the frame element to other frame elements where the frame elements contain monoliths.


    DETAILED DESCRIPTION OF THE INVENTION



    [0022] As used in this specification and the appended claims, the singular forms "a", "an" and "the" include plural referents unless the context clearly indicates otherwise. Thus, for example, reference to a "catalyst" includes a mixture of two or more catalysts, and the like.

    [0023] The term "substantially all" means at least 90%, preferably at least 95%, preferably at least 97%.

    [0024] The term "support" means an inert material to which a catalyst is fixed.

    [0025] The term "element frame" means a structure comprising four walls, each wall comprising a plurality of protrusions, where the four walls form a rectangle or a square, and define an interior of the element frame such that a plurality of monoliths, each having at least one mat covering a portion of each side of the monolith. The element frame can also contain a locking element on the inlet cross section which is used to shield the mat material from direct flow momentum and to act as a tie bar for high mechanical stability. The element frame can be made of steel, where the steel is any one of a number of different grades.

    [0026] The term "locking element" means a structure that holds a monolith within an element frame. The locking element typically is made of the same material as the element frame, i.e. steel of any one of a number of different grades.

    [0027] The term "cut-out" means a part or section of a frame element or locking element that is not present and provides for a reduction in the surface area of the frame element or locking element in relation to the flow of exhaust gas when the frame element or locking element is installed in the flow of exhaust gas. The cut-out increases the number of cells in a monolith that are directly exposed to the flow of exhaust gas. The term "directly exposed" means that exhaust gas enters cells in the monolith at an opening at the inlet side of the monolith.

    [0028] A "mat" is to be understood as meaning a combination of mineral, glass or metallic fibers, for example in the form of a woven fabric, a knitted fabric, an irregular layer or the like. The mat may also be referred to as a web, fleece or non-woven material. The fibers used include a material which is able to withstand high temperatures and is resistant to corrosion. They can include in particular an iron base material to which alloying elements are added, with at least one alloying element being selected from nickel (8-11 % by weight) or chromium (17-24% by weight) advantageously being present. One example of suitable fibers comprises 70% by weight of iron, 17% by weight of chromium and 8% by weight of nickel, although standard impurities may of course also be present. The mat can be produced by using fibers which are identical or different (for example with regard to the fiber length and fiber diameter). The fibers used may also comprise a mineral or glass based material. The mat can be a single piece or can be in the form of strips where the strips cover an entire side, or a portion of one or more sides, of a monolith or surround only a portion of the monolith.

    [0029] The term "catalyst module" means a structure formed by, or containing, a plurality of element frames.

    [0030] In the first aspect of the invention, an element frame for holding monoliths containing catalysts in the flow of exhaust gases from a combustion source, the element frame the element frame comprises two pairs of opposing walls where the walls form a rectangular or square shape, an interior formed by the walls, an inlet end, an outlet end, at least one locking element, at least one mat and at least one monolith comprising an inlet, an outlet, four sides and at least one catalyst effective in reducing the concentration of one or more gases in the exhaust gas, where the at least one mat and the at least one monolith is positioned in the interior of the element frame with at least one mat between the monolith and each adjacent wall, each locking element extending across the inlet end or outlet end of the element frame and being connected to two opposite sides of the element frame. At least one wall, preferably each wall, comprises a plurality of protrusions extending into the interior of the element frame. The plurality of protrusions can be configured to contact a mat and hold the mat against a monolith comprising one or more catalysts when the monolith is located in the interior of the element frame.

    [0031] Figure 4 is a three-dimensional depiction of an element frame. The element frame comprises four walls, and one or more, preferably all of the walls, comprises a plurality of protrusions extending into the interior space formed by the four walls. The frame element can hold a plurality of monoliths within the interior space formed by the four walls, as shown in Figures 5, 11 and 12. The element frame can hold the monoliths in different configurations, such as 1 by 2, 1 by 3, 3 by 3, etc. The length (depth) of the element frame is based on the length the monoliths and the number of monoliths that may be placed serially within the element frame.

    [0032] When two or more monoliths are present in the interior of the element frame and at least two monoliths are located adjacent two each other, at least one mat can be located between monoliths that are adjacent to each other. Preferably at least a portion of one or more mats is positioned: (a) between each side of a monolith and an adjacent monolith; and (b) between each monolith and an adjacent wall of the element frame.

    [0033] The element frame can be formed by joining four walls other to form a rectangle or a square having an interior. Preferably, the element frame can be formed by joining two pieces, each comprising two walls, together. Figure 6 shows a view from the inlet end or outlet end of two pieces (A and B), each comprising two walls formed by bending a single piece. The walls are not shown as they extend into the figure and are hidden by parts of the element frame at the inlet and/or outlet that are bent toward the interior of the element frame. The parts of the element frame at the inlet and outlet of the element frame preferably comprise one or more cut-outs that can increase the exposure area of monoliths placed within the element frame. Cut-outs of the element frame on the inlet and outlet face can reduce the number of cells in a monolith that are not directly seeing the exhaust flow. Preferably less than 10%, more preferably less than 8%, even more preferably less than 7%, even more preferably less than 6%, most preferably less than 5% of the catalyst cells are not directly exposed the exhaust flow. The reduction in the number of cells in the monolith that are not directly exposed to the gas flow can lead to lower back pressure, increase exposure of the exhaust gas to catalysts and higher conversion of compounds in the exhaust gas to other more desired compounds.

    [0034] Pieces comprising the wall can be connected together, preferably by welding.

    [0035] Figure 7 depicts a view of an element frame from an inlet or outlet end with two locking elements attached. Monoliths with their side wall at least partially covered by mats are placed within the walls of the element frame. Each locking element can be connected to each of the four sides by welding. The locking elements shown in Figure 7 do not have cut-outs. Preferably the locking elements will comprise one or more cut-outs.

    [0036] Figure 8 depicts a side view of a frame element where the wall of the frame element has a length that is approximately the same as the length of the monolith. The width of the wall of the frame is dependent upon whether a single monolith or a plurality of monoliths, preferably two or three, are located adjacent to each other against the wall. When only a single monolith is located against a wall, the width of the wall is approximately equivalent to the size of the monolith against the wall plus the thicknesses of two mats. When a plurality of monoliths is located against a wall, the width of the wall is approximately equivalent to sum of the size of the monolith against the wall plus the number of monoliths times the thicknesses of two mats. Depending upon how the walls are put together, allowance may need to be made for the thickness of the walls and manufacturing tolerance of the monoliths.

    [0037] Figure 9 depicts a cross-sectional view of the frame element showing the channels through the monoliths and protrusions in the walls of the element frame. In this drawing two monoliths are placed next to each other with their flow channels having the same direction of flow. The section of the drawing labeled "Z" is shown enlarged in Figure 10 to show details of the protrusions.

    [0038] Two or more monoliths can be placed serially within an element frame, as shown in Figures 11 and 12. The element frame can comprise a plurality of monoliths where two or more monoliths are positioned so that the outlet of a first monolith is adjacent to the inlet of a second monolith and a flow of exhaust gas passes sequentially through at least two monoliths. When three or more monoliths are used, exhaust gas exiting the second monolith can enter a third monolith. In these configurations one or more monoliths can be located downstream of one or more monoliths in the direction of flow of the exhaust gas through the monoliths in the element frame.

    [0039] The element frame can comprise a plurality of monoliths where the two or more monoliths positioned so that the outlet of one monolith is adjacent to the inlet of another monolith contain catalysts having the same functionality. The term "having the same functionality" means that the catalysts adjacent to each other perform the same type of chemical reactions, such as selective catalytic reduction (SCR), ammonia oxidation, hydrocarbon oxidation, NOx storage, oxygen storage, etc.

    [0040] The element frame can comprise a plurality of monoliths where two of the two or more monoliths positioned so that the outlet of one monolith is adjacent to the inlet of another monolith contain catalysts having different functionality. The term "having different functionality" means that the catalysts adjacent to each other perform different types of chemical reactions. Numerous types of configuration are possible. For example, a monolith comprising catalysts for selective catalytic reduction (SCR) can be followed by a monolith comprising catalysts for ammonia oxidation. A monolith comprising catalysts for hydrocarbon oxidation can be followed by a monolith comprising catalysts for selective catalytic reduction (SCR). A monolith comprising a catalyst providing NOx storage can be followed by a monolith comprising catalysts for SCR. Other possible combinations of catalysts are known to those skilled in the art.

    [0041] At least one wall of the element frame can comprise an extended section, where the extended section comprises a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening.

    [0042] At least two walls of the element frame can comprise an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening.

    [0043] Each of the four sides of the element frame can comprise an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening.

    [0044] Extended sections can be present on the inlet side, the outlet side, or both the inlet and outlets sides of the frame element. Figure 13 shows an element frame where each of the sides (30) contain an extended section (34) comprising a plurality of openings. Two types of openings, holes and slots are shown in Figure 13. Other shapes, or combinations of shapes, can be used.

    Protrusions



    [0045] One of more walls, preferably each wall, comprises a plurality of protrusions extending into the interior.

    [0046] The number and size of the protrusions on a wall can vary depending upon several factors, including, but not limited to the physical properties of the mat, the size of the mat and the number of mats used per wall, and the size of the wall of the element frame. Figure 7 shows an element frame with each wall having 25 protrusions in a 5 x 5 matrix.

    [0047] The function of the protrusions is to hold the mat between wall and monolith to suppress destruction of, or damage to, the monolith by shear forces. When a single mat is used to cover all four sides of the monolith, a smaller number of protrusions may be needed that when two or more mats are used to cover each side of the monolith. If the mat is in the form of strips where two or more strips are used on a side of a monolith, more protrusions would be needed that when a single mat is used to cover all four sides of the monolith. Figure 9 depicts a cross sectional view of a protrusion on the frame element, where the protrusion has a height (h) and a base of width (w). The greater the height of a protrusion relative to the area of the base of the protrusion, the more likely that the protrusion can disturb the mat during normal use due to vibrations. However, a protrusion having a small height relative to the area of the base of the protrusion can be less likely to disturb the mat during normal use, and the relatively large base is better able to contact a larger surface area of the mat. The height of the protrusion can be about 1 mm and the protrusion can be about 6 mm wide. Depending upon the properties of the mat, the thickness of the wall of the element frame and the material, protrusions having other height and widths can be used, such as, for example, 2 mm x 10 mm, or 1 mm x 10 mm. A mat can be cut into large strips having a width approximately the same as the depth of the monolith. The mat can then be wrapped around the monolith, and then the monolith covered with the mat can be placed into the element frame. The mat can also be present as two of more strips, where the combined widths of the strips are less than or equal to the depth of the monolith. When two strips are used and the combined widths of the strips are less than the depth of the monolith, it is preferable that the strips are positioned off-center. The element frame is compressed and then the sides are welded together and a locking element is attached by welding to the four walls of the element frame on the inlet end and the outlet end.

    [0048] The element frame according to the invention has an improved open frontal area for catalyst use of the exhaust gas while providing improved mechanical stability against shock and vibrations.

    Monolith



    [0049] The term "monolith", also known as a "honeycomb" type catalyst means a carrier having a plurality of fine, parallel gas flow passages extending from an inlet to an outlet face of the monolith, such that passages are open to fluid flow. A monolith can have a rectangular, preferably square, cross-sectional and inflow surface. The face of the monoliths can be of any dimensions, preferably between 10 cm to 30 cm, inclusive. The length of monolith in the direction of flow typically ranges from 15 cm to 150 cm, although other lengths can be used. The width of the element frame in the direction of exhaust gas flow is approximately the length of the monolith.

    [0050] A monolith has an inlet, an outlet, four sides and a plurality of flow passages (or "cells"). Monoliths can contain up to about 700 or more flow passages per square inch of cross section, although far fewer may be used. For example, for stationary applications the carrier typically may have from about 9 to 600, more usually from about 35 to 300, cells per square inch ("cpsi"). The passages, which are essentially straight paths from their fluid inlet to their fluid outlet, are defined by walls onto which one or more catalysts effective in treating exhaust gases are coated as a "washcoat" so that the gases flowing through the passages contact the catalytic material.

    [0051] One of ordinary skill in the art is familiar with the use and selection of one of more catalysts to reduce nitrogen oxides, carbon monoxides, hydrocarbons, ammonia slip and other pollutants to form nitrogen, water and carbon dioxide, which are relatively harmless compounds. The monolith can comprise one or more of an SCR catalyst, an ammonia oxidation catalyst, a hydrocarbon oxidation catalyst, a NOx storage catalyst, an oxygen storage catalyst, etc. The monolith can be a filter, such as a ceramic filter. Other types of catalyst can be present. The flow passages of the monolithic substrate are thin-walled channels which can be of any suitable cross-sectional shape such as trapezoidal, rectangular, square, triangular, sinusoidal, hexagonal, oval, circular, etc. The invention is not limited to a particular substrate type, material, or geometry. The monolith is generally an extruded material, preferably a ceramic substrate.

    [0052] Ceramic substrates may be made of any suitable refractory material, such as cordierite, cordierite-a alumina, α-alumina, silicon carbide, silicon nitride, zirconia, mullite, spodumene, alumina-silica magnesia, zirconium silicate, sillimanite, magnesium silicates, zircon, petalite, aluminosilicates and mixtures thereof. The ceramic substrate can have catalytic activity itself. In some cases, no additional catalyst material is placed on ceramic substrates having catalytic activity.

    Mats



    [0053] One or more mats can form a seal restricting exhaust gas movement around the monolith. The mats can prevent direct physical contact between the monolith and the element frame and provide damping against shock and vibrations brought onto the element frame from external forces. Mats that can be used in this invention are known in the art.

    [0054] A single mat can cover substantially all of the four sides of a monolith. At least a majority of each of the four sides of a monolith can be covered by a mat. A single mat can cover substantially all of the four sides of a monolith. One or more pieces of mat can surround all, or almost all, of the monolith. The mat can be in the form of strips and the strips can surround only a portion of the monolith.

    [0055] At least a majority of the area of at least one side of a monolith can be covered by one or more mats.

    [0056] At least a majority of the area of each of at least two sides of a monolith can be covered by one or more mats.

    [0057] At least a majority of the area of each of the four sides of a monolith can be covered by one or more mats.

    [0058] The thickness of the mat can be chosen such that the mat fills a gap between the monolith and the frame element and provides cushioning that allows the monolith to withstand a surface pressure of at least approximately 100, preferable approximately 150, more preferably approximately 200 Newtons/mm2 of surface pressure when the element frame is pressed together during assembly.

    [0059] The thickness of one or more mats that are used with a monolith can be determined based upon the size of the monolith onto which the mat is in contact. Monoliths are commercially available in a variety of sizes, with the tolerance of each size monolith being dependent upon the manufacturer. A monolith having a 150 x 150 mm cross-section can have a tolerance of ± 3 mm. By having mats with different thicknesses, monolith having an actual cross-section of 149 x 149 mm would use a mat that is thicker than that used for a monolith having an actual cross-section of 153 x 153 mm. The mat used on the monolith having an actual cross-section of 153 x 153 mm would be thinner than the mat used on a monolith having an actual cross-section of 150 x 150 mm.

    [0060] When the monolith has a nomimal width N and an actual width A, the thickness of a mat used with a monolith having an actual width A equal to the nominal width N is B, and the desired thickness of a mat used with a monolith having an actual width C is:
    1. a) B + (A-C) when C < A;
    2. b) B when C = A; and
    3. c) B - (C-A) when C > A,
    where the actual thickness of the mat used with a monolith having an actual width C is the closest thickness of commercially available mat of the material of width B.

    [0061] Two mats can be used to obtain the desired thickness.

    Locking Element



    [0062] The element frame comprises one or more locking elements where each locking element extends across the inlet end and/or outlet end of the element frame and is connected to opposite walls of the element frame. The locking elements hold the monoliths within the element frame and preclude the movement of opposite walls of the element frame. Figures 5 and 13 each show an element frame containing four monoliths in a 2 by 2 configuration with two locking elements, where each locking element is over the sides of two adjacent monoliths and a gap between the monoliths. In the case of a 1 by 3 monolith element frame, the inlet side and the outlet side each side can each comprise two locking elements, with each of the locking element located over a gap between two adjacent monoliths.

    [0063] The locking elements preferably contain one or more cut-out. The cutout provides for an increase in the number of cells in the monolith that are directly exposed to the flow of exhaust gas when the catalyst module is exposed to exhaust gas from an exhaust gas source. When a locking element does not comprise cut-outs, a larger number of cells in the monoliths are covered by the locking element and this reduces the number of cells that come in direct contact with the exhaust gas. The width of the cut-out locking element is such that the gap between the monoliths is covered. In determining the width of the cut-out, the production tolerance of the widths of the monoliths should be considered. Locking elements located on the element frame on the inlet and outlet face can contain cut outs so that preferably less than 10%, more preferably less than 8%, even more preferably less than 7%, even more preferably less than 6%, most preferably less than 5% of the catalyst cells are not directly exposed the exhaust flow. This leads to lower back pressure and higher utilisation of the catalyst monoliths and therefore higher conversion.

    [0064] When at least one of (a) the walls of an element frame in the inlet and outlet of the element frame (as shown in Figures 6, 7 and 13) and (b) a locking element (as shown in Figures 13 and 14), comprise a cut-out, the amount of conversion of at least one of NH3, NOx, hydrocarbons and carbon monoxide is greater than that of a comparable element frame not having cut-outs.

    [0065] Figure 7 depicts a view of an element frame from an inlet or outlet end with two locking elements attached. Monoliths with their side wall at least partially covered by mats are placed within the walls of the element frame. Each locking element can be connected to opposing walls by welding. The locking element is preferably welded into the element frame under prestress, which minimizes or prevents bulging of the element frame. Bulging of the element frame can lead to lower surface pressure and therefore a higher risk of movement of the monoliths under periodical mechanical stress like shock and vibrations in typical exhaust system conditions.

    Catalyst Module



    [0066] In another aspect of the invention, a catalyst module can comprise an element frame of the first aspect of the invention.

    [0067] Catalyst modules of the invention can be in one of two groups: having a peripheral frame and without a peripheral frame.

    [0068] Catalysts modules with a peripheral frame are known in the art, as shown for example in Figure 1. Catalysts modules with a peripheral frame can have two sides 10, a top 11, a bottom 12 and a number of spaces 15 formed by horizon partitions 13 and vertical partitions 14. An element frame 20 of the first aspect of the invention, containing a plurality of monoliths comprising one or more catalysts, can be inserted within each of the spaces 15. Preferably the frame elements comprise one or more locking elements, as described above.

    [0069] A catalyst module without a peripheral frame can be formed by combining a plurality of element frames to each other by placing frame element adjacent to each other and placing element frames on top of other frame elements and connecting frame elements to adjacent frame elements (See Figure 15). A catalyst module without a peripheral frame is especially useful when only a small number of monoliths are need and the extra weight and complexity in using a catalyst module with a peripheral frame can be avoided.

    [0070] Preferably, the frame elements are connected to adjacent frame elements. Adjacent frame elements can have a sealing element, such as a mat, located between them. Frame element can be connected to adjacent frame elements by welding, adhesives that can withstand temperatures, vibrations and shocks that the catalyst modules are subject to when placed in an exhaust gas stream or mechanical means, such as bolts, nuts, anchors, etc. Preferably, one or more sides of the element frames comprise an extension

    [0071] The element frames in the catalyst module can be arranged to minimize the passage of exhaust gas bypass around the element frames when the catalyst module is installed in an exhaust system.

    [0072] A catalyst module can comprise a plurality of element frames where at least one wall of the element frame comprises an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening and each element frame is connected to one or more elements frames through an extended section on the element frames.

    [0073] A catalyst module comprising a plurality of element frames where at least one wall of the element frame comprises an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening and the element frames are arranged so that there is minimal exhaust bypass around the element frames.

    [0074] A catalyst module can comprise a plurality of element frames where at least two walls of the element frame comprise an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening and the element frames are arranged so that there is minimal exhaust bypass around the element frames

    [0075] A catalyst module can comprise a plurality of element frames where each of the four sides of the element frame comprise an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening and the element frames are arranged so that there is minimal exhaust bypass around the element frames.

    [0076] Each of the frame elements in the catalyst module can be connected to an adjacent frame element when the frame elements comprise an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening.

    [0077] Each of the frame elements in the catalyst module can be connected to all adjacent frame elements when the frame elements comprise an extended section comprising a plurality of openings, where the openings are configured to allow a fastener for joining the element frame to another element frame to pass through the opening.

    [0078] A catalyst module can further comprise a plurality of spaces formed by horizontal partitions and vertical partitions, where a frame element containing a monolith and one or more mats located between each side of the each monolith is present within a space.

    [0079] The catalyst modules can be fixed directly into the exhaust duct or into a larger reaction space, called reactor, into the exhaust stream.

    [0080] An exhaust system can comprise an element frame of the first aspect of the invention.

    [0081] An exhaust system can comprise a catalyst module comprising an element frame of the first aspect of the invention.

    [0082] When the monolith in an element frame, either alone or in a catalyst module, comprises an SCR catalyst, an exhaust system can further comprise a means for injecting a reductant fluid, e.g. a hydrocarbon or nitrogenous reductant or a precursor thereof, into exhaust gas upstream of the .element frame. Preferably the means comprises an injector. One of ordinary skill in the art would realize that ammonia or some other type of reductant is needed when an SCR catalyst is used to convert nitrogen oxides into nitrogen. Such a person would understand how to add the reactant into the exhaust gas and use the SCR catalyst in the system. Such a person would also understand that means for injecting a reductant fluid into exhaust gas upstream are well known in the art.

    [0083] In still another aspect, the invention relates to a method of making an element frame of the first aspect of the invention. A method of making an element frame of the first aspect of the invention comprises wrapping each monolith with a mat, placing the wrapped monolith within the interior of the element frame before the locking element is connected to the element frame and connecting the locking elements to the element frame while the element frame containing the mat wrapped monolith is subject to a compression force. Preferably the element frame is compressed with a pressure of at least approximately 100 Newtons/mm2, preferably at least approximately 150 Newtons/mm2, more preferably at least approximately 200 Newtons/mm2, depending on the nature of the mat.

    [0084] In another aspect, the invention relates to a method of making a catalyst module comprising a plurality of element frames of the first aspect of the invention. The method comprises forming an element frame comprising one or more monoliths, one or more mats and one or more locking elements by wrapping each monolith with a mat, placing the wrapped monolith within the element frame, connecting the one or more locking elements to the element frame while the element frame containing the mat wrapped monolith is subject to a compression force and either (a) connecting one or more element frames to each other to form a catalyst module, or (b) inserting the element frame containing the one or more locking elements into a partition in a frame in a catalyst module. Preferably the element frame is compressed with a pressure of at least approximately 100 Newtons/mm2, preferably at least approximately 150 Newtons/mm2, more preferably at least approximately 200 Newtons/mm2, depending upon the nature of the mat. One of ordinary skill in the art would be familiar with techniques and procedures used to produce a catalyst module having a peripheral frame where the element frames described above can be placed within partitions in the element frame. Such a person would also be familiar with techniques and procedures used to connect element frames comprising an extension, as described above, to each other using mechanical fasteners.

    [0085] A method of treating an exhaust gas comprises passing an exhaust gas through a monolith within an element frame of the first aspect of the invention, where the monolith comprises one or more catalysts effective in reducing the concentration of one or more gases in the exhaust gas.

    [0086] A method of increasing the amount of catalyst contacted with an exhaust gas comprising passing an exhaust gas through an element frame of the first aspect of the invention where the element frame comprises a cut-out.


    Claims

    1. An element frame for holding monoliths containing catalysts in the flow of exhaust gases from a combustion source, the element frame comprising two pairs of opposing walls, wherein the walls form a rectangular or square shape, an interior formed by the walls, an inlet end, an outlet end, at least one locking element, at least one mat and at least one monolith comprising an inlet, an outlet, four sides and at least one catalyst effective in reducing the concentration of one or more gases in the exhaust gas, wherein the at least one mat and the at least one monolith being positioned in the interior of the element frame so that there is at least one mat between the monolith and each adjacent wall, each locking element extending across the inlet end or outlet end of the element frame and being connected to two opposite sides of the element frame, characterized in that one or more of the walls comprises a plurality of protrusions extending into the interior.
     
    2. An element frame according to claim 1, wherein each wall comprises a plurality of protrusions extending into the interior.
     
    3. An element frame according to claim 1 or claim 2, wherein two or more monoliths are present in the interior of the element frame, at least two monoliths are located adjacent to each other, and at least one mat is located between monoliths that are adjacent to each other.
     
    4. An element frame according to any preceding claim, wherein at least two locking elements are located on the inlet end of the element frame and at least two locking elements are located on the outlet end of the element frame.
     
    5. An element frame according to any preceding claim, wherein, when the element frame comprises at least two monoliths, a space is located between adjacent monoliths and at least one of the locking elements is located over, and preferably centered on, space between two monoliths.
     
    6. An element frame according to any preceding claim, wherein a thickness of the mat is chosen such that the mat fills a gap between the monolith and the frame element and provides cushioning that allows the monolith to withstand a surface pressure of at least 100 Newtons/mm2 of surface pressure when the element frame is pressed together during assembly.
     
    7. An element frame according to any preceding claim, wherein the monolith has a nominal width N and an actual width A, the thickness of a mat used with a monolith having an actual width A equal to the nominal width N is B, and the desired thickness of a mat used with a monolith having an actual width C is:

    a) B + (A-C) when C < A;

    b) B when C = A; and

    c) B - (C-A) when C > A,

    wherein the actual thickness of the mat used with a monolith having an actual width C is the closest thickness of commercially available mat of the material of width B.
     
    8. An element frame according to any preceding claim, wherein the monolith comprises an SCR catalyst; an oxidation catalyst; or a filter.
     
    9. An element frame according to any preceding claim comprising a plurality of monoliths and two or more monoliths are positioned so that the outlet of one monolith is adjacent to the inlet of another monolith and a flow of exhaust gas passes sequentially through at least two monoliths.
     
    10. An element frame according to claim 9, wherein the two or more monoliths positioned so that the outlet of one monolith is adjacent to the inlet of another monolith contain catalysts having the same or different functionality.
     
    11. A catalyst module comprising a plurality of element frames according to any preceding claim.
     
    12. An exhaust system comprising an element frame according to any of claims 1 to 10 or a catalyst module according to claim 11.
     
    13. A method of making an element frame according to any of claims 1 to 10, the method comprising wrapping each monolith with a mat, placing the wrapped monolith within the interior of the element frame before the locking element is connected to the element frame and connecting the locking elements to the element frame while the element frame containing the mat wrapped monolith is subject to a compression force.
     
    14. A method of making a catalyst module according to claim 11, the method comprising forming an element frame according to the method of claim 13 and either: (a) connecting one or more element frames to each other to form a catalyst module; or (b) inserting the element frame containing the one or more locking elements into a partition in a frame in a catalyst module.
     
    15. A method of treating an exhaust gas, the method comprising passing an exhaust gas through a catalysed monolith within an element frame according to any of claims 1 to 10.
     


    Ansprüche

    1. Elementrahmen zum Halten von Monolithen, die Katalysatoren enthalten, in der Strömung von Abgasen von einer Verbrennungsquelle, wobei der Elementrahmen zwei Paare von gegenüberliegenden Wänden, wobei die Wände eine rechteckige oder quadratische Form bilden, einen Innenraum, der von den Wänden gebildet wird, ein Eintrittsende, ein Austrittsende, mindestens ein Arretierelement, mindestens eine Matte und mindestens einen Monolithen umfasst, der einen Eintritt, einen Austritt, vier Seiten und mindestens einen Katalysator umfasst, der beim Senken der Konzentration von einem oder mehreren Gasen in dem Abgas wirksam ist, wobei die mindestens eine Matte und der mindestens eine Monolith im Innenraum des Elementrahmens positioniert sind, so dass mindestens eine Matte zwischen dem Monolithen und jeder benachbarten Wand vorliegt, wobei jedes Arretierelement sich über das Eintrittsende oder das Austrittsende des Elementrahmens erstreckt und mit zwei gegenüberliegenden Seiten des Elementrahmens verbunden ist, dadurch gekennzeichnet, dass eine oder mehrere der Wände eine Vielzahl von Vorsprüngen umfassen, die sich in den Innenraum erstrecken.
     
    2. Elementrahmen nach Anspruch 1, wobei jede Wand eine Vielzahl von Vorsprüngen umfasst, die sich in den Innenraum erstrecken.
     
    3. Elementrahmen nach Anspruch 1 oder 2, wobei zwei oder mehr Monolithen im Innenraum des Elementrahmens vorliegen, mindestens zwei Monolithen zueinander benachbart angeordnet sind und mindestens eine Matte zwischen Monolithen angeordnet ist, die zueinander benachbart sind.
     
    4. Elementrahmen nach einem vorhergehenden Anspruch, wobei mindestens zwei Arretierelemente an dem Eintrittsende des Elementrahmens angeordnet sind und mindestens zwei Arretierelemente an dem Austrittsende des Elementrahmens angeordnet sind.
     
    5. Elementrahmen nach einem vorhergehenden Anspruch, wobei, wenn der Elementrahmen mindestens zwei Monolithen umfasst, ein Raum zwischen benachbarten Monolithen angeordnet ist und mindestens eines der Arretierelemente über und vorzugsweise zentriert auf einem Raum zwischen zwei Monolithen angeordnet ist.
     
    6. Elementrahmen nach einem vorhergehenden Anspruch, wobei eine Dicke der Matte derart gewählt ist, dass die Matte einen Spalt zwischen dem Monolithen und dem Rahmenelement füllt und eine Polsterung bereitstellt, die dem Monolithen ermöglicht, einem Oberflächendruck von mindestens 100 Newton/mm2 Oberflächendruck standzuhalten, wenn der Elementrahmen während der Montage zusammengedrückt wird.
     
    7. Elementrahmen nach einem vorhergehenden Anspruch, wobei der Monolith eine Nennbreite N und eine tatsächliche Breite A aufweist, die Dicke einer Matte, die mit einem Monolithen mit einer tatsächlichen Breite A, die gleich der Nennbreite N ist, verwendet wird, B ist und die gewünschte Dicke einer Matte, die mit einem Monolithen mit einer tatsächlichen Breite C verwendet wird, Folgendes ist:

    a) B + (A - C), wenn C < A;

    b) B, wenn C = A; und

    c) B - (C - A), wenn C > A,

    wobei die tatsächliche Dicke der Matte, die mit einem Monolithen mit einer tatsächlichen Breite C verwendet wird, die nächste Dicke einer im Handel erhältlichen Matte des Materials mit der Breite B ist.
     
    8. Elementrahmen nach einem vorhergehenden Anspruch, wobei der Monolith einen SCR-Katalysator; einen Oxidationskatalysator oder einen Filter umfasst.
     
    9. Elementrahmen nach einem vorhergehenden Anspruch, der eine Vielzahl von Monolithen umfasst, und wobei zwei oder mehr Monolithen positioniert sind, so dass der Austritt eines Monolithen benachbart zu dem Eintritt eines anderen Monolithen ist und eine Strömung von Abgasen nacheinander durch mindestens zwei Monolithen strömt.
     
    10. Elementrahmen nach Anspruch 9, wobei die zwei oder mehr Monolithen, die positioniert sind, so dass der Austritt eines Monolithen benachbart zu dem Eintritt eines anderen Monolithen ist, Katalysatoren mit derselben Funktionalität oder unterschiedlichen Funktionalitäten enthalten.
     
    11. Katalysatormodul, das eine Vielzahl von Elementrahmen nach einem vorhergehenden Anspruch umfasst.
     
    12. Abgasanlage, die einen Elementrahmen nach einem der Ansprüche 1 bis 10 oder ein Katalysatormodul nach Anspruch 11 umfasst.
     
    13. Verfahren zur Herstellung eines Elementrahmens nach einem der Ansprüche 1 bis 10, wobei das Verfahren ein Umwickeln jedes Monolithen mit einer Matte, ein Platzieren des umwickelten Monolithen innerhalb des Innenraums des Elementrahmens, bevor das Arretierelement mit dem Elementrahmen verbunden wird, und ein Verbinden der Arretierelemente mit dem Elementrahmen, während der Elementrahmen, der den mit der Matte umwickelten Monolithen enthält, einer Kompressionskraft unterworfen wird, umfasst.
     
    14. Verfahren zur Herstellung eines Katalysatormoduls nach Anspruch 11, wobei das Verfahren ein Bilden eines Elementrahmens gemäß dem Verfahren nach Anspruch 13 und entweder: (a) ein Verbinden von einem oder mehreren Elementrahmen miteinander, um ein Katalysatormodul zu bilden; oder (b) ein Einsetzen des Elementrahmens, der das eine oder die mehreren Arretierelemente enthält, in eine Unterteilung in einem Rahmen in einem Katalysatormodul umfasst.
     
    15. Verfahren zur Reinigung eines Abgases, wobei das Verfahren ein Leiten eines Abgases durch einen katalysierten Monolithen innerhalb eines Elementrahmens nach einem der Ansprüche 1 bis 10 umfasst.
     


    Revendications

    1. Cadre élémentaire pour maintenir des monolithes contenant des catalyseurs dans le flux de gaz d'échappement issus d'une source de combustion, le cadre élémentaire comprenant deux paires de parois opposées, dans lequel les parois forment une forme rectangulaire ou carrée, un intérieur formé par les parois, une extrémité d'entrée, une extrémité de sortie, au moins un élément de verrouillage, au moins un tapis et au moins un monolithe comprenant une entrée, une sortie, quatre côtés et au moins un catalyseur efficace pour réduire la concentration d'un ou de plusieurs gaz dans le gaz d'échappement, dans lequel l'au moins un tapis et l'au moins un monolithe sont positionnés dans l'intérieur du cadre élémentaire de sorte qu'il y ait au moins un tapis entre le monolithe et chaque paroi adjacente, chaque élément de verrouillage s'étendant en travers de l'extrémité d'entrée ou de l'extrémité de sortie du cadre élémentaire et étant raccordé à deux côtés opposés du cadre élémentaire, caractérisé en ce qu'une ou plusieurs des parois comprennent une pluralité de saillies s'étendant jusque dans l'intérieur.
     
    2. Cadre élémentaire selon la revendication 1, dans lequel chaque paroi comprend une pluralité de saillies s'étendant jusque dans l'intérieur.
     
    3. Cadre élémentaire selon la revendication 1 ou la revendication 2, dans lequel deux monolithes ou plus sont présents dans l'intérieur du cadre élémentaire, au moins deux monolithes sont situés de manière adjacente l'un à l'autre, et au moins un tapis est situé entre des monolithes qui sont adjacents l'un à l'autre.
     
    4. Cadre élémentaire selon l'une quelconque des revendications précédentes, dans lequel au moins deux éléments de verrouillage sont situés sur l'extrémité d'entrée du cadre élémentaire et au moins deux éléments de verrouillage sont situés sur l'extrémité de sortie du cadre élémentaire.
     
    5. Cadre élémentaire selon l'une quelconque des revendications précédentes, dans lequel, lorsque le cadre élémentaire comprend au moins deux monolithes, un espace est situé entre des monolithes adjacents et au moins l'un des éléments de verrouillage est situé pardessus, et de préférence de manière centrée sur, l'espace entre deux monolithes.
     
    6. Cadre élémentaire selon l'une quelconque des revendications précédentes, dans lequel une épaisseur du tapis est choisie de telle sorte que le tapis remplisse un interstice entre le monolithe et l'élément de cadre et fournisse un matelassage qui permette au monolithe de résister à une pression de surface d'au moins 100 Newtons/mm2 de pression de surface lorsque le cadre élémentaire est comprimé durant l'assemblage.
     
    7. Cadre élémentaire selon l'une quelconque des revendications précédentes, dans lequel le monolithe a une largeur nominale N et une largeur réelle A, l'épaisseur d'un tapis utilisé avec un monolithe ayant une largeur réelle A égale à la largeur nominale N est B, et l'épaisseur souhaitée d'un tapis utilisé avec un monolithe ayant une largeur réelle C est :

    a) B + (A-C) lorsque C < A ;

    b) B lorsque C = A ; et

    c) B - (C-A) lorsque C > A,

    dans lequel l'épaisseur réelle du tapis utilisé avec un monolithe ayant une largeur réelle C est l'épaisseur la plus proche d'un tapis disponible dans le commerce du matériau de largeur B.
     
    8. Cadre élémentaire selon l'une quelconque des revendications précédentes, dans lequel le monolithe comprend un catalyseur de RCS ; un catalyseur d'oxydation ; ou un filtre.
     
    9. Cadre élémentaire selon l'une quelconque des revendications précédentes comprenant une pluralité de monolithes et deux monolithes ou plus sont positionnés de sorte que la sortie d'un monolithe soit adjacente à l'entrée d'un autre monolithe et un flux de gaz d'échappement traverse séquentiellement au moins deux monolithes.
     
    10. Cadre élémentaire selon la revendication 9, dans lequel les deux monolithes ou plus positionnés de sorte que la sortie d'un monolithe soit adjacente à l'entrée d'un autre monolithe contiennent des catalyseurs ayant une fonctionnalité identique ou différente.
     
    11. Module de catalyseur comprenant une pluralité de cadres élémentaires selon l'une quelconque des revendications précédentes.
     
    12. Système d'échappement comprenant un cadre élémentaire selon l'une quelconque des revendications 1 à 10 ou un module de catalyseur selon la revendication 11.
     
    13. Méthode de réalisation d'un cadre élémentaire selon l'une quelconque des revendications 1 à 10, la méthode comprenant le fait d'envelopper chaque monolithe avec un tapis, le fait de placer le monolithe enveloppé au sein de l'intérieur du cadre élémentaire avant que l'élément de verrouillage soit raccordé au cadre élémentaire et le fait de raccorder les éléments de verrouillage au cadre élémentaire tandis que le cadre élémentaire contenant le monolithe enveloppé d'un tapis est soumis à une force de compression.
     
    14. Méthode de réalisation d'un module de catalyseur selon la revendication 11, la méthode comprenant le fait de former un cadre élémentaire selon la méthode selon la revendication 13 et soit : (a) le fait de raccorder un ou plusieurs cadres élémentaires les uns aux autres afin de former un module de catalyseur ; ou (b) le fait d'insérer le cadre élémentaire contenant les un ou plusieurs éléments de verrouillage à l'intérieur d'une cloison dans un cadre dans un module de catalyseur.
     
    15. Méthode de traitement d'un gaz d'échappement, la méthode comprenant le fait de faire passer un gaz d'échappement à travers un monolithe catalysé au sein d'un cadre élémentaire selon l'une quelconque des revendications 1 à 10.
     




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    Cited references

    REFERENCES CITED IN THE DESCRIPTION



    This list of references cited by the applicant is for the reader's convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.

    Patent documents cited in the description