INHIBITION OF PULP AND PAPER YELLOWING USING HYDROXYLAMINES AND OTHER COADDITIVES

Description

[0001] The instant invention pertains to a method for preventing the loss of brightness and for enhancing resistance to yellowing in pulp or paper, particularly pulp or paper which still contains lignin, by the addition of N,N-dialkylhydroxylamines, an ester, amide or thio substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine, or their salts and other coadditives.

Background of the Invention

[0002] High-yield and ultra-high yield wood pulps undergo rapid light-induced discoloration, particularly when they are exposed to near ultraviolet light (wave lengths 300-400 nm) in indoor fluorescent light and daylight. This characteristic restricts their use to short-life, low-value paper products. High-yield and ultra-high yield wood pulps can be bleached to a high level of whiteness. If this whiteness could be stabilized against discoloration, these bleached high-yield pulps could displace significant amounts of more expensive fully-bleached, low-yield chemical pulps.

[0003] This discoloration is ascribed to the substantial lignin content of high-yield pulps totally about 20-30% by mass. Phenoxy radicals are the key intermediates in the reaction mechanism. Several light-induced reactions have been proposed to account for their formation such as cleavage of the aryl ether bond of phenacyl aryl ether groups, or breakdown of ketyl radicals formed from saturated aryl-glycerol β-aryl ether structures in lignin. The phenoxy radicals are oxidized by other oxygen-centered radicals (alkoxy and perhydroxy) to form yellow chromophores.

[0004] I. E. Arzkin et al., Khymiya drevesiny (Chemistry of Wood), 1982, No. 2, 114 and A. D. Sergeev et al., ibid, 1984, No. 5, 20 disclosed that the use of iminoxyl radicals such as TEMPO (1-oxyl-2,2,6,6-tetramethylpiperidine) is useful in the delignification of wood using the one-stage oxygen-soda (alkaline) process, but made no mention or suggestion of any activity provided by TEMPO on preventing light-induced discoloration of paper or pulp made from such treated wood.

[0005] V. I. Khodyrev et al., Vysokomol soyed, A29, No. 3, 616 (1987) [Polymer Sci. U.S.S.R., 29, No. 3, 688 (1987)] show that the photoinitiated oxidation by oxygen causes weathering of cellulosic textile materials such as flax or cotton, and that the light stability of the cellulose could be improved by photostabilizers such as the UV absorbers, benzophenols and 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine. The UV absorbers offer no protection, and are actually detrimental. The authors noted that the stable nitroxyl radical interacts with alkyl radicals in the cellulose to afford its salubrious stabilizing activity. There is no suggestion by the authors that this stabilizing activity could be applied successfully in wood pulp and/or paper made therefrom.

[0006] M-K. Syler et al., J. Assn. Paper Pulp Tech, 29, 135 (1990) show that selected metal salts such as magnesium sulfate and lower alkanoic acids inhibit color reversion in bleached pulp.

[0007] P. Fornier de Violet et al., Cellulose Chem. Tech., 24, 225 (1990) show that the use of UV absorbers and hydrogen donor agents such as thiols, ascorbic acid, etc. help prevent the photoinduced discoloration of hydrogen peroxide bleached wood pulp, but that chain breakers such as hindered phenols and hindered amines (having >N-H or >N-CH₂- moieties) had no or even a detrimental effect on preventing photoinduced discoloration.

[0008] R. Agnemo et al., 6th International Symposium on Wood and Pulping Chemistry, Appita, 1991, confirmed that free hydroxyl radicals plus lignin lead to undesirable photoyellowing in pulp and paper.

[0009] S. Omori et al., J. Assn. Paper Pulp Tech, 48, 1388 (1993) describes the effect of antioxidants and UV absorbers on light reversion and concludes that the combination of an antioxidant and UV absorber prevents color reversion and has a synergistic effect in that activity.

[0010] M. Paulsson et al., 8th International Symposium Wood and Pulping Chemistry, Helsinki, 1995, show that efficient photostabilization of unbleached paper or hydrogen peroxide bleached TMP pulp can be achieved by acetylation.

[0011] There have been a number of different approaches proposed to inhibiting the yellowing of mechanical pulps. These include: radical scavengers and antioxidants; UV screens; elimination of chromophores after their formation; chemical modification of lignin by alkylation or acetylation; polymeric inhibitors; and two types of coadditives used in combination. Z-H. Wu et al., Holzforschung, 48, (1994), 400 discuss the use of radical scavengers like phenyl-N-tert-butylnitrone to reduce the formation of chromophores during mechanical pulping and give a more light-stable pulp.

[0012] C. Heitner, Chemistry of Brightness Reversion and It Control, Chapter 5, TAPPI, Atlanta, 1996, pp 183-211, summarizes the state of the art in the thermal and light-induced yellowing of lignin-containing pulps such as thermomechanical (TMP) and chemithermomechical (CTMP) pulps, showing the seriousness of these undesirable effects discusses generally the then current prior art methods used to attack this problem. These include bleaching, the use of phosphites, UV absorbers, polyalkylene glycols and free radical scavengers such as ascorbic acid, thiols, thioethers, dienes and aliphatic aldehydes and chelating agents such as ethylenediaminetetraacetic acid (EDTA). The author concluded that, although much progress had been made, much still remains to be done before a successful and practical solution to this loss of brightness and undesirable yellowing of lignin-containing pulp and/or paper is found.

[0013] WO 99/05108 describes a potential solution where the use of selected hindered amine nitroxides, hindered amine hydroxylamines or their salts in combination with selected UV absorbers and metal chelating agents is seen to prevent loss of brightness and to enhance resistance to yellowing in pulp or paper still containing lignin.

[0014] Canadian Patent Application No. 2,164,394 and WO 97/36041 teach a multicomponent system for modifying, degrading or bleaching lignin-containing materials. This system includes an oxidation catalyst as an essential component. The catalysts are selected enzymes such as oxidoreductases of classes 1.1.1 to 1.97. The system also includes a number of mediators which inter alia include lower N,N-dialkylhydroxylamines and N,N-dibenzylhydroxylamine.

[0015] The instant invention describes another approach to this important problem where the use of N,N-dialkylhydroxylamine, an ester, amide or thio substituted N,N-dialkylhydroxyl-amine or N,N-dibenzylhydroxylamine or their salts in combination with selected coadditives also prevents the loss of brightness and enhances resistance to yellowing in pulp or paper, especially pulp or paper still containing lignin. The ester, amide or thio substituted N,N-dialkylhydroxylamines are described in United States Patent Nos. 4,612,393; 4,720,517 and 5,019,285.

Detailed Description of the Invention

[0016] The addition of N,N-dialkylhydroxylamines, derivatives thereof or N,N-dibenzylhydroxylamine to pulp or paper either alone or in combinations with UV absorbers, metal chelating agents, fluorescent whitening agents and/or stabilizing polymers effectively achieves a distinctly improved light and thermal stability. Addition to chemimechanical or thermomechanical pulps or papers, which still contain major amouints of lignin, leads to a light and thermal stability which is similar to that found in papers made from (chemical) kraft pulps. Addition to a kraft pulp or paper, which may still contain traces of lignin, leads to a distinct improvement of the light and thermal stability.

[0017] The addition of N,N-dialkylhydroxylamines, derivatives thereof or N,N-dibenzylhydroxylamine to high-yield pulp or paper which still contain lignin either alone or in combinations with UV absorbers, metal chelating agents, fluorescent whitening agents and/or stabilizing polymers effectively achieves light and thermal stability which is similar to that found in papers made from kraft pulps.

[0018] Hydroxylamines are known to be efficient free radical traps and may limit the production of o-quinones; UV absorbers limit photochemistry in the underlying substrate to which they are applied, and ultimately reduce the production of free radicals. UV absorbers and hydroxylamines are each effective at stemming some of the free radical chemistry leading to paper yellowing when used singly. However, when they are used together, hydroxylamines and UV absorbers can act synergistically to effectively stop photochemical yellowing of lignin containing papers. The hydroxylamines show enhanced inhibiting activity when combined with a metal chelating agent such diethylenetriaminepentaacetic acid or citric acid, or polymeric inhibitors such as polyethylene glycol.

[0019] More particularly, the instant invention pertains to a composition having enhanced resistance to yellowing which comprises

(a) a pulp or paper, especially a pulp or paper which still contains lignin, and

(b) an effective stabilizing amount of an N,N-dialkylhydroxylamine, an ester, amide or thio substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine of formula I, II or III

        R₁R₂N-OH     (I)



        (T₁SCH₂)(T₂SCH₂)N-OH     (II)



        (E₁COCH₂CH₂)(E₂COCH₂CH₂)N-OH     (III)

where
   R₁ and R₂ are independently alkyl of 1 to 18 carbon atoms, alkyl of 1 to 18 carbon atoms substituted by a hydroxyl group; or benzyl;
   T₁ and T₂ are independently alkyl of 1 to 4 carbon atoms, phenyl, 3,5-di-tert-butyl-4-hydroxyphenyl, benzyl or -CH₂COOH;
   E₁ and E₂ are independently -OE₃, -NHE₃ or -NE₃E₄ where E₃ and E₄ are independently hydrogen, alkyl of 1 to 4 carbon atoms or said alkyl substituted by one hydroxyl group; or
of an acid salt of formula IA, IIA or IIIA

        (R₁R₂NH-OH)_h⁺ (X^-)_j     (IA)



        [(T₁SCH₂)(T₂SCH₂)NH-OH]_h⁺ (X^-)_j     (IIA)



        [(E₁COCH₂CH₂)(E₂COCH₂CH₂)NH-OH]_h⁺ (X^-)_j     (IIIA)

where
   X is an inorganic or organic anion, and
   the total charge of cations h is equal to the total charge of anions j, provided that the composition contains no added enzyme.

[0020] Preferably, X is phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartrate. acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, tiglate, ascorbate, polymethacrylate, a carboxylate of nitrilotriacetic acid, hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid or of diethylenetriaminepentaacetic acid, a diethylenediaminetetraacetic acid or of diethylenetriaminepentaacetic acid, an alkylsulfonate or an arylsulfonate.

[0021] Preferably the hydroxylamine is N,N-dimethylhydroxylamine, N,N-diethylhydroxylamine, N,N-bis(2-hydroxypropyl)hydroxylamine, N,N-bis(3-hydroxypropyl)hydroxylamine, N,N-dioctadecylhydroxylamine, the N,N-dialkylhydroxylamine product made by the direct oxidation of N,N-di(hydrogenated tallow)amine, N,N-dibenzylhydroxylamine, N,N-bis(2-carboxyethyl)hydroxylamine or N,N-bis(benzylthiomethyl)hydroxylamine.

[0022] Most preferably, the hydroxylamine is N,N-diethylhydroxylamine, N,N-bis(2-hydroxypropyl)hydroxylamine, N,N-bis(3-hydroxypropyl)hydroxylamine or N,N-dibenzylhydroxylamine; most especially N,N-diethylhydroxylamine or its citric acid salt.

[0023] It is shown that the salts of these hydroxylamines are also beneficial in producing the increase in brightness and the resistance to yellowing in pulp or paper, especially when still containing lignin.

[0024] The effective stabilizing amounts of the hydroxylamine is 0.001 to 5% by weight based on the pulp or paper. Preferably, the effective stabilizing amount is 0.005 to 4% by weight; preferably 0.01 to 4% by weight.

[0025] When a coadditive stabilizer is also present, the effective stabilizing amount of the coadditives is also 0.001 to 5% by weight based on the pulp or paper; preferably 0.005 to 3% by weight; most preferably 0.01 to 2% by weight.

[0026] The instant compounds may additionally include an effective stabilizing amount of at least one stabilizer selected from the group consisting of the UV absorbers, the polymeric inhibitors, the sulfur containing inhibitors, the phosphorus containing compounds, the nitrones, the benzofuran-2-ones, fluorescent whitening agents, hindered amine hydroxylamines and salts thereof, hindered amine nitroxides and salts thereof, hindered amines and salts thereof and metal chelating agents.

[0027] The compositions which also include a UV absorber are especially preferred. The UV absorber is selected from group consisting of the benzotriazoles, the s-triazines, the benzophenones, the α-cyanoacrylates, the oxanilides, the benzoxazinones, the benzoates and the α-alkyl cinnamates.

[0028] Preferably, the UV absorber is a benzotriazole, an s-triazine or a benzophenone, most especially a benzotriazole UV absorber or benzophenone UV absorber.

[0029] Typical and useful UV absorbers are, for example,
   5-chloro-2-(2-hydroxy-3,5-di-tert-butylphenyl)-2H-benzotriazole;
   2-(2-hydroxy-3,5-di-tert-butylphenyl)-2H-benzotriazole;
   2-(2-hydroxy-3,5-di-tert-amylphenyl)-2H-benzotriazole;
   2-(2-hydroxy-3,5-di-acumylphenyl)-2H-benzotriazole;
   2-(2-hydroxy-3-a-cumyl-5-tert-octylphenyl)-2H-benzotriazole;
   2-(2-hydroxy-5-tert-octylphenyl)-2H-benzotriazole;
   2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-2H-benzotriazole-5-sulfonic acid, sodium salt;
   3-tert-butyl-4-hydroxy-5-(2H-benzotriazol-2-yl)-hydrocinnamic acid;
   12-hydroxy-3,6,9-trioxadodecyl 3-tert-butyl-4-hydroxy-5-(2H-benzotriazol-2-yl)-hydrocinnamate;
   octyl 3-tert-butyl-4-hydroxy-5-(2H-benzotriazol-2-yl)-hydrocinnamate;
   4,6-bis(2,4-dimethylphenyl)-2-(4-(3-dodecyloxy*-2-hydroxypropoxy)-2-hydroxyphenyl)-s-triazine (*is mixture of C_12-14oxy isomers);
   4,6-bis(2,4-dimethylphenyl)-2-(4-octyloxy-2-hydroxyphenyl)-s-triazine;
   4,6-diphenyl-2-(4-(2-(1-ethylpentyl-carbonyloxy)ethoxy}-2-hydroxyphenyl)-s-triazine;
   2,4-dihydroxybenzophenone;
   2,2',4,4'-tetrahydroxy-5,5'-disulfobenzophenone, disodium salt;
   2-hydroxy-4-octyloxybenzophenone;
   2-hydroxy-4-dodecyloxybenzophenone;
   2,4-dihydroxybenzophenone-5-sulfonic acid and salts thereof;
   2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and salts thereof;
   2,2'-dihydroxy-4,4'dimethoxybenzophenone-5,5'-disodium sulfonate; and
   3-(2H-benzotriazol-2-yl)-4-hydroxy-5-sec-butylbenzenesulfonic acid, sodium salt (CIBAFAST W).

[0030] Other preferred compositions are those which additionally contain a polymeric inhibitor; preferably poly(ethylene glycol), poly(propylene glycol), poly(butylene glycol) or poly(vinyl pyrrolidone).

[0031] Still other preferred compositions are those wherein the additional stabilizer is a sulfur containing inhibitor; preferably polyethylene glycol dithiolacetate, polypropylene glycol dithiolacetate, polybutylene glycol dithioacetate, 1-thioglycerol, 2-mercaptoethyl ether, 2,2'thiodiethanol, 2,2'-dithiodiethanol, 2,2'oxydiethanethiol, ethylene glycol bisthioglycolate, 3-mercapto-1,2-propanediol, 2-(2-methoxyethoxy)-ethanethiol, glycol dimercaptoacetate, 3,3'-dithiopropionic acid, polyethylene glycol dithiol, polypropylene glycol dithiol, polybutylene glycol dithiol or ethylene glycol bis(mercaptoacetate).

[0032] Other preferred compositions are those wherein the additional stabilizer is a phosphorus containing compound; preferably tris(2,4-di-tert-butylphenyl) phosphite, 2,2',2"-nitrilo[triethyl-tris(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphite], bis(2,4-di-tert-butyl-6-methylphenyl) ethyl phosphite, sodium hydroxymethyl phosphinate, tetrakis(2,4-di-butylphenyl) 4,4'-biphenylenediphosphonite, tris(nonylphenyl) phosphite, bis(2,4-di-tert-butylphenyl) pentaerythrityl diphosphite, 2,2'-ethylidenebis(2,4-di-tert-butylphenyl) fluorophosphite or 2-butyl-2-ethylpropan-1,3-diyl 2,4,6-tri-tert-butylphenyl phosphite.

[0033] Still other preferred compositions are those wherein the additional stabilizer is a benzofuran-2-one; preferably 5,7-di-tert-butyl-3-(3,4-dimethylphenyl)-2H-benzofuran-2-one.

[0034] Still other preferred composition are those wherein the additional stabilizer is a metal chelating agent; preferably citric acid, keto acids, gluconates, heptagluconates, phosphates, phosphonates and aminocarboxylic acid chelates, such as ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), hydroxyethylethlenediaminetriacetic acid (HEDTA), nitrilotriacetic acid (NTA) and diethylenetriaminepentamethylenephosphonic acid (DTPMPA).

[0035] Some preferred compositions contain a mixture of additional stabilizers such as a mixture of a UV absorber and polymeric inhibitor; or a mixture of a UV absorber and a sulfur containing compound; or a mixture of a UV absorber and a phosphorus containing compound; or a mixture of a UV absorber and a metal chelating agent; or a mixture of a polymeric inhibitor and a sulfur containing compound; or a mixture of a polymeric inhibitor and a phosphorus containing compound; or a mixture of a sulfur containing compound and a phosphorus containing compound; or a mixture of a UV absorber, a polymeric inhibitor and a sulfur containing compound; or a mixture of a UV absorber, a polymeric inhibitor and a phosphorus containing compound; or a mixture of a UV absorber, a polymeric inhibitor, a sulfur containing compound and a phosphorus containing compound; or a mixture of a UV absorber, a polymeric inhibitor and a metal chelating agent.

[0036] Some preferred compositions are those wherein the additional stabilizer is a mixture of a hindered amine hydroxylamine or hindered amine hydroxylamine salt with at least one other stabilizer selected from the group consisting of the UV absorbers, the polymeric inhibitors, the sulfur containing inhibitors, the phosphorus containing compounds, fluorescent whitening agents (optical brighteners), metal chelating agents and hindered amine nitroxides and salts thereof.

[0037] Also preferred are compositions wherein the additional stabilizer is a mixture of a UV absorber, a polymeric inhibitor and a sulfur containing compound; or a UV absorber, a polymeric inhibitor and a phosphorus containing compound; or a UV absorber, a polymeric inhibitor and a metal chelating agent; or a UV absorber, a polymeric inhibitor, a sulfur containing compound and a phosphorus containing compound; or a UV absorber and a hindered amine nitroxide; or a UV absorber and a hindered amine hydroxylamine; or a UV absorber and a hindered amine hydroxylamine salt.

[0038] (Sterically) hindered amine nitroxides, hydroxylamines or hydroxylamine salts are mainly the compounds disclosed in WO 99/05108 (see formulae A to EE and A* to EE* therein, especially compounds (a) to (mm)).

[0039] Some preferred composition are those wherein the additional stabilizer is a mixture of a hindered amine hydroxylamine with at least one optical brightener such as 2,2'-[(1,1'-diphenyl)-4,4'-diyl-1,2-ethenediyl]bis-benzenesulfonic, disodium salt {or bis[4,4'-(2-stilbenesulfonic acid)], disodium salt} which is TINOPAL SK (Ciba Specialty Chemicals).

[0040] Preferably the compositions are those wherein the compound of formula I, II, III, IA, IIA or IIIA is of low molecular weight or contains hydrophilic moieties or is both of low molecular weight and contains hydrophilic moieties.

[0041] The instant invention also pertains to a process for preventing the loss of brightness and for enhancing resistance to yellowing of a pulp or paper, particularly a chemimechanical or thermomechanical pulp or paper which still contain lignin, or a chemical pulp or paper or kraft pulp or paper which still contains traces of lignin, which comprises
   treating said pulp or paper with an effective stabilizing amount of a compound of formula I, II or III, or formula IA, IIA or IIIA as described above.

[0042] The instant inhibitor additive system can be added to pulp or paper at a number of places during the manufacturing or processing operations. These include

a. on a pulp slurry in the latency chest;

b. on a pulp slurry in or after the bleaching stage in a storage, blending or transfer chest;

c. on pulp during or after bleaching, washing and dewatering followed by cylinder or flash drying;

d. before or after the cleaners;

e. before or after the fan pump to the paper machine headbox;

f. to the paper machine white water;

g. to the silo or save all;

h. in the press section using a size press, coater or spray bar;

i. in the drying section using a size press, coater or spray bar;

j. on the calender using a wafer box;

k. on paper in an off-machine coater or size press; and/or

l. in the curl control unit.

[0043] Clearly, the precise location where the stabilizer additives should be added will depend on the specific equipment involved, the exact process conditions being used and the like. In some cases, the additives may be added at one or more locations for most effectiveness.

[0044] If the stabilizer or other coadditives are not themselves "water-soluble", they may be dispersed or emulsified by standard methods prior to application. Alternatively, the stabilizer and/or coadditives may be formulated into a paper sizing or paper coating formulation.

[0045] The following examples are for illustrative purposes only and are not to be construed to limit the instant invention in any manner whatsoever.

Handsheet Treatment

[0046] All additives are applied by syringe-injecting the appropriate weight % of additive combination in either an aqueous solution when the additive is water soluble, or a solution in 1:1 ethanol/dioxane, onto bleached thermomechanical pulp (BTMP) or chemical (kraft) pulp brightness squares (4 cm x 4cm). The clamped sheets are allowed to air dry for one day.

[0047] The brightness of the handsheets is recorded before and after treatment by light exposure under controled intensity conditions.

[0048] Accelerated testing is carried out by subjecting the treated sheets to accelerated light induced yellowing in a fan-cooled light box containing eight fluorescent lamps with a spectral maximum output at 5700 Å with a total output approximately 43 times greater than normal office fluorescent lamps. The lamps are about ten inches away from the handsheets being illuminated.

[0049] Ambient testing is carried out by placing the treated handsheets on a desk under normal cool-white fluorescent office lights at a nominal distance of six feet.

[0050] In both cases, ISO brightness is tracked as a function of photolysis time and converted to post color number (PC number) in the usual manner.

[0051] Post color (PC) number is defined as follows:



where k and s are the absorption and scattering coefficients, respectively, and R_inf is the value of ISO brightness.

[0052] The relationship between R_inf and the chromophore concentration is non-linear, whereas, the PC number is roughly linearly related to the concentration of the chromophore in the sample.

[0053] Low PC numbers are desired as they indicate less yellowing.

[0054] When, using the ambient test conditions, untreated BTMP handsheets are compared to Kraft handsheets after 60 days, the BTMP handsheets have a PC number which is about 10 while the Kraft paper has a PC number which is about 0.39. The Kraft handsheets are clearly less yellow than untreated BTMP handsheets after exposure to ambient light.

[0055] The incident light flux for the accelerated yellowing experiments (Examples 1-10) is 43 times greater than normal office fluorescent lamps as measured by the A. W. Speery SLM-110 digital light power meter. The brightness of the handsheets is tracked and compared to that of untreated sheets exposed in the same manner. The treated sheets exhibit significant resistance to yellowing as is seen below.

Materials Used in the Examples

[0056] Compound A is N,N-diethylhydroxylamine.

[0057] Compound B is N,N-dibenzylhydroxylamine.

[0058] Compound C is N,N-dioctadecylhydroxylamine.

[0059] Compound D is the N,N-dialkylhydroxylamine product made by the direct oxidation of N,N-di(hydrogenated tallow)amine.

[0060] Compound E is tris(N,N-diethylhydroxylammonium) citrate.

[0061] PEO is poly(ethylene glycol) of molecular weight 300.

[0062] TINUVIN®328 (Ciba) is 2-(2-hydroxy-3,5-di-tert-amylphenyl)-2H-benzotriazole.

[0063] TINOPAL® SK (Ciba) is 2,2'-[(1,1'-diphenyl)-4,4'-diyl-1,2-ethenediyl]bis-benzenesulfonic, disodium salt {or bis[4,4'-(2-stilbenesulfonic acid)], disodium salt}.

[0064] CIBAFAST® W (Ciba) is 3-(2H-benzotriazol-2-yl)-4-hydroxy-5-sec-butylbenzenesulfonic acid, sodium salt.

[0065] Compound F is N,N-bis(2-carboxyethyl)hydroxylamine.

[0066] Compound G is N,N-bis(benzylthiomethyl)hydroxylamine.

Example 1

Accelerated Yellowing with High Intensity Lamps, Bleached Thermomechanical Pulp (BTMP)

[0067] A BTMP sheet is treated with 1.0% by weight of N,N-diethylhydroxylamine (Compound A) and exposed to accelerated aging as described above. The treated sheet in exhibits a substantial inhibition of yellowing compared to the untreated control sheet as seen by inspection of the PC numbers given in the table below. Lower PC numbers indicate less color.

Time hours	Compound A PC number	Control PC number
0	0	0
23.6	2.28	5.14
29.4	2.86	6.07
48.7	5.00	9.01
97.8	10.40	15.75
120.3	12.95	18.54
144.0	15.77	21.48
172.2	19.10	24.95

Example 2

Accelerated Yellowing with High Intensity Lamps

[0068] A BTMP sheet is treated with 0.3% by weight of Compound B and 2.0% by weight of poly(ethylene glycol), molecular weight 300 (PEO). Again, the treated sheet exhibits an excellent resistance to yellowing as compared to the untreated control sheet.

Example 3

Accelerated Yellowing with High Intensity Lamps

[0069] A BTMP sheet is treated with 0.3% by weight of Compound C and 1.0% by weight of 2-(2-hydroxy-3,5-di-tert-amylphenyl)-2H-benzotriazole (TINUVIN® 328, Ciba). The treated sheet shows surprisingly excellent resistance to yellowing especially in contrast to the untreated control sheet.

Example 4

Accelerated Yellowing with High Intensity Lamps

[0070] A BTMP sheet is treated with 0.6% by weight of Compound D, 2.0% by weight of poly(ethylene glycol), molecular weight 300 (PEO), and 1.0% by weight of 2-(2-hydroxy-3,5-di-tert-amylphenyl)-2H-benzotriazole (TINUVIN® 328, Ciba). The treated sheet shows extraordinary resistance to yellowing especially in contrast to the untreated control sheet.

Example 5: Accelerated Yellowing with High Intensity Lamps

[0071] A BTMP sheet is treated with 0.3% by weight of Compound A and 1.0% by weight of TINOPAL® SK. Again, the treated sheet exhibits an excellent resistance to yellowing as compared to the untreated control sheet.

Example 6

Accelerated Yellowing with High Intensity Lamps

[0072] A BTMP sheet is treated with 0.3% by weight of Compound B and 1.0% by weight of CIBAFAST® W. The treated sheet shows surprisingly excellent resistance to yellowing especially in contrast to the untreated control sheet.

Example 7

[0073] A BTMP sheet is treated with 0.33% and with 0.66% by weight of N,N-diethylhydroxylamine (Compound A) and 0.5% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet as seen by inspection of the PC numbers given in the table below. Lower PC numbers indicate less color.

Time in Days	0.5% W 0.66% A PC number	0.5% W 0.33% A PC number	Control PC number
0	0	0	0
0.85	1.18	1.43	2.80
1.84	2.55	2.75	4.71
2.79	3.90	4.24	6.94
3.83	5.46	5.99	8.91
4.75	7.05	7.63	11.03
5.77	8.63	9.23	13.08
6.81	9.92	10.56	14.42
7.75	10.93	11.62	15.57
8.74	11.91	12.53	16.38

Example 8

[0074] A BTMP sheet is treated with 0.33% and with 0.66% by weight of tris(N,N-diethylhydroxylammonium) citrate (Compound E) and 0.5% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet as seen by inspection of the PC numbers given in the table below. Lower PC numbers indicate less color.

Time in Days	0.5% W 0.66% E PC number	0.5% W 0.33% E PC number	Control PC number
0	0	0	0
0.85	0.94	1.26	2.80
1.84	2.10	2.54	4.71
2.79	3.43	3.94	6.94
3.83	5.31	5.66	8.91
4.75	6.97	7.03	11.03
5.77	8.43	8.71	13.08
6.81	9.98	10.08	14.42
7.75	10.78	10.96	15.57
8.74	11.91	12.18	16.38

Example 9

[0075] A BTMP sheet is treated with 1.0% by weight of N,N-bis(2-carboxyethyl)hydroxylamine (Compound F) and 1.0% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet.

Example 10

[0076] A BTMP sheet is treated with 1.0% by weight of N,N-bis(benzylthiomethyl)hydroxylamine (Compound G) and 1.0% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet.
The following examples 11-20 describe accelerated yellowing tests with high intensity lamps conducted on chemical (Kraft) pulp:

Example 11

[0077] A kraft sheet is treated with 1.0% by weight of N,N-diethylhydroxylamine (Compound A) and exposed to accelerated aging as described above. The treated sheet in exhibits a substantial inhibition of yellowing compared to the untreated control sheet.

Example 12

[0078] A kraft sheet is treated with 0.3% by weight of Compound B and 2.0% by weight of poly(ethylene glycol), molecular weight 300 (PEO). Again, the treated sheet exhibits an excellent resistance to yellowing as compared to the untreated control sheet.

Example 13

[0079] A kraft sheet is treated with 0.3% by weight of Compound C and 1.0% by weight of 2-(2-hydroxy-3,5-di-tert-amylphenyl)-2H-benzotriazole (TINUVIN® 328, Ciba). The treated sheet shows surprisingly excellent resistance to yellowing especially in contrast to the untreated control sheet.

Example 14

[0080] A kraft sheet is treated with 0.6% by weight of Compound D, 2.0% by weight of poly(ethylene glycol), molecular weight 300 (PEO), and 1.0% by weight of 2-(2-hydroxy-3,5-di-tert-amylphenyl)-2H-benzotriazole (TINUVIN® 328, Ciba). The treated sheet shows extraordinary resistance to yellowing especially in contrast to the untreated control sheet.

Example 15

[0081] A kraft sheet is treated with 0.3% by weight of Compound A and 1.0% by weight of TINOPAL® SK. Again, the treated sheet exhibits an excellent resistance to yellowing as compared to the untreated control sheet.

Example 16

[0082] A kraft sheet is treated with 0.3% by weight of Compound B and 1.0% by weight of CIBAFAST® W. The treated sheet shows surprisingly excellent resistance to yellowing especially in contrast to the untreated control sheet.

Example 17

[0083] A kraft sheet is treated with 0.33% and with 0.66% by weight of N,N-diethylhydroxylamine (Compound A) and 0.5% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet.

Example 18

[0084] A kraft sheet is treated with 0.33% and with 0.66% by weight of tris(N,N-diethylhydroxylammonium) citrate (Compound E) and 0.5% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet.

Example 19

[0085] A kraft sheet is treated with 1.0% by weight of N,N-bis(2-carboxyethyl)hydroxylamine (Compound F) and 1.0% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet.

Example 20

[0086] A kraft sheet is treated with 1.0% by weight of N,N-bis(benzylthiomethyl)hydroxylamine (Compound G) and 1.0% by weight of CIBAFAST® W and then exposed to accelerated aging as described above. The treated sheet exhibits a substantial inhibition of yellowing compared to the untreated control sheet.

Claims

1. A composition having reduced loss of brightness and enhanced resistance to yellowing which comprises

(a) a pulp or paper, and

(b) an effective stabilizing amount of an N,N-dialkylhydroxylamine, an ester, amide or thio substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine of formula I, II or III

        R₁R₂N-OH     (I)



        (T₁SCH₂)(T₂SCH₂)N-OH     (II)



        (E₁COCH₂CH₂)(E₂COCH₂CH₂)N-OH     (III)

where
   R₁ and R₂ are independently alkyl of 1 to 18 carbon atoms, alkyl of 1 to 18 carbon atoms substituted by a hydroxyl group; or benzyl;
   T₁ and T₂ are independently alkyl of 1 to 4 carbon atoms, phenyl, 3,5-di-tert-butyl-4-hydroxyphenyl, benzyl or -CH₂COOH;
   E₁ and E₂ are independently -OE₃, -NHE₃ or -NE₃E₄ where E₃ and E₄ are independently hydrogen, alkyl of 1 to 4 carbon atoms or said alkyl substituted by one hydroxyl group; or
of an acid salt of formula IA, IIA or IIIA

        (R₁R₂NH-OH)_h⁺ (X^-)_j     (IA)



        [(T₁SCH₂)(T₂SCH₂)NH-OH]_h⁺ (X^-)_j     (IIA)



        [(E₁COCH₂CH₂)(E₂COCH₂CH₂)NH-OH]_h⁺ (X^-)_j     (IIIA)

where
   R₁, R₂, T₁, T₂, E₁ and E₂ are as defined above,
   X is an inorganic or organic anion, and the total charge of cations h is equal to the total charge of anions j,
   provided that the composition contains no added enzyme.

2. A composition according to claim 1 wherein component (a) is a pulp or paper which still contains lignin.

3. A composition according to claim 1 wherein component (a) is a chemimechanical or thermomechanical or kraft pulp or paper.

4. A composition according to daim 1 where in the formula IA, IIA or IIIA, X is phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartrate. acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, tiglate, ascorbate, polymethacrylate, a carboxylate of nitrilotriacetic acid, hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid or of diethylenetriaminepentaacetic acid, a diethylenediaminetetraacetic acid or of diethylenetriaminepentaacetic acid, an alkylsulfonate or an arylsulfonate.

5. A composition according to claim 1 wherein component b is N,N-dimethylhydroxylamine, N,N-diethylhydroxylamine, N,N-bis(2-hydroxypropyl)hydroxylamine, N,N-bis(3-hydroxypropyl)hydroxylamine, N,N-dioctadecylhydroxylamine, the N,N-dialkylhydroxylamine product made by the direct oxidation of N,N-di(hydrogenated tallow)amine, N,N-dibenzylhydroxylamine, N,N-bis(2-carboxyethyl)hydroxylamine or N,N-bis(benzylthiomethyl)hydroxylamine, or a corresponding acid salt.

6. A composition according to claim 1 which additionally includes an effective stabilizing amount of at least one coadditive selected from the group consisting of the UV absorbers, the polymeric inhibitors, the sulfur containing inhibitors, the phosphorus containing compounds, the nitrones, the benzofuran-2-ones, fluorescent whitening agents, hindered amine hydroxylamines and salts thereof, hindered amine nitroxides and salts thereof, hindered amines and salts thereof, and metal chelating agents.

7. A composition according to claim 6 wherein the additional stabilizer is a UV absorber selected from group consisting of the benzotriazoles, the s-triazines, the benzophenones, the α-cyanoacrylates, the oxanilides, the benzoxazinones, the benzoates and the α-alkyl cinnamates;
a polymeric inhibitor selected from poly(ethylene glycol), poly(propylene glycol), poly(butylene glycol) or poly(vinyl pyrrolidone);
a sulfur containing inhibitor selected from the group consisting of polyethylene glycol dithiolacetate, polypropylene glycol dithiolacetate, polybutylene glycol dithioacetate, 1-thioglycerol, 2-mercaptoethyl ether, 2,2'thiodiethanol, 2,2'-dithiodiethanol, 2,2'oxydiethanethiol, ethylene glycol bisthioglycolate, 3-mercapto-1,2-propanediol, 2-(2-methoxyethoxy)-ethanethiol, glycol dimercaptoacetate, 3,3'-dithiopropionic acid, polyethylene glycol dithiol, polypropylene glycol dithiol, polybutylene glycol dithiol and ethylene glycol bis(mercaptoacetate); and/or
a phosphorus containing compound selected from the group consisting of tris(2,4-di-tert-butylphenyl) phosphite, 2,2',2"-nitrilo[triethyl-tris(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphite], tris(2,4-di-tert-butyl-6-ethylphenyl) phosphite, sodium hydroxymethyl phosphinate, tetrakis(2,4-di-butylphenyl) 4,4'-biphenylenediphosphonite, tris(nonylphenyl) phosphite, bis(2,4-di-tert-butylphenyl) pentaerythrityl diphosphite, 2,2'-ethylidenebis(2,4-di-tert-butylphenyl) fluorophosphite and 2-butyl-2-ethylpropan-1,3-diyl-2,4,6-tri-tert-butylphenyl phosphite.

8. A composition according to claim 6 wherein the addditional stabilizer is a mixture containing two of the following components:

a UV absorber and polymeric inhibitor; a UV absorber and a sulfur containing compound; a UV absorber and a phosphorus containing compound; a UV absorber and a metal chelating agent; a polymeric inhibitor and a sulfur containing compound; a polymeric inhibitor and a phosphorus containing compound; a sulfur containing compound and a phosphorus containing compound; a UV absorber and a hindered amine;

9. A composition according to claim 1 wherein the effective stabilizing amount of the hydroxylamine or hydroxylamine salt of component b is 0.001 to 5% by weight based on the pulp or paper.

10. A composition according to claim 7 wherein the effective stabilizing amount of a coadditive is 0.001 to 5% by weight based on the pulp or paper.

11. A process for preventing the loss of brightness and for enhancing resistance to yellowing of pulp or paper which comprises
   treating said pulp or paper with an effective stabilizing amount of a hydroxylamine compound of formula I, II or III or hydroxylamine salt of formula IA, IIA or IIIA according to claim 1.

12. Use of a hydroxylamine compound of formula I, II or III or hydroxylamine salt of formula IA, IIA or IIIA according to claim 1 for stabilizing pulp or paper against loss of brightness and yellowing.

Ansprüche

1. Zusammensetzung mit einem verminderten Verlust an Helligkeit beziehungsweise Glanz und erhöhter Beständigkeit gegenüber Vergilben, welche umfasst

(a) einen Zellstoff oder Papier, und

(b) eine zum Stabilisieren wirksame Menge eines N,N-Dialkylhydroxylamins, eines Ester-, Amid- oder Thio-substituierten N,N-Dialkylhydroxylamins oder N,N-Dibenzylhydroxylamins der Formel I, II oder III

        R₁R₂N-OH^-     (I)



        (T₁SCH₂)(T₂SCH₂)N-OH     (II)



        (E₁COCH₂CH₂)(E₂COCH₂CH₂)N-OH     (III)

worin
   R₁ und R₂ unabhängig voneinander Alkyl mit 1 bis 18 Kohlenstoffatomen, Alkyl mit 1 bis 18 Kohlenstoffatomen, substituiert durch eine Hydroxyl-Gruppe; oder Benzyl darstellen;
   T₁ und T₂ unabhängig voneinander Alkyl mit 1 bis 4 Kohlenstoffatomen, Phenyl, 3,5-Di-tert-butyl-4-hydroxyphenyl, Benzyl oder -CH₂COOH darstellen;
   E₁ und E₂ unabhängig voneinander -OE₃, -NHE₃ oder -NE₃E₄ darstellen, worin E₃ und E₄ unabhängig voneinander Wasserstoff, Alkyl mit 1 bis 4 Kohlenstoffatomen oder Alkyl, substituiert durch eine Hydroxyl-Gruppe, darstellen; oder
eines Säuresalzes der Formel IA, IIA oder IIIA

        (R₁R₂NH-OH)_h⁺ (X^-)_j     (IA)



        [(T₁SCH₂)(T₂SCH₂)NH-OH]_h⁺ (X^-)_j     (IIA)



        [(E₁COCH₂CH₂)(E₂COCH₂CH₂NH-OH]_h⁺ (X^-)_j     (IIIA)

worin
R₁, R₂, T₁, T₂, E₁ und E₂ wie oben definiert sind,
   X ein anorganisches oder organisches Anion ist, und die Gesamtladung der Kationen h gleich der Gesamtladung der Anionen j ist,
unter der Voraussetzung, dass die Zusammensetzung kein zugesetztes Enzym enthält.

2. Zusammensetzung nach Anspruch 1, worin die Komponente (a) einenZellstoff oder Papier darstellt, welches noch Lignin enthält.

3. Zusammensetzung nach Anspruch 1, worin die Komponente (a) ein chemimechanischer oder thermomechanischer oder Kraft-Zellstoff oder Papier darstellt.

4. Zusammensetzung nach Anspruch 1, worin in der Formel IA, IIA oder IIIA X Phosphat, Phosphonat, Carbonat, Bicarbonat, Nitrat, Chlorid, Bromid, Bisulfit, Sulfit, Bisulfat, Sulfat, Borat, Formiat, Acetat, Benzoat, Citrat, Oxalat, Tartrat, Acrylat, Polyacrylat, Fumarat, Maleat, Itakonat, Glykolat, Glukonat, Malat, Mandelat, Tiglat, Ascorbat, Polymethacrylat, ein Carboxylat von Nitrilotriessigsäure, Hydroxyethylethylendiamintriessigsäure, Ethylendiamintetraessigsäure oder von Diethylentriaminpentaessigsäure, einer Diethylendiamintetraessigsäure oder von Diethylentriaminpentaessigsäure, ein Alkylsulfonat oder ein Arylsulfonat darstellt.

5. Zusammensetzung nach Anspruch 1, worin die Komponente (b) N,N-Dimethylhydroxylamin. N,N-Diethylhydroxylamin, N,N-Bis(2-hydroxypropyl)hydroxylamin, N,N-Bis(3-hydroxypropyl)hydroxylamin, N,N-Dioctadecylhydroxylamin, das N,N-Dialkylhydroxylamin-Produkt, hergestellt durch direkte Oxidation von N,N-Di(hydrierter Talg)amin, N,N-Dibenzylhydroxylamin, N,N-Bis(2-carboxyethyl)hydroxylamin oder N,N-Bis(benzylthiomethyl)hydroxylamin oder ein entsprechendes Säuresalz darstellt.

6. Zusammensetzung nach Anspruch 1, welche zusätzlich eine zum Stabilisieren wirksamen Menge von mindestens einem Co-Additiv enthält, ausgewählt aus der Gruppe, bestehend aus UV-Absorbern, polymeren Inhibitoren, Schwefel enthaltenden Inhibitoren, Phosphor enthaltenden Verbindungen, Nitronen, Benzofuran-2-onen. fluoreszierenden Weißmachern, gehinderten Aminhydroxylaminen und Salzen davon, gehinderten Aminnitroxiden und Salzen davon, gehinderten Aminen und Salzen davon sowie Metall-komplexierenden Mitteln.

7. Zusammensetzung nach Anspruch 6, worin der zusätzliche Stabilisator einen UV-Absorber darstellt, ausgewählt aus der Gruppe, bestehend aus Benzotriazolen, den s-Triazinen, den Benzophenonen, den α-Cyanoacrylaten, den Oxaniliden, den Benzoxazinonen, den Benzoaten und den α-Alkylcinnamaten; einen polymeren Inhibitor darstellt, ausgewählt aus Poly(ethylenglykol), Poly(propylenglykol), Poly(butylenglykol) oder Poly(vinylpyrrolidon);
einen Schwefel enthaltenden Inhibitor darstellt, ausgewählt aus der Gruppe, bestehend aus Polyethylenglykoldithiolacetat, Polypropylenglykoldithiolacetat, Polybutylenglykoldithioacetat, 1-Thioglycerin, 2-Mercaptoethylether, 2,2'-Thiodiethanol, 2,2'-Dithiodiethanol, 2,2'-Oxydiethanthiol, Ethylenglykolbisthioglykolat, 3-Mercapto-1,2-propandiol, 2-(2-Methoxyethoxy)ethanthiol, Glykoldimercaptoacetat, 3,3'-Dithiopropionsäure, Polyethylenglykoldithiol, Polypropylenglykoldithiol, Polybutylenglykoldithiol und Ethylenglykol-bis(mercaptoacetat); und/oder
eine Phosphor enthaltende Verbindung darstellt, ausgewählt aus der Gruppe, bestehend aus Tris(2,4-di-tert-butylphenyl)phosphit, 2,2',2"-Nitrilo[triethyltris(3.3'.5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl)phosphit], Tris(2,4-di-tert-butyl-6-ethylphenyl)phosphit, Natriumhydroxymethylphosphinat, Tetrakis(2,4-dibutylphenyl)-4,4'-biphenylendiphosphonit, Tris(nonylphenyl)phosphit, Bis(2,4-ditert-butyl)phenylpentaerythrityldiphosphit, 2,2'-Ethylidenbis(2,4-di-tert-butylphenyDfluorphosphit und 2-Butyl-2-ethylpropan-1,3-diyl-2,4,6-tri-tert-butylphenylphosphit.

8. Zusammensetzung nach Anspruch 6, worin der zusätzliche Stabilisator eine Mischung darstellt, enthaltend zwei der folgenden Komponenten:

einen UV-Absorber und polymeren Inhibitor: einen UV-Absorber und eine Schwefel enthaltende Verbindung; einen UV-Absorber und eine Phosphor enthaltende Verbindung; einen UV-Absorber und ein Metall-komplexierendes Mittel; einen polymeren Inhibitor und eine Schwefel enthaltende Verbindung; einen polymeren Inhibitor und eine Phosphor enthaltende Verbindung: eine Schwefel enthaltende Verbindung und eine Phosphor enthaltende Verbindung; einen UV-Absorber und ein gehindertes Amin.

9. Zusammensetzung nach Anspruch 1, worin die zum Stabilisieren wirksamen Menge des Hydroxylamins oder des Hydroxylamin-Salzes der Komponente (b) 0,001 bis 5 Gew.-% auf der Basis des Zellstoffs oder des Papiers beträgt.

10. Zusammensetzung nach Anspruch 7, worin die zum Stabilisieren wirksame Menge eines Co-Additivs 0,001 bis 5 Gew.-% auf der Basis des Zellstoffs oder des Papiers beträgt.

11. Verfahren zum Verhindern beziehungsweise zur Vorbeugung des Verlustes von Helligkeit beziehungsweise Glanz und zum Erhöhen der Widerstandsfähigkeit gegenüber einem Vergilben von Zellstoff oder Papier, welches umfasst Behandeln des Zellstoffs oder des Papiers mit einer zum Stabilisieren wirksamen Menge einer Hydroxylamin-Verbindung mit der Formel I, II oder III oder eines Hydroxylamin-Salzes der Formel IA, IIA, IIIA gemäß Anspruch 1.

12. Verwendung einer Hydroxylamin-Verbindung der Formel I, II oder III oder eines Hydroxylamin-Salzes der Formel IA; IIA oder IIIA nach Anspruch 1 zum Stabilisieren von Zellstoff oder Papier gegenüber einem Verlust an Helligkeit beziehungsweise Glanz und Vergilben.

Revendications

1. Composition ayant une perte réduite de brillance et une résistance améliorée au jaunissement qui comprend :

(a) une pâte à papier ou un papier ; et

(b) une quantité stabilisante efficace d'une N,N-dialkylhydroxylamine, un ester, une N,N-dialkylhydroxylamine ou une N,N-dibenzylhydroxylamine substituée par un groupe amide ou thio de formule I, II ou III :

        R₁R₂N-OH     (I)



        (T₁SCH₂) (T₂SCH₂)N-OH     (II)



        (E₁COCH₂CH₂)(E₂COCH₂CH₂)N-OH     (III)

   où
   R₁ et R₂ représentent, indépendamment l'un de l'autre, un groupe alkyle de 1 à 18 atomes de carbone, un groupe alkyle ayant 1 à 18 atomes de carbone substitués par un groupe hydroxyle ; ou un groupe benzyle ;
   T₁ et T₂ représentent, indépendamment l'un de l'autre, un groupe alkyle ayant 1 à 4 atomes de carbone, un groupe phényle, 3,5-di-tert-butyl-4-hydroxyphényle, benzyle ou -CH₂COOH ;
   E₁ et E₂ représentent, indépendamment l'un de l'autre, - OE₃, -NHE₃ ou -NE₃E₄, où E₃ et E₄ représentent, indépendamment l'un de l'autre, un atome d'hydrogène, un groupe alkyle ayant 1 à 4 atomes de carbone ou ledit groupe alkyle substitué par un groupe hydroxyle ; ou d'un sel d'acide de formule IA, IIA ou IIIA :

        (R₁R₂NH-OH)_h⁺ (X^-)_j     (IA)



        [(T-₁SCH₂) (T₂SCH₂)NH-OH]_h⁺ (X^-)_j     (IIA)



        [(E₁COCH₂CH₂) (E₂COCH₂CH₂)NH-OH]_h⁺ (X^-)_j     (IIIA)

   où
   R₁, R₂, T₁, T₂, E₁ et E₂ sont tels que définis ci-dessus,
   X est un anion inorganique ou organique, et la charge totale des cations h est égale à la charge totale des anions j,
   à condition que la composition ne contienne aucune enzyme ajoutée.

2. Composition selon la revendication 1, dans laquelle le composant (a) est une pâte à papier ou un papier qui contient encore de la lignine.

3. Composition selon la revendication 1, dans laquelle le composant (a) est une pâte à papier ou un papier chimique, thermomécanique ou au sulfate.

4. Composition selon la revendication 1, où, dans la formule IA, IIA ou IIIA, X est le phosphate, le phosphonate, le carbonate, le bicarbonate, le nitrate, le chlorure, le bromure, le bisulfite, le sulfite, le bisulfate, le sulfate, le borate, le formiate, l'acétate, le benzoate, le citrate, l'oxalate, le tartrate, l'acrylate, le polyacrylate, le fumarate, le maléate, l'itaconate, le glycolate, le gluconate, le malate, le mandélate, le tiglate, l'ascorbate, le polyméthacrylate, un carboxylate d'acide nitrilotriacétique, d'acide hydroxy-éthyléthylène-diaminetriacétique, d'acide éthylènediamine-tétraacétique ou d'acide diéthylènetriaminepentaacétique, d'un acide diéthylènediaminetétraacétique ou d'acide diéthylènetriaminepentaacétique, un alkylsulfonate ou un arylsulfonate.

5. Composition selon la revendication 1, dans laquelle le composant b est la N,N-diméthylydroxylamine, la N,N-diéthylhydroxylamine, la N,N-bis(2-hydroxypropyl)-hydroxylamine, la N,N-bis(3-hydroxypropyl)hydroxylamine, la N,N-dioctadécylhydroxylamine, le produit de la N,N-dialkylhydroxylamine étant fait par oxydation directe de N,N-di(suif hydrogéné)amine, la N,N-dibenzylhydroxylamine, la N,N-bis(2-carboxyéthylhydroxylamine ou la N,N-bis-(benzylthiométhyl)hydroxylamine, ou un sel d'acide correspondant.

6. Composition selon la revendication 1, qui comprend de plus une quantité stabilisante efficace d'au moins un co-additif choisi dans le groupe constitué par les stabilisants anti-UV, les inhibiteurs polymères, les inhibiteurs contenant du soufre, les composés contenant du phosphore, les nitrones, les benzofuran-2-ones, les agents blanchissants fluorescents, les hydroxylamines d'amine encombrée et leurs sels, les nitroxydes d'amine encombrée et leurs sels, les aminés encombrées et leurs sels et les agents chélatants métalliques.

7. Composition selon la revendication 6, dans laquelle le stabilisant supplémentaire est
   un stabilisant anti-UV choisi dans le groupe constitué par les benzotriazoles, les s-triazines, les benzophénones, les α-cyanoacrylates, les oxanilides, les benzoxazinones, les benzoates et les α-alkylcinnamates ;
   un inhibiteur polymère choisi parmi le poly-(éthylèneglycol), le poly(propylèneglycol), le poly-(butylèneglycol) ou la poly(vinylpyrrolidone) ;
   un inhibiteur contenant du soufre choisi dans le groupe constitué par le dithiolacétate de poly-(éthylèneglycol), le dithiolacétate de poly(propylène-glycol), le dithiolacétate de poly(butylèneglycol), le 1-thioglycérol, l'éther 2-mercaptoéthylique, le 2,2'-thio-diéthanol, le 2,2'-dithiodiéthanol, le 2,2'-oxydiéthane-thiol, le bisthioglycolate d'éthylèneglycol, le 3-mercapto-1,2-propanediol, le 2-(2-méthoxyéthoxy)-éthane-thiol, le dimercaptoacétate de glycol, l'acide 3,3'-dithiopropionique, le poly(éthylèneglycol dithiol), le poly(propylèneglycol dithiol), le poly(butylèneglycol dithiol) et le bis(mercaptoacétate) d'éthylèneglycol ; et/ou
   un composé contenant du phosphore choisi dans le groupe constitué par le tris(2,4-di-tert-butylphényl)-phosphite, le 2,2',2"-nitrilo[triéthyl-tris(3,3',5,5'-tétra-tert-butyl-1,1'-biphényl-2,2'-diyl)phosphite], le tris(2,4-di-tert-butyl-6-éthylphényl)phosphite, l'hydroxy-méthylphosphinate de sodium, le tétrakis(2,4-di-butylphényl)-4,4'-biphénylènediphosphonite, le tris(nonylphényl)phosphite, le bis(2,4-di-tert-butylphényl)pentaérythrityldiphosphite, le 2,2'-éthylidènebis(2,4-di-tert-butylphényl)fluorophosphite et le 2-butyl-2-éthylpropan-1,3-diyl-2,4,6-tri-tert-butylphénylphosphite.

8. Composition selon la revendication 6, dans laquelle le stabilisant supplémentaire est un mélange contenant deux des composants suivants :

un stabilisant anti-UV et un inhibiteur polymère ; un stabilisant anti-UV et un composé contenant du soufre ; un stabilisant anti-UV et un composé contenant du phosphore ; un stabilisant anti-UV et un agent chélatant métallique ; un inhibiteur polymère et un composé contenant du soufre ; un inhibiteur polymère et un composé contenant du phosphore ; un composé contenant du soufre et un composé contenant du phosphore ; un stabilisant anti-UV et une amine encombrée.

9. Composition selon la revendication 1, dans laquelle la quantité stabilisante efficace de l'hydroxylamine ou du sel d'hydroxylamine du composant b va de 0,001 à 5% en poids par rapport à la pâte ou au papier.

10. Composition selon la revendication 7, dans laquelle la quantité stabilisante efficace d'un co-additif va de 0,001 à 5% en poids par rapport à la pâte ou au papier.

11. Procédé pour empêcher la perte de brillance et pour améliorer la résistance au jaunissement d'une pâte ou d'un papier qui consiste à :

traiter ladite pâte ou ledit papier avec une quantité stabilisante efficace d'un composé hydroxylamine de formule I, II ou III ou d'un sel d'hydroxylamine de formule IA, IIA ou IIIA selon la revendication 1.

12. Utilisation d'un composé hydroxylamine de formule I, II ou III ou d'un sel hydroxylamine de formule IA, IIA ou IIIA selon la revendication 1 pour stabiliser une pâte ou un papier contre une perte de brillance et le jaunissement.