[0001] The invention relates to the art of conjugate filaments splittable into sub-filaments.
More particularly, it relates to a process and product wherein the conjugate filament
itself has no substantial texture while sub-filaments splittable therefrom have substantial
latent torqueless helical crimp.
[0002] Conjugate filaments splittable into sub-filaments are known to the art, as typified
by Hayashi U.S.-Patent 4,051,287. As disclosed therein, alternating segments of polyamide
and polyester are spun in a side-by-side adhering relationship to form a hollow filament
splittable into sub-filaments. Such sub-filaments can be of smaller denier than can
be conventiently spun as separate filaments, lending a soft hand to fabrics made therefrom.
The sub-filaments of Hayashi are not disclosed as possessing significant crimp, and,
as illustrated in Figure 10 of the patent, are substantially flat (untextured) even
though the conjugate filament had been textured by the false-twist heat-set method
before being split into sub-filaments.
[0003] According to the invention, there is provided a conjugate filament splittable into
sub-filaments having substantial latent torqueless helical crimp.
[0004] According to a major aspect of the invention, there is provided a process for melt-spinning
a hollow conjugate filament splittable into spontaneously texturing sub-filaments,
the process comprising extruding a hollow molten stream formed from axially extending
segments of dissimilar polymers arranged alternately in side-by-side adhering relationship
to form the hollow molten stream; quenching the stream under given conditions to form
a filament; and withdrawing the filament from the molten stream at a given spinning
speed, the polymers, the given spinning speed and the given conditions being selected
such that sub-filaments split from the filament possess substantial latent torqueless
helical crimp.
[0005] According to another aspect of the invention, some of the segments are of polyamide
polymer and others of the segments are of polyester polymer.
[0006] According to another aspect of the invention, the polyamide polymer is nylon 66 and
the polyester polymer is polyethylene terephthalate.
[0007] According to another major aspect of the invention, there is provided a conjugate
filament comprising sub-filaments releasably attached to one another in a side-by-side
relationship, the filament being substantially free of crimp, the sub-filaments possessing
substantial latent torqueless helical crimp.
[0008] According to another aspect of the invention, the filament is hollow.
[0009] According to another aspect of the invention, some of the sub-filaments are formed
from a polyamide polymer and others of the sub-filaments are formed from a polyester
polymer.
[0010] According-to another aspect of the invention, the polyamide polymer is nylon 66 and
the polyester polymer is polyethylene terephthalate.
[0011] Other aspects of the invention will in part appear hereinafter and will in part be
obvious from the following detailed description taken together with the accompanying
drawing, in which:
[0012] The FIGURE is a bottom plan view (looking up) of the preferred spinneret orifice
used in practicing the invention.
[0013] As shown in the FIGURE, the preferred spinneret construction includes several generally
arched or horseshoeshaped slots 20 in spinneret blank 22 arranged symmetrically about
a central point, the open ends of the horseshoe shape facing inwardly. The several
slots 20 constitute a combined orifice for spinning a single filament. Slots 20 extend
entirely through blank 22 except for a recessed web region 24 at the apex of each
slot 20. The two dissimilar polymers are fed to the combined orifice as a sheath-core
stream, with dotted circle 26 representing the interface between the two polymers.
The adjacent ends of adjacent slots 20 are sufficiently close that the streams issuing
therefrom unite just below the spinneret. The molten stream is thus a hollow structure
composed of alternating axially extending segments of the two polymers. Surface tension
and other effects tend to make the molten stream approach a hollow circular cross-
section prior to solidification, substantially as shown in Hayashi Figure 1.
[0014] Each polymer segment accordingly has a portion of its periphery exposed to quenching
on the exterior of the hollow stream, and an opposite portion shielded and not so
exposed since it lies in the interior. According to the invention, the molten stream
is exposed while under the stress of spinning to quenching sufficiently rapid as to
produce substantial latent torqueless helical crimp in the sub-filaments splittable
from the conjugate filament.
Example I
[0015] Nylon 66 polymer and polyethylene terephthalate polymer, each of normal molecular
weight for apparel end uses, are extruded at a temperature of 290°C. through the combined
orifice, the nylon polymer being the core of the sheath-core stream approaching the
combined orifice. Equal volumes of the two polymers are supplied, with the extrusion
rate selected to produce a conjugate filament having a denier of 19.5 at a spinning
speed of 1500 yards (about 1350 meters) per minute. A quench zone just beneath the
spinneret and 12 meters in height is supplied with quenching air at 20°C., the air
being directed horizontally onto the polymer stream and having a speed of 25 meters
per minute. Below the quench zone, steam is applied to the filament, a conventional
finish is applied, and the filament is wound.
[0016] The spun filament is then drawn at 65 meters per minute and at a draw ratio of 2.16
over a contact heater at 132°C., the heater being 0.4 meters long. The resulting drawn
yarn, when mechanically worked to break the conjugate filament into 12 sub-filaments,
develops substantial torqueless helical crimp when subjected to boiling water.
Example II
[0017] Seventeen of the above spun filaments are spun simultaneously and collected as a
multifilament yarn under the spinning conditions of Example I. The spun yarn is then
draw- textured at 540 meters per minute over a two meter heater set at 220°C. The
resulting textured yarn, when separated into sub-filaments and relaxed, is very voluminous
and has high covering power.
Example III
[0018] Example I is repeated, except that the spinning speed is increased to 4500 meters
per minute while the denier of the conjugate filament is reduced to 4. The resulting
sub-filaments, after separation and immersion in boiling water, form a highly voluminous
and lofty yarn. Fabrics formed from the conjugate yarn acquire a very soft hand and
increased bulk and covering power when the fabric is mechanically worked enough to
separate the yarn into sub-filaments. Simple exposure of the fabric to boiling water
is adequate in many instances, since the flexing of the yarn involved in certain fabric
formations separates the sub-filaments.
1. A process for melt-spinning a hollow conjugate filament splittable into spontaneously
texturing sub-filaments, said process comprising:
a. extruding a hollow molten stream formed from axially extending segments of dissimilar
polymers arranged alternately in side-by-side adhering relationship to form said hollow
molten stream;
b.. quenching said stream under given conditions to form a filament; and
c. withdrawing said filament from said molten stream at a given spinning speed, said
polymers, said given spinning speed and said given conditions being selected such
that sub-filaments split from said filament possess substantial latent torqueless
helical crimp.
2. The process defined in claim 1, wherein some of said segments are of polyamide
polymer and others of said segments are of polyester polymer.
3. The process defined in claim 2, wherein said polyamide polymer is nylon 66 and
said polyester polymer is polyethylene terephthalate.
4. A conjugate filament comprising sub-filaments releasably attached to one another
in a side-by-side relationship, said filament being substantially free of crimp, said
sub-filaments possessing substantial latent torqueless helical crimp.
5. The filament defined in claim 4, wherein said filament is hollow.
6. The filament defined in claim 4, wherein some of said sub-filaments are formed
from a polyamide polymer and others of said sub-filaments are formed from a polyester
polymer.
7. The filament defined in claim 6, wherein said polyamide polymer is nylon 66 and
said polyester polymer is polyethylene terephthalate.
8. A method comprising splitting a filament defined in any of claims 4 to 7 into sub-filaments.