Apparatus for casting metal filaments

Description

[0001] The present invention relates to an apparatus for chill casting of metallic materials.

[0002] Extraction of filaments from a liquid melt has been employed to form amorphous metal filaments. For example, the US-A-3 863 700 discloses a method and apparatus for filament extraction from molten metal contained in a vessel. This patent offers no teaching which overcomes the problem of reaction of the melt with the vessel containing the melt when either

[0003] a high melting or a reactive material is employed. Alloys containing large concentrations of titanium, zirconium, niobium, vanadium, chromium, and the like, when molten are known to react with refractory crucible materials such as alumina, fused silica, zirconia, thoria, yttria, beryllia, and the like. Reaction with the crucible can cause: contamination of the melt which can result in embrittlement of the cast filament; formation of insoluble inclusions in the melt which can reduce the fluidity of the melt, and thereby changing its casting characteristics; and attach of the crucible by the melt which will shorten the life of the crucible.

[0004] By the appropriate selection of the crucible material employed with a particular alloy, the abovementioned problems can be minimized but not eliminated. The selection process may require extensive experimentation to determine the compatible combinations of alloy and crucible material. In many cases the crucible material that is subject to minimal attack by the alloy may suffer from thermal instability and be subject to cracking when thermally cycled.

[0005] High temperature nickel-base, nickel- chromium-titanium-aluminum alloys have been melted in water-cooled copper crucibles. GB-A-1 517 283 teaches the use of a water-cooled crucible to contain nickel-based alloys. The melt is removed from the crucible by spinning the crucible about its axis to generate atomized particles of liquid which move out radially from the edge of the crucible. This patent offers no teaching that the melt can be extracted from the crucible in the form of a continuous stream of limited dimensions.

[0006] Likewise, GB-A-1 428691 teaches that alloys can be melted in water-cooled molds. The melt is then solidified in situ. This patent offers no teaching of a technique for the extraction of liquid metal from a water-cooled mold.

[0007] Since the electrodes used to supply heat to the melts in the above examples are directly above the melt, it is necessary to form a stream of controlled dimensions away from these electrodes if a filament of metal is to be extracted. Thus, while the above examples show a method for melting materails in water-cooled crucibles, they provide no teachings which are suitable for extraction of filaments from the liquid melt.

[0008] The most relevant DE-A-2 827 731 discloses an apparatus for the extraction of filaments from a metallic melt having a tiltable crucible. But also this patent publication offers no teaching to overcome the problem of reaction of the melt when either a high melting or a reactive material is used.

[0009] Finally there is made reference to the EP-A-0 055 827 having the same priority. Thus, the objective of the invention was to provide an apparatus for chill casting of high temperature and/or reactive metallic materials. More particularly, the objective related to an apparatus for the extraction of rapidly-quenched filaments from a high melting point and/or reactive melt.

[0010] According to the invention the apparatus for casting metal filaments directly from the melt comprising a tiltable crucible which is constructed of thermally conductive material for holding a metal charge, means for supplying heat to melt the metal charge contained in said crucible to form a melt, a chill surface provided by a heat extracting member for deposition of molten metal thereon for quenching into filament together with means for advancing said chill surface, and means for tilting said crucible is characterized in that the apparatus comprises a pouring spout forming an integral part of said crucible, one or more cooling passages internal to said crucible for passing a cooling medium therethrough to provide a solidified layer of the melt for preventing interaction between the melt and said crucible and the means for tilting said crucible elevate the melt into said spout for deposition onto the chill surface as it is being advanced.

[0011] The invention provides an apparatus for casting metal filament directly from the melt when the metal filament is made from high temperature and/or reactive materials. A heating source such as an electric arc is employed for heating the metal and/or holding it in molten condition. The metal charge is held in a cooled, tiltable crucible, which is constructed of high thermal conductive material. When an arc source is employed, an electrically conductive material is employed for crucible material. Suitable materials of construction for the crucible include copper, graphite, brass, etc.

[0012] The crucible has one or more internal passages, and a cooling medium is passed through these channels. When the apparatus includes an electrode, it is associated with the crucible and an arc is struck between the electrode and the metal charge contained in the crucible. The heat generated by the arc is used to melt the metal and/or hold it in molten condition.

[0013] To effect rapid quenching of the molten metal and thereby form a continuous filament, the apparatus further includes an advanceable chill surface for depositing the molten metal thereon. The crucible has a pouring spout, and means are provided for tilting the crucible to elevate the molten metal into the spout of the crucible for deposition onto the chill surface as it is being advanced. The chill surface is provided with a heat extracting member which may be constructed of any metal having relatively high thermal 'conductivity, such as copper, beryllium-copper, molybdenum, iron, and the like. The metal solidifies in contact with the chill surface and is drawn out by the advancing chill surface into a continuous metal strip.

Fig. 1 is a schematic view of a cross-section of one embodiment of the present invention.

Fig. 2 is a schematic of the crucible and spout configuration of one embodiment of the present invention wherein the spout contains an insulating insert.

Fig. 3 is a perspective view of another embodiment of the invention where a chamber encloses the crucible and the heat extracting disk.

Fig. 1 is one embodiment of the present invention. The apparatus has a heat extracting crucible 2 for containment of a molten melt 4. The crucible 2 is fabricated of a high conductivity material such as copper, brass or graphite. The crucible 2 has a coolant inlet 5, a channel 6 and a coolant outlet 7 for the passage of a coolant such as water therethrough. The coolant enhances the heat extracting characteristics of the crucible 2. A spout 8 is positioned on the peripheral edge of the crucible 2.

[0014] The spout 8 can optionally be insulated with an insulating insert 10 as is illustrated in Fig. 2. This insert can be made of a material such as zirconia, boron nitride, alumina, or alternatively of a material such as clay graphite. The insert can be heated by heating element 12. When the insert is graphite or clay graphite, it can be readily coupled to a magnetic field, and the heating may be with an induction coil.

[0015] Again referring to Fig. 1, a metal charge may be melted to form the molten metal 4 which is maintained liquid in the crucible 2 by means for supplying heat to the charge and/or the molten metal 4. The heating means illustrated is an arc source 14 which preferably has a water-cooled electrode holder 16 and a non-consumable electrode 18. Typically, tungsten is used as a non-consumable electrode 18. This electrode 18 is maintained at a potential with respect to the molten metal 4. Typically, the voltage applied between the molten metal 4 and an electrode 18 will be between about 200 and 500 volts AC. A power supply 20 is connected between the electrode holder 16 and the crucible 2. The power supply 20 may alternatively be connected to multiple electrodes to provide a potential between the electrodes and the molten metal 4.

[0016] It should be appreciated that while the means for heating the molten metal 4 is illustrated as an arc source 14, other means such as an e-beam or a laser could be employed. The molten metal 4 is isolated from the crucible by a solidified layer 22. This solidified layer 22 has the same composition as the molten metal 4. This solidified layer 22, or crust, prevents reaction between the molten metal 4 and the crucible 2.

[0017] A heat extracting disk 24 having a circumferential peripheral edge 26 is connected to a means for rotating the disk, such as a motor 27 shown by dashed lines. The disk 24 provides a heat extracting surface with a means for moving the heat extracting surface. Other means such as a rotating belt could also be employed.

[0018] When the spout 8 of the crucible 2 is coplanar with the peripheral edge 26 of the disk 24, the spout 8 can be brought into close proximity with the peripheral edge 26 by pivoting the crucible 2 on the pivotal mounts 28. The pivotal motion will bring the molten metal 4 into the spout 8. As the molten metal 4 makes contact with the peripheral edge 26, a filament 30 will be drawn. When the peripheral edge 26 is a right cylindrical surface, the filament drawn will tend to be a flattened ribbon.

[0019] For the best control of the filament size, it is preferred that the spout 8 have a channel with a radius of curvature of between about 0.15 cm. and 0.5 cm. The lower limit insures that the channel will remain unconstricted during the casting of the filament 30, while the upper limit is a practical limit beyond which it is difficult to maintain a constant head during the formation of the filament -30.

[0020] In the event that a more cylindrical filament is sought, the peripheral edge 26' can be made a tapered convex surface as is illustrated in Fig. 3 by the surface 26'. In this case the spout 8 must be modified so as to have a contoured surface which is a mirror image of the peripheral edge 26'. When the molten metal 4 readily reacts in air, it is. preferred to provide a controlled atmosphere. Fig. 3 illustrates a chamber 32 which is provided for enclosing the crucible 2 and the disk 24. The chamber 32 has an outlet 34 for evacuation which is closeable by a valve 36. There is an inlet 38 which again is provided with a valve 40. This inlet 38 serves to supply a protective atmosphere for the crucible 2. The arc source 14 passes through a cover 42 of the chamber 32. A rotatable seal 44 is provided between the electrode holder 16 and the removable cover 42. A removable cover 42 allows access to the crucible 2 and the disk 24. In order to further illustrate the present invention the following examples are given.

Examples 1-9

[0021] A series of samples were melted in a water-cooled copper crucible. The charge size varied between 50 and 100 grams. A nonconsumable tungsten electrode was employed to heat the melts. The melts were cast under an argon atmosphere. This was accomplished by placing the crucible and the disk in a chamber which was evacuated to 10-⁴ torr (1.33 to-²Pa) and thereafter backfilled with high purity argon to about 20 cm of mercury. An arc was struck between the charge which was in the form of a pellet, and the electrode. By gradually tilting the crucible the molten metal was brought into the spout and in kissing contact with the right cylindrical surface of the rotating chill disk. The disk had a diameter of about 12 inches (30.5 cm) and was rotated at between about 1200 rpm and 1600 rpm. The disk was a water-cooled molybdenum wheel. A filamentary fiber was extracted or dragged from the melt by the wheel. The materials cast are summarized in the table.

Claims

1. Apparatus for casting metal filaments directly from the melt comprising a tiltable crucible (2) which is constructed of thermally conductive material for holding a metal charge, means (14) for supplying heat to melt the metal charge contained in said crucible to form a melt, a chill surface (26) provided by a heat extracting member for deposition of molten metal thereof for quenching into filament, together with means (27) for advancing said chill surface, and means for tilting (28) said crucible, characterized in that the apparatus comprises a pouring spout (8) forming an integral part of said crucible (2), one or more cooling passages (6) internal to said crucible for passing a cooling medium therethrough to provide a solidified layer of the melt for preventing interaction between the melt (4) and said crucible and the means for tilting (28) said crucible elevate the melt (4) into said spout (8) for deposition onto the chill surface (26) as it is being advanced.

2. The apparatus of claim 1 wherein said spout (8) has a channel with a radius of curvature between about 0.15 cm and 0.5 cm.

3. The apparatus of claim 1 wherein said thermally conductive crucible (2) is also electrically conducting and said means (14) for supplying heat to the metal charge is an electrode associated with said crucible for striking an arc between said electrode and the metal charge contained in said crucible to melt the metal charge.

4. The apparatus of claim 3 wherein said spout (8) has an insulating insert (10) with means (12) for heating said insert.

5. The apparatus of claim 2 wherein said means for supplying heat (14) to the metal charge comprises at least two non-consumable electrodes; and a power supply connected between said electrodes, said power supply passing a current between said electrodes via said metal charge.

Revendications

1. Appareil pour couler des filaments métalliques directement à partir du bain fondu comprenant; un creuset basculable (2) qui est construit en un matériau thermiquement conducteur pour contenir une charge de métal, des moyens (14) pour fournir de la chaleur afin de fondre la charge de métal contenue dans ledit creuset, de façon à former un bain fondu, une surface de refroidissement (26) formée par un organe d'extraction de chaleur pour le dépôt sur elle du métal fondu pour la trempe sous forme d'un filament, ainsi que des moyens (27) pour faire avancer ladite surface de refroidissement, et des moyens (28) pour basculer ledit creuset, caractérisé en ce que l'appareil comprend un goulot (8) de déversement formant une partie intégrale dudit creuset (2), un ou plusieurs passages (6) de refroidissement à l'intérieur dudit creuset pour y faire passer un milieu de refroidissement de façon à former une couche solidifiée du bain fondu afin d'empêcher une interaction entre le bain fondu (4) et ledit creuset, et lesdits moyens pour basculer ledit creuset élevant le bain fondu (4) jusque dans ledit goulot (8) pour former un dépôt sur ladite surface (26) de refroidissement pendant qu'elle avance.

2. L'appareil de la revendication 1 dans lequel ledit goulot (8) comporte un canal avec un rayon de courbure compris entre 0,15 et 0,5 cm environ.

3. L'appareil de la revendication 1, dans lequel ledit creuset thermiquement conducteur (2) est également électriquement conducteur, et lesdits moyens (14) pour fournir de la chaleur à ladite charge de métal sont constitués par une électrode associée audit creuset pour former un arc entre ladite électrode et la charge de métal contenue dans ledit creuset de façon à faire fondre la charge de métal.

4. L'appareil de la revendication 3, dans lequel ledit goulot (8) comporte une pièce rapportée isolante (10) avec des moyens (12) pour la chauffer.

5. L'appareil selon la revendication 2, dans lequel lesdits moyens pour fournir de la chaleur (14) à la charge de métal comprennent au moins deux électrodes non consommables; et une source de puissance reliée entre lesdites électrodes, ladite source de puissance faisant passer un courant entre lesdites électrodes à travers ladite charge de métal.

Ansprüche

1. Vorrichtung zum Gießen von Metalldrähten direkt aus der Schmelze mit einem kippbaren Schmelzbehälter (2), der aus wärmeleitfähigem Material konstruiert ist, zur Aufnahme einer Metallcharge, Einrichtungen (14) zur Zuführung von Wärme zum Schmelzen der in dem Schemlzbehälter enthaltenen Metallcharge unter Bildung einer Schmelze, einer Abkühloberfläche (26), die von einem wärmeextrahierenden Teil gebildet wird, zur Ablagerung von geschmolzenem Metall darauf, um dieses zu einem Draht abzukühlen, zusammen mit Einrichtungen (27) zum Vorrücken dieser Abkühloberfläche und Einrichtungen zum Kippen (28) des Schmelzbehälters, dadurch gekennzeichnet, daß die Vorrichtung eine aus einem Stück mit dem Schmelzbehälter (2) bestehende Ausgußtülle (8) und einen oder mehrere Kühlkanäle (6) im Inneren des Schmelzbehälters zum Durchleiten eines Kühlmediums besitzt, um eine verfestigte Schicht der Schmelze zu bekommen und so eine Wechselwirkung zwischen der Schmelze (4) und dem Schmelzbehälter zu verhindern, und daß die Einrichtungen zum Kippen .(28) des Schemlzbehälters die Schmelze (4) in die Tülle (8) zur Ablagerung auf der Abkühloberfläche (26), während diese vorangerückt wird, heben.

2. Vorrichtung nach Anspruch 1, worin die Tülle (8) einen Kanal mit einem Krümmungsradius zwischen etwa 0,15 cm und 0,5 cm besitzt.

3. Vorrichtung nach Anspruch 1, worin der wärmeleitfähige Schmelzbehälter (2) auch elektrisch leitend ist und die Einrichtung (14) zur Zuführung von Wärme zu der Metallcharge eine mit dem Schmelzbehälter verbundene Elektrode ist, die einen Lichtbogen zwischen der Elektrode und der in dem Schemlzbehälter enthaltenen Metallcharge erzeugt, um die Metallcharge zu schmelzen.

4. Vorrichtung nach Anspruch 3, worin die Tülle (8) einen isolierenden Einsatz (10) mit Einrichtungen (12) zum Erhitzen dieses Einsatzes besitzt.

5. Vorrichtung nach Anspruch 2, worin die Einrichtung zur Zufuhr von Wärme (14) zu der Metallcharge wenigstens zwei nicht verbrauchbare Elektroden und eine mit diesen Elektroden verbundene Stromzufuhr besitzt, wobei die Stromzufuhr einen elektrischen Strom zwischen diesen Elektroden über die Metallcharge leitet.

Drawing