(19)
(11)EP 3 472 255 B1

(12)EUROPEAN PATENT SPECIFICATION

(45)Mention of the grant of the patent:
04.12.2019 Bulletin 2019/49

(21)Application number: 17734652.5

(22)Date of filing:  15.06.2017
(51)International Patent Classification (IPC): 
C09K 3/18(2006.01)
C08K 3/26(2006.01)
C08L 83/04(2006.01)
C08K 3/16(2006.01)
C08K 5/098(2006.01)
C08L 95/00(2006.01)
(86)International application number:
PCT/EP2017/064661
(87)International publication number:
WO 2017/220421 (28.12.2017 Gazette  2017/52)

(54)

ANTI-ICING ADDITIVE COMPOSITION FOR BITUMINOUS CONGLOMERATES

ENTEISUNGSADDITIVZUSAMMENSETZUNG FÜR BITUMINÖSE KONGLOMERATE

COMPOSITION D'ADDITIF ANTI-GIVRAGE DESTINÉE À DES CONGLOMÉRATS BITUMINEUX


(84)Designated Contracting States:
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
Designated Extension States:
BA ME
Designated Validation States:
MA MD

(30)Priority: 20.06.2016 IT UA20164510

(43)Date of publication of application:
24.04.2019 Bulletin 2019/17

(73)Proprietor: Iterchimica S.r.l.
24040 Suisio (BG) (IT)

(72)Inventors:
  • BERTULETTI, Elisa
    24040 Suisio (BG) (IT)
  • BARUZZI, Piero
    24040 Suisio (BG) (IT)
  • GIANNATTASIO, Federica
    24040 Suisio (BG) (IT)

(74)Representative: Ferreccio, Rinaldo 
Botti & Ferrari S.r.l. Via Cappellini, 11
20124 Milano
20124 Milano (IT)


(56)References cited: : 
EP-A1- 0 506 984
WO-A1-2007/096690
EP-A2- 0 332 803
US-A1- 2003 070 578
  
  • Anonymous: "WINTERPAVE; SAFETY DATA SHEET", , 6 May 2014 (2014-05-06), pages 1-8, XP055349429, Retrieved from the Internet: URL:https://www.cargill.com/doc/1432076882 120/winterpave-sds.pdf [retrieved on 2017-02-24]
  • Anonymous: "WINTERPAVE AD | ANTI-FREEZE PRODUCT FOR BITUMINOUS MIXES", , 5 August 2016 (2016-08-05), pages 1-3, XP055349588, Bergamo, Italy Retrieved from the Internet: URL:https://www.cargill.com/doc/1432076882 176/winterpave-tds.pdf [retrieved on 2017-02-27]
  
Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).


Description

Field of Application



[0001] The present invention refers to the technical sector of the production of bituminous conglomerates for road paving.

[0002] In particular, the invention refers to an additive composition for bituminous conglomerates, which allows to prevent, reduce or delay the formation of ice on the surface of the road paving.

Prior art



[0003] It is well known that during the winter season the tire adhesion to the paved road surface can be greatly reduced due to the formation of ice on this surface, with subsequent risk of slipping, loss of control and reduction of braking capacity of the vehicles.

[0004] It is also known that the measure conventionally adopted to reduce the aforementioned risks lies in spreading beforehand onto the road surface salts, generally sodium chloride, which lower the freezing point of water so as to prevent ice formation and to avoid the adhesion of snow to the road paving.

[0005] It is clear, however, that the salt spreading must be carried out promptly before the beginning of a snowfall or a sharp drop in temperature under high atmospheric humidity conditions, and this does not always happen, or anyway not always over the entire length of the road.

[0006] In some cases, electric resistances have been inserted in road pavements, but this entails considerable production and management costs and reduces the resistance of the road surface.

[0007] It has also been proposed to pave the roads in areas with high risk of ice formation with special bituminous conglomerates incorporating additives adapted to prevent or reduce ice formation.

[0008] An example in this sense is provided in patent application EP 0 332 803, which refers to an anti-icing road cover obtained by incorporating into a bituminous conglomerate 3 to 5% of a granular mixture comprising an alkali chloride, a thermoplastic material and an additive such as talc, cement or polyurethane powder.

[0009] Another example is given in EP 0 506 984, which describes an anti-icing composition to be incorporated into a bituminous conglomerate or to be directly applied on a road surface, comprising 5-95% of an alkali metal and/or alkaline earth metal chloride and 5-15% of an alkaline metal alkene siliconate.

[0010] A further example is provided by patent application WO 2007/096690, which describes an anti-icing composition to be incorporated into a bituminous conglomerate, comprising an alkaline and/or alkaline earth salt with a molecular weight lower than 200 Da, for example a sodium or calcium formate or acetate, and at least one surfactant, which is preferably a polyamine alkylamide, and optionally also a siloxane.

[0011] The Applicant herself has been producing and marketing for several years an anti-icing composition, called Winterpav, suitable for incorporation into bituminous conglomerates, comprising sodium chloride, calcium chloride, sodium formate and calcium carbonate. Such composition has proven to be very effective in preventing or at least significantly reducing the formation of ice on the surface of the road paving that incorporates it and its anti-ice effect is maintained for many months.

[0012] Furthermore, it has been verified that the presence of such composition in a conglomerate for road paving in quantities up to 5% by weight of the conglomerate does not lead to any substantial modification of the physical-mechanical properties of the road paving obtained with it.

[0013] Such anti-icing composition, however, has some drawbacks in relation to its handling and storage. Indeed, this is a composition of solid compounds in the form of powder, with a variable particle size, where very fine particles are present too, which can lead to potential risks of inhalation by the operators who use it. Also, some of the components, particularly calcium chloride and sodium chloride, are highly hygroscopic and this can lead to packing phenomena during storage.

[0014] In the light of the above-discussed prior art and above all of the drawbacks highlighted with reference to the product Winterpav, the problem underlying the present invention was that of providing an anti-icing composition suitable to be incorporated into bituminous conglomerates for road paving, having the same effectiveness of the aforementioned product and being at the same time free from the drawbacks outlined above.

Summary of the invention



[0015] Such a problem has been solved by providing an anti-icing composition suitable to be incorporated into bituminous conglomerates for road paving, comprising an alkali metal chloride, an alkaline-earth metal carbonate, an alkali or alkaline-earth metal formate, a polysiloxane and optionally an alkaline-earth metal chloride, wherein the polysiloxane is contained in an amount between 0.5 and 2.0% by weight on the total weight of the composition.

[0016] Preferably the composition comprises an alkali metal chloride and an alkaline-earth metal chloride and conveniently the alkali metal chloride is sodium chloride and the alkaline-earth metal chloride is calcium chloride.

[0017] Preferably, the alkaline-earth metal carbonate is calcium carbonate.

[0018] Preferably the composition comprises an alkali metal formate, conveniently sodium formate.

[0019] The polysiloxane preferably consists of a polydimethylsiloxane or dimethicone, which preferably has a viscosity of between 300 and 400 mm2/s, conveniently between 325 e 375 mm2/s at 25°C.

[0020] A particularly preferred anti-icing composition is formed by the following components, expressed in percentages by weight on the total weight of the composition:
sodium chloride 60-84
sodium formate 5-15
calcium chloride 5-15
calcium carbonate 2-8
polysiloxane 0.5-2.0


[0021] All the percentages indicated in the text of the present application are to be understood as percentages weight/weight, unless otherwise specified.

[0022] With the anti-icing composition according to the invention, a bituminous formulation intended to be used as a component of a bituminous conglomerate can be prepared.

[0023] The bituminous formulation prepared from the anti-icing composition according to the present invention generally comprises from 20 to 70% of said anti-icing composition and from 30 to 80% bitumen.

[0024] Preferably, this bituminous formulation comprises from 30 to 60% of said anti-icing composition and from 40 to 70% of bitumen.

[0025] The bituminous formulation can in turn be used to prepare a bituminous conglomerate adapted to make anti-icing road paving. Such bituminous conglomerate includes aggregates, including, for example, inert, inorganic materials such as crushed stone materials, granular and crushed slag, artificial aggregates produced, for example, by high temperature melting of certain minerals or rocks (e.g. bauxite or certain clays), fillers and, where appropriate, polymeric materials in granular form, in addition to the above-mentioned bituminous formulation, which is generally contained in amounts from 3 to 10% by weight on the weight of the aggregates.

[0026] Alternatively, the anti-icing composition according to the invention can be directly added to a bituminous conglomerate comprising aggregates, fillers and bitumen and mixed with it in such quantity that the final bituminous conglomerate comprises from 2% to 6%, preferably from 3% to 5%, by weight of said composition on the weight of the aggregates.

[0027] The present invention thus relates also to a bituminous conglomerate adapted to provide an anti-icing road paving, comprising aggregates, fillers and bitumen and from 2 to 6%, preferably from 3 to 5%, by weight of the weight of the aggregates, of the aforementioned anti-icing composition, as well as to a bituminous conglomerate adapted to provide an anti-icing road paving comprising aggregates, fillers and from 3 to 10%, by weight of weight of the aggregates, of the aforementioned anti-icing bituminous formulation.

[0028] In one of its further aspects, the present invention refers to a method for producing a bituminous conglomerate adapted to provide an anti-icing road paving, comprising the step of adding, under stirring and at a temperature varying from 130°C to 200°C, bitumen and an anti-icing composition as described above to a mixture of aggregates and fillers.

[0029] In another aspect, the present invention refers to a method for producing a bituminous conglomerate adapted to provide an anti-icing road paving, comprising the step of adding, under stirring and at a temperature varying from 130°C to 200°C, to a mixture of aggregates and fillers, an anti-icing bituminous formulation as described above.

[0030] Finally, the present invention relates to a method for producing an anti-icing composition as described above, which comprises the steps of mixing the alkali metal chloride, the alkaline-earth metal carbonate, the alkali or alkaline-earth metal formate and optionally the alkaline-earth metal chloride to obtain a mixture in the form of a homogeneous powder and adding the polysiloxane dispersed in a finely divided form into said mixture in the form of a homogeneous powder.

[0031] This way, the polysiloxane uniformly coats the powder granules, including the smallest ones, and prevents them from spreading in the air during handling and transport operations of the anti-icing composition according to the invention, thus preventing any risk of inhalation by the people involved in such operations.

[0032] Preferably, the polysiloxane addition step is performed by spraying the polysiloxane by means of a spray device onto the mixture in the form of homogeneous powder kept under stirring in a mixer, preferably a screw mixer.

[0033] When added to bituminous conglomerates for road paving, the anti-icing composition according to the present invention allows to obtain a road paving that can prevent or at least significantly reduce the formation of ice on the surface, without any substantial change of the physical-mechanical properties with respect to a road paving obtained from an equal bituminous conglomerate without the addition of anti-ice composition.

[0034] The anti-icing effect conferred on a road pavement by the anti-icing composition incorporated in the bituminous conglomerate remains substantially unchanged for at least two months, typically for about 12 months, then it gradually decreases, being, however, still useful to provide a good protection against ice formation for another 24 months.

[0035] Moreover, the composition according to the present invention is easy and safe to handle, because it is free from fine powders, which might be inhaled by the operators who use it.

[0036] The composition according to the present invention can moreover be stored for long periods of time, even for many months, without risks of packing, and maintains its flowability properties unaltered over time, which properties are important when adding this composition to the bituminous conglomerate, in order to ensure its accurate and reproducible dosing.

[0037] The characteristics and the advantages of the present invention will be further highlighted by some embodiments thereof, which are hereinafter exposed by way of illustration and not of limitation, with reference also the annexed figures.

Brief description of the figures



[0038] 

Figure 1 is a photograph of a slab made in laboratory with the bituminous conglomerate A of Example 6, containing the anti-icing composition according to Example 1.

Figure 2 is a photograph of a slab made in laboratory with the comparison bituminous conglomerate B of Example 6, not containing the anti-icing composition according to the present invention.


Detailed description



[0039] Hereinafter are some examples of anti-icing compositions according to the present invention, which have been prepared and tested with favorable results in relation to their effect of ice formation prevention.

Example 1



[0040] 
Sodium chloride 70%
Calcium chloride 13%
Sodium formate 11%
Calcium carbonate 5%
Dimethicone with a viscosity of 350 mm2/s at 25°C 1%

Example 2



[0041] 
Sodium chloride 80%
Sodium formate 12%
Calcium carbonate 6%
Dimethicone with a viscosity of 300 mm2/s at 25°C 2%

Example 3



[0042] 
Sodium chloride 60%
Calcium chloride 15%
Sodium formate 15%
Calcium carbonate 8%
Dimethicone with a viscosity of 400 mm2/s at 25°C 2%

Example 4



[0043] 
Sodium chloride 84%
Calcium chloride 5%
Sodium formate 5%
Calcium carbonate 5.5%
Dimethicone with a viscosity of 350 mm2/s at 25°C 0.5%


[0044] The compositions of Examples 1 to 4 were prepared by mixing the various salts listed, except calcium carbonate, in the form of coarse powders inside a screw mixer and uniformly spraying dimethicone over them by a spray gun, while they are kept under stirring. After the addition of dimethicone, the powdered calcium carbonate is added under stirring and stirring is continued until a homogeneous mixture is obtained.

Example 5 (comparative)



[0045] 
Sodium chloride 71%
Calcium chloride 13%
Sodium formate 11%
Calcium carbonate 5%


[0046] This composition is prepared by dosing the ingredients in the form of coarse powder in a screw mixer under stirring and stirring is continued until a homogeneous mixture is obtained.

Example 6



[0047] Using the composition according to Example 1 three slabs of bituminous conglomerate containing such composition in the proportions indicated in the following Table 1 and having a diameter of 100 mm and a thickness of about 25 mm were prepared in the laboratory. Three slabs of bituminous conglomerate with the same composition but not containing the above composition were also prepared.
Table 1
 Bituminous conglomerate A, containing the composition of example 1Bituminous conglomerater B, without the composition of example 1
Materials Parts by weight Parts by weight
Inerts 6/12 20 20
Inerts 3/8 50 50
Sand 0-4 25 25
Filler (CaCO3) 5 5
Bitumen 50/70 5.5 5.5
Composition of example 1 4 0
Total 109.5 105.5


[0048] The bituminous conglomerate is prepared in the laboratory by bringing the aggregates (inerts, sand) and the filler to a temperature of 180°C inside a 5 liter planetary mixer and adding to them, under stirring, the bitumen heated at 150°C and, in the case of bituminous conglomerate A, also the composition of Example 1, both at room temperature, after which stirring is continued for 5 minutes.

[0049] The bituminous conglomerate is then discharges from the planetary mixer, dosed in quantities of about 300 g inside a porcelain container and inserted into a rotary press (30 cycles) kept at a temperature of 150°C, applying a pressure of about 600 kPa to form respective slabs with a diameter of 100 mm, with a thickness of about 30 mm and a weight of about 100 g.

[0050] The three slabs of conglomerate A and the three slabs of conglomerate B are then placed on respective non-metallic discs and introduced into a refrigerator at a temperature of -5°C for at least 2 hours, so as to obtain the thermal normalization of the samples. Subsequently the slabs are sprayed onto their surface with water at a temperature of 4°C (which simulates a situation of rain mixed with snow), 6 sprays (about 8-9 ml) and kept in the refrigerator at -5°C for another 12 hours, afterwards a visual examination of the slabs is carried out to determine the possible presence of frost or ice on their surface.

[0051] In case neither frost nor ice is formed, the slab is brought back to room temperature, the excess water is removed, the disc is cleaned, the slab is thrice immersed in water inside a becker and the procedure of normalization in refrigerator at -5°C, spraying with water at 4°C and storage in refrigerator at -5°C for 12 hours is repeated, eventually verifying the possible formation of ice or frost.

[0052] Figures 1 and 2 show respective photos of a slab of the bituminous conglomerate A and of a slab of the bituminous conglomerate B. In particular, Figure 2 shows a slab of bituminous conglomerate B at the end of only one cycle of normalization, water spraying and storage at - 5°C for 12 hours, while Figure 1 shows a slab of conglomerate A at the end of 5 cycles as above with the interposition of immersions in water as described above between each cycle. It is quite obvious that there is no ice in slab A while a layer of ice is clearly visible on the surface of slab B, formed at the end of the first step of the procedure described above.

[0053] This shows that the presence of the anti-icing composition according to example 1 of the present invention inside the bituminous conglomerate A has completely prevented the formation of ice, wherein conglomerate B, in every single way equal to the conglomerate A except for the absence of the composition according to Example 1, did not show any anti-ice effect.

Example 7



[0054] The absorption of moisture from the atmosphere by the composition according to Example 1 was verified and compared with the composition according to example 5, which is free of dimethicone.

[0055] The verification was conducted by depositing a carefully measured quantity of each one of the above-mentioned compositions on four respective Petri glass plates and leaving these plates exposed to the atmospheric air at a temperature of about 20°C for the periods indicated in the following Table 2. At the end of each period the quantity of humidity absorbed was determined (humidity content %) by means of a thermobalance at 120°C for 20 minutes.
Table 2
TimeExample 1 (humidity content %)Example 5 (humidity content %)
1 day 1.02 2.3
30 days 1.7 4.6
60 days 2.0 9.5
90 days 1.8 9.3


[0056] From the results presented in Table 2 it clearly emerges that the presence of a polysiloxane in the composition according to the present invention gives it a high degree of protection against atmospheric humidity, which results in the above-noted advantage of avoiding any packing phenomenon and any reduction of its flowability properties.

Example 8



[0057] It has been verified whether the addition of the composition according to the present invention to a bituminous conglomerate would cause some alteration of the physical-mechanical properties of a wear layer made with such a conglomerate.

[0058] For this purpose, specimens of bituminous conglomerate were made according to a SMA curve as shown in Table 3 below.
Table 3
 Bituminous conglomerate SMA1, containing the composition of Example 1Bituminous conglomerate SMA2, without the composition of Example 1
Materials Parts by weight Parts by weight
Inerts 6/12 10 10
Inerts 3/6 60 60
Sand 0-4 20 20
Filler (CaCO3) 10 10
Plastomers and microfibers 0.6 0.6
Bitumen 50/70 6.5 6.5
Composition of example 1 4 0
Total 111.1 107.1


[0059] The specimens were prepared by depositing about 1.2 kg of bituminous conglomerate in a cylindrical container kept at 150°C for at least 2 hours and pressing it in a rotary press to form a respective cylindrical specimen, with a diameter of 100 mm and a height of about 65 mm. For each specimen, the physical-mechanical determinations set out in Table 4 were performed:
Table 4
 Conglomerate SMA1Conglomerate SMA2Technical specifications
Residual voids (%) at 10 cycles 12,5 10,5 9-13
Residual voids (%) at 120 cycles 4.6 3.8 2-5
Residual voids (%) at 200 cycles 3.5 1.1 ≥1
GMM1 at 200 cycles (Maximal Specific Gravity) (kg/m3) 2449 2384 -
GMB2 at 200 cycles (Bulk Specific Gravity) (kg/m3) 2365 2358 -
ITS3 at 200 cycles 25°C (N/mm2) 1.30 1.33 1.0-1.80
CTI4 at 200 cycles 25°C (N/mm2) 112 123 ≥85
1 GMM is the theoretical maximum specific gravity (at zero air voids) of the bituminous conglomerate, measured according to AASHTO T 209 standard.
2 GMB is the density of the conglomerate with the voids (bulk specific gravity), measured according to AASHTO T 166 standard.
3 ITS indicates the tensile strength evaluated according to UNI EN 12697-23 standard at a temperature of 25°C.
4 CTI indicates the indirect tensile strength coefficient evaluated according to UNI EN 12697-23 standard at a temperature of 25 °C.


[0060] The percentage of residual voids at 10 cycles simulates the compacting of the bituminous conglomerate after the paver has been applied; the 120-cycle residual voids percentage simulates the compacting of the bituminous conglomerate after rolling (i.e. after the paved road has been opened to traffic) and the percentage of voids at 200 cycles simulates the compacting of the bituminous conglomerate towards the end of the service life of the asphalt pavement (10-15 years).

[0061] As it can be noted from the data set out in Table 3, the wear layer made with the SMA1 conglomerate, containing the anti-icing composition according to Example 1, showed GMM and GMB values fully comparable to those of the SMA2 conglomerate, free of such anti-icing composition, and excellent values of tensile strength and indirect tensile strength coefficient.

[0062] This means that the addition of the anti-icing composition according to the present invention to a bituminous conglomerate for road paving provides excellent protection against ice formation on the surface without significantly altering the physical-mechanical properties of the road pavement obtained with it.

Example 9



[0063] A comparison test was performed between a composition according to the present invention and the composition according to Example 5, free of dimethicone and corresponding to the known product Winterpav.

[0064] For this purpose, specimens of bituminous conglomerate were made according to a SMA curve as shown in Table 5 below.
Table 5
 Bituminous conglomerate SMA1, containing the composition of Example 1Bituminous conglomerate SMA5, containing the composition of Example 5
Materials Parts by weight Parts by weight
Inerts 6/12 10 10
Inerts 3/6 60 60
Sand 0-4 20 20
Filler (CaCO3) 10 10
Plastomers and microfibers 0.6 0.6
Bitumen 50/70 6.5 6.5
Composition of example 1 4 0
Composition of example 5 0 4
Total 111.1 111.1


[0065] The specimens were prepared by depositing about 1.2 kg of bituminous conglomerate in a cylindric container kept at 150°C for at least 2 hours and by pressing it in a rotary press to form a respective specimen of cylindrical form, with a diameter of 100 mm and a height of about 65 mm. For each sample, the physical-mechanical determinations set out in Table 6 were performed:
Table 6
 Conglomerate SMA1Conglomerate SMA5Technical specifications
Residual voids (%) at 10 cycles 12.3 12.4 9-13
Residual voids (%) at 120 cycles 4.5 2.0 2-5
Residual voids (%) at 200 cycles 3.1 1.0 ≥1
GMM1 at 200 cycles (Maximal Specific Gravity) (kg/m3) 2399 2420 -
GMB2 at 200 cycles (Bulk Specific Gravity) (kg/m3) 2301 2424 -
ITS3 at 200 cycles 25°C (N/mm2) 1.28 1.60 1.0-1.80
CTI4 at 200 cycles 25°C (N/mm2) 108 134 ≥85
1 GMM is the theoretical maximum specific gravity (at zero air voids) of the bituminous conglomerate, measured according to AASHTO T 209 standard.
2 GMB is the density of the conglomerate with the voids (bulk specific gravity), measured according to AASHTO T 166 standard.
3 ITS indicates the tensile strength evaluated according to UNI EN 12697-23 standard at a temperature of 25°C.
4 CTI indicates the indirect tensile strength coefficient evaluated according to UNI EN 12697-23 standard at a temperature of 25 °C.


[0066] As it can be noted from the data set out in Table 6, the wear layer made with the SMA1 conglomerate, containing the anti-icing composition according to Example 1, showed GMM and GMB values fully comparable to those of the SMA5 conglomerate containing the anti-icing composition according to Example 5, and excellent values of tensile strength and indirect tensile strength coefficient.

[0067] This means that the presence of polysiloxane within the anti-icing composition according to the present invention has allowed to solve the above mentioned technical problem of overcoming the disadvantages associated with the product Winterpav (risk of inhalation of the very fine powder particles contained therein and packing phenomena due to hygroscopicity), ensuring the same anti-icing effect and without jeopardizing in any way the physical-mechanical properties of the road pavement made with a bituminous conglomerate containing such composition.

Example 10



[0068] The behavior during storage of a batch of a product with a composition according to Example 1 was verified by keeping in a store at room temperature 1500 kg of this product closed in two polyethylene "big bags" (FIBCs) placed one over the other and the two of them over four bags made of low melting LDPE , each of which in turn contained 25 kg of the same composition. Two months later, the two big bags were inspected to check the status of the product and no packing phenomenon was detected and it was possible to empty the contents of these bags by gravity in only about 30 seconds, without any appreciable generation of fine dust. No packing phenomenon was found in the four low melting bags either.


Claims

1. An anti-icing composition suitable for incorporation in bituminous conglomerates for road paving, comprising an alkali metal chloride, an alkaline-earth metal carbonate, an alkali or alkaline-earth metal formate, a polysiloxane and optionally an alkaline-earth metal chloride, in which the polysiloxane is contained in an amount between 0.5 and 2.0% by weight of the total weight of the composition.
 
2. The anti-icing composition according to claim 1, comprising an alkali metal chloride and an alkaline-earth metal chloride, wherein said alkali metal chloride is sodium chloride and said alkaline earth metal chloride is calcium chloride.
 
3. The anti-icing composition according to claim 2, wherein said alkaline earth metal carbonate is calcium carbonate.
 
4. The anti-icing composition according to claim 3, wherein said formate is an alkali metal formate, preferably sodium formate.
 
5. The anti-icing composition according to claim 4, consisting of the following components, indicated in percentages by weight of the total weight of the composition:
sodium chloride 60-84
sodium formate 5-15
calcium chloride 5-15
calcium carbonate 2-8
polysiloxane 0.5-2.0

 
6. The anti-icing composition according to any one of claims 1 to 5, wherein said polysiloxane is a polydimethylsiloxane (dimethicone).
 
7. The anti-icing composition according to claim 6, wherein said polydimethylsiloxane has a viscosity of between 300 and 400 mm2/s, preferably between 325 and 375 mm2/s.
 
8. An anti-icing bituminous formulation comprising from 20 to 70% by weight of the anti-icing composition according to any one of claims 1 to 7 and 30 to 80% by weight of bitumen.
 
9. The bituminous formulation according to claim 8, comprising from 30 to 60% by weight of said anti-icing composition and from 40 to 70% by weight of bitumen.
 
10. A bituminous conglomerate adapted to provide an anti-icing road paving, comprising aggregates, bitumen, filler and from 2 to 6%, preferably 3 to 5%, by weight of the weight of said aggregates, of said anti-icing composition according to any one of claims 1 to 7.
 
11. A bituminous conglomerate adapted to provide an anti-icing road paving, comprising aggregates, filler and from 3 to 10%, by weight of the weight of said aggregates, of said anti-icing bituminous formulation according to claim 8 or 9.
 
12. A method for producing a bituminous conglomerate according to claim 10, comprising a step of adding, under stirring and at a temperature varying from 130°C to 200°C, to a mixture of aggregates and filler, bitumen and an anti-icing composition according to one any one of claims 1 to 7.
 
13. A method for producing a bituminous conglomerate according to claim 11, comprising the step of adding, under stirring and at a temperature varying from 130°C to 200°C, to a mixture of aggregates and filler, an anti-icing bituminous formulation according to any one of claims 8-9.
 
14. A method for producing an anti-icing composition according to claim 1, which comprises the steps of mixing said alkali metal chloride, said alkali-earth metal carbonate, said alkali or alkaline-earth metal formate, and optionally said alkaline-earth metal chloride to obtain a mixture in the form of a homogeneous powder, and adding said polysiloxane dispersed in a finely divided form to said mixture in the form of a homogenous powder.
 
15. The method according to claim 14, wherein said step of adding the polysiloxane is performed by spraying the polysiloxane by means of a spray device onto said mixture in the form of a homogeneous powder while the latter is kept under stirring in a mixer, preferably a screw mixer.
 


Ansprüche

1. Vereisungsschutzzusammensetzung, die sich zur Einbindung in bitumenhaltige Konglomerate zur Straßenpflasterung eignet, die ein Alkalimetallchlorid, ein Erdalkalimetallcarbonat, ein Alkali- oder Erdalkalimetallformiat, ein Polysiloxan und optional ein Erdalkalimetallchlorid umfasst, wobei das Polysiloxan in einer Menge zwischen 0,5 und 2,0 Gew.-% des Gesamtgewichts der Zusammensetzung enthalten ist.
 
2. Die Vereisungsschutzzusammensetzung nach Anspruch 1, die ein Alkalimetallchlorid und ein Erdalkalimetallchlorid umfasst, wobei das Alkalimetallchlorid Natriumchlorid ist und das Erdalkalimetallchlorid Calciumchlorid ist.
 
3. Die Vereisungsschutzzusammensetzung nach Anspruch 2, wobei das Erdalkalimetallcarbonat Calciumcarbonat ist.
 
4. Die Vereisungsschutzzusammensetzung nach Anspruch 3, wobei das Formiat ein Alkalimetallformiat, vorzugsweise Natriumformiat, ist.
 
5. Die Vereisungsschutzzusammensetzung nach Anspruch 4, die aus den folgenden Komponenten besteht, die in Gewichtsprozentsätzen bezogen auf das Gesamtgewicht der Zusammensetzung angegeben sind:
Natriumchlorid 60 bis 84
Natriumformiat 5 bis 15
Calciumchlorid 5 bis 15
Calciumcarbonat 2 bis 8
Polysiloxan 0,5 bis 2,0

 
6. Die Vereisungsschutzzusammensetzung nach einem der Ansprüche 1 bis 5, wobei das Polysiloxan ein Polydimethylsiloxan (Dimethicon) ist.
 
7. Die Vereisungsschutzzusammensetzung nach Anspruch 6, wobei das Polydimethylsiloxan eine Viskosität zwischen 300 und 400 mm2/s, vorzugsweise zwischen 325 und 375 mm2/s, aufweist.
 
8. Bitumenhaltige Vereisungsschutzformulierung, die 20 bis 70 Gew.-% der Vereisungsschutzzusammensetzung nach einem der Ansprüche 1 bis 7 und 30 bis 80 Gew.-% Bitumen umfasst.
 
9. Die bitumenhaltige Formulierung nach Anspruch 8, die 30 bis 60 Gew.-% der Vereisungsschutzzusammensetzung und 40 bis 70 Gew.-% Bitumen umfasst.
 
10. Bitumenhaltiges Konglomerat, das so ausgelegt ist, dass es eine Vereisungsschutzstraßenpflasterung bereitstellt, das Aggregate, Bitumen, Füllstoff und 2 bis 6 Gew.-%, vorzugsweise 3 bis 5 Gew.% bezogen auf das Gewicht der Aggregate der Vereisungsschutzzusammensetzung nach einem der Ansprüche 1 bis 7 umfasst.
 
11. Bitumenhaltiges Konglomerat, das so ausgelegt ist, dass es eine Vereisungsschutzstraßenpflasterung bereitstellt, das Aggregate, Füllstoff und 3 bis 10 Gew.% bezogen auf das Gewicht der Aggregate der bitumenhaltigen Vereisungsschutzformulierung nach Anspruch 8 oder 9 umfasst.
 
12. Verfahren zum Herstellen eines bitumenhaltigen Konglomerats nach Anspruch 10, das einen Schritt des Hinzufügens von Bitumen und einer Vereisungsschutzzusammensetzung nach einem der Ansprüche 1 bis 7 unter Rühren und bei einer Temperatur, die von 130 °C bis 200 °C variiert, zu einer Mischung von Aggregaten und Füllstoff umfasst.
 
13. Verfahren zum Herstellen eines bitumenhaltigen Konglomerats nach Anspruch 11, das den Schritt des Hinzufügens einer bitumenhaltigen Vereisungsschutzformulierung nach einem der Ansprüche 8 bis 9 unter Rühren und bei einer Temperatur, die von 130 °C bis 200 °C variiert, zu einer Mischung von Aggregaten und Füllstoff umfasst.
 
14. Verfahren zum Herstellen einer Vereisungsschutzzusammensetzung nach Anspruch 1, das die Schritte des Mischens des Alkalimetallchlorids, des Erdalkalimetallcarbonats, des Alkali- oder Erdalkalimetallformiats und optional des Erdalkalimetallchlorids, um eine Mischung in Form eines homogenen Pulvers zu erhalten, und des Hinzufügens des in einer feinverteilten Form dispergierten Polysiloxans zur Mischung in Form eines homogenen Pulvers umfasst.
 
15. Das Verfahren nach Anspruch 14, wobei der Schritt des Hinzufügens des Polysiloxans durch Sprühen des Polysiloxan mithilfe einer Sprühvorrichtung auf die Mischung in Form eines homogenen Pulvers durchgeführt wird, während Letztere unter Rühren in einem Mischer, vorzugsweise einem Schneckenmischer, gehalten wird.
 


Revendications

1. Composition antigivrage apte à être incorporée dans des conglomérats bitumineux pour le revêtement routier, comprenant un chlorure de métal alcalin, un carbonate de métal alcalino-terreux, un formiate de métal alcalin ou alcalino-terreux, un polysiloxane et éventuellement un chlorure de métal alcalino-terreux, dans laquelle le polysiloxane est présent en une quantité comprise entre 0,5 et 2,0 % en poids rapporté au poids total de la composition.
 
2. Composition antigivrage selon la revendication 1, comprenant un chlorure de métal alcalin et un chlorure de métal alcalino-terreux, ledit chlorure de métal alcalin étant du chlorure de sodium et ledit chlorure de métal alcalino-terreux est du chlorure de calcium.
 
3. Composition antigivrage selon la revendication 2, dans laquelle le carbonate de métal alcalino-terreux est du carbonate de calcium.
 
4. Composition antigivrage selon la revendication 3, dans laquelle le formiate est un formiate de métal alcalin, de préférence du formiate de sodium.
 
5. Composition antigivrage selon la revendication 4, constituée des composants suivants, indiqués en pourcentages en poids rapporté au poids total de la composition :
chlorure de sodium 60 - 84
formiate de sodium 5 - 15
chlorure de calcium 5 - 15
carbonate de calcium 2 - 8
polysiloxane 0,5 - 2,0

 
6. Composition antigivrage selon l'une quelconque des revendications 1 à 5, dans laquelle le polysiloxane est un polydiméthylsiloxane (diméthicone).
 
7. Composition antigivrage selon la revendication 6, dans laquelle le polydiméthylsiloxane a une viscosité comprise entre 300 et 400 mm2/s, de préférence entre 325 et 375 mm2/s.
 
8. Formulation bitumineuse antigivrage comprenant de 20 à 70 % en poids de la composition antigivrage selon l'une quelconque des revendications 1 à 7, et 30 à 80 % en poids de bitume.
 
9. Formulation bitumineuse selon la revendication 8, comprenant de 30 à 60 % en poids de la composition antigivrage et de 40 à 70 % en poids de bitume.
 
10. Conglomérat bitumineux adapté pour réaliser un revêtement routier antigivrage, comprenant des agrégats, du bitume, une charge et de 2 à 6 % en poids, de préférence de 3 à 5 % en poids, rapporté au poids desdits agrégats, de la composition antigivrage selon l'une quelconque des revendications 1 à 7.
 
11. Conglomérat bitumineux adapté pour réaliser un revêtement routier antigivrage, comprenant des agrégats, une charge et de 3 à 10 % en poids rapporté au poids desdits agrégats, de la formulation bitumineuse antigivrage selon la revendication 8 ou 9.
 
12. Procédé de production d'un conglomérat bitumineux selon la revendication 10, comprenant une étape consistant à ajouter du bitume et une composition antigivrage selon l'une quelconque des revendications 1 à 7 à un mélange d'agrégats et de charges, sous agitation et à une température variant de 130 °C à 200 °C.
 
13. Procédé de production d'un conglomérat bitumineux selon la revendication 11, comprenant l'étape consistant à ajouter une formulation bitumineuse antigivrage selon l'une quelconque des revendications 8 - 9 à un mélange d'agrégats et de charges, sous agitation et à une température variant de 130 °C à 200 °C.
 
14. Procédé de production d'une composition antigivrage selon la revendication 1, qui comprend les étapes consistant à mélanger le chlorure de métal alcalin, le carbonate de métal alcalino-terreux, le formiate de métal alcalin ou alcalino-terreux et éventuellement le chlorure de métal alcalino-terreux pour obtenir un mélange sous forme de poudre homogène, et à ajouter le polysiloxane dispersé sous une forme finement divisée audit mélange sous forme de poudre homogène.
 
15. Procédé selon la revendication 14, dans lequel l'étape consistant à ajouter du polysiloxane est réalisée par pulvérisation du polysiloxane au moyen d'un dispositif de pulvérisation sur le mélange sous la forme de poudre homogène tout en maintenant l'agitation de ce dernier dans un mélangeur, de préférence un mélangeur à vis.
 




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Cited references

REFERENCES CITED IN THE DESCRIPTION



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Patent documents cited in the description