(57) A transfer sheet for ceramics has a support, a water-soluble layer formed thereon, and a resin film layer with a thickness of 1 µm or more formed on the water-soluble layer, the resin film layer bearing thereon a toner image which is capable of producing a chromatic color after sintered, and is prepared by an electrophotographic process using a toner which contains a coloring agent, a binder agent, and a fritted glaze. A toner image is fire fixed to a heat-resistant solid surface by forming the toner image on the above-mentioned resin film layer of the transfer sheet by the electrophotographic process using the toner, separating the resin film layer and the toner image together from the support to form a toner-image- bearing resin film member, superimposing the toner-image-bearing resin film member on the heat-resistant solid surface in such a manner that a non-toner-image-bearing side of the resin film member closely adheres to the heat-resistant solid surface, and sintering the toner-image-bearing resin film member at a sintering temperature of the resin film layer or more.