(19)
(11)EP 3 812 439 B1

(12)EUROPEAN PATENT SPECIFICATION

(45)Mention of the grant of the patent:
27.07.2022 Bulletin 2022/30

(21)Application number: 19841100.1

(22)Date of filing:  29.07.2019
(51)International Patent Classification (IPC): 
C09J 133/08(2006.01)
C09J 183/04(2006.01)
C09J 7/20(2018.01)
C08F 230/08(2006.01)
C09D 133/08(2006.01)
C09J 139/06(2006.01)
C09J 133/10(2006.01)
C09J 11/00(2006.01)
C09J 7/40(2018.01)
C09D 133/06(2006.01)
C08F 290/06(2006.01)
(52)Cooperative Patent Classification (CPC):
C09J 133/08; C09J 7/385; C09J 2203/318; C09J 2400/226; C09J 2301/312; C08L 33/08; C09J 183/06; C08G 77/445; C08G 77/14; C08G 77/20; C08F 230/08; C08F 290/068; C09J 139/06; C08F 220/1808; C08L 51/085; C09D 151/085; H01L 51/5253; C08F 283/124
 
C-Sets:
  1. C09J 133/08, C08L 43/04;
  2. C09J 139/06, C08L 43/04;
  3. C08F 290/068, C08F 220/1818;
  4. C08F 283/124, C08F 220/1818;
  5. C08L 33/08, C08L 43/04, C08K 5/0025;

(86)International application number:
PCT/KR2019/009429
(87)International publication number:
WO 2020/022866 (30.01.2020 Gazette  2020/05)

(54)

ADHESIVE COMPOSITION, ADHESIVE FILM COMPRISING ADHESIVE COMPOSITION, BACK PLATE FILM COMPRISING ADHESIVE FILM, AND PLASTIC ORGANIC LIGHT EMITTING DISPLAY COMPRISING ADHESIVE FILM

HAFTZUSAMMENSETZUNG, HAFTFOLIE MIT HAFTZUSAMMENSETZUNG, RÜCKPLATTENFOLIE MIT HAFTFOLIE UND ORGANISCHE LICHTEMITTIERENDE KUNSTSTOFFANZEIGE MIT HAFTFOLIE

COMPOSITION ADHÉSIVE, FILM ADHÉSIF COMPRENANT UNE COMPOSITION ADHÉSIVE, FILM DE PLAQUE ARRIÈRE COMPRENANT UN FILM ADHÉSIF, ET AFFICHAGE ÉLECTROLUMINESCENT ORGANIQUE EN PLASTIQUE COMPRENANT UN FILM ADHÉSIF


(84)Designated Contracting States:
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

(30)Priority: 27.07.2018 KR 20180087790

(43)Date of publication of application:
28.04.2021 Bulletin 2021/17

(73)Proprietor: LG CHEM, LTD.
Yeongdeungpo-gu, Seoul 07336 (KR)

(72)Inventors:
  • HAN, Sanghun
    Daejeon 34122 (KR)
  • KWON, Yoonkyung
    Daejeon 34122 (KR)
  • PARK, Byungsu
    Daejeon 34122 (KR)
  • LEE, Hui Je
    Daejeon 34122 (KR)
  • KANG, Seongwook
    Daejeon 34122 (KR)

(74)Representative: Hoffmann Eitle 
Patent- und Rechtsanwälte PartmbB Arabellastraße 30
81925 München
81925 München (DE)


(56)References cited: : 
WO-A1-2015/141294
KR-A- 20140 029 135
KR-A- 20150 143 507
KR-A- 20160 142 286
US-A1- 2017 081 557
JP-A- 2009 102 542
KR-A- 20140 029 135
KR-A- 20160 134 677
US-A1- 2017 043 566
  
      
    Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).


    Description

    [Technical Field]



    [0001] This application claims priority to and the benefits of Korean Patent Application No. 10-2018-0087790, filed with the Korean Intellectual Property Office on July 27, 2018.

    [0002] The present application relates to an adhesive composition, an adhesive film comprising the same, a backplate film comprising the adhesive film, and a plastic organic light emitting display comprising the adhesive film.

    [Background Art]



    [0003] In the art, an adhesive sheet having high adhesive strength from the beginning of adhesion has been known. In addition, when fixing a base using such an adhesive sheet, an adhesive sheet having sufficient adhesive strength is selected in order to fix the base.

    [0004] Meanwhile, bubbles generated during a process of bonding the adhesive sheet to the base or unexpected foreign substances may be introduced, which is not preferred in terms of appearance or adhesiveness, and re-adhesion of the adhesive sheet is sometimes required. However, such re-adhesion is difficult in the case of an adhesive sheet with high adhesive strength.

    [0005] Therefore, technologies reducing such bubbles have been devised. For example, a technology of forming an uneven surface shape on an adhering surface of a pressure-sensitive adhesive using an embossed liner has been devised. In this case, even when the pressure-sensitive adhesive is bonded to the base and bubbles are mixed into the two, air readily flows out through the surface groove of the pressure-sensitive adhesive, and therefore, the bubbles are readily removed without re-adhesion. However, the pressure-sensitive adhesive described above needs to have some thickness in order to form a groove. In addition, when lightly adhering this pressure-sensitive adhesive to a base, the adhered area decreases due to the presence of the groove, and sufficient adhesive strength may not be obtained although work such as rework or position refresh is readily conducted.

    [0006] In addition, in order to obtain active bending in addition the re-adhesion work, a part of a panel of a plastic organic light emitting diode (POLED) needs to have a process of removing an adhesive sheet, and low adhesive strength is required in order to remove a part of the adhesive sheet from a substrate during the process.

    [0007] However, a general adhesive sheet has high adhesive strength after being laminated to an adhered base such as a substrate, and when removing the adhesive sheet, the panel may be damaged, and particularly, a problem of an increase in the adhesive strength occurs when stored for a long period of time even without going through a specific process.

    [0008] Accordingly, in view of the above, development of an adhesive sheet in which low adhesive strength is maintained at the beginning of adhesion, the adhesive strength is maintained low even after adhesion with a base until a process of removing the adhesive sheet, the adhesive strength is also maintained low even when a temperature is raised to a specific temperature, and sufficient adhesive strength required to fix the base is obtained has been required.

    Prior Art Documents


    Patent Documents



    [0009] Japanese Patent Application Laid-Open Publication No. 2006-299283

    [0010] US 2017/081557 A1 and US 2017/043566 describe pressure-sensitive adhesive sheets which have a substrate and a pressure-sensitive adhesive layer laminated on at least one side of the substrate. The pressure-sensitive adhesive layers have a time-dependent adhesive force and contain a (meth)acrylic polymer. WO 2015/141294 A1 discloses a temperature-sensitive adhesive which is based on a polymer obtained by polymerizing (meth)acrylate derivatives and a polysiloxane compound. Moreover, KR 2014-0029135 A relates to an organic light emitting element which comprises a pressure-sensitive adhesive layer which may be an acrylic adhesive film.

    [Disclosure]


    [Technical Problem]



    [0011] The present application is directed to providing an adhesive composition, an adhesive film comprising the same, a backplate film comprising the adhesive film, and a plastic organic light emitting display comprising the adhesive film.

    [Technical Solution]



    [0012] One embodiment of the present application provides an adhesive composition comprising a (meth)acrylate-based resin; and a polymer having a melting temperature (Tm) of 60°C or higher, as measured by using a differential scanning calorimetry (DSC), wherein the polymer is a copolymer of a monofunctional polysiloxane and one type of monomer, wherein the polymer having a melting temperature of 60°C or higher comprises, based on 100 parts by weight of the polymer having a melting temperature of 60°C or higher, the monofunctional polysiloxane in greater than or equal to 10 parts by weight and less than or equal to 40 parts by weight, and the monomer in greater than or equal to 60 parts by weight and less than or equal to 90 parts by weight, and wherein the monomer is represented by the following Chemical Formula 1:

    in Chemical Formula 1,

    X is N or O;

    R1 is hydrogen or a methyl group; and

    n is an integer of 10 to 30.



    [0013] Another embodiment provides an adhesive film comprising a base film; and an adhesive sheet comprising the adhesive composition according to one embodiment of the present application or a cured material thereof provided on one surface of the base film.

    [0014] Another embodiment provides a backplate film comprising the adhesive film according to the present application; and a protective film provided on the base film side of the adhesive film.

    [0015] Lastly, one embodiment of the present application provides a plastic organic light emitting display comprising the adhesive film according to the present application; a plastic substrate provided on the adhesive sheet side of the adhesive film; and an organic light emitting layer provided on a surface opposite to the surface in contact with the adhesive film of the plastic substrate.

    [Advantageous Effects]



    [0016] An adhesive composition according to one embodiment of the present application comprises a polymer having a melting temperature (Tm) of 60°C or higher and a (meth)acrylate-based resin, and an adhesive sheet comprising the same has low initial adhesive strength with an adhered base.

    [0017] Particularly, the adhesive sheet included in an adhesive film according to one embodiment of the present application has, while having low initial adhesive strength with an adhered base, adhesive strength maintained constant without increasing even when stored for a long period of time at room temperature, and in particular, adhesive strength is maintained low in a state of high temperature (55°C) as well as in a state of room temperature.

    [0018] Particularly, in order to obtain active bending, a part of a panel of a plastic organic light emitting diode (POLED) needs to have a process of removing an adhesive sheet, and a backplate film comprising the adhesive sheet according to the present application is capable of preventing damages on the panel by having a property of maintaining low initial adhesive strength even in a state of high temperature (55°C).

    [Description of Drawings]



    [0019] 

    FIG. 1 is a diagram illustrating a schematic lamination structure of an adhesive film according to one embodiment of the present application.

    FIG. 2 is a diagram illustrating a schematic lamination structure of a backplate film according to one embodiment of the present application.

    FIG. 3 is a diagram illustrating a schematic lamination structure of a plastic organic light emitting display according to one embodiment of the present application.

    FIG. 4 is a diagram presenting a DSC graph of a polymer showing a glass transition temperature behavior.

    FIG. 5 is a diagram presenting a DSC graph of a polymer showing a melting temperature behavior.


    [Mode for Disclosure]



    [0020] Hereinafter, the present specification will be described in more detail.

    [0021] In the present specification, a description of a certain part "including" certain constituents means capable of further comprising other constituents, and does not exclude other constituents unless particularly stated on the contrary.

    [0022] Embodiments of the present disclosure will be described in detail with reference to accompanying drawings so that those skilled in the art may readily implement the present disclosure. However, the present disclosure may be embodied in various different forms, and is not limited to the embodiments described herein.

    [0023] One embodiment of the present application provides an adhesive composition comprising a (meth)acrylate-based resin; and a polymer having a melting temperature (Tm) of 60°C or higher, as measured by using a differential scanning calorimetry (DSC), wherein the polymer is a copolymer of a monofunctional polysiloxane and one type of monomer, wherein the polymer having a melting temperature of 60°C or higher comprises, based on 100 parts by weight of the polymer having a melting temperature of 60°C or higher, the monofunctional polysiloxane in greater than or equal to 10 parts by weight and less than or equal to 40 parts by weight, and the monomer in greater than or equal to 60 parts by weight and less than or equal to 90 parts by weight, and wherein the monomer is represented by the following Chemical Formula 1:



    in Chemical Formula 1,

    X is N or O;

    R1 is hydrogen or a methyl group; and

    n is an integer of 10 to 30.



    [0024] In addition, the adhesive composition of the present application may comprise a curing agent, and one embodiment of the present application provides an adhesive composition comprising a (meth)acrylate-based resin; a polymer having a melting temperature (Tm) of 60°C or higher; and a curing agent, wherein the polymer is a copolymer of a monofunctional polysiloxane and one type of monomer as defined above.

    [0025] The components of the polymer included in the adhesive composition may be identified through a gas chromatography (GC) analysis, and the composition may each be identified through a nuclear magnetic resonance (NMR) analysis.

    [0026] By the adhesive composition according to one embodiment of the present application comprising a polymer having a melting temperature of 60°C or higher, adhesive strength of an adhesive sheet prepared later on using the same is maintained low, and particularly, adhesive strength is maintained low in a state of high temperature (55°C) as well as in a state of room temperature.

    [0027] Particularly, in order to obtain active bending, a part of a panel of a plastic organic light emitting diode (POLED) needs to have a process of removing an adhesive sheet, and a backplate film comprising the adhesive sheet according to the present application is capable of preventing damages on the panel by having a property of maintaining low initial adhesive strength even in a state of high temperature (55°C).

    [0028] The adhesive strength being maintained low means that, after laminating the adhesive sheet on an adhered base, there is no difference between adhesive strength at the beginning and adhesive strength after a specific temperature and a specific time.

    [0029] The melting temperature according to the present application means a temperature at which a material experiences a phase transition from a solid state to a liquid state. Particularly, in the case of a polymer, significant changes in the three-dimensional structure are obtained at a specific temperature as the polymer is heated, and changes corresponding to a phase transition may be observed, and the temperature herein may be defined as a melting temperature.

    [0030] The melting temperature is measured using a differential scanning calorimetry (DSC). Specifically, it is a value measured by, after approximately 10 mg of a sample is sealed in a dedicated pan and heated under a constant temperature-raising environment, drawing endothermic and exothermic amounts of the material resulting from the occurrence of a phase transition depending on a temperature.

    [0031] In the adhesive composition of the present application, the monomer is represented by the following Chemical Formula 1.

    In Chemical Formula 1,

    X is N or O,

    R1 is hydrogen or a methyl group, and

    n is an integer of 10 to 30.



    [0032] In one embodiment of the present application, n of Chemical Formula 1 may be an integer of 10 to 30.

    [0033] In another embodiment, n of Chemical Formula 1 may be an integer of 15 to 25.

    [0034] In another embodiment, n of Chemical Formula 1 may be an integer of 16 to 24.

    [0035] In one embodiment of the present application, X may be N.

    [0036] In one embodiment of the present application, X may be O.

    [0037] In Chemical Formula 1, when the n value is in the above-mentioned range, partial crystallization begins to form due to entanglement between carbon side chains, and as a result, the polymer comprising the same may show a melting temperature (Tm) behavior.

    [0038] The following FIG. 4 is a DSC graph of a polymer showing a glass transition temperature (Tg) behavior, and the following FIG. 5 is a DSC graph of a polymer showing a melting temperature (Tm) behavior.

    [0039] As shown in FIG. 4, it is identified that, in a polymer showing a glass transition temperature behavior, a phase transition occurs as a temperature is slowly raised for a stable section (Glassy), and the phase transition (Glassy->Rubbery) slowly occurs in a wide range of temperature section. In other words, when comprising a polymer showing a glass transition temperature behavior, variable characteristics may occur, however, since the phase transition temperature section is wide, a phase transition partially occurs when stored for a long period of time in a state of raised temperature (55°C or lower), which results in an increase in the adhesive strength of an adhesive layer causing a result of unfavorable stability over time, and variable characteristics may not be superior as well since the phase transition state is a rubbery state.

    [0040] As shown in FIG. 5 on the other hand, it is seen that, in a polymer showing a melting temperature behavior, a rapid phase transition (solid->liquid) occurs at a specific temperature (melting) when slowly raising a temperature for a stable section (solid). In other words, when comprising a polymer showing a melting temperature behavior, a rapid phase transition occurs at a specific temperature value, which may suppress an increase in the adhesive strength (excellent stability over time) since a phase transition does not occur at a temperature lower than a melting temperature, and at a temperature higher than a melting temperature, a phase transition occurs resulting in a rapid increase in the adhesive strength (excellent variable characteristics).

    [0041] The polymer having a melting temperature of 60°C or higher means, when copolymerizing the monofunctional polysiloxane and the one type of monomer represented by Chemical Formula 1, a final polymer having a melting temperature value of 60°C or higher.

    [0042] In one embodiment of the present application, the polymer may have a melting temperature of 70°C or lower, preferably 68°C or lower, and more preferably 66°C or lower.

    [0043] The copolymer means a material obtained by polymerizing two or more types of different monomers, and in the copolymer, two or more types of monomers may be irregularly or regularly arranged.

    [0044] The copolymer may comprise a random copolymer having monomers mixed with each other without order, a block copolymer having arranged blocks repeated by a certain section, or an alternating copolymer having monomers alternately repeated and polymerized, and the polymer having a melting temperature of 60°C or higher according to one embodiment of the present application may be a random copolymer, a block copolymer or an alternating copolymer.

    [0045] In one embodiment of the present application, the monomer represented by Chemical Formula 1 may be behenyl acrylate (BHA) .

    [0046] As the monofunctional polysiloxane according to the present application, FM-0721 manufactured by Chisso Corporation, KF2012 manufactured by Shin-Etsu Chemical Co., Ltd., or the like may be used, however, the monofunctional polysiloxane is not limited thereto.

    [0047] In one embodiment of the present application, the polymer having a melting temperature of 60°C or higher may have a weight average molecular weight of 30,000 g/mol to 200,000 g/mol.

    [0048] In another embodiment, the polymer having a melting temperature of 60°C or higher may have a weight average molecular weight of 30,000 g/mol to 150,000 g/mol, and preferably 30,000 g/mol to 100,000 g/mol.

    [0049] When the polymer having a melting temperature of 60°C or higher according to the present application has a weight average molecular weight value in the above-mentioned range, molecular arrangements in the polymer are excellent, and properties of low initial adhesive strength are obtained when preparing the adhesive sheet later on.

    [0050] The weight average molecular weight is one of an average molecular weight in which a molecular weight is not uniform and a molecular weight of a certain polymer material is used as a standard, and is a value obtained by averaging molecular weights of component molecular species of a polymer compound having molecular weight distribution by a weight fraction.

    [0051] The weight average molecular weight may be measured through a gel permeation chromatography (GPC) analysis.

    [0052] The polymer having a melting temperature of 60°C or higher may be prepared comprising a thermal polymerization initiator in a polymer composition comprising the monofunctional polysiloxane; the one type of monomer; and a solvent.

    [0053] As the solvent, toluene may be used, however, the solvent is not limited thereto as long as it is capable of dissolving the monofunctional polysiloxane and the one type of monomer, and such general organic solvents may be used.

    [0054] In the adhesive composition of the present application, the polymer having a melting temperature of 60°C or higher comprises, based on 100 parts by weight of the polymer having a melting temperature of 60°C or higher, the monofunctional polysiloxane in greater than or equal to 10 parts by weight and less than or equal to 40 parts by weight, and the monomer in greater than or equal to 60 parts by weight and less than or equal to 90 parts by weight.

    [0055] In one embodiment of the present application, the polymer having a melting temperature of 60°C or higher may comprise, based on 100 parts by weight of the polymer having a melting temperature of 60°C or higher, the monofunctional polysiloxane in greater than or equal to 15 parts by weight and less than or equal to 30 parts by weight, and more preferably in greater than or equal to 18 parts by weight and less than or equal to 25 parts by weight.

    [0056] In one embodiment of the present application, the polymer having a melting temperature of 60°C or higher may comprise, based on 100 parts by weight of the polymer having a melting temperature of 60°C or higher, the monomer in greater than or equal to 65 parts by weight and less than or equal to 85 parts by weight, and more preferably in greater than or equal to 70 parts by weight and less than or equal to 85 parts by weight.

    [0057] When the polymer having a melting temperature of 60°C or higher according to the present application comprises the monofunctional polysiloxane and the monomer in the above-mentioned parts by weight, the melting temperature value may be properly formed, and accordingly, initial adhesive strength of the adhesive sheet later on at room temperature may be maintained low.

    [0058] In the adhesive composition provided in one embodiment of the present application, the adhesive composition comprises the polymer having a melting temperature of 60°C or higher in 1 parts by weight to 10 parts by weight based on 100 parts by weight of the (meth)acrylate-based resin.

    [0059] In another embodiment, the adhesive composition may comprise, based on 100 parts by weight of the (meth)acrylate-based resin, the polymer having a melting temperature of 60°C or higher in 1 parts by weight to 7 parts by weight, and preferably in 2 parts by weight to 6 parts by weight.

    [0060] When the polymer having a melting temperature of 60°C or higher is included in the adhesive composition in the above-mentioned parts by weight range, the polymer may be present in a proper amount leading to excellent stability over time in states of both room temperature and high temperature (55°C), and as a result, adhesive strength may be maintained constant, and a property of excellent variable performance is obtained in a variable process when used in a plastic organic light emitting display later on.

    [0061] In one embodiment of the present application, the acrylate-based resin may comprise a (meth)acrylate-based resin having a weight average molecular weight of 100,000 g/mol to 5,000,000 g/mol.

    [0062] In the present specification, (meth)acrylate means comprising both acrylate and methacrylate. Examples of the (meth)acrylate-based resin may comprise a copolymer of a (meth)acrylic acid ester-based monomer and a crosslinking functional group-containing monomer.

    [0063] The (meth)acrylic acid ester-based monomer is not particularly limited, however, examples thereof may comprise an alkyl (meth)acrylate, and more specifically, as a monomer having an alkyl group with 1 to 12 carbon atoms, one, two or more types among pentyl (meth)acrylate, n-butyl (meth)acrylate, ethyl (meth)acrylate, methyl (meth)acrylate, hexyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, dodecyl (meth)acrylate and decyl (meth)acrylate may be included.

    [0064] The crosslinking functional group-containing monomer is not particularly limited, however, examples thereof may comprise one, two or more types among hydroxy group-containing monomers, carboxyl group-containing monomers and nitrogen-containing monomers.

    [0065] Examples of the hydroxyl group-containing monomer may comprise 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6-hydroxyhexyl (meth)acrylate, 8-hydroxyoctyl (meth)acrylate, 2-hydroxyethylene glycol (meth)acrylate, 2-hydroxypropylene glycol (meth)acrylate or the like.

    [0066] Examples of the carboxyl group-containing monomer may comprise (meth)acrylic acid, 2-(meth)acryloyloxyacetic acid, 3-(meth)acryloyloxypropyl acid, 4-(meth)acryloyloxybutyric acid, an acrylic acid dimer, itaconic acid, maleic acid, a maleic anhydride or the like.

    [0067] Examples of the nitrogen-containing monomer may comprise (meth)acrylonitrile, N-vinyl pyrrolidone, N-vinyl caprolactam or the like.

    [0068] To the (meth)acrylate-based resin, at least one of vinyl acetate, styrene and acrylonitrile may also be further copolymerized in terms of other functional improvements such as compatibility.

    [0069] In one embodiment of the present application, the (meth)acrylate-based resin may be selected from the group consisting of alkyl (meth)acrylates, hydroxyalkyl acrylates and nitrogen-containing monomers.

    [0070] Examples of the alkyl acrylate and the alkyl methacrylate may comprise, as a monomer having an alkyl group with 1 to 12 carbon atoms, one, two or more types among pentyl (meth)acrylate, n-butyl (meth)acrylate, ethyl (meth)acrylate, methyl (meth)acrylate, hexyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, dodecyl (meth)acrylate and decyl (meth)acrylate.

    [0071] Examples of the hydroxyalkyl acrylate may comprise 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 4-hydroxybutyl acrylate, 6-hydroxyhexyl acrylate, 8-hydroxyoctyl acrylate, 2-hydroxyethylene glycol acrylate, 2-hydroxypropylene glycol acrylate or the like.

    [0072] Examples of the nitrogen-containing monomer may comprise N-vinyl pyrrolidone (VP).

    [0073] In one embodiment of the present application, the (meth)acrylate-based resin may comprise, based on 100 parts by weight of the (meth)acrylate-based resin, the alkyl acrylate in 50 parts by weight to 70 parts by weight, the alkyl methacrylate in 5 parts by weight to 40 parts by weight, the nitrogen-containing monomer in 0.1 parts by weight to 10 parts by weight and the hydroxyalkyl acrylate in 1 parts by weight to 30 parts by weight.

    [0074] The (meth)acrylate-based resin comprising the alkyl acrylate in 50 parts by weight to 70 parts by weight, the alkyl methacrylate in 5 parts by weight to 40 parts by weight, the nitrogen-containing monomer in 0.1 parts by weight to 10 parts by weight and the hydroxyalkyl acrylate in 1 to 30 parts by weight means the alkyl acrylate monomer, the alkyl methacrylate monomer, the nitrogen-containing monomer and the hydroxyalkyl acrylate monomer being polymerized in the above-mentioned weight ratio.

    [0075] In one embodiment of the present application, the (meth)acrylate-based resin may comprise, based on 100 parts by weight of the (meth)acrylate-based resin, the alkyl acrylate in 50 parts by weight to 70 parts by weight, preferably in 55 parts by weight to 70 parts by weight, and more preferably in 60 parts by weight to 70 parts by weight.

    [0076] In one embodiment of the present application, the (meth)acrylate-based resin may comprise, based on 100 parts by weight of the (meth)acrylate-based resin, the alkyl methacrylate in 5 parts by weight to 40 parts by weight, preferably in 7 parts by weight to 35 parts by weight, and more preferably in 10 parts by weight to 30 parts by weight.

    [0077] In one embodiment of the present application, the (meth)acrylate-based resin may comprise, based on 100 parts by weight of the (meth)acrylate-based resin, the nitrogen-containing monomer in 0.1 parts by weight to 10 parts by weight, preferably in 1 parts by weight to 10 parts by weight, and more preferably in 3 parts by weight to 10 parts by weight.

    [0078] In one embodiment of the present application, the (meth)acrylate-based resin may comprise, based on 100 parts by weight of the (meth)acrylate-based resin, the hydroxyalkyl acrylate in 1 parts by weight to 30 parts by weight, preferably in 5 parts by weight to 25 parts by weight, and more preferably in 5 parts by weight to 20 parts by weight.

    [0079] When the (meth)acrylate-based resin has the above-mentioned composition and content, properties of excellent variable characteristics of the adhesive sheet are obtained later on.

    [0080] In one embodiment of the present application, the adhesive composition may further comprise one or more selected from the group consisting of a solvent, a dispersant, a photoinitiator, a thermal initiator and a tackifier.

    [0081] According to one embodiment of the present specification, the crosslinking compound may comprise one or more types selected from the group consisting of a compound obtained by esterifying a polyalcohol such as hexanediol di(meth)acrylate, ethylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate having 2 to 14 ethylene groups, trimethylolpropane di(meth)acrylate, trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, 2-trisacryloyloxymethylethylphthalic acid, propylene glycol di(meth)acrylate having 2 to 14 propylene groups, dipentaerythritol penta(meth)acrylate, dipentaerythritol hexa(meth)acrylate or a mixture of an acidic modification of dipentaerythritol penta(meth)acrylate and dipentaerythritol hexa(meth)acrylate (TO-2348, TO-2349 of TOAGOSEI Co., Ltd. as a trade name) with α, β-unsaturated carboxylic acid; a compound obtained by adding (meth)acrylic acid to a compound containing a glycidyl group such as a trimethylolpropane triglycidyl ether acrylic acid adduct or a bisphenol A diglycidyl ether acrylic acid adduct; an ester compound of a compound having a hydroxyl group or an ethylenic unsaturated bond and a polycarboxylic acid, or an adduct with polyisocyanate such as a phthalic acid diester of β-hydroxyethyl(meth)acrylate or a toluene diisocyanate adduct of β-hydroxyethyl (meth)acrylate; a (meth)acrylic acid alkyl ester such as methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate or 2-ethylhexyl (meth)acrylate; and 9,9'-bis[4-(2-acryloyloxyethoxy)phenyl]fluorene. However, the crosslinking compound is not limited thereto, and general compounds known in the art may be used.

    [0082] According to one embodiment of the present specification, the photoinitiator may be substituted with one, two or more substituents selected from the group consisting of triazine-based compounds, biimidazole compounds, acetophenone-based compounds, O-acyloxime-based compounds, thioxanthone-based compounds, phosphine oxide-based compounds, coumarin-based compounds and benzophenone-based compounds.

    [0083] Specifically, according to one embodiment of the present specification, the photoinitiator may use a triazine-based compound such as 2,4-trichloromethyl-(4'-methoxyphenyl)-6-triazine, 2,4-trichloromethyl-(4'-methoxystyryl)-6-triazine, 2,4-trichloromethyl-(bifluorenyl)-6-triazine, 2,4-trichloromethyl-(3',4'-dimethoxyphenyl)-6-triazine, 3-{4-[2,4-bis(trichloromethyl)-s-triazin-6-yl]phenylthio}propanoic acid, 2,4-trichloromethyl-(4'-ethylbiphenyl)-6-triazine or 2,4-trichloromethyl-(4'-methylbiphenyl)-6-triazine; a biimidazole-based compound such as 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenylbiimidazole or 2,2'-bis(2,3-dichlorophenyl)-4,4',5,5'-tetraphenylbiimidazole; an acetophenone-based compound such as 2-hydroxy-2-methyl-1-phenylpropan-1-one, 1-(4-isopropylphenyl)-2-hydroxy-2-methylpropan-1-one, 4-(2-hydroxyethoxy)-phenyl (2-hydroxy)propyl ketone, 1-hydroxycyclohexyl phenyl ketone, 2,2-dimethoxy-2-phenyl acetophenone, 2-methyl-(4-methylthiophenyl)-2-morpholino-1-propan-1-one (Irgacure-907) or 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butan-1-one (Irgacure-369); an O-acyloxime-based compound such as Irgacure OXE 01 or Irgacure OXE 02 of Ciba Geigy Ltd.; a benzophenone-based compound such as 4,4'-bis(dimethylamino)benzophenone or 4,4'-bis(diethylamino)benzophenone; a thioxanthone-based compound such as 2,4-diethyl thioxanthone, 2-chloro thioxanthone, isopropyl thioxanthone or diisopropyl thioxanthone; a phosphine oxide-based compound such as 2,4,6-trimethylbenzoyl diphenylphosphine oxide, bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentyl phosphine oxide or bis(2,6-dichlorobenzoyl)propyl phosphine oxide; a coumarin-based compound such as 3,3'-carbonylvinyl-7-(diethylamino)coumarin, 3-(2-benzothiazolyl)-7-(diethylamino)coumarin, 3-benzoyl-7-(diethylamino)coumarin, 3-benzoyl-7-methoxy-coumarin or 10,10'-carbonylbis[1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-Cl]-benzopyrano[6,7,8-ij]-quinolizin-11-one, or the like either alone or as a mixture of two or more, however, the photocuring agent is not limited thereto.

    [0084] In addition, as the thermal initiator, those known in the art may be used.

    [0085] As the solvent, toluene may be used, however, the solvent is not limited thereto as long as it is capable of dissolving certain materials, and such general organic solvents may be used.

    [0086] One embodiment of the present application is directed to providing an adhesive film comprising a base film; and an adhesive sheet comprising the adhesive composition according to one embodiment of the present application or a cured material thereof provided on one surface of the base film.

    [0087] In one embodiment of the present application, the adhesive sheet may comprise the adhesive composition according to one embodiment of the present application as it is.

    [0088] In one embodiment of the present application, the adhesive sheet may comprise a cured material of the adhesive composition according to one embodiment of the present application.

    [0089] One embodiment of the present application provides an adhesive film further comprising a release film on a surface opposite to the surface in contact with the base film of the adhesive sheet.

    [0090] The release film refers to, as a layer for protecting a very thin adhesive sheet, a transparent layer attached on one surface of the adhesive sheet, and a hydrophobic film may be used, and films having excellent mechanical strength, thermal stability, moisture shielding property, isotropy and the like may be used. For example, resin films of acetate-based such as triacetyl cellulose (TAC), polyester-based, polyethersulphone-based, polycarbonate-based, polyamide-based, polyimide-based, polyolefin-based, cycloolefin-based, polyurethane-based, acryl-based and the like may be used, however, the release film is not limited thereto as long as it is a commercially available silicone-treated release film.

    [0091] In one embodiment of the present application, the base film may be selected from the group consisting of polyethylene terephthalate (PET), polyester, polycarbonate, polyimide (PI), polyethylene naphthalate (PEN), polyether ether ketone (PEEK), polyarylate (PAR), polycyclic olefin (PCO), polynorbornene, polyethersulphone (PES) and a cycloolefin polymer (COP).

    [0092] In another embodiment, the base film may be polyethylene terephthalate (PET).

    [0093] In one embodiment of the present application, the base film may have a thickness of greater than or equal to 10 µm and less than or equal to 200 µm, preferably greater than or equal to 15 µm and less than or equal to 100 µm, and more preferably greater than or equal to 20 µm and less than or equal to 75 µm.

    [0094] In addition, the base film is preferably transparent. The meaning of the base film being transparent described herein represents light transmittance of visible light (400 nm to 700 nm) being 80% or higher.

    [0095] When the base film has a thickness in the above-mentioned range, the laminated adhesive film may be prepared to a thin film.

    [0096] In one embodiment of the present application, the adhesive sheet may have a thickness of greater than or equal to 3 µm and less than or equal to 100 µm.

    [0097] In another embodiment, the adhesive sheet may have a thickness of greater than or equal to 3 µm and less than or equal to 100 µm, preferably greater than or equal to 5 µm and less than or equal to 80 µm, and more preferably greater than or equal to 10 µm and less than or equal to 50 µm.

    [0098] When the adhesive sheet has a thickness in the above-mentioned range, rework properties are superior when incorrectly attached, and particularly, no foreign substances remain when removing the adhesive sheet.

    [0099] In the adhesive film provided in one embodiment of the present application, the adhesive film has a thickness of greater than or equal to 50 µm and less than or equal to 300 µm.

    [0100] In another embodiment, the adhesive film may have a thickness of greater than or equal to 50 µm and less than or equal to 300 µm, preferably greater than or equal to 50 µm and less than or equal to 250 µm, and more preferably greater than or equal to 55 µm and less than or equal to 250 µm.

    [0101] By the adhesive film having a thickness in the above-mentioned range, a proper thickness as a back plate is obtained when used in a plastic organic light emitting display later on, and in addition thereto, rework properties are superior when incorrectly attached, and particularly, no foreign substances remain when removing the adhesive sheet.

    [0102] One embodiment of the present application provides an adhesive film in which, after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate),

    initial adhesive strength after leaving unattended for 2 hours at 23°C is 19.5 N/m (50 gf/inch) or less,

    middle adhesive strength after leaving unattended for 24 hours at 23°C is 21.5 N/m (55 gf/inch) or less, and

    late adhesive strength after leaving unattended for 24 hours at 55°C is 23.4 N/m (60 gf/inch) or less.



    [0103] The initial adhesive strength, the middle adhesive strength and the late adhesive strength are each measured using a texture analyzer (Stable Micro Systems) at a 180° angle and a peeling rate of 1800 mm/minute, and after attaching the adhesive sheet prepared according to the present disclosure to stainless (SUS304 substrate) using a 2 kg rubber roller going back and forth once.

    [0104] In another embodiment, initial adhesive strength after leaving unattended for 2 hours at 23°C after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate) may be 19.5 N/m (50 gf/inch) or less, preferably 17.6 N/m (45 gf/inch) or less, and more preferably 16.7 N/m (43 gf/inch) or less.

    [0105] In another embodiment, initial adhesive strength after leaving unattended for 2 hours at 23°C after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate) may be 2 N/m (5 gf/inch) or greater, preferably 3.9 N/m (10 gf/inch) or greater, and more preferably 9.8 N7m (25 gf/inch) or greater.

    [0106] In another embodiment, middle adhesive strength after leaving unattended for 24 hours at 23°C after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate) may be 21.5 N/m (55 gf/inch) or less, preferably 19.5 N/m (50 gf/inch) or less, and more preferably 17.6 N/m (45 gf/inch) or less.

    [0107] In another embodiment, middle adhesive strength after leaving unattended for 24 hours at 23°C after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate) may be 3.9 N/m (10 gf/inch) or greater, preferably 5.9 N/m (15 gf/inch) or greater, and more preferably 11.7 N/m (30 gf/inch) or greater.

    [0108] In another embodiment, late adhesive strength after leaving unattended for 24 hours at 55°C after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate) may be 23.4 N/m (60 gf/inch) or less, preferably 21.5 N/m (55 gf/inch or less), and more preferably 19.5 N/m (50 gf/inch) or less.

    [0109] In another embodiment, late adhesive strength after leaving unattended for 24 hours at 55°C after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate) may be 5.9 N/m (15 gf/inch) or greater, preferably 7.8 N/m (20 gf/inch) or greater, and more preferably 11.7 N/m (30 gf/inch) or greater.

    [0110] By the adhesive sheet according to the present application comprising the polymer having a melting temperature of 60°C or higher as described above, adhesive strength is maintained at a low level after leaving unattended for 2 hours/leaving unattended for 24 hours at room temperature (23°C), and particularly, adhesive strength is maintained constant at a low level even after leaving unattended for 24 hours in a state of high temperature (55°C).

    [0111] One embodiment of the present application provides an adhesive film in which the late adhesive strength/the initial adhesive strength is greater than or equal to 0.3 and less than or equal to 2.0.

    [0112] In another embodiment, the late adhesive strength/the initial adhesive strength may be greater than or equal to 0.3 and less than or equal to 2.0, preferably greater than or equal to 0.6 and less than or equal to 1.5, and more preferably greater than or equal to 0.9 and less than or equal to 1.3.

    [0113] In one embodiment of the present application, the adhesive sheet and the base film may be laminated in plurality.

    [0114] In the present application, the adhesive film may be prepared by coating the adhesive composition on the base film using a bar coater.

    [0115] One embodiment of the present application provides a backplate film comprising the adhesive film according to the present application; and a protective film provided on the base film side of the adhesive film.

    [0116] One embodiment of the present application is directed to providing a backplate film comprising the adhesive film according to the present application; and a protective film provided on one surface of the adhesive film, wherein the adhesive film is formed with a base film and an adhesive sheet, and the protective film is provided on a surface opposite to the surface in contact with the adhesive sheet of the base film.

    [0117] A lamination structure of the backplate film may be identified in FIG. 2. Specifically, the backplate film has a lamination structure of an adhesive film (103) and a protective film (104), and more specifically, the adhesive sheet (103) is formed with a base film (101) and an adhesive sheet (102), and one surface of the base film (101) is bonded to the protective film (104) in the backplate film (105).

    [0118] In the backplate film, the protective film performs a role of protecting the adhesive film when transferring the backplate film or conducting the process, and the protective film may be removed when using the backplate film in a plastic organic light emitting display later on.

    [0119] In one embodiment of the present application, the protective film may be formed with a protective base; and an adhesive layer.

    [0120] As the protective base, an identical material may be used as the base film.

    [0121] The adhesive layer is not limited thereto as long as it is capable of adhering the protective base and the base film, and commercially available general adhesive layers may be used.

    [0122] One embodiment of the present application provides a plastic organic light emitting display comprising the adhesive film according to the present application; a plastic substrate provided on the adhesive sheet side of the adhesive film; and an organic light emitting layer provided on a surface opposite to the surface in contact with the adhesive film of the plastic substrate.

    [0123] One embodiment of the present application is directed to providing a plastic organic light emitting display comprising the adhesive film according to the present application; a plastic substrate provided on one surface of the adhesive film; and an organic light emitting layer provided on a surface opposite to the surface in contact with the adhesive film of the plastic substrate, wherein the adhesive film is formed with a base film and an adhesive sheet, and the plastic substrate is provided on a surface opposite to the surface in contact with the base film of the adhesive sheet.

    [0124] One embodiment of the present application provides a plastic organic light emitting display comprising a protective film provided on the base film side of the adhesive film.

    [0125] A lamination structure of the plastic organic light emitting display may be identified in FIG. 3. Specifically, the plastic organic light emitting display has a lamination structure of a protective film (104); an adhesive film (103); a plastic substrate (106); and an organic light emitting layer (107), and more specifically, a lamination structure of the plastic organic light emitting display in which the adhesive sheet (102) of the adhesive film (103) and the plastic substrate (106) are bonded may be identified.

    [0126] In the lamination structure of the plastic organic light emitting display, the protective film may be removed.

    [0127] As the plastic substrate, polyimide (PI) may be used.

    [0128] The organic light emitting layer may be selected from the group consisting of an organic photoelectric device, an organic transistor, an organic solar cell, an organic light emitting device and a micro LED device.

    [0129] Hereinafter, the present disclosure will be described in detail with reference to examples so that those skilled in the art may readily implement the present disclosure. However, the present disclosure may be embodied in various different forms, and is not limited to the examples described herein.

    <Preparation Example>


    <Preparation Example 1> Polymerization of (Meth)acrylate-Based Resin



    [0130] After introducing ethylhexyl acrylate (EHA)/methyl methacrylate (MMA)/N-vinylpyrrolidone (VP)/hydroxyethyl acrylate (HEA) to ethyl acetate (EA) in a weight ratio of 65/20/5/10, azobisisobutyronitrile (AIBN), a thermal polymerization initiator, was introduced thereto to prepare a (meth)acrylate-based resin having a weight average molecular weight of 1,000,000 g/mol.

    <Preparation Example 2> Polymerization of Polymer



    [0131] A polymer having a composition and a melting temperature of the following Table 1 was prepared.
    [Table 1]
     Preparation 1Preparation 2Preparation 3Preparation 4
    Composition (Content) FM0721:BHA (20:80) FM0721:BHA (20:80) FM0721:HAD (20:80) FM0721:STA (20:80)
    Molecular Weight (g/mol) 60,000 60,000 60,000 60,000
    Melting Temperature (Tm, °C) 65 65 36 48


    [0132] In Table 1, FM0721 is a monofunctional polysiloxane and a product of Chisso Corporation was used, and the FM0721 is polysiloxane-present (meth)acrylate.

    [0133] BHA, STA and HDA monomers used in Preparations 1 to 4 are monomers having only a Tm property when polymerized, and do not exhibit a Tg property.

    [0134] In Table 1, BHA is behenyl acrylate, HDA is hexadecyl acrylate, and STA is stearyl acrylate.

    <Example>-Manufacture of Backplate Film


    <Example 1>



    [0135] With respect to 100 parts by weight of the (meth)acrylate-based resin prepared in Preparation Example 1, 1 parts by weight of an isocyanate crosslinking agent (Samyoung Ink&Paint Industrial, Co., Ltd., DR7030HD) was added, and after adding 3 parts by weight of the polymer of Preparation 1 polymerized in Preparation Example 2 thereto, an adhesive composition was prepared to have a solid content of 20% using a toluene solution.

    [0136] On a PET film (T9145J75) of Mitsubishi Plastics Inc. (MPI) having both surfaces anti-static (AS) treated, the adhesive composition of Example 1 was coated to prepare an adhesive sheet to a thickness of 15 µm, then PET (RF12ASW) having both surfaces anti-static (AS) treated was coated on the PET film as a protective film, and the result was aged for 2 days at 40°C to manufacture a backplate film.

    <Example 2>



    [0137] With respect to 100 parts by weight of the (meth)acrylate-based resin prepared in Preparation Example 1, 1 parts by weight of an isocyanate crosslinking agent (Samyoung Ink&Paint Industrial, Co., Ltd., DR7030HD) was added, and after adding 5 parts by weight of the polymer of Preparation 2 polymerized in Preparation Example 2 thereto, an adhesive composition was prepared to have a solid content of 20% using a toluene solution.

    [0138] On a PET film (T9145J75) of Mitsubishi Plastics Inc. (MPI) having both surfaces anti-static (AS) treated, the adhesive composition of Example 2 was coated to prepare an adhesive sheet to a thickness of 15 µm, then PET (RF12ASW) having both surfaces anti-static (AS) treated was coated on the PET film as a protective film, and the result was aged for 2 days at 40°C to manufacture a backplate film.

    <Comparative Example 1>



    [0139] With respect to 100 parts by weight of the (meth)acrylate-based resin prepared in Preparation Example 1, 1 parts by weight of an isocyanate crosslinking agent (Samyoung Ink&Paint Industrial, Co., Ltd., DR7030HD) was added, and then an adhesive composition was prepared to have a solid content of 20% using a toluene solution.

    [0140] On a PET film (T9145J75) of Mitsubishi Plastics Inc. (MPI) having both surfaces anti-static (AS) treated, the adhesive composition of Comparative Example 1 was coated to prepare an adhesive sheet to a thickness of 15 µm, then PET (RF12ASW) having both surfaces anti-static (AS) treated was coated on the PET film as a protective film, and the result was aged for 2 days at 40°C to manufacture a backplate film.

    <Comparative Example 2>



    [0141] With respect to 100 parts by weight of the (meth)acrylate-based resin prepared in Preparation Example 1, 1 parts by weight of an isocyanate crosslinking agent (Samyoung Ink&Paint Industrial, Co., Ltd., DR7030HD) was added, and after adding 3 parts by weight of the polymer of Preparation 3 polymerized in Preparation Example 2 thereto, an adhesive composition was prepared to have a solid content of 20% using a toluene solution.

    [0142] On a PET film (T9145J75) of Mitsubishi Plastics Inc. (MPI) having both surfaces anti-static (AS) treated, the adhesive composition of Comparative Example 2 was coated to prepare an adhesive sheet to a thickness of 15 µm, then PET (RF12ASW) having both surfaces anti-static (AS) treated was coated on the PET film as a protective film, and the result was aged for 2 days at 40°C to manufacture a backplate film.

    <Comparative Example 3>



    [0143] With respect to 100 parts by weight of the (meth)acrylate-based resin prepared in Preparation Example 1, 1 parts by weight of an isocyanate crosslinking agent (Samyoung Ink&Paint Industrial, Co., Ltd., DR7030HD) was added, and after adding 3 parts by weight of the polymer of Preparation 4 polymerized in Preparation Example 2 thereto, an adhesive composition was prepared to have a solid content of 20% using a toluene solution.

    [0144] On a PET film (T9145J75) of Mitsubishi Plastics Inc. (MPI) having both surfaces anti-static (AS) treated, the adhesive composition of Comparative Example 3 was coated to prepare an adhesive sheet to a thickness of 15 µm, then PET (RF12ASW) having both surfaces anti-static (AS) treated was coated on the PET film as a protective film, and the result was aged for 2 days at 40°C to manufacture a backplate film.

    [0145] The T9145J75 is an adhesive-coated base film, and the RF12ASW may be expressed as a release film.

    [0146] Adhesive strength after laminating the adhesive sheet of one of the backplate films manufactured in Example 1, Example 2, and Comparative Example 1 to Comparative Example 3 with stainless (SUS substrate) was measured, and the measurement details are described in the following Table 2. Herein, when a stick & slip phenomenon occurred in the adhesive strength, an average value of the maximum value was recorded, and when a stick & slip phenomenon did not occur, an average value was recorded.
    [Table 2]
     Example 1Example 2Comparative Example 1Comparative Example 2Comparative Example 3
    Initial Adhesive Strength (gf/in) 42 31 1754 676 36
    Middle Adhesive Strength (gf/in) 43 37 1810 758 38
    Late Adhesive Strength (gf/in) 45 38 1901 921 1876
    1. 1. Initial adhesive strength: the adhesive sheet of one of the backplate films manufactured in Example 1, Example 2, and Comparative Example 1 to Comparative Example 3 was laminated with stainless (SUS substrate) using a 2 kg rubber roller going back and forth once, and after leaving the result unattended for 2 hours at 23°C, adhesive strength was measured by peeling the backplate film from the stainless (SUS substrate) at a 180° angle and a peeling rate of 1800 mm/minute using a texture analyzer.
    2. 2. Middle adhesive strength: the adhesive sheet of one of the backplate films manufactured in Example 1, Example 2, and Comparative Example 1 to Comparative Example 3 was laminated with stainless (SUS substrate) using a 2 kg rubber roller going back and forth once, and after leaving the result unattended for 24 hours at 23°C, adhesive strength was measured by peeling the backplate film from the stainless (SUS substrate) at a 180° angle and a peeling rate of 1800 mm/minute using a texture analyzer.
    3. 3. Late adhesive strength: the adhesive sheet of one of the backplate films manufactured in Example 1, Example 2, and Comparative Example 1 to Comparative Example 3 was laminated with stainless (SUS substrate) using a 2 kg rubber roller going back and forth once, and after leaving the result unattended for 24 hours at 55°C, adhesive strength was measured by peeling the backplate film from the stainless (SUS substrate) at a 180° angle and a peeling rate of 1800 mm/minute using a texture analyzer.


    [0147] As identified in Table 2, the adhesive sheet comprising the adhesive composition of the present application had low initial adhesive strength by comprising a polymer having a melting temperature (Tm) of 60°C or higher and a (meth)acrylate-based resin. Particularly, as identified in Example 1 and Example 2, it was identified that initial adhesive strength was maintained very low compared to Comparative Example 1 and Comparative Example 2. In addition, it was identified that Comparative Example 3 had initial adhesive strength maintained low, however, as identified with late adhesive strength, adhesive strength increased under a high temperature condition (55°C), and stability over time decreased compared to Examples 1 and 2 of the present application. Comparative Example 1 was a case of not using the polymer according to the present application as the adhesive sheet, Comparative Example 2 is a case of using an adhesive sheet having a melting temperature of 36°C as the adhesive sheet, and Comparative Example 3 is a case of using an adhesive sheet having a melting temperature of 48°C as the adhesive sheet.

    [0148] In addition, Example 1 and Example 2 included the polymer having a melting temperature of 60°C or higher in 1 parts by weight to 10 parts by weight with respect to 100 parts by weight of the (meth)acrylate-based resin, and stability over time at a high temperature was excellent, and when not further comprising the (meth)acrylate-based resin, the adhesive sheet was not formed.

    [0149] Particularly, it was identified that the adhesive sheet of the adhesive film according to one embodiment of the present application (Example 1 and Example 2) had, while having low initial adhesive strength, adhesive strength maintained constant without increasing even when stored for a long period of time under a high temperature condition (55°C) compared to Comparative Example 1 to Comparative Example 3, and particularly, adhesive strength was maintained low under a high temperature condition (55°C) as well as under a room temperature condition. This was characteristics obtained by comprising the polymer showing a Tm behavior in the adhesive sheet, and it was identified that stability over time was excellent compared to when comprising the Tg-type polymer.

    [0150] Particularly, in order to obtain active bending, a part of a panel of a plastic organic light emitting diode (POLED) needs to have a process of removing an adhesive sheet, and the backplate film comprising the adhesive sheet according to the present application is capable of preventing damages on the panel by having a property of maintaining low initial adhesive strength even in a state of high temperature (55°C), and it was identified that the backplate film according to the present application was suited.

    [Reference Numeral]



    [0151] 
    101:
    Base Film
    102:
    Adhesive Sheet
    103:
    Adhesive Film
    104:
    Protective Film
    105:
    Backplate Film
    106:
    Plastic Substrate
    107:
    Organic Light Emitting Layer



    Claims

    1. An adhesive composition comprising:

    a (meth)acrylate-based resin; and

    a polymer having a melting temperature (Tm) of 60°C or higher, as measured by using a differential scanning calorimetry (DSC),

    wherein the polymer is a copolymer of a monofunctional polysiloxane and one type of monomer,

    wherein the polymer having a melting temperature of 60°C or higher comprises, based on 100 parts by weight of the polymer having a melting temperature of 60°C or higher, the monofunctional polysiloxane in greater than or equal to 10 parts by weight and less than or equal to 40 parts by weight, and the monomer in greater than or equal to 60 parts by weight and less than or equal to 90 parts by weight, and

    wherein the monomer is represented by the following Chemical Formula 1:

    in Chemical Formula 1,

    X is N or O;

    R1 is hydrogen or a methyl group; and

    n is an integer of 10 to 30.


     
    2. The adhesive composition of Claim 1, wherein n is an integer of 16 to 24.
     
    3. The adhesive composition of Claim 1, wherein adhesive composition comprises, based on 100 parts by weight of the (meth)acrylate-based resin, the polymer having a melting temperature of 60°C or higher in 1 parts by weight to 10 parts by weight.
     
    4. The adhesive composition of Claim 1, wherein the monomer represented by Chemical Formula 1 is behenyl acrylate (BHA).
     
    5. An adhesive film comprising:

    a base film; and

    an adhesive sheet comprising the adhesive composition of any one of Claims 1 to 4 or a cured material thereof provided on one surface of the base film.


     
    6. The adhesive film of Claim 5, further comprising a release film on a surface opposite to the surface in contact with the base film of the adhesive sheet.
     
    7. The adhesive film of Claim 5, wherein, after bonding the surface opposite to the surface in contact with the base film of the adhesive sheet with stainless (SUS304 substrate),

    initial adhesive strength after leaving unattended for 2 hours at 23°C is 19.5 N/m (50 gf/inch) or less;

    middle adhesive strength after leaving unattended for 24 hours at 23°C is 21.5 N/m (55 gf/inch) or less; and

    late adhesive strength after leaving unattended for 24 hours at 55°C is 23.4 N/m (60 gf/inch) or less,

    with the initial adhesive strength, the middle adhesive strength and the late adhesive strength are each measured using a texture analyzer (Stable Micro Systems) at a 180° angle and a peeling rate of 1800 mm/minute, and after attaching the adhesive sheet to stainless (304 substrate) using a 2 kg rubber roller going back and forth once.


     
    8. The adhesive film of Claim 7, wherein the late adhesive strength/the initial adhesive strength is greater than or equal to 0.3 and less than or equal to 2.0, wherein the initial adhesive strength and the late adhesive strength are each measured using a texture analyzer (Stable Micro Systems) at a 180° angle and a peeling rate of 1800 mm/minute, and after attaching the adhesive sheet to stainless (304 substrate) using a 2 kg rubber roller going back and forth once.
     
    9. The adhesive film of Claim 5, wherein the adhesive sheet has a thickness of greater than or equal to 3 µm and less than or equal to 100 µm.
     
    10. The adhesive film of Claim 5, which has a thickness of greater than or equal to 50 µm and less than or equal to 300 µm.
     
    11. A backplate film comprising:

    the adhesive film of Claim 5; and

    a protective film provided on the base film side of the adhesive film.


     
    12. A plastic organic light emitting display comprising:

    the adhesive film of Claim 5;

    a plastic substrate provided on the adhesive sheet side of the adhesive film; and

    an organic light emitting layer provided on a surface opposite to the surface in contact with the adhesive film of the plastic substrate.


     
    13. The plastic organic light emitting display of Claim 12, comprising a protective film provided on the base film side of the adhesive film.
     


    Ansprüche

    1. Haftzusammensetzung, umfassend:

    ein Harz auf (Meth)acrylat-Basis; und

    ein Polymer mit einer Schmelztemperatur (Tm) von 60°C oder höher, gemessen unter Verwendung von dynamischer Differenzkalorimetrie (DDK),

    worin das Polymer ein Copolymer eines monofunktionalen Polysiloxans und einer Art Monomer ist,

    worin das Polymer mit einer Schmelztemperatur von 60°C oder höher, basierend auf 100 Gewichtsteile des Polymers mit einer Schmelztemperatur von 60°C oder höher, das monofunktionale Polysiloxan in mehr als oder gleich 10 Gewichtsteilen und weniger als oder gleich 40 Gewichtsteilen und das Monomer in mehr als oder gleich 60 Gewichtsteilen und weniger als oder gleich 90 Gewichtsteilen umfasst, und

    worin das Monomer durch die folgende chemische Formel 1 dargestellt ist:

    in der chemischen Formel 1,

    X für N oder O steht;

    R1 für Wasserstoff oder eine Methylgruppe steht; und

    n eine ganze Zahl von 10 bis 30 ist.


     
    2. Haftzusammensetzung gemäß Anspruch 1, worin n eine ganze Zahl von 16 bis 24 ist.
     
    3. Haftzusammensetzung gemäß Anspruch 1, worin die Haftzusammensetzung, basierend auf 100 Gewichtsteile des Harzes auf (Meth)acrylat-Basis, das Polymer mit einer Schmelztemperatur von 60°C oder höher in 1 Gewichtsteil bis 10 Gewichtsteile umfasst.
     
    4. Haftzusammensetzung gemäß Anspruch 1, worin das durch die chemische Formel 1 dargestellte Monomer Behenylacrylat (BHA) ist.
     
    5. Haftfolie, umfassend:

    eine Basisfolie; und

    einen Haftbogen, der die Haftzusammensetzung gemäß einem der Ansprüche 1 bis 4 oder ein gehärtetes Material davon auf einer Oberfläche des Basisfilms bereitgestellt umfasst.


     
    6. Haftfolie gemäß Anspruch 5, ferner umfassend einen Trennfilm auf einer Oberfläche, die der Oberfläche gegenüberliegt, die mit der Basisfolie des Haftbogens in Kontakt steht.
     
    7. Haftfolie gemäß Anspruch 5, worin nach dem Verkleben der Oberfläche, die der Oberfläche gegenüberliegt, die in Kontakt mit der Basisfolie des Haftbogens mit rostfreiem (SUS304-Substrat) steht,

    die anfängliche Haftkraft nach 2 Stunden unbeaufsichtigter Lagerung bei 23°C 19,5 N/m (50 gf/inch) oder weniger beträgt;

    die mittlere Haftkraft nach 24 Stunden unbeaufsichtigter Lagerung bei 23 °C 21,5 N/m oder weniger beträgt; und

    die späte Haftkraft nach 24 Stunden unbeaufsichtigter Lagerung bei 55 °C 23,4 N/m (60 gf/inch) oder weniger beträgt,

    wobei die anfängliche Haftkraft, die mittlere Haftkraft und die späte Haftkraft jeweils mit einem Texturanalysator (Stable Micro Systems) bei einem Winkel von 180° und einer Abziehgeschwindigkeit von 1800 mm/Minute und nach dem Anbringen des Haftbogens auf rostfreiem (304er Substrat) mit einer 2 kg schweren Gummiwalze, die einmal hin und her bewegt wird, gemessen werden.


     
    8. Haftfolie gemäß Anspruch 7, worin die späte Haftkraft/die anfängliche Haftkraft größer oder gleich 0,3 und kleiner oder gleich 2,0 ist, wobei die anfängliche Haftkraft und die späte Haftkraft jeweils unter Verwendung eines Texturanalysators (Stable Micro Systems) bei einem Winkel von 180° und einer Abziehgeschwindigkeit von 1800 mm/Minute und nach dem Anbringen des Haftbogens auf rostfreiem (304er) Substrat unter Verwendung einer 2 kg schweren Gummiwalze, die einmal hin und her bewegt wird, gemessen werden.
     
    9. Haftfolie gemäß Anspruch 5, worin der Haftbogen eine Dicke von mehr als oder gleich 3 µm und weniger als oder gleich 100 µm aufweist.
     
    10. Haftfolie gemäß Anspruch 5, die eine Dicke von mehr als oder gleich 50 µm und weniger als oder gleich 300 µm aufweist.
     
    11. Rückplattenfolie, umfassend:

    eine Haftfolie gemäß Anspruch 5; und

    eine Schutzfolie, die auf der Seite der Basisfolie der Haftfolie angeordnet ist.


     
    12. Organische lichtemittierende Kunststoffanzeige, umfassend:

    die Haftfolie gemäß Anspruch 5;

    ein Kunststoffsubstrat, das auf der Seite des Haftbogens der Haftfolie angeordnet ist; und

    eine organische lichtemittierende Schicht, die auf einer Oberfläche angeordnet ist, die der Oberfläche gegenüberliegt, die in Kontakt mit der Haftfolie des Kunststoffsubstrats steht.


     
    13. Organische lichtemittierende Kunststoffanzeige gemäß Anspruch 12, umfassend eine auf der Seite der Basisfolie der Haftfolie angeordnete Schutzfolie.
     


    Revendications

    1. Composition adhésive comprenant :

    une résine à base de (méth)acrylate ; et

    un polymère présentant une température de fusion (Tm) de 60 °C ou plus, telle que mesurée en utilisant une calorimétrie différentielle à balayage (DSC),

    dans laquelle le polymère est un copolymère d'un polysiloxane monofonctionnel et d'un type de monomère,

    dans laquelle le polymère présentant une température de fusion de 60 °C ou plus comprend, sur la base de 100 parties en poids du polymère présentant une température de fusion de 60 °C ou plus, le polysiloxane monofonctionnel supérieur ou égal à 10 parties en poids et inférieur ou égal à 40 parties en poids, et le monomère supérieur ou égal à 60 parties en poids et inférieur ou égal à 90 parties en poids, et

    dans laquelle le monomère est représenté par la formule chimique 1suivante :

    dans la formule chimique 1,

    X vaut N ou 0 ;

    R1 est l'hydrogène ou un groupe méthyle ; et

    n est un nombre entier de 10 à 30.


     
    2. Composition adhésive sellon la revendication 1, dans laquelle n est un nombre entier de 16 à 24.
     
    3. Composition adhésive selon la revendication 1, dans laquelle la composition adhésive comprend, sur la base de 100 parties en poids de la résine à base de (méth)acrylate, le polymère présentant une température de fusion de 60 °C ou plus dans 1 partie en poids à 10 parties en poids.
     
    4. Composition adhésive selon la revendication 1, dans laquelle le monomère représenté par la formule chimique 1 est l'acrylate de béhényle (BHA).
     
    5. Film adhésif comprenant :

    un film de base ; et

    une feuille adhésive comprenant la composition adhésive selon l'une quelconque des revendications 1 à 4 ou un matériau durci de celle-ci fourni sur une surface du film de base.


     
    6. Film adhésif selon la revendication 5, comprenant en outre un film à libération sur une surface opposée à la surface en contact avec le film de base de la feuille adhésive.
     
    7. Film adhésif selon la revendication 5, dans lequel, après la liaison de la surface opposée à la surface en contact avec le film de base de la feuille adhésive avec de l'acier inoxydable (substrat SUS304),

    une résistance adhésive initiale après avoir été laissée sans surveillance pendant 2 heures à 23 °C est de 19,5 N/m (50 gf/pouce) ou moins ;

    une résistance adhésive médiane après avoir été laissée sans surveillance pendant 24 heures à 23 °C est de 21,5 N/m (55 gf/pouce) ou moins ; et

    une résistance adhésive tardive après avoir été laissée sans surveillance pendant 24 heures à 55 °C est de 23,4 N/m (60 gf/pouce) ou moins,

    la résistance adhésive initiale, la résistance adhésive médiane et la résistance adhésive tardive étant chacune mesurées en utilisant un analyseur de texture (Stable Micro Systems) selon un angle de 180° et un taux de pelage de 1800 mm/minute, et après la fixation de la feuille adhésive à de l'acier inoxydable (substrat 304) en utilisant un rouleau de caoutchouc de 2 kg effectuant un aller-retour.


     
    8. Film adhésif selon la revendication 7, dans lequel la résistance adhésive tardive/la résistance adhésive initiale est supérieure ou égale à 0,3 et inférieure ou égale à 2,0, dans lequel la résistance adhésive initiale et la résistance adhésive tardive sont chacune mesurées en utilisant un analyseur de structure (Stable Micro Systems) selon un angle de 180 ° et un taux de pelage de 1 800 mm/minute, et après la fixation de la feuille adhésive à de l'acier inoxydable (substrat 304) en utilisant un rouleau de caoutchouc de 2 kg effectuant un aller-retour.
     
    9. Film adhésif selon la revendication 5, dans lequel la feuille adhésive présente une épaisseur supérieure ou égale à 3 µm et inférieure ou égale à 100 µm.
     
    10. Film adhésif selon la revendication 5, qui présente une épaisseur supérieure ou égale à 50 µm et inférieure ou égale à 300 µm.
     
    11. Film de contre-plaque comprenant :

    le film adhésif selon la revendication 5 ; et

    un film protecteur fourni sur la face de film de base du film adhésif.


     
    12. Dispositif d'affichage électroluminescent organique en plastique comprenant :

    le film adhésif selon la revendication 5 ;

    un substrat en plastique fourni sur la face de feuille adhésive du film adhésif ; et

    une couche électroluminescente organique fournie sur une surface opposée à la surface en contact avec le film adhésif du substrat en plastique.


     
    13. Dispositif d'affichage électroluminescent organique en plastique selon la revendication 12, comprenant un film protecteur fourni sur la face de film de base du film adhésif.
     




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    Cited references

    REFERENCES CITED IN THE DESCRIPTION



    This list of references cited by the applicant is for the reader's convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.

    Patent documents cited in the description