[0001] The present invention relates particularly, though not exclusively to moulds for
producing precision cast articles.
[0002] In, for example, the precision casting of components for turbine machinery it is
virtually universal practice to employ the technique known as investment or lost-wax
casting.
[0003] Investment casting generally requires that a pattern or facsimile of the component
to be cast is first made in a wax material. The wax pattern is then coated by dipping
with a face, or prime ceramic slurry of a controlled composition and rheology, the
dipped pattern then receives a stucco coating of dry grains of a ceramic material.
The ceramic material commonly comprises one or more selected from the group which
includes alumina, silica, alumino-silicates, zirconium silicate, for example, and
is of a controlled particle size range. The dipped and stucco coated pattern is then
dried and given a second slurry coating, again of a carefully controlled composition
and rheology, which again also receives a second stucco coating of ceramic material.
The desired mould is built-up in this fashion with several slurry and stucco repeat
coatings until the desired mould thickness is achieved. The wax pattern is finally
removed, usually in a steam autoclave, to leave a mould cavity having the desired
shape. The resulting "green" or unfired mould is then fired under a precisely controlled
heating cycle to increase its strength and to burn off residual wax. The binder material
in the slurry is often colloidal silica, in which case, the strength increase is achieved
by creation of siloxane bonds within the ceramic matrix. Such moulds possess a degree
of inherent porosity, typically up to 30 vol.%, and are characterised by thermal diffusivity
values in the range 0.7 to 1.6 mm²s⁻¹.
[0004] There are two principal casting techniques whereby turbine blades, for example, are
cast. These two techniques result in three different metal grain structures in the
resulting casting, depending on the process controls applied to the solidification
of the cast metal.
[0005] The first and oldest technique, and also the technique which is employed to produce
the majority of precision cast components used in gas turbine engines, for example,
is that which results in a component having an equiaxed grain structure. In this technique,
molten metal is poured into a preheated mould which is then allowed to cool by radiation
of heat from the mould exterior. The metal solidifies by nucleation and growth at
many sites throughout the casting to give an equiaxed grain structure.
[0006] The second technique is directional solidification where, depending upon the process
constraints applied, the component may solidify either in polycrystalline form with
a structure made up of directionally aligned columnar crystals or it may solidify
in the form of a single crystal.
[0007] It is with the first technique for forming components with equiaxed grain structures
that the present invention is primarily concerned.
[0008] Turbine components, especially blades, frequently employ an airfoil portion. This
particular portion is often significantly thinner in section than the remainder of
the component. These thin airfoil sections, and indeed any other thin casting sections,
are prone to premature solidification due to the lower ratio of hot metal to cooler
mould. If solidification is too rapid, defects such as cold-shuts, misruns and shrinkage
porosity frequently occur.
[0009] European patent application No. 0,399,727 addresses the same problem and seeks to
provide a mould having improved insulative properties by coating a disposable pattern
with ceramic slurry and applying one or more layers of hollow granular bubble material.
However, the bubble walls are dense and relatively conductive, allowing heat to be
transferred quickly around the bubble void.
[0010] It is an object of the present invention to provide a mould and a method of making
a mould which has significantly improved insulative properties over known moulds.
[0011] According to a first aspect of the present invention, there is provided a method
of making a mould for the casting of metal articles, the method comprising the steps
of coating a pattern of the article to be cast with a ceramic slurry, dusting the
coated pattern with ceramic particles to form a face layer, drying the slurry coated
and dusted layer so formed, coating the coated and dried pattern with a slurry for
a second time and dusting with a particulate material and again drying, repeating
the slurry coating, dusting with particulate material and drying cycles until a desired
thickness of mould material has been built-up wherein at least one of the dusting
steps employs fugitive particulate material which is removed during a subsequent heating
step to leave residual voids in a ceramic matrix.
[0012] In one embodiment of a method according to the present invention the fugitive particulate
material may be a polymeric plastics material such as, for example, expanded polystyrene.
[0013] The heating step to remove the fugitive material may be a firing process to which
the mould is subjected.
[0014] The thermal diffusivity of the resulting mould may be controlled through adjustment
of the sizes of particles of fugitive material included in, and the number of, layers
from which are formed layers having voids therein.
[0015] In some cases, it may be desirable that a stucco coating step for a layer of particulate
material may be effected with a mixture of both fugitive material particles and ceramic
particles. In this manner, more accurate control of the thermal diffusivity may be
effected.
[0016] Preferably, the ceramic matrix may comprise low density, and hence low thermal conductivity,
refractories such as, for example, silica or high silica content alumino-silicates.
[0017] According to a second aspect of the present invention, there is provided a mould
for the casting of metal articles, the method of making the mould includes the steps
of coating a pattern of the article to be cast with a ceramic slurry, dusting the
coated pattern with ceramic particles to form a face layer, drying the slurry coated
and dusted layer so formed, coating the coated and dried pattern with a slurry for
a second time and dusting with a particulate material and again drying, repeating
the slurry coating, dusting with particulate material and drying cycle until a desired
thickness of mould material has been built up, thereby the mould comprising a face
layer adjacent a metal to be cast and a plurality of successive layers wherein at
least one of the successive layers comprises a ceramic matrix having voids therein
formed by the removal of a fugitive particulate material.
[0018] Moulds made in accordance with the method of the present invention have resulted
in thermal diffusivity value of 0.5 to 0.7 mm²s⁻¹.
[0019] Where there is more than one layer containing voids, these may be interspersed with
layers having only ceramic stucco particles contained therein to maintain sufficient
mould strength to withstand metallostatic pressures on casting.
[0020] In order that the present invention may be more fully understood an example will
now be described by way of illustration only with reference to the accompanying drawing,
which shows a schematic representation of a section taken through part of the thickness
of a mould in accordance with the present invention.
[0021] Referring now to the drawing and where the mould wall is designated at 10. The mould
wall comprises a face layer 12 which is initially adjacent a wax pattern 14 and, after
pattern removal and firing of the mould, is adjacent the cast metal. Initially the
face layer comprises a slurry of a colloidal, or otherwise finely divided, ceramic
material.
[0022] Any such slurry may include further finely divided material, and/or at least one
material in the form of particles of a size conventionally referred to as a grit size.
In the illustrated example the slurry forming the face layer 12 is of colloidal silica
having a filler of zircon flour therein. The wax pattern 14 is coated by being dipped
into the slurry, and is then dusted with fine zircon sand particles indicated at 18.
The dipped and dusted pattern is then dried and subsequently redipped in a similar
slurry to the first, but having a controlled lower viscosity. The dipped pattern is
then dusted with -22 to +50 B.S mesh Molochite (trade mark) stucco grains 21, and
dried again to form the layer 20. This is followed by a further slurry dipping step,
after which the dipped pattern is given a stucco coating of expanded polystyrene beads
22 having a size, in this instance, in the range from 1 to 1.5 mm in diameter. After
drying to form the layer 23, the pattern is recoated with a slurry having a composition
of about 30 wt% colloidal silica (25% concentration), 50 wt% Molochite flour of about
200 B.S mesh size and 20 wt% Molochite grains of -22 to +50 B.S mesh size. This coating
is dusted with Molochite grains and dried. The Molochite grains are indicated at 24,
and are in a layer indicated at 26. The cycle of dipping with slurry, stucco coating
and drying is repeated until a sufficient mould wall thickness has been established.
In the example shown a second stucco coating of polystyrene beads is shown at 28,
in relation to a layer 29; followed by a second stucco coating of Molochite grains
30 in relation to a layer 32. Layer 34 is formed from a dipped coating of a ceramic
slurry dusted with a mixture of both fugitive material particles 36 and ceramic particles
38. Thus a matrix is built up in successive layers, and so that the ceramic material
has particles embedded therein. After the required mould wall thickness has been built
up the mould is finally dried and the wax pattern 14 removed, usually in a steam autoclave.
The mould is then subjected to a firing cycle to burn-off the polystyrene beads 22,
28, leaving behind voids of the same size in their place, and to strengthen the matrix
by creation of siloxane bonds. A typical burn-off and firing cycle may comprise heating
the mould to 800 to 1000
oC for 30 to 45 minutes. Because of the inherent porosity levels of up to 30 vol% in
the ceramic matrix of these types of investment casting mould, it is possible to burn-off
the polystyrene, or any other polymeric material, without the danger of rupturing
the mould.
[0023] Moulds were prepared according to the example given above and the schematic representation
shown in the drawing. The moulds each contained four nozzle guide vane segment cavities,
each segment comprising six airfoils. The airfoils were 160 mm in length, 30 mm chordal
dimension, and approximately 0.6 mm maximum thickness. The moulds were cast using
preheat and pouring temperatures typical for casting nickel-based superalloys. The
resulting cast components were compared with castings made using a conventional zircon
and alumino-silicate mould.
[0024] There was no evidence of premature solidification in the form of misrun, and the
components were of sufficient soundness to make them acceptable to specification without
the need for post-cast hot isostatic pressing. Acceptable casting soundness could
not be achieved using conventional moulds without resorting to post-cast hot isostatic
pressing.
1. A method of making a mould for the casting of metal articles, the method comprising
the steps of coating a pattern of the article to be cast with a ceramic slurry, dusting
the coated pattern with ceramic particles to form a face layer, drying the slurry
coated and dusted layer so formed, coating the coated and dried pattern with a slurry
for a second time and dusting with a particulate material and again drying, repeating
the slurry coating, dusting with particulate material and drying cycles until a desired
thickness of mould material has been built-up, characterised in that at least one
of the dusting steps employs fugitive particulate material which is removed during
a subsequent heating step to leave residual voids in a ceramic matrix.
2. A method according to claim 1 characterised in that the fugitive particulate material
is a polymeric plastics material.
3. A method according to claim 2 characterised in that the polymeric material is expanded
polystyrene.
4. A method according to any one preceding claim characterised in that the at least one
dusting step employs both ceramic and fugitive particulate material.
5. A method according to any one preceding claim characteirsed in that the ceramic matrix
comprises low density refractories.
6. A method according to claim 5 characterised in that the low density refractories are
selected from the group comprising silica and alumino-silicates.
7. A method according to any one preceding claim characterised in that the heating step
is a mould firing process.
8. A mould for the casting of metal articles, the method of making the mould includes
the steps of coating a pattern of the article to be cast with a ceramic slurry, dusting
the coated pattern with ceramic particles to form a face layer, drying the slurry
coated and dusted layer so formed, coating the coated and dried pattern with a slurry
for a second time and dusting with a particulate material and again drying, repeating
the slurry coating, dusting with particulate material and drying cycle until a desired
thickness of mould material has been built up, thereby the mould comprising a face
layer adjacent a metal to be cast and a plurality of successive layers, characterised
in that at least one of the successive layers comprises a ceramic matrix having voids
therein formed by the removal of a fugitive particulate material.
9. A mould according to claim 8 characterised in that the thermal diffusivity value lies
in the range from 0.5 to 0.7mm²s⁻¹.
10. A mould according to either claim 8 or claim 9 characterised in that the voids are
from about 1 to 1.5 mm in diameter.
11. A mould according to claim 8, or claim 9, or claim 10, characterised in that there
is more than one void containing layer, and these are interspersed with layers having
only ceramic stucco particles contained therein.
12. A mould according to any one preceding claim from 8 to 11 characterised in that a
void containing layer also contains ceramic stucco particles.