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Jouve S.A., EPO - Publication - KB, TaggedPDF v1.27
EP-0495548-A2-19920722
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EP-0495548-A2-19920722
The invention relates to a process for the carbonylation of olefins in which process an olefin is reacted with carbon monoxide in the presence of an alcohol or water and of a catalyst system, obtainable by combining:(a) a metal of Group VIII or a compound thereof and(b) a bidentate phosphine, arsine and/or stibine derivative, wherein as bidentate (b) a compound is selected having the general formula R¹R²-M¹-R-M²-R³R⁴ Iwherein M¹ and M² are independently P, As or Sb, R is a divalent organic bridging group with at least 2 carbon atoms in the bridge, and R¹-R⁴ represent the same or different optionally substituted tertiary alkyl groups. The invention further relates to a catalyst system suitable for this process.
The invention relates to a process for the carbonylation of olefins in which process an olefin is reacted with carbon monoxide in the presence of an alcohol or water and of a catalyst system, obtainable by combining:(a) a metal of Group VIII or a compound thereof and(b) a bidentate phosphine, arsine and/or stibine derivative, wherein as bidentate (b) a compound is selected having the general formula R¹R²-M¹-R-M²-R³R⁴ Iwherein M¹ and M² are independently P, As or Sb, R is a divalent organic bridging group with at least 2 carbon atoms in the bridge, and R¹-R⁴ represent the same or different optionally substituted tertiary alkyl groups. The invention further relates to a catalyst system suitable for this process.
en
European Patent Office
EP0495548
EP 0495548
C07C 51/14
C07C 67/38
Process for the carbonylation of olefin
Process for the carbonylation of olefin - European Patent Office - EP 0495548 A2
Process for the carbonylation of olefin - European Patent Office - EP 0495548 A2
Adobe PDF Library 8.0
"EP0495548"; "EP 0495548"; "C07C 51/14"; "C07C 67/38"; "Process for the carbonylation of olefin"
1.4
1
B
12
EP
0495548
A2
1992-07-22
92200060
1992-01-10
EP
91203014
1991-11-19
GB
9100801
1991-01-15
C07C 51/14
C07C 67/38
SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
Drent, Eit
Kragtwijk, Eric
Process for the carbonylation of olefin
Verfahren zur Karbonylierung von Olefin
Process for the carbonylation of olefin
Procédé de carbonylation d'oléfine
The invention relates to a process for the carbonylation of olefins in which process an olefin is reacted with carbon monoxide in the presence of an alcohol or water and of a catalyst system, obtainable by combining:(a) a metal of Group VIII or a compound thereof and(b) a bidentate phosphine, arsine and/or stibine derivative, wherein as bidentate (b) a compound is selected having the general formula R¹R²-M¹-R-M²-R³R⁴ Iwherein M¹ and M² are independently P, As or Sb, R is a divalent organic bridging group with at least 2 carbon atoms in the bridge, and R¹-R⁴ represent the same or different optionally substituted tertiary alkyl groups. The invention further relates to a catalyst system suitable for this process.
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