[0001] The present invention is concerned with a process for dry cleaning soiled textile
articles, in particular, textile articles having a visually dominant colour.
[0002] Textile articles, such as upholstery fabric, curtains and articles of clothing, are
conventionally dry cleaned in a dry cleaning machine using a dry cleaning solvent
comprising a chlorinated and/or fluorinated hydrocarbon, or a hydrocarbon solvent.
Examples of conventional dry cleaning solvents include carbon tetrachloride, ethylene
dichloride, perchloroethylene, trichlorofluoromethane, tetrachlorodifluoroethanes,
dichlorotetrafluoroethanes, trichlorotrifluoroethanes, or mixtures thereof, and hydrocarbon
solvents such as solvent naphtha.
[0003] While such a dry cleaning process generally results in satisfactory cleanliness,
improvements in the process are continually being sought.
[0004] According to the present invention, there is provided a process of dry cleaning a
soiled textile -article having a visually dominant colour, the dry cleaning being
effected by means of a dry cleaning solvent in one or niore stages, the solvent having
dissolved therein, in at least the last stage, a liquid vehicle in which is dispersed
a dye or pigment which is substantive for fibres constituting the article, the dye
or pigment being such that it colour-matches the visually dominant colour.
[0005] In the case of an article having a single colour, the visually dominant colour is,
of course, that single colour; in the case of an article having a plurality of colours,
one of the perceived colours is often perceived as appearing to have a greater colour
intensity than other colours and it is this perceived colour which is visually dominant.
The visually dominant colour is often the background in, for example, upholstery fabrics
having a plurality of colours.
[0006] The process according to the invention results in restoration of the perceived colour
(or visually dominant colour) of the cleaned article, which gives the latter a fresher,
cleaner appearance.
[0007] The liquid vehicle in which the dye or pigment is dispersed is preferably a detergent
liquid which is soluble in the dry cleaning solvent; an example of such a detergent
liquid is available commercially under the trade mark Fluoradet. Such detergent liquids
are conventionally added to the dry-cleaning solvent before and during dry-cleaning.
[0008] The detergent liquid is preferably anionic, non-ionic, or a mixture thereof. (Cationic
detergent liquids are not preferred, because it is preferred to use an anionic dye
in the process according to the invention, and such dyes would have undesirable reactions
with cationic detergent liquids). Examples of suitable anionic and non-ionic detergents
are given in British Specification 1)07318; an example of a preferred non-ionic detergent
liquid is sorbitan mono-oleate.
[0009] The detergent liquid is generally used in a very low concentration, such as less
than about 5 ml. per litre of dry cleaning solvent. A typical amount used is in the
range 100 to 200 ml. per 60 litres of dry cleaning solvent.
[0010] The dye or pigment dispersed in the detergent liquid (in undissolved form) is preferably
an anionic dye, such as an Aniline dye. Suitable dyes of this type are commercially
available under the trade mark Nylomine (this trade mark is used for a range of water-soluble
anionic reactive dyes).
[0011] When an ionic dye is used, it preferably has a pH within two units (more preferably
within one unit) of that of the fibres being treated. Thus when the fibres have a
pH of, say, 4-6, the dye bath preferably has a pH in the range 4 to 5, or 6.'
[0012] The amount of dye or pigment used is substantially less than would be used in a conventional
dyeing process because the purpose of the dye is merely to restore or enhance an existing
colour. A typical proportion of dye for use according to the invention is up to 1.5
grams per litre of dry cleaning solvent.
[0013] Loss of dye or pigment in the process according to the invention can be minimal;
for example, about 98% (or more) of the dye or pigment not taken up by the textile
article can be recovered from the dry cleaning solvent. This represents a considerable
advantage over sequential dry cleaning and dyeing (the latter is normally carried
out using an aqueous medium, from which it is generally more difficult to recover
the dye).
[0014] The process according to the invention can be employed for any conventional textile
material, such as polyamides, polyesters, wool, acrylics, cellulosic materials, and
even polypropylene, which is notoriously difficult to colour. The fibres preferably
have a pH
'not exceeding 3.
[0015] The process according to the invention is preferably carried out in a sealed dry
cleaning machine (which is preferably a conventional sealed unit) and not in situ
in the case of, for example, upholstery fabric and curtains, since the immersion of
the textile in dry cleaning solvent containing dissolved liquid in which a dye or
pigment is dispersed ensures even penetration of the fabric and even colour restoration.
[0016] When the process according to the invention is carried out in a sealed dry cleaning
machine, the dye or pigment is preferably added to the dry cleaning solvent in a final
rinse stage only. In this case, the dye or pigment is preferably added in the form
of a concentrated dispersion in a detergent liquid; such a dispersion preferably contains
30 to 100 grams of dye or pigment per litre of detergent liquid.
[0017] The dry cleaning solvent and the liquid vehicle dissolved therein may additionally
contain materials such as antistatic agents, flame retardants, biocides and/or perfumes;
treatment which might previously have been carried out in several stages can advantageously
be carried out according to the invention in a single stage.
[0018] When the textile article being dry cleaned according to the invention has previously
been provided with a flame-retardant finish, it is particularly preferred that a concentrated
dispersion of dye or pigment in a detergent liquid (added during the final rinse stage
as described above) contains dispersed or dissolved flame retardant material. This
is because it has been found that staining of textile material often causes deterior--
ation of an existing flame retardant finish; the flame retardant properties of the
textile article can be restored according to the invention at the same time as the
article is cleaned.
[0019] The cleaned article obtained according to the invention can have a restored colour
which is fast to water, acid, alkalies, perspiration,washing,wet and dry rubbing and
Xenon light.
[0020] The present invention is illustrated by the following Example.
example
[0021] An industrial dry cleaning machine was loaded with soiled wool-based upholstery-fabric
having a red/orange pattern (of which the red was visually dominant).
[0022] The fabric was subjected to a conventional washing cycle, using 60 litres of a dry
cleaning solvent based on 1,1,2-trichloro 1,2,2-trifluoroethane, and then spun dry.
[0023] The fabric was then subjected to a rinsing cycle, using 60 litres of the same dry
cleaning solvent as used in the first cycle. During the rinsing a solution of 100
ml. of sorbitan mono-oleate in 1,1,2-trichloro 1,2,2-trifluoroethane, the solution
having dispersed therein 0.5 g. of a red Aniline dye (available commercially as Nylomine
Red C-3B).
[0024] Two litres of Protiflam (a commercially available flame retardant material) was added
to the solvent at a subsequent stage of the rinsing cycle,and the fabric was then
spun dry.
[0025] The resulting cleaned fabric had a restored red colour, and a cleaner fresher appearance.
The cleaned fabric also had its flame retardant properties restored. The fabric passed
the following tests of British Standard 1006 (
1978); E07, E04, E03, X12 and B02, and a special wash test designated IS03 (Marks and
Spencer).
1. A process of dry cleaning a soiled textile article having a visually dominant colour,
the dry cleaning being effected using a dry cleaning solvent in one or more stages,
the dry cleaning solvent containing, in at least the last stage, a dye or pigment
which is substantive for fibres constituting the article and which colour-matches
said visually dominant colour, the dye or pigment being dispersed in a liquid vehicle
which is itself dissolved in said solvent.
2. A process according to claim 1, in which the dye or pigment is present in said
solvent in an amount not exceeding 1.5 grams per litre.
3. A process according to claim 1 or 2, in which said liquid vehicle is a detergent
liquid.
4. A process according to any of claims 1 to 3, in which the dry cleaning solvent
also contains an antistatic agent, a flame retardant, a biocide, a perfume, or a mixture
of two or more thereof.
5. A process according to any of claims 1 to 4, in which the textile article is soiled
upholstery fabric which has been removed from furniture.
6. A process according to any of claims 1 to 5, which is carried out in a sealed dry
cleaning machine.
7. A process according to claim 6, in which the dye or pigment is present in the dry
cleaning solvent only in a final rinse stage.