[0001] This invention relates to lubricating oil compositions and more particularly to lubricating
oil compositions rich have excellent defoamability (defoaming ability) and are utilizable
as engine oils, gear oils, hydraulic oils, automatic transmission oils, bearing oils
or the like.
[0002] Generally, lubricating oils are made to circulate through lubricating portions (which
are those to be lubricated) during their use to save the amount thereof used. Therefore.
the oils which passed through the lubricating portions are then returned to a sump.
Since the oils have air caught therein at the lubricating portions, the oils so returned
ordinarily foam or bubble. If the foam in the oils is difficultly breakable, it will
gradually increase during the use of the oils whereupon the oils will finally overflow
the sump. Accordingly, defoamability is required in lubricating oils.
[0003] Antifoaming agents, such as silicone oils and polyacrylates, have heretofore been
added to base oils for the sake of improving the resulting lubricating oils in defoamability.
[0004] Although silicone oils are known as good antifoaming agents, they have comparatively
high solubility to light-fraction oils thereby they will remarkably lower in defoamability
when used in the light-fraction oils. Further, the silicone oils will deteriorate
when used for a long period of time, used under hard conditions or used with certain
chemical materials, thereby causing the silicone oils to lose their defoamability.
[0005] Polyacrylates are inferior in defoamability.
[0006] On the other hand, although perfluoro ethers are known as base oils for synthetic
lubricating oils, they have never been used as minor components in lubricating oils
since they are hardly soluble in other mineral oils and synthetic oils.
[0007] Accordingly, it is desired to develop an antifoaming agent which solves the above
problems.
[0008] The present invention has an object to provide a lubricating oil composition having
excellent defoamability or defoaming ability which is little lowered even if the composition
is used for a long period of time or under hard conditions.
[0009] The present inventors had made intensive studies in attempts to achieve the object
mentioned above and, as the result of their studies, they found that a lubricating
oil composition including a perfluoroalkyl ether has excellent defoamability. The
present invention is based on this finding.
[0010] The lubricating oil composition of the present invention includes as an essential
component a perfluoro ether in an amount by weight of 1-1000 ppm based on the total
weight of the composition.
[0011] The present invention will be further explained in detail.
[0012] All binds of base oils ordinarily used for lubricating oils are utilizable as base
oils used in the lubricating oil compositions of the present invention, and it does
not matter whether said base oils are mineral oil-based or synthetic oil-based ones.
[0013] Examples of the mineral oil-based lubricating oils used herein are those produced
by subjecting fractions obtained by atmospheric distillation or reduced pressure distillation
of mineral oils, to any suitable refining treatment such as solvent deasphalting,
solvent extraction, hydrocracking, solvent dewaxing, hydrodewaxing, sulfuric acid
treatment, clay treatment, hydrorefining or the like, or any suitable combination
thereof.
[0014] Further, examples of the synthetic oil-based lubricating oils include alpha-olefin
oligomers such as normal paraffin, isoparaffin, polybutene, polyisobutylene and 1-decene
oligomers: alkylbenzenes such as a monoalkylbenzene, dialkylbenzene and polyalkylbenzene;
alkylnaphthalenes such as a monoalkylnaphthalene, dialkylnaphthalene and polyalkylnaphthalene;
diesters such as di-2-ethylhexyl sebacate, dioctyl adipate, diisodecyl adipate, ditridecyl
adipate and ditridecyl glutarate; polyol esters such as trimethylolpropane caprylate,
trimethylolpropane pelargonate, pentaerythritol-2-ethyl hexanoate and pentaerythritol
pelargonate; polyglycols such as polyethylene glycol, polyethylene glycol monoether,
polypropylene glycol and polypropylene glycol monoether; polyphenyl ethers; tricresyl
phosphate; and silicone oils.
[0015] In the present invention, these oils may be used singly or jointly.
[0016] The base oils mentioned above should have a viscosity at 40°C of preferably 2 to
1000 centistokes.
[0017] Perfluoro ethers having various chemical structures can be used as an essential component
in the lubricating oil composition of the present invention. The perfluoro ethers
may be any compound represented by the general formula R₁-O⁅R₃-O⁆
nR₂ or may be a mixture thereof.
[0018] In the above general formula, R₁ and R₂ may be identical with, or different from,
each other and each represent a straight-chain or branched-chain perfluoralkyl group
having 1-4 carbon atoms, R₃ represents a straight-chain or branched-chain perfluoroalkylene
group having 1-4 carbon atoms, and n is an integer of 2 or more, preferably 10-300.
Each of R₁ and R₂ is exemplified by perfluoromethyl group, perfluoroethyl group, perfluoropropyl
group, iso-perfluoropropyl group, perfluorobutyl group, iso-perfluorobutyl group,
sec.-perfluorobutyl group, tert.-perfluorobutyl group or the like. Further, R₃ is
exemplified by perfluoromethylene group, perfluoroethylene group, perfluorotrimethylene
group, perfluoropropylene group, perfluorotetramethylene group, perfluorobutylene
group, perfluoro 1,2-dimethylethylene group, perfluoro 1-methyltrimethylene group,
perfluoro 2-methyltrimethylene group or the like.
[0019] The perfluoro ether used in the present invention may contain different perfluoroalkylene
groups in the molecule. In this case, the different perfluoroalkylene groups may form
a random copolymer or a block copolymer.
[0020] The viscosity of the perfluoro ether used in the present invention is not particularly
limited, but it is in the range of usually 10-10000 cSt at 20°C, preferably 20-2000
cSt at 90°C. Further, the average molecular weight of the perfluoro ether is not particularly
limited, but it is in the range of usually 500-50000, preferably 1800-10000.
[0021] It is important that the lubricating oil composition of the present invention include
the perfluoro ether in an amount by weight of 1-1000 ppm, preferably 3-100 ppm, based
on the total weight of the composition. In a case where the content of the perfluoro
ether in such a lubricating oil composition is less than 1 ppm by weight, the perfluoro
ether will undesirably not exert a satisfactory defoaming effect , while in a case
where the content of the perfluoro ether exceeds 1000 ppm by weight in such a lubricating
oil composition, the perfluoro ether may undesirably be sedimented to be separated
from the composition.
[0022] The lubricating oil compositions of the present invention may further include, as
required, known additives for the purpose of further improving them in properties
or performances. Such additives include, for example, antioxidants, detergent-dispersants,
viscosity index improvers, pour point depressants, oiliness improvers, wear resistant
agents, extreme pressure agents, corrosion inhibitors, metal-deactivators, antifoaming
agents (except for the perfluoro ethers mentioned above), emulsifiers, demulsifiers,
bactericides and colorants. These various additives are described in detail, for example,
in "Junkatsuyu Gakkaishi (Japanese Journal of Lubricating Oil Society), Vol.15, No.6"
and "Sekiyuseihin Tenkazai (Additives For Petroleum Products" written by Toshio Sakurai
and published by Saiwai Bookstore. These additives may suitably be selected depending
on the purpose for which the resulting lubricating oil is used. The lubricating oil
compositions of the present invention are also superior in the respect that the perfluoro
ethers which are the essential components of said compositions will be less deteriorated
by interaction with other additives to be used therewith than the heretofore known
antifoaming agents, thereby to enable a wider-range selection of the other additives.
[0023] The total amount of these various additives used is ordinarily up to 50% by weight,
preferably up to 30% by weight, based on the total weight of the composition.
[0024] The lubricating oils of the present invention may be used as engine oils such as
a four-cycle gasoline engine oil, land diesel engine oil, marine diesel engine oil
and gas engine oil; turbine oils such as an industrial turbine oil, marine turbine
oil and gas turbine oil; gear oils such as an automobile gear oil, industrial gear
oil and automatic transmission oil; hydraulic oils; compressor oils; vacuum pump oils;
refrigerator oils; metal working oils such as a cutting oil, grinding oil, rolling
oil, pressing oil, drawing oil, throttling-ironing oil and forging oil; slide guiding
surface oils; bearing oils; and the like.
[0025] The lubricating oil compositions of the present invention contain a certain small
amount of the perfluoro ethers whereby they can be excellent ones which are featured
as follows:
(1) The present lubricating oil compositions enable the foaming a light-fraction oil
as their base oil to be prevented ;
(2) They exhibit less reduction in defoamability due to the degradation thereof, thereby
to lessen the oil change frequency and achieve the cost reduction; and
(3) They can include therein additives which have heretofore been unable to be used
for lubricating oils because of degrading silicone oils.
[0026] This invention will be better understood by the following Examples and Comparative
Examples.
Example 1 and Comparative Example 1
[0027] A perfluoro ether (trade name, Fomblin Y25: viscosity, 250 cSt at 20°C: molecular
weight, 3000: produced by Asahi Glass Co., Ltd.) was added in an amount by weight
of 30 ppm based on the total oil, to an industrial bearing oil as the base oil (mineral
oil-based base oil whose viscosity was 220 cSt at 40°C) to obtain a lubricating oil
composition (Example 1), while a silicone oil (viscosity: 3000 cSt at 95°C), instead
of the perfluoro ether, was added in an amount by weight of 30 ppm based on the total
oil, to the same industrial bearing oil as in Example 1 to obtain a lubricating oil
composition (Comparative Example 1). The thus obtained lubricating oil compositions
were subjected to the following oxidizing test and then to the following foaming test,
respectively. The test conditions are indicated below, and the results of the foaming
test are indicated in Table 1.
(Oxidizing Test)
[0028] The oil compositions were each subjected to oxidition at 150°C for 120 hours in accordance
with JIS K 2514 3.1.
(Foaming Test)
[0029] A foaming test was carried out on each of the oxidized oil compositions at 24°C in
accordance with JIS K 2518.
Table 1
|
Degree of foaming (mℓ) |
Stability of foam (mℓ) |
Example 1 |
30 |
0 |
Comparative Example 1 |
560 |
20 |
Example 2 and Comparative Example 2
[0030] A perfluoro ether (trade name, Fomblin Y45: viscosity, 250 cSt at 20°C: molecular
weight, 3000: produced by Asahi Glass Co., Ltd.) was added in an amount by weight
of 30 ppm based on the total oil, to an automobile transmission oil as the base oil
(mineral oil-based base oil whose viscosity is 14 cSt at 100°C) to obtain a lubricating
oil composition (Example 2), while a polyacrylate instead of the perfluoro ether was
added in an amount by weight of 200 ppm based on the total oil, to the same automobile
transmission oil as in Example 2 to obtain a lubricating oil composition (Comparative
Example 2). The thus obtained lubricating oil compositions were subjected to the following
oxidizing test and then to the same foaming test as in Example 1, respectively. The
oxidizing test conditions are indicated hereunder, and the results of the foaming
test are indicated in Table 2.
(Oxidizing Test)
[0031] The oil compositions were each subjected to oxidation at 150°C for 100 hours in accordance
with JIS K 2514 3.1.
Table 2
|
Degree of foaming (mℓ) |
Stability of foam (mℓ) |
Example 2 |
20 |
0 |
Comparative Example 2 |
130 |
0 |