[0001] This invention relates to the electrostatic coating of plastic substrates. More particularly,
it relates to a two coat primer system comprising a non-conductive, chromatically
pigmented first coat and a relatively thin translucent conductive second coat. It
relates still more particularly to a conductive primer that is color-keyed to the
hue of the topcoat.
[0002] Until recently, conductive black primers were the only primers available for the
electrostatic coating of plastic parts. This made it difficult to hide the primer
with white or colored topcoats and also made chips in the topcoat quite visible. The
introduction of conductive white or clear pigments in recent years has allowed the
development of conductive primers in chromatic colors to match the topcoat but these
pigments are very expensive and the cost of primers made therefrom is prohibitive.
[0003] The creation of a one-coat non-black conductive coating capable of both good substrate
hiding and conductivity is fraught with a number of problems. To obtain hiding with
a colored system, a substantial number of non-conductive pigment particles must be
present in the coating composition but then it must be converted into a conductive
coating. To do this, one must add the expensive conductive pigment in an amount sufficient
to overcome the insulating effect of the hiding pigments. The cost of such a one-coat
coating system is very high because the amount of conductive pigment which is sufficient
is very large indeed.
[0004] It is an object of this invention, therefore, to provide an inexpensive, two coat
primer system for the electrostatic coating of plastic parts in which hiding of the
substrate is achieved with a colored non-conductive first coat and the conductivity
is supplied by a thin translucent coat containing the conductive pigment.
[0005] It is a related object of this invention to provide a color-keyed primer for electrostatically
coated plastic parts.
[0006] It is another related object of this invention to provide a wet-on-wet method for
applying a two-coat, colored primer suitable for the electrostatic application of
a topcoat.
[0007] These and other objects of this invention which will become apparent from the following
description are achieved by a method comprising applying a non-conductive, colored
primer coating composition to hide the substrate and then applying a translucent conductive
primer coating to the wet surface of the non-conductive primer and baking the coated
substrate. In the context of this invention, the word color and all derivatives of
it are used to mean a chromatic color as opposed to white and black, which actually
are the absence of color and the combination of all colors of the spectrum, respectively.
The substrate may be metal as well as plastic but the invention finds its reason in
the coating of plastic parts. The translucency of the conductive coating is an attribute
of the poor hiding power of the conductive pigment; as well as the relatively thin
layer of the conductive primer as compared to the first layer which hides the substrate.
[0008] The preferred binder for both the non-conductive and conductive primer coating compositions
is a hydroxyl-functional polyester having an OH value of from 170 to 240, preferably
from 190 to 220. The polyesters are preferably made from saturated aliphatic acids
and polyols by methods which are well known by and routinely practiced by those of
ordinary skill in the art. The reactants may be heated to a temperature in the range
of from 135 to 220°C (275 to 430°F) while being sparged with a stream of inert gas
such as nitrogen to remove water as it forms. Vacuum or an azeotrope-forming solvent
may be used at the appropriate temperature to assist the removal of water. Examples
of suitable dicarboxylic acids include malonic, succinic, adipic, methyladipic, sebacic,
and suberic acid. Among the suitable polyols are ethylene glycol, 1,3-propylene glycol,
diethylene glycol, neopentyl glycol, and trimethylolpropane. Mixtures of the acids
and of the polyols may be used. The use of vacuum to assist the removal of water must
take into account the potential loss of polyol through sublimation. A catalyst may
be used but satisfactory results are achieved without one.
[0009] The weight average molecular weight (Mw) may range from about 500 to about 20,000,
preferably between about 600 and about 1000. The hydroxy functionality of a preferred
resin is about 3/molecule and the carboxy functionality is about 0.1/molecule. The
Brookfield viscosity of the resin, using a # 3 spindle at 20 rpm, is from about 3600
to about 7200 centipoises. Its density is about 1.09 grams/cc or about 9.06 pounds
per gallon. Suitable polyesters for the practice of this invention are available from
Ruco and Miles under the trademarks Rucoflex and Desmophen.
[0010] Dispersions in a solvent of one or more non-conductive pigments and from about 20
to about 40 per cent by weight of the polyester and, optionally the appropriate amount
of curing agent and/or an epoxy resin, are made in a sand mill to a Hegman grind of
about 6.5 + or a particle size on the order of about 20 microns or less.
[0011] Epoxy resins suitable for this invention are generally known and are prepared by
well known techniques. They are conpounds or mixtures of compounds containing at least
one, but typically more than one, 1,2-epoxy group. They may be saturated or unsaturated,
aliphatic, cycloaliphatic, aromatic, or heterocyclic. Examples of suitable epoxy resins
include polyglycidyl ethers of polyphenols such as bisphenol A and bisphenol F, polyglycidyl
ethers of mononuclear polyhydric phenols such as resorcinol and pyrogallol, polyglycidyl
ethers of polyhydric alcohols such as ethylene glycol and pentaerythritol, and glycidyl
esters of acrylic and methacrylic acid. Minimal amounts of up to about 2 % by weight
of the coating composition are useful in certain formulations.
[0012] These dispersions are then blended with a curing agent, flatteners, flow agents,
and other additives such as dispersants, surfactants, UV absorbers and, sufficient
additional amounts of the polyester to make the first or non-conductive coating composition
and the second, conductive coating composition having the desired properties.
[0013] The non-conductive coating composition of this invention may be made from about 1
to about 55 per cent by weight of the non-conductive dispersion and from about 5 to
about 20 per cent by weight of additional polyester. Titanium dioxide is the major
ingredient in the non-conductive dispersion mentioned above and it becomes the major
pigment in the non-conductive primer coating compositions for its hiding power. In
order to provide a color-keyed primer for electrostatically coated plastic parts,
the colored pigments preferably are the same as those present in the topcoat and may
be organic or inorganic and are exemplified by phthalocyanine blue, phthalocyanine
green, quinacridone red, perylene red, isoindolenone yellow, and the various iron
oxides. Very small amounts, on the order of about 0.15 per cent by weight of the total
weight of the non-conductive composition, of these pigments are sufficient to impart
the desired color. About 0.1 per cent by weight of a conductive pigment such as carbon
black may be present in the non-conductive composition. The non-conductive coating
composition may also contain up to about 4 % by weight of a microgel solution.
[0014] The conductive primer coating composition contains from about 15 to about 25 % by
weight of a conductive white or clear pigment as exemplified by an antimony doped
tin oxide on a mica support sold under the trademark MINATEC by EM Industries, Inc.
Another example of a suitable conductive pigment is the potassium titanate fiber sold
by Otsuka Chemical Co., Ltd. under the trademark TISMO. The TISMO 200B powder is a
particular example of such pigments. Antimony/tin oxides are described in U. S. Patent
Nos. 4,655,966 and 5,104,583, which are incorporated herein by reference. It is preferred
to add colored pigments like those given above to tint the conductive composition
to approximate the color of the non-conductive primer coat and maintain the color
match between the primer and the topcoat that is the object of this invention. Again,
small amounts of conductive black pigments may be tolerated. The pigment to binder
ratio in the conductive composition is about 1:1.7 or less by weight; in terms of
percent, the weight of the pigment is about 60 % or less of the weight of the binder.
The final conductive coating composition of this invention may be made with from about
15 to about 25 per cent by weight of the conductive pigment and from about 20 to about
30 per cent by weight of the polyester beyond that which comes from the pigmented
dispersions.
[0015] The polyesters are curable through the hydroxyl groups, preferably with aminoplasts,
which are oligomers that are the reaction products of aldehydes, particularly formaldehyde,
with amino- or amido-group-carrying substances exemplified by melamine, urea, dicyanodiamide,
and benzoguanamine. Especially advantageous are the aminoplasts, which are modified
with alkanols having from one to four carbon atoms. Other suitable aminoplast resins
include the alkoxymethyl glycourils such as tetra (methoxymethyl) glycouril. Thus,
a wide variety of commercially available aminoplasts and their precursors can be used
for combining with the linear polyesters of this invention. Particularly preferred
are the amino crosslinking agents sold by American Cyanamid under the trademark Cymel
and by Monsanto under the trademark Resimene. In particular, the Cymel 301, Cymel
303, Cymel 385, Resimene 745 and Resimene 755 alkylated melamine-formaldehyde resins
are useful. Of course, it is possible to use mixtures of all of the above N-methylol
products. Hydroxyl-reactive cross-linking is generally provided in an amount sufficient
to react with at least one-half the hydroxyl groups of the polyester, i.e., be present
at at least one-half the stoichiometric equivalent of the hydroxyl functionality.
Preferably, the cross-linking agent is sufficient to substantially completely react
with all of the hydroxyl functionality of the polyester, and cross-linking agents
having nitrogen cross-linking functionality are provided in amounts of from about
1 to about 12 equivalents of nitrogen cross-linking functionality per equivalent of
hydroxyl functionality of the polyester. The first, non-conductive coating composition
contains from about 10 to about 20 per cent by weight of the curing agent while the
conductive coating composition contains from about 12 to about 25 per cent by weight.
[0016] The solvent used in making the dispersions and further in making the coating compositions
from them is one that will give good wet out and flow properties to the coatings and
at the same time it is one that will not attack the plastic substrate being coated.
N-methyl-2-pyrrolidone (NMP) , ethyl benzene, isobutanol, xylene, ethyl-3-ethoxypropionate,
aromatic naphtha, dipropylene glycol monomethyl ether acetate (DPMA), propylene glycol
methyl ether acetate (PM acetate), and mineral spirits are examples of suitable solvents.
Often a mixture of selected solvents is used to meet such requirements. The dispersions
contain from about 15 to about 65 per cent by weight of solvent and the solvent content
of the coating compositions is from about 20 to about 40 per cent by weight.
[0017] A preferred thixotrope is a fumed silica such as is available under the trademarks
Cab-O-Sil and Aerosil. When present in a coating composition, it is used in amounts
of less than 1 per cent of the total weight. An amorphous silica available from SCM
Corporation is useful at less than 2 per cent by weight as a flattening agent. The
dispersants, surfactants, UV absorbers, and other additives are all as conventionally
used in coating compositions. A conventional curing catalyst is added to each of the
primer compositions prior to use. The amount of active catalyst may be from about
0.2 to about 1.2 % by weight of the total composition. The catalyst may be most any
organic soluble acid as exemplified by p-toluene sulfonic acid and phenyl acid phosphate.
A catalyst solution containing 17.5 % p-toluene sulfonic acid and 13.1 % phenyl acid
phosphate, by weight, is suitable but other ratios of the two may also be used to
meet the demands of particular coating compositions.
[0018] The following examples illustrate the invention. Unless otherwise indicated, all
amounts, parts, and percentages are by weight.
EXAMPLE I
[0019] A dispersion of a non-conductive pigment was made from the following constituents
in a water cooled sand mill, Model No.Red Head L3J standard, sold by Chicago Boiler
Company. The Hegman grind of the non-conductive dispersion was 7+.

EXAMPLE II
[0020] A non-conductive coating composition was made from the dispersion of Example I according
to the formula:

EXAMPLE III
[0021] A conductive coating composition was made according to the formula:

[0022] Shortly before the first primer coat is to be applied, the non-conductive composition
is reduced with 3 parts of catalyst per 100 parts of the product of Example II. Likewise,
the conductive composition is reduced with 3 parts of catalyst per 100 parts of the
product of Example III.
[0023] In this invention, the two primer compositions are preferably applied wet-on-wet
by spray gun in order to increase the throughput of coated parts. The first coat is
sprayed onto the plastic part from a gun at an air pressure of about 60 psi to build
a film having a dry thickness sufficient to hide the substrate, e.g., from about 0.7
to 0.8 mil, and then allowed to stand at ambient temperature for about 1 minute to
flash off a portion of the solvent. The conductive coat is then sprayed in similar
fashion to a dry film thickness of from about 0.3to about 0.4 mil. After air drying
at ambient temperature for about 10 minutes, the coated part is baked at about 250°F
for about 30 minutes to cure both primer coats. The coated part has a conductivity
of from about 130 to about 165 Ransburg units as measured with a Ransburg Sprayability
Meter No. 8333-00.
1. A method for adapting a plastic substrate for an electrostatic deposition of a topcoat,
said method comprising applying a non-conductive, coloured primer coating composition
to the substrate to hide the substrate and then applying an amount of a conductive,
primer coating composition sufficient to give a dry film thickness of from 7.6 to
10.2 µm (0.3 to 0.4 mil) to the surface of the non-conductive primer and baking the
coated substrate.
2. A method according to claim 1 wherein the non-conductive coating is still wet when
the conductive coating is applied.
3. A method according to claim 1 or claim 2 wherein the non-conductive primer is colour-keyed
to the topcoat.
4. A method according to any preceding claim wherein the conductive primer composition
contains a coloured pigment.
5. A method according to claim 3 wherein the coloured pigment is chosen to approximate
the colour of the non-conductive primer.
6. A method according to any preceding claim wherein the conductive coating composition
comprises a binder and a conductive pigment in a ratio of 1:4 or less by weight.
7. A plastic article having a coloured, non-conductive first primer coat and a translucent
conductive second primer coat having a thickness of 7.6 to 10.2 µm (0.3 to 0.4 mil).
8. A plastic article according to claim 7 wherein the conductive primer coat is tinted
to approximate the non-conductive primer coat.
9. A plastic article having a coloured, non-conductive first primer coat, a conductive
second primer coat having a thickness of 7.6 to 10.2 µm (0.3 to 0.4 mil), and an electrostatically
applied topcoat colour matched to the non-conductive primer coat.
10. A plastic article according to any one of claims 7 to 9 wherein the conductive second
primer coat has a pigment to binder ratio of 1:1.7 or less by weight.