BACKGROUND OF THE INVENTION
[0001] This invention relates to a process for producing a shelded wire for use in wiring
of electric/electronic equipment, more particularly, to a process for producing a
shelded wire by covering a stranded insulated wire with shield metal wires or a metal
foil, coating the wires or foil with insulating paint and hardening the paint for
sheathing and insulating purposes.
[0002] A shielded wire for use in wiring of electric/electronic equipment comprises a single
stranded wire or a combination of plural stranded wires with weft-wound or knitted
metal wires or a metal foil thereon and sheathed with an insulator. That is, the shielded
wire is formed with the combination of a core conductor, an insulator for the core,
shield metal wires or foil and a sheath insulator.
[0003] With the recent inclination to the miniaturization and improvement of performance
of electric/electronic equipment, it has strongly been required that shielded wires
for practical use should be.as thin and lightweight as possible. The present inventors
have invented, in the process of manufacturing stranded insulated wires, a method
for obtaining a thin-film stranded insulated wire through the formation of an insulating
film by, instead of extrusion molding, applying and hardening insulating paint. Use
of the thin-film stranded insulated wire, obtained by applying and hardening insulating
point, as a core for a shielded wire has naturally made it possible to provide a thin
lightweight shielded wire.
[0004] The present inventors has further made efforts to develop a shielded wire which is
thinner and lighter in weight. One of the methods thus developed comprises applying
and hardening insulating paint, in place of conventional extrusion molding for forming
a sheath insulator. The shielded wire thus obtained has a thinner insulator and satisfies
the demand for thin, lightweight wires. However, when solvent type insulating paint
is employed, it is essential to heat the paint to evaporate the solvent after it is
applied or to cause reaction to make the resin of a high polymer. During the process
of heating the paint, the air confined around the shield metal wire or foil is expanded,
whereby foam is often produced in the film of the paint.
SUMMARY OF THE INVENTION
[0005] An object of the present invention is to provide a process for producing a shielded
wire having a sheath insulating film free from roughness and foam.
[0006] The above object is achieved by a process including the following features.
[0007] A feature of the process for producing a shielded wire for use in electric/electronic
equipment comprises the steps of shielding a single stranded insulated wire or the
combination of such wires prepared by covering a stranded conductor with insulating
material with metal wires or a metal foil, coating the wires with non-solvent type
paint being hardened by ultraviolet ray or electron beam irradiation, and hardening
the paint by the ultraviolet ray or electron beam irradiation, thereby preventing
th
p generation of foam in thn film layer. The feature also includes the step of removing
air bubbles left in the layer.
[0008] Another feature of the process for producing a shielded wire comprises the steps
of providing shield metal wires or the like and, in forming at least the lowermost
film layer, applying and hardening thermohardening insulating paint by using a felt
or roller to prevent foam generation in the layer.
[0009] Still another feature of the process for producing a shielded wire comprises the
steps of providing shield metal wires or the like, applying a solvent prior to applying
insulating paint, applying and hardening thermohardening paint to prevent foam generation
in the film layer.
[0010] A further feature of the process for producing a shielded wire comprises the steps
of providing shield metal wires or the like and, when at least the lowermost film
layer is formed, applying and hardening thermohardening insulating paint whose viscosity
is 300 cps or less at 30°C to prevent foam generation in the film.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011]
Fig. 1 is a sectional view showing a shielded wire according to a process of the present
invention,
Fig. 2 is a sectional view of a shielded wire which includes air bubbles in a shieth
isulating film,
Fig. 3 is a sectional view showing a paint tank provided with a reduced chamber according
to the present invention, and
Figs. 4 and 5 are sectional views showing a shielded wire obtained by a precess of
the present invention, respectively.
DETAILED DESCRIPTION OF THE INVENTION
[0012] The present invention comprising the above features will subsequently be described
in detail.
[0013] An attempt was made to produce a shielded wire for use in electric/electronic equipment
in accordance with a process comprising the steps of winding shield metal wires or
a metal foil on a single stranded insulated wire or a comination of plural wires,
applying non-solvent type paint being hardened by ultraviolet ray or electron beam
irradiation to the metal wires or metal foil at the room temperature, hardening the
paint by irradiation of ultraviolet ray or electron beam, confining the air present
in the gap 5 shown in Fig. 1, and further applying and hardening the same or different
kind of insulating paint to obtain desired film thickness and the shielded insulated
wire. According to the above process, foaming in the film due to the expansion of
the air within the shielded wire did not occur and a shielded wire available for practical
use was obtained.
[0014] The above manufacturing process includes the following features which will subsequently
be described in detail.
[0015] A feature of the above process comprises the steps of, when paint being hardened
by ultraviolet ray or electron beam irradiation is applied onto shield metal and hardened
more than once, applying the paint thereto, passing the wire through a heating oven
to remove small air bubbles present in the film before being hardened, and hardening
the paint by ultraviolet ray or electron beam irradiation. When the paint being hardened
by irradiation is applied to the shield metal wound on the stranded insulated wire
by using dies or a felt, small air bubbles may still be present in the paint film
even though it it squeezed by the dies or the like. If the ultraviolet ray or electron
beam is irradiated in the above state, a problem arises that the film is hardened
with the samll air bubbles contained. The small air bubbles thus contained are undesirable
because they increase the electric charactaristic variation. Thus the problem should
be solved. Fig. 2 is a transverse sectional view of a shielded insulated wire containing
air bubbles. When the irradiation-hardened paint is supplied to a tank in continouse
operation, air bubbles are gradually mixed into the paint.. The air bubble is produced
since the air at the surface of an object being coated is surrounded by the paint
while the object being coated is led to the paint. In the case of conventional thermohardening
paint, since heat is added in an oven after the coating, air bubbles rises to surface
and vanish due to the expansion of the air bubbles contained in the film before being
hardened and the decrease in paint viscosity.
[0016] In the case of the irradiation-hardened paint, however, it is hardened instantly
after being applied so that there is no time during which air bubbles rise to the
surface. The present inventors'have therefore devised a method of reducing paint viscosity
after an object to be painted is coated with irradiation-hardened paint, positively
heating the object to the extent that air bubbles are caused to rise to surface and
then hardening the paint by irradiation. The method was successful in obtaining a
shielded insulated wire whose film contains no foam. Heating for the purpose of reducing
paint viscosity and raising the air bubbles to surface must be varied with manufacturing
conditions, e.g., the viscosity-temperature characteristics of the paint, film thickness,
linear velocity of the object and the like. However, in general, the satisfactory
temperatures inside the oven of about 1 m
- 2 m long are within the range of 100°C - 250°C. The temperatures of the shielded
insulated wire itself should preferably be within the range of 60°C ~ 150°C. In case
the temperature is too high, the air confined in the gap between the shield metal
wires or in the foil may be expanded and forced into the film. The number of times
the irradiation-hardened paint is applied should be varied with the desired film thickness
and, provided the thickness of the paint applied first is within the range of about
10 - 20 um, air bubbles will vanish even though they are contained therein while the
paint viscosity is decreased by heating.
[0017] Another feature of the above process comprises the steps of installing a vacuum chamber
under an irradiation-hardened paint tank into which an object being coated is led,
removing the air on the periphery of the object by passing the object through the
chamber so that air bubbles are prevented from being introduced in the irradiation-hardened
paint in the tank, and coating the object with the irradiation-hardened paint free
from the air bubbles by leading the object into the irradiation-hardened paint tank.
[0018] No heating oven is necessary after the painting process according to the present
invention. To prevent air bubbles from penetrating into the liquid tank, the present
inventors installed a chamber where the pressure is reducible, i.e., the vacuum chamber
beneath the liquid tank to remove air accompanied with the object being coated and
introduced the object without air on its surface into the liquid tank. With respect
to the extent to which the pressure in the vacuum chamber is reduced, if the pressure
is lower than one atmospheric pressure, the number of air bubbles allowed to enter
the paint tank decreases to the extent. However, by reducing the pressure to 150 mmHg
or less, the film is caused to contain almost nearly no air bubbles and a shielded
insulated wire having stable electric characteristics becomes available. In case the
reduced pressure is greater than 150 mmHg, the film may include small air bubbles.
Elastic packing such as rubber must be held between the paint tank and the vacuum
chamber because the paint tends to be readily dragged from the upper paint tank into
the vacuum chamber as the pressure is further reduces, whereas a hole for passing
the object being coated must be as small as possible to prevent the packing from deforming
because of the suction froce generated by the pressure reduotion.'
Moreover, a counter measure should be taken to prevent air from penetrating into the
vacuum chamber through a hole in the bottom thereof for passing the object being coated
as the pressure is reduced. For example, elastic material such as rubber should be
installed on the bottom of the vacuum chamber to minimize the size of the hole by
making use of the elasticity thereof and to prevent the air from penetrating therethrough.
The degree of pressure reduction can also be maintained effectively by attaching a
reinforcing plate to the bottom of the elastic material to increase the resistance
against the suction force while the pressure is reduced. A hole made in the reinforcing
plate should naturally be as small as possible.
[0019] The longer the time during which the stranded conductor is passed through the vacuum
chamber, the greater the amount of air removed from that carried by the stranded conductor
becomes. From the results obtained from the experiments conducted by the present inventors,
the vacuum chamber of 5 to 10 cm long has been proved satisfactory.
[0020] Fig. 3 shows a paint tank 7 equipped with a vacuum chamber 11 in the portion where
a stranded conductor is introduced into the former, wherein an object being coated
10 is passed through the vacuum chamber 11 before being introduced into the paint
tank 7. A vacuum pump 12 is such that it is capable of reduce the pressure to 150
mmHg or less. Numerals 13 and 14 show a packing and a reinforcing plate, respectively.
The installation of the vacuum chamber has contributed to greately reducing the amount
of air bubbles contained in the paint tank and also preventing them from being contained
in the film coated and hardened.
[0021] As the insulating paint that can be hardened by ultraviolet ray or electron beam
irradiation, use can be made of polyester acrylate, polyol acrylate, urethane acrylate,
epoxy acrylate, silicone acrylate, polybutadien acrylate, melamine acrylate, polyene/polythiol,
unsaturated polyester, etc. in the form of a single substance or their.mixture.
[0022] A photosensitizer must be added to the above compound to be hardened by ultraviolet
ray irradiation. As the photosensitizer, benzoin alkyl ethers such as benzoin ethyl
ether, benzoin-n-butyle ether, acetophenone derivatives such as diethoxyacetophenone,
amyl oxyme esters and many known photosensitizers are usable.
[0023] The present inventors have continued examination and established a method of preventing
air bubbles from being produced because of the air among shield metal wires even if
solvent type heat-hardened insulated paint is used. An description will subsequently
be given of this case.
[0024] Shield insulating metal wires or a metal foil is wound on a stranded insulated wire
and coated with solvent type insulating paint, which is then hardened to produce a
shielded insulated wire. When dies are used to apply the insulating paint, the die
having a diameter larger than the outer diameter of an object being coated must be
used. In this case, the paint it thickly applied between the stranded wires. As a
result, the air between the shield metals iz caused to readily produce air bubbles
because of the expansion of the air and the vaporization of the solvent contained
in the insulating paint. Actually, it may become impossible to continue production
because of troubles resulting from disconnection or quality deterioration. If the
die whose diameter is almost equal to the outer diameter of the object being coated
is used to apply the insulating paint further thinly, it will quickly wear and the
uneven frictional force between the object and the die due to variations in the outer
diameter of the former makes uniform coating impossible.
[0025] According to the present invention, when at least the lowermost insulating film is
formed during the process of manufacturing shielded wires, solvent type heat-hardening
insulating paint is thinly applied using a felt or roller and then heat-hardened to
prevent the generation of air bubbles.
[0026] The heat-hardening insulating paint thus applied is urged to fill the gap between
the shield metal wires or in the metal foil. If the quantity of paint applied between
the shield metal wires by means of the felt or roller is so arranged as to conform
to AC≦ 1/2AB (see Fig. 4), the expanded air confined between the shield metal wires
is caused to readily escape from the structure. Under this condition, it was confirmed
through experiments that no air bubbles were generated in the film.
[0027] When the insulating paint is applied to portions AB shown in Fig. 4, it should preferably
be applied 2 ~ 5 times and then applied further using dies depending on the desired
film thickness. After a film of about 2 ~ 4 µm thick is formed on the outer surface
of the object being coated, the total number of times the paint is coated and heated
can be minimized if the dies are effectively used for the coating. This process is
of high practical value. If it is attempted to obtain a film of about 20 ~ 25 µm thick
by employing only the felt or roller coating method, the number of times that the
paint must be applied will become over 10 ~ 15. If the paint is applied thickly at
one time in accordance with the felt or roller method, the film thickness in the longitudianl
direction tends to become uneven and therefore it must be applied thinly. A number
of times the paint must be applied means that the number of pieces allowed to be hooked
in the oven is limited, so that a serious problem arises that productivity in actual
production is lowered. After a thin film free from air bubbles is formed on the metal
wires by means of a felt or roller, no air bubbles ara generated even though dies
are used to apply the paint, so that the manufacturing process is superior'in productivity.
[0028] The material of the felt according to the present invention may be any one of wool,
polyester, Teflon, polypropylene, polyvinylidene chloride, rayon, etc. whose density
should preferably be about 0.20 ~ 0.60 g/cm
3. With respect to the shape and material quality of the die, use can be made of what
is capable of applying insulating paint for enamel wires in general. In other words,
super-hard metal, super-hard diamond, sapphire, artificial diamond, natural diamond,
etc. with a hole of a suitable shape may be used. As for the roller coating, a conventional
method of manufacturing enamel wires is usable.
[0029] An additional feature of the present invention to provide a shielded insulated wire
of good quality whose film is free from air bubbles, comprises applying a solvent
to an object being coated before applying and heating heat-hardening insulating paint
thereto after winding shield metal wires or a metal foil on stranded insulated wires.
That is, by applying the solvent to the object to wet the surfaces of the shield metal
wires, applying the solvent type heat-hardening insulating paint thereto and baking
the paint, the generation of air bubbles is remarkably reduced. This method makes
it possible to form a film free from air bubbles and has an important technical meaning
to the industry. The reasons why the foaming decreases are considered as follows:
The air present between the shield metal wires is partially replaced with the solvent
when the shield metal wires or the metal foil is wetted with the solvent so that the
air escapes from the structure or otherwise the insulating paint for use in the later
process is caused to insert into the portion between the shield metal wires and thus
replace itself with the remaining air. In consequence, the foaming resulting from
the expansion of the air when heated, it considered as being suppressed. It is important,
however, that the solvent and the insulating paint coated in the later process are
soluble in each other.
[0030] More specifically, a mixture of various cresol acids, xylene, toluene, naphtha having
different boiling points and the like are often used for insulating paint of polyvinyl
formal,' polyurethane, polyester or polyester imide. On the other hand, for polyamide
imide or polyimide paint for use in heat resistant winding, pyrrolidone as a main
solvent with xylene, toluene or naphtha having different boiling points as a diluent
can be selectively used.
[0031] The solvent precoated on the shield metal may be the above solvent in the form of
a single substance or mixture of them but are preferable to be capable of being mixed
with the resin and solvent contained in the paint. The solvent may be applied to the
shield metal by using the felt soaked with the solvent, by the roller coating method,
or by dipping the object being coated in the solvent tank and uniformly wiping it
with the felt or the like.
[0032] The present invention is further intended to provide a method for obtaining a shielded
insulated wire of good quality which is free from air bubbles. When insulating paint
is applied to an object being coated and hardened to form the lowermost layer, heat-hardening
paint whose viscosity is less than 300 cps (measured by a B type viscometer under
the measuring temperature of 30°C or lower) is applied thereto by a felt or roller
and baked more than once and further the insulating paint is applied thereto and hardened
more than once.
[0033] When the insulating paint is applied and baked, foaming is caused mainly by (1) the
air present in the gap between the shield metals and (2) the vaporization of the solvent
used for the insulating paint. The present inventors have already ascertained the
fact that, in the case of the above reason (1), the air present in the gap between
the shield metal and the stranded insulated wire is caused to escape and prevented
from foaming, provided that the heat-hardening insulating paint is thinly'applied
by using a felt or roller.
[0034] The present inventors have further made examinations and confirmed that the viscosity
of the heat-hardening insulating paint is correlated to foaming in the film. In particular,
the viscosity of the heat-hardening insulating paint to be applied . first is most
closely related to foaming in the film. That is, it was found that considerations
must be given to not only the thickness.of the paint applied first but also its viscosity.
[0035] The viscosity of the heat-hardening insulating paint applied to the object being
coated is temporarily reduced while it is heated in the oven. Furthermore, the air
present in the gap expands in volume and is forced to escape from the structure through
the paint. The intensity of the viscosity at that time corresponds to that of the
resistance against the air escaping from the structure.
[0036] When the viscosity is high, the air is hardly allowed to eacape therefrom and tends
to generate air bubbles. Even though the air is allowed to escape therefrom, the drawback
it that the surface is hardly smoothed despite the surface tension if the viscosity
is high. The present inventors have further confirmed the fact through experiments
that the viscosity(measured by B type viscometer, at 30°C) of the insulating paint
should preferably be lower than 300 cps, more preferably 200 cps and further more
preferably 100 cps to depress the occurrence of foaming.
[0037] The low viscosity of the heat-hardening insulating paint is further lowered in the
oven and, in consequence, the expanded air is allowed to readily escape from the structure
and the ruggedness on-the surface of the paint by the air escaping therefrom is smoothed
because of the low viscosity and the action of surface tension. The above facts have
also been confirmed through the experiments conducted by the present inventors. When
heat-hardening insulating paint, whose viscosity is 300 cps or less, was used for
forming the lowermost layer film between the shield metals as shown in Fig. 4, it
was confirmed that no air bubbles were generated even if the insulating paint was
applied up to the portions A and B at one time.
[0038] when the insulating paint is applied again after the first coating of the paint,
it is possible to use heat-hardening insulating paint whose viscosity is higher than
what is used for the first time. The reason is that most of the air present in the
gap between the shield metal wires has already been allowed to escape from the structure.
Even if the air is present in the film, it will be not allowed to escape from the
film formed by the first coating and thus not attributable to foaming. However, during
or after the insulating paint is applied and hardened twice, if the paint film is
excessively thick or its viscosity is too high, undesirable foaming occurs in the
film due to the vaporization of the solvent. When the felt is used to apply the insulating
paint after the first coating, the viscosity thereof should preferably be less than
about 700 cps and less than 5,000 cps when the dies are used therefor.
[0039] Fig. 5 is a transverse sectional view of the shielded insulated wire according to the
present invention.
[0040] Any ordinary insulating paint may be used in the present invention by adjusting its
viscosity. However, it is needless to say necessary to select the kind in accordance
with required property.
[0041] If a sheath insulator for a shielded wire is formed by applying and hardening insulating
paint, instead of extrusion molding, the sheath insulator can be made thinner and
accordingly the total outer finished diameter of the shielded wire is made thinner
and light in weight. When the sheath insulator is provided by extrusion molding, the
film thickness generally exceeds 0.3 mm, whereas the use of the insulating paint makes
it possible to provide such a film of 0.005 mm thick uniformly. However, when the
insulating paint is applied and hardened to form such a sheath insulator, it is strongly
adhesive to the shield metal wire or foil. Thus, when it is put to practical use,
it tends to pose a problem that the separation of the film is difficult at its end.
In that case, it is possible to improve the separation characteristics of the film
at the end by applying lubricant to the surface of the shield metal wire or by coating
the wound shield metal wires with a thin film.
[0042] Examples of the present invention will subsequently be described.
Reference Example (1)
[0043] Seven stranded conductors/0.127 mm were covered with vinyl chloride resin to form
a film of 0.27 mm thick by extrusion molding, weft-wound shield metal wires (0.05
mm x 35) and a sheath insulator of 0.40 mm thick by extrusion molding. The finished
shielded wire was 1.83 mm in outer diameter.
Comprative Example (1)
[0044] The manufacturing process of this example is identical to that of Reference Example
(1) except for the following:
[0045] Vinyl cholide resin paint (with solvent of methyl ketone,
naphasa) was applied by using dies and hardened by baking to provide a sheath insulator
whose thickness was 0.06 mm, so that the shield wire of finished outer diameter 1.15
mm was obtained. Air bubless were seen on the surface of the film.
Example (1-1)
[0046] The manufacturing process of this example is identical to that of comparative Example
(1) except for the following:
For sheathing insulation, ultraviolet-hardend type paint (base polymer: polyester
urethane acrylate origomer, reactive diluent: ethylene glycol diacrylate, vinyl pyrrolidine,
light starting agents benzoin ethyle ether) was applied by using dies and hardened
by ultraviolet ray irradiation to form a sheath insulator of 0.06 mm thick, so that
the shielded wire of the finished outer diameter of 1.15 mm was obtained. Air bubbles
were not seen on the surface of the film.
Example (1-2)
[0047] The manufacturing process of this example is identical to that of Reference Example
(1) or Example (1-1) except for the following:
Stranded conductors were coated with the ultraviolet-hardened type paint used in Example
(1-1), which was hardened by ultraviolet ray irradiation, to make a stranded insulated
wire having a film of 0.05 mm thick. Shield wires were laterally wound on the stranded
insulated wire and the same sheath insulator as that of Example (1-1) was formed,
so that the shielded wire of the finished outer diameter of 0.72 mm was obtained.
Example (1-3)
[0048] The manufacturing process of this example is identical to that of Example (1-2) except
for the following:
The shield metal wires were coated with ultraviolet hardened type paint and was passed
through an oven of 1.5 m long whose temperature was held at 230°C. Thereafter the
paint was hardened by ultraviolet ray irradiation. No air bubbles were contained in
the sheath insulator.
Example (1-4)
[0049] The manufacturing process of this example is identical to that of Example (1-3) except
for the following: An object being coated was passed through a vacuum chamber with
the pressure reduced to 50 mmHg before forming of sheath insulator, coated with paint
hardened by ultraviolet ray irradiation and then hardened thereby. No air bubbles
were observed in the sheath insulator.
Comparative Example (2-1)
[0050] Seven stranded conductors /0.127 mm were coated with vinyl chloride resin by extrusion
molding to form an insulating film of 0.27 mm thick and weft-wound shield metal wires
(0.05 mm x 35) were added thereto and that combination was coated with polyester insulating
paint (whose concentration is 40%) by using dies, which was baked. The number of paint
application and baking was 7. There was obtained a shielded wire with a 0.05 mm thick
sheath insulator, on the surface of which several grains due to foaming were observed.
Comparative Example ( 2 -2 )
[0051] The manufacturing process of this example is identical to that of Comparative Example
(2-1) except for the following:
Polyester insulating paint (concentration being about 20%) was applied by using a
wool felt and baked. The paint was applied 20 times to obtain a sheath insulating
film of 0.05 mm thick. No grains due to foaming were observed on the surface thereof.
Example (2)
[0052] .The manufacturing process of this example is identical to that of Comparative Example
(2-1) except for the following:
Stranded conductors were insulated by extrusion-molding and weft-wound shield metal
wires were wound thereon. Thereafter, polyester insulating paint (concentration: 20%)
were coated by using a wool felt and baked three times and then polyester insulating
paint (40%) was applied thereto using dies and baked four times. The shielded wire
obtained had a sheath insulator of 0.05 mm thick which was free from grains due to
foaming.
Comparative Example (3)
[0053] Seven stranded conductors/0.127 mm were coated with vinyl chloride resin by extrusion
molding to form a film of 0.27 mm and weft-wound metal wires (0.05 mm x 35) were added
thereto. That combination was further coated with polyester insulating paint (solvent:
m-cresole, naphtha) using dies and hardened by baking to form a film of 0.06 mm thick.
[0054] There appeared grains on the surface due to foaming.
Example (3)
[0055] The process of this example is identical to that of Example (3) except for the following:
The solvent composed of naphtha and butylcellosolve was applied to the surface of
the shield metal wire by using a felt and then polyester insulating paint was applied
and baked. No foaming was observed on the surface of the film.
Comparative Example (4)
[0056] Seven stranded conductors/0.127 mm were coated with vinyl chloride resin by extrusion
molding to form a film of 0.27 mm and weft-wound metal wires (0.05 mm x 35) were added
thereto. The combination was further coated with nylon 66 insulating paint (concentration
20%; viscosity 1,400 cps) using a wool felt and baked. The number of times the paint
was applied and baked was 15 to form the shielded insulated wire having a film of
0.045 mm. Grains due to foaming were observed on the surface of the film.
Example (4)
[0057] The process of this example is identical to that of Comparative Example 4 except
for the following: Nylon 66 insulating paint was adjusted to concentration 13% and
130 cps in viscosity and'applied and baked first. The same insulating paint as that
in Comparative Example (4) was used secondly and thereafter. Grains due to foaming
were not observed in the film.
1. A process for producing a shielded wire for use in electric/ electronic equipment,
comprising the steps of: shielding a single stranded insulated wire prepared by covering
a stranded conductor with insulating material or a combination of such wires with
metal wires or a metal foil; coating said metal wires or said metal foil with insulating
paint; and hardening said paint to form an insulating film.
2. A process for producing a shielded wire for use in electric/ electronic equipment
as claimed in claim 1, wherein said insulating paint is non-solvent type ultraviolet
ray or electron beam irradiation-hardened paint and is hardened by ultraviolet ray
or electron beam irradiation after the coating step.
3. A process for producing a shielded wire for use in electric/ electronic equipment
as claimed in claim 2, further comprising the step of passing the stranded insulated
wire through a heating oven to remove air.bubbles in said film after the coating step
and prior to the hardening step.
4. A process for producing a shielded wire for use in electric/ electronic equipment
as claimed in claim 2, further comprising the steps of: passing the stranded insulated
wire through a vacuum chamber to remove the air around said shield metal wires or
metal foil after the shielding step; and leading the stranded insulated wire to a
tank containing said ultraviolet ray or electron beam irradiation-hardened paint prior
to the coating step.
5. A process for producing a shielded wire for use in electric/ electronic equipment
as claimed in claim 4, wherein the pressure in said vacuum chamber is reduced to 150
mmHg or less.
6. A process for producing a shielded wire as claimed in claim 1, wherein, after the
shielding step, said insulating paint of heat-hardening type is coated on said metal
wires or said metal foil by using a felt or roller and is hardened when at least the
lowermost layer of said film is formed
7. A process for producing a shielded wire as claimed in claim 1, further comprising
the step of coating the metal wires or metal foil with a solvent after the shielding
step and prior to coating and hardening said paint of heat-hardening type.
8. A process for producing a shielded wire as claimed in claim 7, wherein said solvent
and said paint of heat-hardening type are soluble in each other.
9. A process for producing a shielded wire as claimed in claim 1, wherein a heat-hardening
insulating paint having viscosity of 300 cps or less is coated on said metal wires
or said metal foil after the shielding step and is hardened when at least the lowermost
layer of said film is formed.