(19)
(11) EP 0 107 109 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
25.07.1984 Bulletin 1984/30

(43) Date of publication A2:
02.05.1984 Bulletin 1984/18

(21) Application number: 83109814

(22) Date of filing: 30.09.1983
(84) Designated Contracting States:
AT BE CH DE FR GB IT LI LU NL SE

(30) Priority: 30.09.1982 US 429055

(71) Applicant: LeaRonal, Inc.
 ()

(72) Inventor:
  • Houman, John
     ()

   


(54) Electrolytic copper plating solutions and a method for their application


(57) Acid copper electroplating solutions containing the reaction product of

(1) a compound of the formula

wherein R1 and R2 are lower alkyl radicals of with 1 to 6 carbon atoms, a hydrogen atom or mixtures thereof and R4 is an alkali metal, hydrogen, magnesium, or the groups SX or SSX, wherein X is an alkali metal, hydrogen or magnesium, or a compound of the formula

wherein R3 is an aromatic, heterocyclic or alicyclic radical containing 3 to 12 carbon atoms and R4 is an alkali metal, hydrogen, magnesium, or the groups SX or SSX where X is an alkali metal, hydrogen or magnesium,

(2) a compound of the formula

wherein R, and R2 are the same or different and are alkylene radicals containing 1 to 6 carbon atoms, X is hydrogen or -SO,H and n equals 2 to 5, and

(3) acrylamide in a sufficient amount to increase the brightness of the deposit and/or to prevent the formation of cracks during thermal shock.







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