[0001] The invention relates to a process for the gasification of coal to produce synthesis
gas comprising the steps of
feeding particulate coal to a gasification zone, and partially oxidizing coal with
oxygen in said gasification zone, producing a gas stream comprising synthesis gas,
and impurity materials which are collected in a water bath as char, fine slag, and
coarse slag;
removing a material comprising char from said water bath.
[0002] Usually in processes for the gasification of coal to produce synthesis gas, significant
quantities of unreacted impurity matter, variously referred to as char and slag, are
produced during combustion or oxidation in the gasification zone. Upon separation
of the char and/or slag from the gasification zone, a disposal problem exists, since
these materials have undesirable properties which limit options for their disposal.
At the same time, the char, and at least some of the fine slag, contains, in addition
to mineral matter or components, a residual carbon content that has significant energy
value. For example, the char and fine slag may contain from about 5 per cent to about
90 per cent by weight carbon, based on the total weight of the char and fine slag.
If the char, or char and fine slag are disposed of, e.g., as land fill, this energy
value is lost. Accordingly, a procedure which captured this energy value, at the same
time reducing the volume of material to be disposed of, could have economic importance.
The invention provides such a procedure.
[0003] Additionally, if coal is dried to remove the bulk of the moisture therein before
gasification, the removal of this moisture involves a significant energy expenditure.
If coal is combusted to provide the heat necessary for the drying, from about 2 per
cent to about 12 per cent by weight of the total coal supplied to the process may
be utilized, thus lowering the efficiency of the process. The invention, in a further
embodiment, is directed to reducing this energy expenditure.
[0004] A process for gasification of coal characterized by utilization of heat values obtained
from flyash, with concomitant reduction of material for disposal has already been
proposed. The present invention is complementary thereto, such that a common fluidized
bed oxidation zone for heat energy recovery may be employed.
[0005] Therefore, it is an object of the invention to provide a process for the partial
oxidation or combustion of coal in which disposal problems for the char and fine slag
are reduced, and energy costs for the process are reduced. The invention, further,
combines a procedure for reducing char and fine slag disposal with a coal drying procedure,
so that improvement in both techniques is achieved.
[0006] Therefore, the process of the invention is characterized by the steps of fluidizing
removed char in a fluidized bed in a fluidization zone, and oxidizing said char in
said fluidized bed with oxygen at a temperature below the fusion temperature of the
mineral components of the char and the bed, producing a substantially carbon-free
residue and heated gases, and utilizing the heat in the heated gases. In an advantageous
form, the invention comprises a process, as described, in which the partial oxidation
or gasification is carried out in a gasification zone, the outlet temperature of which
is from 1100 °C to 1800 °C, more advantageously 1200 °C to 1600 °C, and char separated
(advantageously, fine slag is also separated) is oxidized in a fluidized bed in a
fluidization zone at a temperature of from 500 °C to 1150 °C, more advantageously
650 °C to about 1120 °C. Pressures in the gasification zone may be varied widely,
but will advantageously range from 10 to 100 atmospheres, more advantageously from
20 to 50 atmospheres, while pressures in the fluidization zone will range from atmospheric
to 10 atmospheres or higher. A rough separation of char and fine slag from coarse
slag may be made in the gasification zone, or char and fine slag and all or a portion
of the coarse slag may both be sent to the fluidization zone. As used herein, the
term "char" refers to those materials, whether solid or molten, which remain in the
gasifier upon production of synthesis gas, and have an average particle size (on solidification,
if molten) of less than 250 microns in width. "Fine slag" refers to those materials,
whether solid or molten, which remain in the gasifier upon production of synthesis
gas, and have an average particle size (on solidification, if molten) of greater than
250 microns, but less than 1 millimetre in size. As used herein, the term "coarse
slag" refers to those materials which remain in the gasifier upon production of synthesis
gas, and which have an average particle size upon solidification of greater than 1
millimetre in width. As indicated, char and fine slag contain varying portions of
residual carbon, e.g., form 5 per cent by weight to 90 per cent by weight of residual
carbon, based on the total weight of the char or fine slag, while coarse slag, which
is generally a vitreous type of material, contains less than 1 per cent by weight
of residual carbon.
[0007] Advantageously, the heat liberated may be used to generate steam or, the heat may
be used to dry feed coal to the process. That is, in this embodiment, the invention
relates to a process for the gasification of coal to produce synthesis gas in which
particulate coal is dried in at least one drying zone, the coal is fed from at least
one drying zone to a gasification zone, and partially oxidized or combusted, as hereinbefore
described, to produce synthesis gas, char, fine slag, and coarse slag, which is treated
as described, and the heat generated by oxidizing the char or char and fine slag is
utilized in drying coal in at least one drying zone. As used herein, the term "oxygen",
unless otherwise evident from the context where employed, is taken herein to include
air, pure oxygen, air enriched with oxygen, and other oxygen-containing gases.
[0008] While the particular gasification or partial oxidation or combustion procedure employed
is not per se part of the invention, the invention is particularly applicable to high
pressure coal gasification slagging processes in which the coal is partially oxidized
or combusted to produce, in addition to the synthesis gas, flyash, a bottom "char"
material, fine slag and a vitreous or coarse slag which are collected in water bath
in or associated with the gasification zone. The oxygen and coal flows are controlled
so that little CO₂ is produced in the gaseous product. In general, these procedures
are carried out by feeding coal, advantageously dry coal, e.g., coal having a moisture
content of below about ten per cent by weight, entrained in a gas, such as an inert
gas, into a gasification zone, and combusting or oxidizing the coal with oxygen. Flame
temperatures may reach 3500 °C, with zone outlet temperatures advantageously from
1100 °C to 1800 °C. Pressures in these processes will range from 10 atmospheres to
100 atmospheres, advantageously from 20 atmospheres to 50 atmospheres. In one such
process, the synthesis gas and flyash are removed from the upper portion of the gasification
zone, and the char, fine slag, and coarse slag are collected from the lower portion
in a water bath.
[0009] A wide variety of coals are suitable for use in the invention. For example, anthracite,
bituminous coal, lignite, and so-called brown coal may be used in the invention. A
real advantage of the invention is the ability to use lower grade coals, such as lignite.
As used herein, the term "coal" is taken to include these inferior grade carbonaceous
fuels, as well as the higher quality coals. The coal will advantageously be fed to
the gasification zone in a particle size suitable for boiler furnace operation, e.g.,
80 to 90 microns in diameter, although those skilled in the art may select the appropriate
particle size, as desired. In an advantageous embodiment, the invention is practised
with "dry" coal, that is, coal having a moisture content of less than 10 per cent
by weight, based on the weight of the moist coal.
[0010] Synthesis gas and entrained matter, which is known as, or becomes what is known as,
flyash, is removed from the gasification zone and treated as described therein. Heavier
solid particulate matter and molten matter remaining in the gasification zone are
allowed to fall into the lower part of the reactor, and thence for example into a
water bath, and are collected in the lower portion of the gasification zone. As those
skilled in the art will recognize, a significant distinction between "flyash" and
"char" is the density. Fine slag is somewhat denser, while coarse or vitreous slag
has, as noted, little carbon content, and has a "glassy" appearance.
[0011] The char and fine slag may be separated roughly in the water bath by this density
differential, although there will be some intermixture. That is, the coarse slag particles
tend to fall to the bottom of the water bath, the fine slag above the coarse slag,
and the char generally above the fine slag. Means, e.g., a sluice, may be provided
for achieving the separation of the char, and fine slag, if desired, from the coarse
slag. Alternately, all material may be removed, either intermittently or continuously,
from the bottom or lower portion of the gasification zone water bath. It is thus not
a requirement of the invention that the particles in question be separated in the
gasification zone water bath; the portions may be separated by sizing equipment external
to the bath. Moreover, it is within the concept of the invention that all of the "bottoms"
material, i.e., char, fine slag, and coarse slag, be sent to the fluidization zone.
If desired, the bottoms material may be crushed to ensure the desired size for fluidization.
[0012] According to the invention, at least the char, and advantageously the fine slag,
are oxidized in a fluidization zone comprising at least one fluidized bed to remove
the carbonaceous matter therein, producing a denser, more easily disposal of material.
The heat liberated during oxidation may be captured by generation of steam, or may
be used either directly or indirectly to dry the coal to be fed to the gasifier. As
will be appreciated by those skilled in the art, the amount of heat generated from
the bottoms material will be insufficient to dry the large volume of coal needed for
the process. The bottoms material may be combined, as mentioned, with flyash, in the
manner provided in the above-mentioned application. To supplement the heat generated
by the bottoms material and flyash, other combustible or partially combustible materials
or fuels, such as coal or coal fines, may be added to the fluidized bed and oxidized.
Obviously, a separate drying technique may also be used, but it is an advantage of
the invention that an independent dryer or drying zone may be eliminated.
[0013] The type of fluidized bed or beds employed is a matter of choice. What is required,
however, is that the bed or beds be operated at a temperature below the fusion temperature
of the mineral matter in the bed, including that of a coal or fuel supplement. In
general, the mineral content of flyash comprises silica, alumina, and other inorganic
components in varying quantities, and the melting point of the mixture may be determined
routinely. Since these temperatures are normally above 1482 °C (although some may
be less), problems with clogging will normally not be encountered if the bed is operated
below this temperature. As indicated, the fusion temperature or range of temperatures
may be determined routinely for each flyash or fuel utilized, and the temperature
in the fluidized bed may be controlled accordingly. Advantageously, the temperatures
are operated well below the fusion temperature, e.g., from 500 °C to 1150 °C, more
advantageously from about 650 °C to about 1120 °C. Pressures in the fluidization zone
may be varied to the extent suitable for fluidized beds, but may be ranged from atmospheric
to 10 atmospheres, for example from atmospheric pressure to 5 atmospheres. The fluidized
bed or beds may be jacketed, or may have coils to absorb the heat produced by the
oxidation. The bed may contain other particulate matter, including catalysts. The
combustion gases generated are removed from the fluidization zone, and transfer their
heat, either directly or indirectly, as desired, advantageously to the coal feed.
The coal can be ground and dried in a combination procedure, and to allow conventional
equipment to be used, a moderating gas, such as air, or nitrogen, at a temperature
of, for example, 15 °C to 40 °C, is added to the combustion gases to lower the temperature
to 200 °C to 500 °C.
[0014] The invention will now be described in more detail by way of example with reference
to the accompanying drawing, in which the figure is a schematic illustration of the
process flow type showing an embodiment wherein the heat generated by oxidation of
the bottoms material is used to dry feed coal. All values are calculated or exemplary.
[0015] Accordingly, reference numeral (1) designates a supply line from, for example, a
storage vessel, not shown, in which coal having an average particle size diameter
of 1.3 cm is fed to a drying zone (2) which contains a combination pulverizer-dryer
wherein the coal is crushed to an average particle size of from 80 to 90 microns and
dried by the gas stream in a line (3) to a moisture content of 10 per cent by weight,
based on the weight of the moisture and the coal. In this illustration, the gas stream
in the line (3) has a temperature of 250 °C, contacts the coal directly in the combination
pulverizer-dryer, and exits the drying zone (2) via a line (4). The exit gas may be
treated for control of pollutants, or utilized (not shown). Concomitantly, dried particulate
coal is removed from the drying zone (2) through a line (5) and forwarded to a gasifier
(6). Means may be provided (not illustrated), for raising the pressure of the coal
and entraining gas up to the level employed in the gasification zone. In the gasification
zone (6), the coal is injected in an entraining gas, e.g. nitrogen, through nozzles
and combusted in a reducing atmosphere or partially oxidized with pure oxygen at 25
atmospheres and at a flame temperature of 3400 °C to 3500 °C. Synthesis gas and impurity
particles are removed overhead from the gasification zone at a temperature of 1400
°C, and sent to a quenching and cooling zone (7). Char and slag, which are heavier
impurity materials, fall downward into the gasifier, and are removed from the lower
portion thereof. The quench and cooling zone (7) can be connected directly to the
outlet of the gasifier (6). The synthesis gas can be first quenched and cooled with
cold recycle gas. The temperature of the synthesis gas can be lowered to 900 °C, and
molten impurities in the gas are solidified to what is known as flyash. The quenching
and cooling sequence can be carried out in more than one stage, the final temperature
before separation of the flyash being from 235 °C to 320 °C.
[0016] In order to separate the flyash from the synthesis gas, the stream is forwared via
a line (8) to a cyclone (9) (or the cooling zone may discharge directly thereto).
The great bulk of the flyash is separated in the cyclone (9), and the flyash is removed
from the cyclone (9) via a line (10). The gas stream is removed from the cyclone (9)
via a line (11) and sent for further processing, such as for H₂S removal, and for
product use. Because the cyclone is not totally effective, a final solids cleanup
stage (12), e.g., bag filters, is provided in the line (11). Solids are removed from
a unit (12) via a line (13). Solids from the cyclone (9) and the solids removal stage
(12) may be utilized for energy recovery according to the invention.
[0017] The impurity molten materials and solids not removed with the synthesis gas from
the reaction zone fall to the lower portion of the gasifier (6), and through a slag
tap (20) into a water bath (21). Primarily because of differences in the density of
the particles, a rough separation of the particles takes place, as mentioned previously.
A sluice (22) is provided for removal of fine slag and char, and coarse slag may be
removed from the bottom of the bath at a line (23). The material separated in the
sluice (22) is passed via a line (24) to a fluidization zone (14), wherein it is treated,
as described hereinafter.
[0018] Accordingly, solids in the lines (10), (13) and (24) are injected into the fluidized
bed (14), and are reacted with oxygen in excess from a line (15) at a temperature
of 800 °C to 900 °C, which is well below the fusion temperature of the mineral components
of the bed. The oxygen may serve as the fluidizing gas, or a separate fluidizing gas
may be provided. The substantially carbon free residue may be removed via a line (16).
Residence times of the solids will depend on the operating conditions, such as the
temperatures, pressures, and specific equipment, and may be adjusted suitably by
those skilled in the art. The combustion gas is removed from the bed (14) via the
line (3), and is utilized as described previously. As noted previously, the total
carbon present in the bottoms solids is insufficient to provide the required heat
for drying the coal to the process. Normally, even the addition of flyash is not sufficient
for this large requirement, and the flyash may be diverted for other purposes. To
supplement the heat requirements, additional carbon-containing materials, such as
coal fines, may be added to the fluidized bed (14) via a line (25).
[0019] In order to determine if the bulk density of a sample of fine slag and char remaining
from the gasification of coal might be increased, the sample was heated in a quartz
dish for at least one hour in air at 750 °C in a muffle furnace. The sample weighed
69.11 grams and had a volume of about 82 ml. After the heat treatment, the sample
weighed 61.2 grams, had a volume of about 55 ml. The loss on ignition was 11.4 per
cent by weight, based on the weight of the original sample.
[0020] While the invention has been illustrated with particular apparatus, those skilled
in the art will recognize that, except where indicated as material herein, other equivalent
or analogous equipment may be employed. For example, crushing and drying equipment
may be separate, and the gasifier need not have the specific configuration shown.
Means other than a sluice may be provided for fine slag and char removal.
[0021] Again, as used herein, the term "zone", as employed in the specification and claims,
includes, where suitable, the use of segmented equipment operated in series, or the
division of one unit into multiple units to improve efficiency or overcome size constraints,
etc. For example, a series of cyclones may be employed, and the quench and cooling
operations are preferably carried out in multiple units, utilizing different techniques.
Parallel operation of units, is, of course, well within the scope of the invention,
and all equipment, such as pumps, valves, control units, etc. has not been illustrated.
1. A process for the gasification of coal to produce synthesis gas comprising the
steps of
feeding particulate coal to a gasification zone, and partially oxidizing coal with
oxygen in said gasification zone, producing a gas stream comprising synthesis gas,
and impurity materials which are collected in a water bath as char, fine slag, and
coarse slag;
removing a material comprising char from said water bath; characterized by the steps
of
fluidizing removed char in a fluidized bed in a fluidization zone, and oxidizing said
char in said fluidized bed with oxygen at a temperature below the fusion temperature
of the mineral components of the char and the fluidized bed, producing a substantially
carbon-free residue and heated gases, and
utilizing the heat in the heated gases.
2. The process as claimed in claim 1 characterized in that fine slag is present in
the material removed from the water bath, and the fine slag is fluidized and oxidized
in the fluidized bed, the temperature employed also being below the fusion temperature
of the mineral components of the fine slag.
3. The process as claimed in claim 1 characterized in that coarse slag is present
in the material moved from the water bath, and the coarse slag is fluidized in the
fluidized bed, the temperature employed also being below the fusion temperature of
the mineral components of the slag.
4. The process as claimed in claim 2 characterized in that the temperature in the
fluidized bed is maintained below about 1482 °C, but below the fusion temperature
of the mineral components of the fluidized bed.
5. The process as claimed in claim 2 characterized in that the heat from the heated
gases is used to generate steam.
6. The process as claimed in claim 2 characterized in that the heat is utilized by
contacting the heated gases directly with moist coal to remove moisture from the coal.
7. The process as claimed in claim 1 characterized in that the heat is utilized by
contacting the moist coal with a solid or gas heated directly or indirectly by said
heated gases.
8. The process as claimed in any one of claims 1-7 comprising the steps of partially
oxidizing coal with oxygen in said gasification zone at a pressure of from 10 atmospheres
to 100 atmospheres, the gasification zone outlet temperature being from 1100 °C to
1800 °C, characterized by the steps of oxidizing said char in said fluidized bed with
oxygen at a temperature of from 500 °C to 1150 °C, but below the fusion temperature
of the mineral components of the fluidized bed, and a pressure of about atmospheric
or higher.