[0001] This invention relates to fuel additive compositions that can be used for control
of intake valve deposits without significantly affecting octane requirement increase
in the engine.
[0002] Over the years considerable work has been devoted to additives for controlling (preventing
or reducing) deposit formation in the fuel induction systems of spark-ignition internal
combustion engines. In particular, additives that can effectively control intake valve
deposits represent the focal point of considerable research activities in the field
and despite these efforts, further improvements are desired. Among relatively recent
efforts along these lines is U.S. 5,242,469 and published Canadian patent application
2,089,833.
[0003] The additive systems described in U.S. 5,242,469 comprise an ester and at least one
dispersant component chosen from certain monosuccinimides, bis(succinimides), polyolefin
polyamines, and benzylamine derivatives. The benzylamine derivatives appear to be
Mannich-type detergents*. These additive combinations may further contain a polyoxyalkylene
glycol or derivative thereof having a molecular weight of 500-5000, preferably 1000-3000.
Also, a specified type of lubricating oil fraction may be included in the additive
mixture. The polyoxyalkylene glycol derivatives referred to in the text of the patent
include the ethers, esters and ether aminoacid esters of the polyoxyalkylene glycol.
* According to the patent the hydroxybenzyl amine derivatives are made by alkylating
a hydroxybenzyl amine which in turn presumably would be formed by a Mannich reaction
among phenol, formaldehyde and polyamine. The resultant product should be similar,
if not identical, to a product made in the more usual sequence of alkylating the phenol
and then conducting the Mannich reaction with the resultant alkylated phenol, formaldehyde
and a polyamine
[0004] Canadian patent application 2,089,833 bearing a publication date of August 21, 1993
describes a similar additive system. In particular, the gasoline is to contain (a)
from 75 to 450 ppmw of a specified group of Mannich base detergents in combination
with (b) from 75 to 175 ppmw of an oil-soluble poly(oxyalkylene) alcohol, glycol or
polyol or mono or di ether thereof, wherein the weight ratio of (a) to (b) in the
mixture is at least 0.43.
[0005] It has now been discovered that oil-soluble poly(oxyalkylene) alcohols, glycols or
polyols or mono or di ethers thereof do not yield equivalent results on intake valve
cleanliness when used in conjunction with a Mannich base detergent, and that for reasons
not presently understood, the viscosity properties of the poly(oxyalkylene) component
appear to have a profound effect on the intake valve cleanliness performance of the
overall composition.
[0006] Accordingly, in one of its embodiments, this invention provides, a fuel-soluble additive
composition which comprises
a) a gasoline-soluble Mannich reaction product of
(i) a high molecular weight alkyl-substituted phenol wherein the alkyl group has a
number average molecular weight of from 600 to 3000,
(ii) amine and (iii) aldehyde;
b) a gasoline-soluble poly(oxyalkylene) compound having a viscosity in its undiluted
state of at least 70 cSt at 40°C and at least 13 cSt at 100°C; and
c) one or more poly-α-olefins collectively having viscosities at 40°C and 100°C that
are not more than approximately 25% higher than the respective viscosities of said
poly(oxyalkylene) compound at 40°C and 100°C,
wherein the proportions of a) to b) are such that there are from 0.2 to 5 parts by
weight of active Mannich base in a) per part by weight of b).
[0007] The composition contains one or more liquid poly-α-olefins which, whether a single
poly-α-olefin or a mixture of different poly-α-olefins, has a viscosity that is not
substantially in excess of the viscosity of the poly(oxyalkylene) compound.
[0008] Typically the proportions of a) to b) in the compositions of this invention are such
that there are from 0.2 to 5 parts by weight of a) per part by weight of b), preferably
from 0.5 to 3 parts by weight of a) per part by weight of b), and more preferably
from 0.8 to 2 parts by weight of a) per part by weight of b), with the weight of a)
being on an "active ingredient basis". By this is meant that component a) will usually
be supplied in admixture on a weight basis with a minor amount of a hydrocarbon diluent
and a minor amount of unreacted polyolefin used in making the alkylated phenol from
which the Mannich detergent is produced. Thus the foregoing proportions of a) to b)
are based on the content of Mannich base detergent in component a) excluding the weight
of any diluent or solvent and any unreacted polyolefin which may be associated therewith
in the form in which it is supplied. Component b) will normally be supplied in undiluted
form, and in such case its weight can be used directly in calculating the ratio of
a) to b). But if the poly(oxyalkylene) compound is being blended with a) when the
poly(oxyalkylene) compound is in admixture with a solvent or diluent, the weight of
b) should be based on the weight of the poly(oxyalkylene) compound itself and should
likewise exclude the weight of any such solvent or diluent associated therewith.
[0009] It will be understood that any such ancillary solvent or diluent, whether hydrocarbon
or otherwise, must not adversely affect the intake valve deposit control performance
of the above additive composition in any material way. Thus as long as they do not
exert such adverse effect, ethers, esters or other inert solvents or diluents may
be present in the additive composition.
[0010] As component c) the compositions of the invention include one or more poly-α-olefins
which collectively have viscosities at 40°C and 100°C that are not substantially in
excess of the viscosity of the poly(oxyalkylene) compound. More particularly, these
collective poly-α-olefin viscosities are not more than approximately 25 percent higher
than the corresponding 40°C and 100°C viscosities of the poly(oxyalkylene) compound
being used. Not only does this ensure that the intake valve deposit control effectiveness
of the composition will not be adversely affected in any material way, but it keeps
the cost of the additive composition to a minimum.
[0011] In another embodiment, this invention provides a method for reducing intake valve
deposits in gasoline engines. The method comprises fueling and operating said engines
with the fuel composition of the present invention.
[0012] As noted above, the Mannich reaction product component of this invention typically
contains a significant portion of hydrocarbonaceous ingredients which are inactive
in the sense that they do not possess polarity or surface activity and therefore do
not serve as detergents. For example, subsequent to the manufacture of the Mannich
reaction product, hydrocarbon solvent is typically added to dilute the product to
facilitate handling and blending. Thus, the Mannich product as received typically
contains 40 to 55 wt.% of the active Mannich base ingredient, the balance being solvent
or diluent, and unreacted materials from the synthesis steps, such as polyolefin polymer.
A generally used dilution solvent is a mixture of aromatic hydrocarbons such as o-,
p-, and m-xylene, mesitylene, and higher boiling aromatics such as Aromatic 150 (commercially
available from Chemtech).
[0013] The Mannich reaction products of this invention are obtained by condensing an alkylphenol
whose alkyl substituent, for example alkyl derived from 1-monoolefin polymer, has
a number average molecular weight of from 600 to 3000, preferably 750 to 1200, more
preferably 800 to 1200, and most preferably 800 to 950; an amine having at least one
>NH group, preferably an alkylene polyamine of the formula
H
2N - (A - NH -)
xH
where A is a divalent alkylene radical having 1 to 10 carbon atoms and x is an integer
from 1 to 10; and an aldehyde, preferably formaldehyde or a formaldehyde precursor,
in the presence of a solvent. Commercial grades of alkylene polyamines often contain
mixtures of linear, branched and cyclic species.
[0014] High molecular weight Mannich reaction products useful as additives in the fuel additive
compositions of this invention are preferably prepared according to conventional methods
employed for the preparation of Mannich condensation products, using the above-named
reactants in the respective molar ratios of (i) high molecular weight alkyl-substituted
hydroxyaromatic compound, (ii) amine, and (iii) aldehyde of 1.0 : 0.1-10 : 1-10. For
example it is common to charge about 1 to 3 moles of polyamine and about 1.2 to 4
moles of aldehyde per mole of (i).
[0015] Preferred Mannich reaction product additives employed in this invention are derived
from high molecular weight Mannich condensation products, formed by reacting an alkylphenol,
an ethylene polyamine, and a formaldehyde affording reactants in the respective molar
ratio of 1.0 : 0.5-2.0 : 1.0-3.0, wherein the alkyl group of the alkylphenol has a
number average molecular weight (Mn) of from 600 to 3,000, and more preferably from
750 to 1,200.
[0016] Representative of the high molecular weight alkyl-substituted hydroxyaromatic compounds
are polypropylphenol (formed by alkylating phenol with polypropylene), polybutylphenol
(formed by alkylating phenol with polybutenes or polyisobutylene), and other similar
long-chain alkylphenols. Polypropylphenol is the most preferred reactant. Polyalkylphenols
may be obtained by the alkylation, in the presence of an alkylating catalyst such
as BF
3, of phenol with high molecular weight polypropylene, polybutylene and other polyalkylene
compounds to give alkyl substituents on the benzene ring of phenol having a number
average molecular weight (Mn) of from 600 to 14,000.
[0017] The alkyl substituents on the hydroxyaromatic compounds may be derived from high
molecular weight polypropylenes, polybutenes, and other polymers of mono-olefins,
principally 1-mono-olefins. Also useful are copolymers of mono-olefins with monomers
copolymerizable therewith wherein the copolymer molecule contains at least 90% by
weight, of mono-olefin units. Specific examples are copolymers of butenes (butene-1,
butene-2, and isobutylene) with monomers copolymerizable therewith wherein the copolymer
molecule contains at least 90% by weight of propylene and butene units, respectively.
The monomers copolymerizable with propylene or butenes include monomers containing
a small proportion of unreactive polar groups such as chloro, bromo, keto, ether,
aldehyde, which do appreciably lower the oil-solubility of the polymer. The comonomers
polymerized with propylene or such butenes may be aliphatic and can also contain non-aliphatic
groups, e.g., styrene, methylstyrene, p-dimethylstyrene, divinyl benzene, for example.
From the foregoing limitation placed on the monomer copolymerized with propylene or
the butenes, it is clear that the resulting polymers and copolymers are substantially
aliphatic hydrocarbon polymers. Thus, the resulting alkylated phenols contain substantially
alkyl hydrocarbon substituents having a number average molecular weight (Mn) of from
600 to 3000.
[0018] In addition to the foregoing high molecular weight hydroxyaromatic compounds, other
phenolic compounds which may be used include, high molecular weight alkyl-substituted
derivatives of resorcinol, hydroquinone, cresol, catechol, xylenol, hydroxydi-phenyl,
benzylphenol, phenethylphenol, naphthol, tolylnaphthol, among others. Preferred for
the preparation of such preferred Mannich condensation products are the polyalkylphenol
reactants, e.g., polypropylphenol and polybutylphenol whose alkyl group has a number
average molecular weight of 600-3000, the more preferred alkyl groups having a number
average molecular weight of 740-1200, while the most preferred type of alkyl groups
is a polypropyl group having a number average molecular weight of 900-950.
[0019] The preferred configuration of the alkyl-substituted hydroxyaromatic compound is
that of a para-substituted mono-alkylphenol. However, any alkylphenol readily reactive
in the Mannich condensation reaction may be employed. Thus, Mannich products made
from alkylphenols having only one ring alkyl substituent, or two ring alkyl substituents
are suitable for use in this invention.
[0020] Representative amine reactants are alkylene polyamines, principally polyethylene
polyamines. Other representative organic compounds containing at least one HN< group
suitable for use in the preparation of the Mannich reaction products are well known
and include the mono and di-amino alkanes and their substituted analogs, e.g., ethylamine,
dimethylamine, dimethylaminopropyl amine, and diethanol amine; aromatic diamines,
e.g., phenylene diamine, diamino naphthalenes; heterocyclic amines, e.g., morpholine,
pyrrole, pyrrolidine, imidazole, imidazolidine, and piperidine; melamine and their
substituted analogs.
[0021] The alkylene polyamine reactants which are useful with this invention include polyamines
which are linear, branched or cyclic; or a mixture of linear, branched and/or cyclic
polyamines wherein each alkylene group contains from 1 to 10 carbon atoms. A preferred
polyamine is a polyamine containing from 2 to 10 nitrogen atoms per molecule or a
mixture of polyamines containing an average of from 2 to 10 nitrogen atoms per molecule
such as ethylenediamine, diethylene triamine, triethylene tetramine, tetraethylene
pentamine, pentaethylene hexamine, hexaethylene heptamine, heptaethylene octamine,
octaethylene nonamine, nonaethylene decamine, and mixtures of such amines. Corresponding
propylene polyamines such as propylene diamine, and dipropylene triamine, tripropylene
tetramine, tetrapropylene pentamine, pentapropylene hexamine are also suitable reactants.
A particularly preferred polyamine is a polyamine or mixture of polyamines having
from 3 to 7 nitrogen atoms with diethylene triamine or a combination or mixture of
ethylene polyamines whose physical and chemical properties approximate that of diethylene
triamine being the most preferred. In selecting an appropriate polyamine, consideration
should be given to the compatibility of the resulting detergent/dispersant with the
gasoline fuel mixture with which it is mixed.
[0022] Ordinarily the most highly preferred polyamine, diethylene triamine, will comprise
a commercially available mixture having the general overall physical and/or chemical
composition approximating that of pure diethylene triamine but which can contain minor
amounts of branched-chain and cyclic species as well as some other linear polyethylene
polyamines such as triethylene tetramine and tetraethylene pentamine. For best results,
such mixtures should contain at least 50% and preferably at least 70% by weight of
the linear polyethylene polyamines of which at least 50 mole % is diethylene triamine.
In one embodiment the amine is selected from diethylene triamine and triethylene tetramine
or mixtures thereof.
[0023] Representative aldehydes for use in the preparation of high molecular weight Mannich
products include the aliphatic aldehydes such as formaldehyde, acetaldehyde, propionaldehyde,
butyraldehyde, valeraldehyde, caproaldehyde, heptaldehyde, stearaldehyde. Aromatic
aldehydes which may be used include benzaldehyde and salicylaldehyde. Illustrative
heterocyclic aldehydes for use herein are furfural and thiophene aldehyde, for example.
Also useful are formaldehyde-producing reagents such as paraformaldehyde, or aqueous
formaldehyde solutions such as formalin. Most preferred is formaldehyde or formalin.
[0024] Important considerations insofar as the present invention is concerned, are to insure
that the alkylphenol having an alkyl substituent with the desired number average molecular
weight be reacted with the preferred polyethylene polyamine and aldehyde compounds
and that the reactants be employed in proportions such that the resultant Mannich
reaction product contains the requisite proportions of the chemically combined reactants,
all as specified herein. When utilizing this combination of features, the resultant
compositions of this invention not only possess exceptional effectiveness in controlling
or reducing the amount of induction system deposits formed during engine operation
but which permit adequate demulsification performance.
[0025] A key feature of this invention is that the Mannich reaction products are used in
combination with one or more poly(oxyalkylene) compounds having the requisite viscosity
parameters referred to hereinabove.
[0026] The poly(oxyalkylene) compounds suitable for use in the practice of this invention
comprise one or more gasoline-soluble poly(oxyalkylene) alcohols, glycols or polyols
or mono or diethers thereof, with the proviso that such compounds have in their undiluted
state a viscosity of at least 70 centistokes (cSt) at 40°C and at least 13 cSt at
100°C. Such compounds can be represented by the following formula
R
1-(-R
2O-)
n-R
3 (I)
wherein R
1 is a hydrogen atom, or hydroxy, alkyl, cycloalkyl, aryl, alkaryl, aralkyl, alkoxy,
cycloalkoxy, or amino group having in the range of 1-200 carbon atoms, R
2 is an alkylene group having 2-10 carbon atoms (preferably 2-5 carbon atoms), R
3 is a hydrogen atom or alkyl, cycloalkyl, aryl, alkaryl, aralkyl, or hydrocarbylamino
group having 1-200 carbon atoms, and n is an integer in the range from 1 to 500 (and
preferably in the range of from 3 to 120) representing the number of repeating alkyleneoxy
groups, all with the proviso that the product in its undiluted state is a gasoline-soluble
liquid having a viscosity of at least 70 centistokes (cSt) at 40°C and at least 13
cSt at 100°C.
[0027] Generally speaking, the poly(oxyalkylene) compounds used in the practice of this
invention will have viscosities of no more than 400 cSt at 40°C and no more than 50
cSt at 100°C. Preferably, the viscosities of the poly(oxyalkylene) compounds used
will not exceed 300 cSt at 40°C and 40 cSt at 100°C. The most preferred poly(oxyalkylene)
compounds will have viscosities of no more than 200 cSt at 40°C, and no more than
30 cSt at 100°C.
[0028] Preferred poly(oxyalkylene) compounds are poly(oxyalkylene) glycol compounds and
monoether derivatives thereof that satisfy the above viscosity requirements and that
are comprised of repeating units formed by reacting an alcohol or polyalcohol with
an alkylene oxide, such as propylene oxide and/or butylene oxide with or without use
of ethylene oxide, and especially products in which at least 80 mole % of the oxyalkylene
groups in the molecule are derived from 1,2-propylene oxide. Details concerning preparation
of such poly(oxyalkylene) compounds are referred to, for example, in Kirk-Othmer,
Encyclopedia of Chemical Technology, Third Edition, Volume 18, pages 633-645 (Copyright 1982 by John Wiley & Sons), and
in references cited therein. U.S. Patent Nos. 2,425,755; 2,425,845; 2,448,664; and
2,457,139 also describe such procedures.
[0029] Preferred poly(oxyalkylene) compounds can be represented by the formula
R
4O-(R
5O)
p-R
6 (II)
wherein R
4 is a hydrogen atom, or a hydrocarbyl group having up to 18 carbon atoms, and more
preferably an alkyl group having up to 10-12 carbon atoms; R
5 is an alkylene group of 2-5 carbon atoms which thus can be an ethylene group (i.e.,
dimethylene) group, but which preferably is a propylene (i.e., methyldimethylene)
group, or butylene (i.e., ethyldimethylene) group; R
6 is a hydrogen atom, or a hydrocarbyl group having up to 18 carbon atoms, and more
preferably an alkyl group having up to 10-12 carbon atoms; and p is a integer that
yields a product having the viscosity parameters given above. Commercially available
products are often composed of mixtures in which the individual species of the mixture
have different numerical values for p, and thus in the case of such mixtures the value
of p for the overall product represents an average value. The alkylene groups R
5 can all be the same or they can be different and if different, can be arranged either
randomly or in prearranged blocks or sequences. Particularly preferred are the poly(oxyalkylene)
alcohols and glycols in which from 70 to 100% and especially 80 to 100% of the alkylene
groups are propylene groups (methyldimethylene groups) derived from use 1,2-propylene
oxide in the alkoxylation reaction usually employed in the production of such products.
In these particularly preferred poly(oxyalkylene) alcohols, glycols and diethers,
if less than 100% of the alkylene groups are propylene groups, the remainder are either
ethylene or butylene groups, or both, proportioned to yield a liquid gasoline-soluble
product having the requisite viscosity properties specified above. Monools derived
by propoxylation of alkanols (R
4 in Formula (II) is alkyl, R
5 is methyldimethylene groups, R
6 is a hydrogen atom, and p is as defined above) are most preferred. Such compounds
can also be thought of as monoethers of poly(oxyalkylene) glycols.
[0030] Other poly(oxyalkylene) glycols and ethers which may be employed can be represented
by the formula
R
7O-(-R
8O-)
q-R
9-(-OR
10-)
r-OR
11 (III)
wherein R
7 and R
11 can be the same or different and each is independently a hydrogen atom or a hydrocarbyl
group, preferably an alkyl group of up to 18 carbon atoms, and more preferably of
up to 10-12 carbon atoms; R
8 and R
10 can be the same or different and are alkylene groups of 2-5 carbon atoms each, which
thus can be ethylene groups (i.e., dimethylene groups), but which preferably comprise
or consist of propylene (i.e., methyldimethylene) groups, and/or butylene (i.e., ethyldimethylene)
groups; R
9 is an divalent hydrocarbylene group derived from the initiator, and thus can be a
group such as a phenylene group or an alkylene group which is preferably an ethylene
(i.e., dimethylene) group, a propylene (i.e., methyldimethylene) group, or a butylene
(i.e., ethyldimethylene) group, and q and r are independently integers that yield
a product having the viscosity parameters given above. Commercially available products
are often composed of mixtures in which the individual species of the mixture have
different numerical values for q and different numerical values for r, and thus in
the case of such mixtures the values of q and r for the overall product represent
average values. As noted, the alkylene groups can all be the same or they can be different
and if different, can be arranged either randomly or in blocks or sequences.
[0031] The poly(oxyalkylene) compounds used pursuant to this invention will contain a sufficient
number of branched oxyalkylene units (e.g., methyldimethyleneoxy units and/or ethyldimethyleneoxy
units) to render the poly(oxyalkylene) compound gasoline soluble.
[0032] The most preferred poly(oxyalkylene) glycol derivative compound useful in the compositions
and methods of this invention is known commercially as EMKAROX AF22 available from
ICI Chemicals & Polymers Ltd. This compound has a pour point of about -42°C, a density
of about 0.980 g/ml at 20°C, an open cup flash point of about 230°C, a viscosity of
about 90 cSt (typically in the range of 87 to 98 cSt) at 40°C and about 17 cSt (typically
in the range of 15 to 19 cSt) at 100°C, an average molecular weight of about 1700,
a viscosity index of about 200, and a volatility as determined by the Volatility Determination
Method described hereinafter of less than about 50%. The number average molecular
weight of the poly(oxyalkylene) compounds of this invention is preferably in the range
of from about 200 to about 5000, more preferably from 500 to 3000, and most preferably
from 1500 to 2500.
[0033] The hydrocarbon component c) of the fuel compositions of this invention is a poly-α-olefin.
The poly-α-olefins (PAO) useful in compositions and methods of this invention can
be fully hydrogenated (hydrotreated), partially hydrogenated, or unhydrogenated poly-α-olefins.
These materials are poly-α-olefins oligomers, primarily trimers, tetramers, and pentamers
of alpha-olefin monomers containing from 6 to 12, generally 8 to 12 and most preferably
about 10 carbon atoms. Preferred for use in the compositions of the present invention
are poly-α-olefins having a viscosity (measured at 100°C) of at least 8 centistokes,
and most preferably about 10 centistokes at 100°C. The volatility of the poly-α-olefin
is also of significance and may be determined by the Volatility Determination Method
described below.
[0034] To determine the volatility of a substance the following Volatility Determination
Method is used. The substance, e.g., a poly-α-olefin (110-135 grams) is placed in
a three-neck, 250 mL round-bottomed flask having a threaded port for a thermometer.
Such a flask is available from Ace Glass (Catalog No. 6954-72 with 20/40 fittings).
Through the center nozzle of the flask is inserted a stirrer rod having a Teflon blade,
19 mm wide x 60 mm long (Ace Glass catalog No. 8085-07). The substance (e.g., poly-α-olefin)
is heated in an oil bath to 300°C for 1 hour while stirring the substance in the flask
at a rate of 150 rpm. During the heating and stirring, the free space above the substance
in the flask is swept with 7.5 L/hr of inert gas (e.g., nitrogen, argon, etc.). The
volatility of the substance poly-α-olefin thus determined is expressed in terms of
the weight percent of material lost based on the total initial weight of material
tested. Utilizing the foregoing procedure, it is particularly preferred to select
poly-α-olefins for use in the additive formulations of this invention that have a
volatility of less than about 50%, more preferably less than about 25%.
[0035] In an embodiment of the invention, the alkyl group of the alkyl-substituted phenol
(i) has a number average molecular weight of from 800 to 1200, the amine is a polyamine,
the aldehyde is formaldehyde or a formaldehyde precursor, and the poly(oxyalkylene)
compound has a viscosity of from 87 to 98 cSt at 40°C and of from 15 to 19 cSt at
100°C, and an average molecular weight of 1700.
[0036] While not required for the purposes of this invention, it is preferred that the fuel
compositions of this invention include other conventional additives such as antioxidants,
demulsifiers, corrosion inhibitors, aromatic solvents, for example. Accordingly, components
for use in the formulations of this invention will now be described.
[0037] Antioxidant. Various compounds known for use as oxidation inhibitors can be utilized in the practice
of this invention. These include phenolic antioxidants, amine antioxidants, sulfurized
phenolic compounds, and organic phosphites, among others. For best results, the antioxidant
should be composed predominantly or entirely of either (1) a hindered phenol antioxidant
such as 2-tert-butylphenol, 2,6-di-tert-butylphenol, 2,4,6-tri-tert-butylphenol, 4-methyl-2,6-di-tert-butylphenol,
4,4'-methylenebis (2,6-di-tert-butylphenol), and mixed methylene bridged polyalkyl
phenols, or (2) an aromatic amine antioxidant such as the cycloalkyl-di-lower alkyl
amines, and phenylenediamines, or a combination of one or more such phenolic antioxidants
with one or more such amine antioxidants. Particularly preferred for use in the practice
of this invention are tertiary butyl phenols, such as 2,6-di-tert-butylphenol, 2,4,6-tri-tert-butylphenol,
o-tert-butylphenol, and mixtures thereof.
[0038] Demulsifier. A wide variety of demulsifiers are available for use in the practice of this invention,
including, for example, poly(oxyalkylene) glycols, oxyalkylated phenolic resins, for
example. Particularly preferred are mixtures of poly(oxyalkylene) glycols and oxyalkylated
alkylphenolic resins, such as are available commercially from Petrolite Corporation
under the TOLAD trademark. One such proprietary product, identified as TOLAD 9308,
is understood to be a mixture of these components dissolved in a solvent composed
of heavy aromatic naphtha and isopropanol. This product has been found efficacious
for use in the compositions of this invention. However, other known demulsifiers can
be used such as TOLAD 286.
[0039] Corrosion Inhibitor. Here again, a variety of materials are available for use as corrosion inhibitors
in the practice of this invention. Thus, use can be made of dimer and trimer acids,
such as are produced from tall oil fatty acids, oleic acid or linoleic acid, for example.
Another useful type of corrosion inhibitor for use in the practice of this invention
are the alkenyl succinic acid and alkenyl succinic anhydride corrosion inhibitors
such as, for example, tetrapropenylsuccinic acid, tetrapropenylsuccinic anhydride,
tetradecenylsuccinic acid, tetradecenylsuccinic anhydride, hexadecenylsuccinic acid,
hexadecenylsuccinic anhydride, for example. Also useful are the half esters of alkenyl
succinic acids having 8 to 24 carbon atoms in the alkenyl group with alcohols such
as the polyglycols. Also useful are the aminosuccinic acids or derivatives thereof
represented by the formula:
wherein each of R
2, R
3, R
5 and R
6 is, independently, a hydrogen atom or a hydrocarbyl group containing 1 to 30 carbon
atoms, and wherein each of R
1 and R
4 is, independently, a hydrogen atom, a hydrocarbyl group containing 1 to 30 carbon
atoms, or an acyl group containing from 1 to 30 carbon atoms.
[0040] The groups R
1, R
2, R
3, R
4, R
5, and R
6 when in the form of hydrocarbyl groups, can be, for example, alkyl, cycloalkyl or
aromatic containing groups. Preferably R
1, R
2, R
3, R
4 and R
5 are hydrogen or the same or different straight-chain or branched-chain hydrocarbon
radicals containing 1-20 carbon atoms. Most preferably, R
1, R
2, R
3, R
4, and R
5 are hydrogen atoms. R
6 when in the form of a hydrocarbyl group is preferably a straight-chain or branched-chain
saturated hydrocarbon radical.
[0041] Most preferred is a tetralkenyl succinic acid of the above formula wherein R
1, R
2, R
3, R
4 and R
5 are hydrogen and R
6 is a tetrapropenyl group.
[0042] Aromatic Hydrocarbon Solvent A wide variety of aromatic hydrocarbon solvents can be used with this invention such
as benzene, and alkyl substituted benzene or mixtures thereof. Particularly useful
are mixtures of o-, p-, and m- xylenes and mesitylene and higher boiling aromatics
such as Aromatic 150 which is available from Chemtech. However, other mixtures of
aromatic hydrocarbon solvents may also be used.
[0043] The relative proportions of the various ingredients used in the additive concentrates
and fuels of this invention can be varied within reasonable limits. However, for best
results, the additive concentrate should contain, on an active ingredient basis, from
20 to 35 parts by weight (preferably from 25 to 30 parts by weight) of Mannich reaction
product; up to 50 parts by weight (preferably from 20 to 40 parts by weight) of poly(oxyalkylene)
component; up to 40 parts by weight (preferably from 0 to 30 parts by weight) of hydrotreated
or unhydrotreated poly-α-olefin; 0 to 5 parts by weight (preferably, from 1 to 3 parts
by weight) of antioxidant; from 0 to 10 parts by weight (preferably, from 0.1 to 3
parts by weight) of demulsifier; from 25 to 80 parts by weight (preferably 30 to 75
parts by weight) of aromatic hydrocarbon solvent (including any diluent or solvent
present in the Mannich detergent as received); and from 0 to 5 parts by weight (preferably,
from 0.025 to 1.0 parts by weight) of corrosion inhibitor per each one hundred parts
by weight of fuel additive composition. The composition of the invention generally
comprises, per 100 parts by weight of the composition, 1 to 5 parts by weight of gasoline-soluble
antioxidant, 0.1 to 3 parts by weight of gasoline-soluble demulsifier, and 0.025 to
1.0 part by weight of gasoline-soluble corrosion inhibitor.
[0044] The above additive compositions of this invention are preferably employed in hydrocarbon
mixtures in the gasoline boiling range or hydrocarbon/oxygenate mixtures, or oxygenates,
but are also suitable for use in middle distillate fuels, notably, diesel fuels and
fuels for gas turbine engines. The nature of such fuels is so well known to those
skilled in the art as to require no further comment. By oxygenates is meant alkanols
and ethers such as methanol, ethanol, propanol, methyl-tert-butyl ether, ethyl-tert-butyl
ether, tert-amyl-methyl ether, for example, or combinations thereof. It will of course
be understood that the base fuels may contain other commonly used ingredients such
as cold starting aids, dyes, metal deactivators, lubricity additives, octane improvers,
cetane improvers, emission control additives, antioxidants, metallic combustion improvers,
for example. Cyclopentadienyl manganese tricarbonyl compounds such as methylcyclopentadienyl
manganese tricarbonyl are preferred because of their outstanding ability to reduce
tailpipe emissions such as NOX and smog forming precursors and to significantly improve
the octane quality of gasolines, both of the conventional variety and of the newer
"reformulated" types.
[0045] When formulating the fuel compositions of this invention, the additives are employed
in amounts sufficient to reduce or inhibit deposit formation on intake valves. Deposits
on fuel injectors may also be reduced or at least controlled. Generally speaking,
the finished additized fuel will contain, by weight and on an active ingredient basis,
no more than (and usually less than) about 5000 parts of the combination of components
a) and b) per million parts of gasoline, and preferably, up to (and more preferably
less than) about 3000 parts of the combination of components a) and b) per million
parts of gasoline. On an active ingredient basis, the total amount of components a)
and b), proportioned as above, in the finished fuels of this invention, is preferably
no more than about 2000 ppm (by weight), and most preferably in the range of 200 to
1000 ppm (by weight). An additive comprising a Mannich reaction product, a poly(oxyalkylene)
compound, and at least one liquid hydrocarbon such as one or more low boiling aromatic
hydrocarbons, a poly-α-olefin oligomer and/or a mineral oil of suitable viscosity
will be employed in unleaded gasoline in minor amounts such that the gasoline portion
of the fuel (including oxygenates such as ethers or alcohol blending agents) is the
major component, usually amounting to over 95% by weight. The other components which
are preferably used in conjunction with the fuel additive composition can be blended
into the fuel individually or in various subcombinations. However, it is definitely
preferable to blend all of the components concurrently using an additive concentrate
of this invention as this takes advantage of the mutual compatibility afforded by
the combination of ingredients when in the form of an additive concentrate, and reduces
the possibility of blending errors.
[0046] In order to illustrate the advantages of this invention, the following examples are
given. In these examples, the concentrations of additives are typically referred to
in terms of pounds per thousand barrels (ptb). One pound per thousand barrels of additive
in a gasoline of typical specific gravity is generally equivalent to 3.8 to 4.0 parts
per million (ppm) on a weight basis. In addition, the amount of the Mannich dispersant
is given on an "as received basis". Since the Mannich dispersant contained approximately
40% by weight of active Mannich Reaction Product (the balance being hydrocarbon diluent
and unreacted polyolefin), the actual quantity of active Mannich detergent is approximately
40% of the values reported in the examples.
Reference Example 1
[0047] The vital importance of the viscosity properties of component b) in providing the
exhaust valve deposit control performance achievable by the practice of this invention
was demonstrated by a series of series of engine tests. For each run, a 1991 Oldsmobile
Cutlass equipped with a General Motors 2.3L QUAD 4 engine was operated on an chassis
dynamometer for the equivalent of 8047 km (5,000 miles) and the amount of engine deposits
was determined. The engine was operated on a driving cycle representative of 10% city,
20% suburban and 70% highway driving. Average speed was equivalent to 72.4 km/hr (45
miles per hour) with the engine accumulating 1448 km/day (900 miles per day). Before
each test was begun, the intake manifold and cylinder head were cleaned and inspected,
the fuel injectors were checked for proper flow and spray pattern. Following each
cleaning and inspection, the engine was rebuilt with new intake valves and the crankcase
oil was changed. The base fuel was a clear (i.e., unadditized) regular unleaded gasoline.
The crankcase oil used in the test runs was an SAE 5W-30 SG API-quality oil.
[0048] In this series of engine tests various poly(oxyalkylene) compounds of differing viscosities
were mixed in the same proportions with separate portions of the same Mannich base
detergent, viz., a reaction product of (i) a 900 number average molecular weight polypropyl-substituted
phenol, (ii) formalin, and (iii) diethylene triamine (a Mannich base detergent commercially
available from Ethyl Petroleum Additives, Inc. as HiTEC® 4997 additive.) Each additive
mixture also contained Super High Flash Naphtha, a liquid hydrocarbon product having
a flash point of about 40°C (about 100°F) and consisting of essentially 100% of aromatic
hydrocarbons. These three additives were formulated into additive concentrates in
which the weight ratio of component a) (using the weight on an as received basis):
component b) : aromatic hydrocarbon diluent was 70:35:100. The additive concentrates
were then blended into separate quantities of the same base fuel and the resultant
fuel compositions were then evaluated in the above engine test. A control run was
also carried out in which the clear (i.e., unadditized) base fuel was used in the
test.
[0049] Six different poly(oxyalkylene) products from different commercial manufacturers
were used in these tests. Two met the viscosity requirements of this invention, the
other four did not.
[0050] The two poly(oxyalkylene) products meeting the viscosity parameters of this invention
were:
A - EMKAROX AF22 (ICI Chemicals & Polymers Ltd.), apparently a poly(oxypropylene)
monool with a molecular weight of about 1700 with a viscosity typically in the range
of 87 to 98 cSt at 40°C and typically in the range of 15 cSt at 100°C. The sample
used had a viscosity of 96 cSt at 40°C and 17 cSt at 100°C.
B - DFA36 (ICI Chemicals & Polymers Ltd.), a proprietary experimental poly(oxyalkylene)
product obtained under a non-analysis agreement, for which the manufacturer specified
a viscosity of 73 cSt at 40°C and 13.5 cSt at 100°C. Other properties given were Appearance,
Clear by Method C&P Appendix 2-1; Water Content, 0.055% by Method C&P/CO/pm/584; Color
(Hazen), 10 by Method C&P/CO/pm/579; Density, 0.9725 g/mL by Method C&P/CO/pm/561;
Pour Point, -34°C by Method NFT60105; and Flash Point, 228°C by Method C&P/CO/pm/578.
[0051] The four poly(oxyalkylene) products not meeting the viscosity parameters of this
invention were:
C - An experimental proprietary poly(oxyalkylene) monool having a viscosity of 63
cSt at 40°C and 8 cSt at 100°C. Properties specified by the manufacturer were Approximate
Molecular Weight, 1000; Mw/Mn, 1.79; OH Number (meq KOH/g), 86; and Viscosity, 120
cP at 25°C.
D - A commercially available polyoxypropylene glycol butyl ether having a viscosity
of 57 cSt at 40°C and 11 cSt at 100°C. Typical properties specified by the manufacturer
were Average Molecular Weight, 1150; Average Freezing Point, -40°C; Flash Point (PMCC),
>400°F (>204.4°C); Refractive Index, 1.446 at 25°C; Specific Gravity, 0.9888 at 25°C;
and Viscosity Index, 177.
E - A proprietary experimental poly(oxyalkylene) product obtained under a non-analysis
agreement, but identified by the manufacturer to be an alkylphenol propoxylate. It
has a viscosity of 67 to 70 cSt at 40°C and 10 cSt at 100°C.
F - A proprietary experimental poly(oxyalkylene) product obtained under a non-analysis
agreement having a viscosity of 44 to 45 cSt at 40°C and 8.4 to 8.6 cSt at 100°C.
Other properties given were Appearance, Clear by Method C&P Appendix 2-1; Water Content,
0.07% by Method C&P/CO/pm/584; Color (Hazen), 15 by Method C&P/CO/pm/579; Density,
0.9586 g/mL by Method C&P/C0/pm/561; Pour Point, -39°C by Method NFT60105; and Flash
Point, 220°C by Method C&P/CO/pm/578.
[0052] The intake valve deposit performance of this series of tests is summarized in Table
1. The fuels designated A through F contained the poly(oxyalkylene) compounds identified
above as A through F, respectively. Fuels A through F each contained component a)
at a concentration of 70 pounds per thousand barrels (equivalent to approximately
0.027 wt%), the respective poly(oxyalkylene) compound at a concentration of 35 pounds
per thousand barrels (equivalent to approximately 0.013 wt%), and the aromatic hydrocarbon
solvent (which in effect became part of the gasoline) at a concentration of 100 pounds
per thousand barrels (equivalent to approximately 0.04 wt%).
Table 1
Fuel |
40°C Viscosity, cSt |
100°C Viscosity, cSt |
Intake Valve Deposits, mg |
A |
96 |
17 |
36.3* |
B |
73 |
13.5 |
74.2 |
C |
63 |
8 |
221.5 |
D |
57 |
11 |
143.4 |
E |
67-70 |
10 |
142.6 |
F |
44-45 |
8.4-8.6 |
105.3 |
Control |
-- |
-- |
128.0 |
[0053] In addition, the total combustion chamber deposits formed when using fuels A and
B was almost 3% less than the total combustion chamber deposits formed in the runs
using fuels C, D, E and F.
Example 1
[0054] Another group of tests was conducted in a 1991, General Motors 2.3L QUAD 4 engine
operated as described in Reference Example 1. Once again the base fuel was an unadditized
regular unleaded gasoline, and the fuel detergent used was the reaction product of
(i) a 900 number average molecular weight polypropyl-substituted phenol, (ii) formalin,
and (iii) diethylene triamine. In this group of tests some of the test fuels contained,
in addition to the combination of the detergent and a poly(oxyalkylene) compound,
a poly-α-olefin oligomer (a 10 cSt unhydrotreated poly-α-olefin of 1-decene, hereinafter
referred to as PAO) or an antioxidant (HiTEC® 4733 additive (commercially available
from Ethyl Petroleum Additives, Inc.). HiTEC® 4733 additive is a mixture of tert-butyl
phenols containing about 10 wt.% 2-tert-butyl phenol, about 75 wt.% 2,6-di-tert-butyl
phenol, about 2 wt.% 2,4-di-tert-butyl phenol, and about 13 wt.% 2,4,6-tri-tert-butyl
phenol.
[0055] The poly(oxyalkylene) compounds used both satisfied the requirements of this invention,
one of them being the poly(oxyalkylene) product identified as A in Example 1. The
other product, G, is P1200 (Dow Chemical Company), a commercially available polyoxypropylene
glycol having a typical viscosity of about 90 cSt at 40°C and about 13.5 cSt at 100°C.
Typical properties as given by the manufacturer were Average Molecular Weight, 1200;
Average Pour Point, -40°C; Flash Point (PMCC), 345°F (174°C); Refractive Index, 1.448
at 25°C; Specific Gravity, 1.007 at 25°C; and Viscosity Index, 161.
[0056] Table 2 gives the compositions of additives in the fuel for each run (where ptb is
pounds per thousand barrels) as well as the average of the intake valve (IVD) and
combustion chamber deposits (CCD) for each cylinder. The combustion chamber deposits
are a combination of the piston top deposits and the cylinder head deposits. Runs
1 and 2 give base line results for the unadditized fuel, and fuel containing Mannich
detergent and PAO only. Runs 5 and 7 are of the invention and illustrate the reduction
in deposits that can be achieved by additive formulations in accordance with the present
invention.
Table 2
Run No. |
HiTEC® 4997, ptb |
HiTEC® 4733, ptb |
Prod. A, ptb |
Prod. G, ptb |
PAO, ptb |
Avg. dep., mg |
1 |
-- |
-- |
-- |
-- |
-- |
905 |
2 |
80 |
4 |
-- |
-- |
40 |
877 |
3 |
80 |
-- |
-- |
40 |
-- |
962 |
4 |
80 |
4 |
-- |
40 |
-- |
736 |
5 |
80 |
-- |
-- |
20 |
20 |
864 |
6 |
80 |
4 |
40 |
-- |
-- |
846 |
7 |
80 |
-- |
20 |
-- |
20 |
805 |
8 |
80 |
-- |
40 |
-- |
-- |
746 |
Example 2
[0057] In another series of runs, a stationary 1985, Ford 2.3L, 4 cylinder, single spark
plug engine was run for 200 hours under various loads utilizing Union Oil fuel and
containing the additives indicated in Table 3. The transient test cycle consisted
of 2 minutes at 1,400 rpm and under a load of 18 inches of Hg intake manifold vacuum,
5 minutes at 2,000 rpm and a of 0.4 bar (12 inches of Hg) intake manifold vacuum,
and 3 minutes at 2,500 rpm at 10 inches Hg intake manifold vacuum. The engine coolant
temperature was maintained at about 74°C and the combustion air was controlled at
a temperature of 32°C and a humidity of 80 grains of moisture per pound of dry air.
The test is primarily an intake valve deposit test, but measurements of combustion
chamber deposits and octane requirement increase can be made. In Table 3 octane requirement
increase is the difference in octane requirement of the engine as measured at 0 and
200 hours. The crankcase oil used in the test runs was an SAE 5W-30 SG API-quality
oil. New intake valves and valve stem seals were installed after each test run, and
new exhaust valves were installed every fourth test run. Prior to and subsequent to
each test run, the intake valves, ports, manifolds, and throttle blade were weighed
and/or rated. Runs 10, 11, and 12, are given for comparative purposes and represent
the baseline case of fuel without additive. Runs 10, 11, 12, and 13 were run with
a different lot of the same fuel as runs 14, 15, 16, and 17. Results of the tests
indicate a significant reduction in intake valve deposits (IVD) with surprisingly
little change in ORI or combustion chamber deposits. The poly(oxyalkylene) compound
used pursuant to the invention was the same as product A of Reference Example 1. The
fuel in Run 16 contained 4 ptb of sulfurized 2,6-di-tert-butylphenol as antioxidant
and the fuel in run 17 had 4 ptb of nonyl phenol sulfide as antioxidant. No antioxidant
was added to the other fuels of this series.
Table 3
Run No. |
HiTEC® 4997 (ptb) |
Product A (ptb) |
PAO (ptb) |
IVD (mg) |
CCD (mg) |
ORI |
10 |
-- |
-- |
-- |
721.0 |
1587 |
10 |
11 |
-- |
-- |
-- |
519.8 |
1668 |
8 |
12 |
-- |
-- |
-- |
577 |
1855 |
8-10 |
13 |
90 |
45 |
-- |
28.3 |
2210 |
11 |
14 |
90 |
45 |
-- |
43.1 |
1481 |
10 |
15 |
90 |
22.5 |
22.5 |
41.6 |
1655 |
11 |
16 |
90 |
45 |
-- |
37.8 |
1745 |
11 |
17 |
90 |
45 |
-- |
28.0 |
1740 |
9 |
Example 3
[0058] This series of runs is similar to the runs of Example 1. In this series of runs,
a 1985, 2.3L, 4 cylinder Ford engine containing a single spark plug was run for 112
hours, operating between a 3-minute "power" cycle (37 HP) at 2,800 rpm and a 1-minute
"idle" cycle (0-4 HP) at 2,000 rpm. The engine coolant temperature was maintained
at about 74°C and the combustion air was not temperature and humidity controlled.
The octane requirement increase is the difference in octane requirement as measured
at 0 and 112 hours. The crankcase oil used in the test runs was an SAE 10W-40 SG API-quality
oil. New intake valves and valve stem seals were installed after each test run, and
new exhaust valves were installed every fourth test run. Prior to and subsequent to
each test run, the intake valves, ports, manifolds, and throttle blade were weighed
and/or rated. Table 4 illustrates the advantages of fuel additives of this invention.
The poly(oxyalkylene) compound used pursuant to the invention was the same as product
A of Reference Example 1.
Table 4
Run No. |
HiTEC® 4997 (ptb) |
Product A (ptb) |
PAO (ptb) |
IVD (mg) |
CCD (mg) |
ORI |
18 |
90 |
45 |
-- |
19.8 |
1348 |
7 |
19 |
90 |
45 |
-- |
14.1 |
1469 |
8 |
20 |
90 |
22.5 |
22.5 |
22.5 |
1282 |
10 |
21 |
90 |
45 |
-- |
29.6 |
1273 |
8 |
22 |
90 |
45 |
-- |
24.9 |
1193 |
10 |
Example 4
[0059] This series of runs is similar to the runs of Example 3. In this series, a 1993,
dual spark plug, 4 cylinder 2.3 L Ford engine was run for 100 hours, operating between
a 3-minute "power" cycle at 2,800 rpm and a 1-minute "idle" cycle at 2,000 rpm. The
combustion air was controlled at a temperature of 32°C and a humidity of 80 grains
of moisture per pound of dry air. Runs 23-27 were run at an engine coolant temperature
of 91°C and Runs 28 and 29 were run at an engine coolant temperature of 74°C. The
octane requirement increase is the difference in octane requirement as measured at
0 and 100 hours. The crankcase oil used in the test runs was an SAE 5W-30 SG API-quality
oil. Prior to and subsequent to each test run, the intake valves, ports, manifolds,
and throttle blade were weighed and/or rated. New spark plugs, intake valves and valve
guide seals were installed every test run. New exhaust valves were installed every
fourth test run. Table 5 illustrates the advantages of fuel additives of this invention.
The fuels in Runs 26 and 27 contained 4 ptb of sulfurized 2,6-di-tert-butylphenol
as antioxidant. No antioxidant was added to the other fuels of this series.
Table 5
Run No. |
HiTEC® 4997 (ptb) |
Product A (ptb) |
PAO (ptb) |
IVD (mg) |
CCD (mg) |
ORI |
23 |
-- |
-- |
-- |
261.0 |
647 |
6 |
24 |
90 |
45 |
-- |
41.6 |
961 |
5 |
25 |
90 |
22.5 |
22.5 |
29.5 |
1283 |
5 |
26 |
90 |
45 |
-- |
31.2 |
1183 |
6 |
27 |
90 |
22.5 |
22.5 |
37.3 |
1258 |
6 |
28 |
-- |
-- |
-- |
338.0 |
719 |
8 |
29 |
90 |
45 |
-- |
29.5 |
1283 |
5 |
[0060] As used herein the term "fuel soluble" means that the additive under discussion has
sufficient solubility in the particular gasoline fuel composition in which it is being
used to dissolve at 20°C to the extent of at least the minimum concentration required
to achieve control of intake valve deposits in an internal combustion engine operated
on the resulting fuel. Preferably, and in almost all cases, the additive should (and
will) have a substantially greater gasoline solubility than this. However, the term
does not require that the additive be soluble in all proportions in the gasoline fuel
composition.