[0001] The present invention relates to a granulated material comprising a refractory framework
coated with a material fit for providing "lustrous carbon" and suitable for the composition
of foundry molding sands.
[0002] The invention also relates to a method for the production of said granulated material
as well as to the compositions of the molding sands containing such material.
[0003] Molding sand actually used in foundry practice for the production of molds for cast-iron
castings consists of sand and clay as binder. Bentonite is especially used with advantage
as binding clay.
[0004] In the composition of molding sands a coal dust is usually added with the main purpose
of preventing formation of defects on the surface of castings. Said defects, as it
is known, are prevalently due to the thermal expansion of the sand and to metal-mold
material reactions such as the formation of ferrous oxide on the surface of castings
which, by reaction with silic , produces low-melting point silicates responsible for
surface roughness in the castings. The coal dust absorbs the thermal expansion of
the sand, since during the casting, when the surface temperature of the mold rises
to about 1000°C, it is caused to distill releasing volatile matter and increasing
the void around the expanding sand grains. Furthermore said volatile matter generates
an inert atmosphere and produces "lustrous carbon" which coats the sand grains with
a refractory film, not wettable by molten metal, thus avoiding the metal from reacting
with the mold material.
[0005] "Lustrous carbon" is defined as an allotropic, optically isotropic state of the carbon
having a microcrystalline, essentially bidimensional structure, intermediate between
amorphous carbon and graphite. Lustrous carbon is obtained on wide specific surfaces
by pirolysis of heavy hydrocarbons which are released by carbon-based materials during
contact with the molten metal. Properties, characteristics and methods of analysis
concerning lustrous carbon are extensively described by V.I. Bindermagel, A. Kolors,
K. Orthus: Schnellverfahren zur Bestimmung der aus Formstoffzu- satzen (method of
analysis for mold materials additives), Giesserei,Vol. 51, 12 Nov., page 729-730 (1964).
[0006] Moreover, the addition of coal dust improves green and dry strength of the sand and
reduces gas permeability.
[0007] Coal dusts which have been extensively used in the past are natural substances such
as milled low-grade anthracite or pearl-pitch, characterized by a low content of ash
and noxious products such as sulphur, with a lustrous carbon yield not greater than
12% of its own weight and normally lower than 10%. More recently advanced techniques
for the preparation of coal dusts have introduced the use of synthetic substances
yielding more than 70% of lustrous carbon, thus considerably reducing (up to 7 times)
the amount of coal dust used.
[0008] Therefore recent practice in the preparation of molding sands (which contain 80-85%
by weight of a refractory material, clay substance as binders and the above mentioned
carbon-based materials) is to use both synthetic substances with a high yield of lustrous
carbon and natural substances such as low-grade anthracite powders or mixtures thereof.
[0009] In any case the molding sands, after their use for molding, are continuously regenerated
to produce new molds and are added with refractory material, clay binder and carbon-based
additives at each cycle.
[0010] The most common refractory material used for the preparation of molding sands is
silica sand because of its low cost; other types of sand, such as olivine, chamotte,
chromite, zircon, sillimanite, mullite and the like can be used for particular purposes.
Nevertheless it is well known that with respect to other kinds of sands, a serious
drawback of silica sand consists in that it has a higher thermal expansion coefficient,
which moreover increases suddently at about 500°C in correspondence to the quartz
allotropic transformation from the alpha to beta state.
[0011] According therefore to actual foundry practice for regenerating additions, silica
sand is generally used, as well as compositions based on bentonite or binding clays
as binders, low-grade anthracite powders or synthetic materials or mixtures thereof
as carbon-based additives.
[0012] Dilatometric properties of molding sand, according to this way of working, remain
nearly unchanged or tend to get worse progressively with regenerating cycles. Furthermore
the actual practice is to add the additives as powders to the molding sand, especially
the carbon-based ones and particularly the synthetic ones with a high lustrous carbon
yield. This fact produces a serious pollution problem, a suspension of fine dust being
present in the working environment, besides a further problem concerning the metering
of the various additives to the exhausted sand. In this connection the addition of
synthetic material with a high lustrous carbon yield was suggested by the Applicant
to be carried out in form of a pre-mixed matter together with the clay binder, thereby
partly reducing handling and working problems.
[0013] It is the object of the invention to improve the composition of green molding sands
by adding to them, during regeneration, a refractory material, characterized by a
lower thermal expansion coefficient than the one of the initially used sand, which
is, in other words, able to positively and progressively modify its dilatometric properties.
[0014] Another object of the invention is to produce quartz- and dust-free material to be
used for the preparation of molding sands, thereby reducing both pollution of the
working environment and material handling problems.
[0015] According to the invention, a granulated material for the preparation of molding
sands is provided, the size of the granules being in the range of 0.1+0.4 mm, i.e.
a dust-free material, comprising a refractory framework externally coated with.a synthetic
coal dust material fit for providing lustrous carbon in a similar amount to the one
produced by a natural coal dust. In particular, the refractory framework will be made
with a material having a null or very low thermal expansion coefficient, such as zircon,
chamotte, chromite, olivine, sillimanite or mullite sands and preferably consisting
of a silicate with a content of free crystalline silica not greater than 3%.
[0016] In this way the addition of only one component to the foundry molding sands has the
double effect of adding a coal dust and of regenerating the sand with a refractory
material. Thus avoiding the handling of powder-producing materials and contemporaneously
adding a refractory material, during regenerative additions, which progressively improves
the dilatometric properties of the refractory framework as a whole.
[0017] The refractory framework material, according to the invention, is precoated with
a substance fit for producing a considerable amount of lustrous carbon upon melting.
As lustrous carbon producing material, organic polymers with softening temperature
range of 70-180°C are generally used, such as plastics or resins of the type of polyethylene,
polypropylene, coumaronic resins, polystyrene, glycerophtalic resins, petrolic resins,
glysonite and pitchy substances, phenolic resins and more generally any other material
fit for producing, upon melting, lustrous carbon according to foundry methods in an
amount ranging between 15 and 90% of its own weight.
[0018] A method for producing the granulated material according to the invention comprises
melting the organic material and mixing it in a hot process with the granules of refractory
material.
[0019] Another method is based on the fact that said organic material is solvent-soluble
and therefore can be directly added to the granules of refractory material when mixed
in a drum with a solvent, in order to produce a proper resin coating on the granules
by evaporating the solvent, which is recovered in a subsequent step. A person skilled
in the art is well aware of how selection of the solvent, on the basis of the type
of organic material used, is to be carried out. A particularly preferred solvent is
white spirit.
[0020] The material produced according to said methods is homogeneous, granular and dust-free,
each granule being coated with a layer of carbon-based material yielding a high percentage
of lustrous carbon. Such homogeneous granulated material is directly used for regenerating
molding sands, in place of the two separate components of refractory framework and
coal dust.
[0021] A practical, particularly preferred application of this invention provides for the
use of olivine sand,, chromite sand or the like or their mixtures either with a granule
size ranging between 0.1 and 0.4 mm or as a powder. The sand, or sand mixture, is
heated to 150°C and then mixed with coumaronic resin; the percentage of the resin
is 10% calculated on the weight of the refractory framework. After a few minutes of
mixing, during which liquefied resin produces a coating on the refractory granules,
the mixture is cooled and sieved to break any possible lump, thus obtaining a dust-free
granulated material.
[0022] Practical examples concerning the production of the granulated material according
to the invention will be given hereinafter.
Example 1
[0023] 900 kg of chromite sand with a particle size of 0.1-0.3 mm and a Cr
20
3 content of 44.5% are fed to a mixing drum and heated to 160°C, then 100 kg of polystyrene
in the form of granules or powder are added whith the following characteristics:
[0024] After 3-4 minutes of mixing, the mixture is cooled and discharged onto a vibrating
screen to obtain a granulated material with a granule size ranging between 0.1 and
0.3 mm, each granule being coated with polystyrene.
[0025] Said cromite sand precoated with polystyrene yields 7-8% of its own weight in lustrous
carbon, the same amount being provided by a coal dust obtained from the grinding of
a low-grade anthracite. Such a synthetic material can be added to a molding sand according
to normal practice in the art for the addition of coal dust.
Example 2
[0026] 950 kg of olivine sand with granule size ranging between 0.06 and 0.4 mm,and the
following chemical analysis:
are fed to a mixing drum with 100 kg of a solution containing 50% of white spirit
and 50% of petrolic resin, with the following characteristics:
after a few minutes of mixing, the solvent is sucked from the mixing drum to completely
coat the sand granules with the resin. Any possible dot is broken on a vibrating screen
thus obtaining a dust-free material yielding a percentage of lustrous carbon corresponding
to 3-3.5% of its own weight.
[0027] Said material is added to a molding sand in such an amount so as to have a constant
lustrous carbon yield equal to 0.2-0.6%. In this way the molding sand is also enriched
with a non-expandable refractory material, thus minimizing surface defects on castings
due to thermal expansion problems.
[0028] According to the practice of the invention, the amount of resin-based coating on
the refractory material will be of 0.5 to 60% by weight and in particular more preferably
1.0 to 30.% by weight. For example, a refractory material with 25% of coating consisting
of a synthetic substitute of a mineral coal dust, would be able to. release upon melting
lustrous carbon in the percentage of 15-16% by weight.
[0029] In addition to the above mentioned advantages concerning dust-free handling of the
material and the progressive improvement of the dilatometric properties of the initial
molding sand, the granulated material according to the invention further offers the
advantage of improving the extracting properties of castings and obtaining better
surfaces on same.
1. A granulated material for the preparation of foundry molding sand, characterized
in that it comprises a refractory framework in the form of granules, whose size ranges
from 0.1 to 0.4 mm, and an external coating on said refractory framework, consisting
of a material fit for providing lustrous carbon in an amount ranging from 15 to 90%
of its own weight, the amount of coating of said material on said refractory framework
being 0.5 to 60% of the total weight of the granulated material.
2. The granulated material according to claim 1, in which said refractory framework
consists of a material ser lected between zircon sand, chamotte, chromite, olivine,
sillimenite,mullite, or mixtures thereof, with a free silica content not greater than
3%.
3. The granulated material according to claims 1 or 2, in which said material fit
for providing lustrous carbon is a material selected among plastics or resins as polyethylene,
polypropylene, coumaronic resins, polystyrene, glycerophtalic resins, petrolic resins,
glysonite and pitchy substances, phtalic anidride, phenolic resins and their mixtures,
the amount of lustrous carbon supplied by said material during the melting process
being from 15 to 90% of its own weight.
4. A method for the production of a granulated material as claimed in any of the preceding
claims from 1 to 3, including the steps of: heating in a mixing drum at a temperature
of 70-180°C a refractory material in the form of granules with a size range of 0.1
to 0.4 mm; feeding the mixing drum with a material fit for providing lustrous carbon
in an amount of 15 to 90% of its own weight, thus producing a mixture therein; mixing
the mixture so that the material fit for providing lustrous carbon coats the refractory
granules; cooling the mixture, and sieving it in order to break any possible lump.
5. The method for the production of a granulated material as claimed in any of the
previous claims from 1 to 3, consisting of: feeding a mixing drum with a refractory
material in the form of granules with a size range of 0.1 to 0.4 mm; feeding said
mixing drum with a material fit for providing lustrous carbon in an amount of 15 to
90% of its own weight, said material being dissolved in a solvent; mixing the mixture;
evaporating said solvent so as to cause the material fit for providing lustrous carbon
to coat the refractory granules; and sieving said granulated material in order to
break any possible lump.
6. A foundry molding sand including a granulated material as claimed in any of the
claims from 1 to 3, in such an amount that the lustrous carbon yield of said molding
sand is 0.2 to 9.6% of the total weight of said molding sand.