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EP 1 518 609 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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26.10.2005 Bulletin 2005/43 |
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Date of filing: 07.05.2002 |
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International application number: |
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PCT/ES2002/000214 |
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International publication number: |
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WO 2003/095109 (20.11.2003 Gazette 2003/47) |
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METHOD OF DECORATING METAL PARTS THROUGH THE APPLICATION OF A POWDER PAINT
VERFAHREN ZUR DEKORIERUNG VON METALLTEILEN MITTELS VERWENDUNG EINES PULVERLACKS
PROCEDE DE DECORATION DE PIECES METALLIQUES PAR APPLICATION DE PEINTURE EN POUDRE
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Designated Contracting States: |
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AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
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Date of publication of application: |
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30.03.2005 Bulletin 2005/13 |
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Proprietor: Hig-Tecnic, S.L. |
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46901 El Vedat de Torrente (Valencia) (ES) |
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Inventor: |
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- ALVAREZ SANCHIS, Elia, Maria
E-46901 El Vedat de Torrente (Valencia) (ES)
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Representative: Carpintero Lopez, Francisco |
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Herrero & Asociados, S.L.,
Alcalá, 35 28014 Madrid 28014 Madrid (ES) |
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References cited: :
EP-A- 0 818 248 FR-A- 2 685 351
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WO-A-97/05965 JP-A- 6 287 487
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Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
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OBJECT OF THE INVENTION
[0001] The present invention comprises a process for the decoration of metallic parts in
general, and preferably of aluminium or iron profiles to which it is desired to apply
a decorative coat imitating a natural finish such as marble, wood, etc.
[0002] The object of the present invention is to provide a process for decoration in which
the decorative motif can be reproduced with great precision offering therefore a very
high quality finish, and at the same time permitting that the parts to be treated
can be manipulated during the decoration stage without this affecting the final quality
of the decorative effect.
[0003] The present invention is of application in the field of decorating metallic pieces,
and in particular in the decoration of aluminium or iron profiles by means of the
application of powder paints.
BACKGROUND OF THE INVENTION
[0004] The use of aluminium profiles for the production of windows, doors and other enclosures,
has to a great extent replaced the employment of wood due to their lower cost and
to their structural and manufacturing advantages.
[0005] There have been multiple attempts to achieve a decorative finish of aluminium as
similar as possible to wood, however none of these attempts has produced a satisfactory
result.
[0006] One of these first attempts is that described in the Japanese patent JP-4318195 which
presents an electrolytic procedure for the decoration of aluminium, by means of which
the final finish obtained is very resistant to weather conditions, however the quality
of the decorative effect is very far from being acceptable.
[0007] Other known systems are based on the employment of the technique known as "sublimation"
widely employed in the textile industry, which has allowed the quality of the decorative
appearance to be perfected considerably, but the resistance of their colours to light
and their high cost have resulted in a limitation of their application.
[0008] Other known techniques of decoration are those described in the European patents
EP-0.843.598 and EP-0.656.231, based on the application of paint on paint, wherein
the problems of cost and of resistance to light have been resolved, but they have
not achieved a decorative appearance with sufficient precision to reproduce satisfactorily
the appearance of wood.
[0009] Another example of this type of procedure is that disclosed in the European patent
EP-0.818.248 based on the application of screen printing with powder paint, but which
has not resolved the design accuracy either because the grain size of the second coat
of powder paint, is very similar or identical to that of the first base coat of powder
paint.
[0010] The procedure described in the European patent EP-0.818.248, comprises the following
stages:
application of a first powder paint electrostatically charged for the adherence thereof
to the metallic surface to be treated,
subjecting this profile to a first temperature of between 170° C and 200° C during
an appropriate time in order to start the process of polymerisation of said paint
with the object of fusing it and extending it homogeneously on the surface of said
profile,
cooling this profile to halt the polymerisation process,
applying by screen printing a second powder paint of the same type of resin but with
a hue or colour different to that of the first paint,
taking said profile to a final temperature for a certain time to obtain the complete
polymerisation of this first and second coat of paint.
[0011] Conventionally the commercial paints applied in these procedures for protecting and
decorating aluminium destined for the manufacture of doors and enclosures in general,
are paints of polyester powder with a distribution in the size of particles of the
powder that depends on each manufacturer, but which conventionally lies between 40
and 150 microns.
[0012] The experts in these techniques are aware that the size of the powder particles has
a direct influence on the electrostatic deposition of the paint. During the decoration
process it is necessary to manipulate the metallic part, for example in a change of
position of the part to apply paint to another of its faces, whereby during said manipulation
the particles of very small grain size suffer displacements which deform the decorative
motif and impair the quality of the final result.
DESCRIPTION OF THE INVENTION
[0013] The procedure for decoration disclosed in the present invention, resolves satisfactorily
the shortcomings of the procedures known at the present time, since it allows the
decoration of metallic pieces with an extremely high degree of accuracy in the reproduction
of decorative designs, and therefore it provides a finish of a quality much superior
to the procedures for decoration known in the state of the art.
[0014] The procedure object of the invention starts from a first conventional stage, wherein
a first polyester-based powder paint is deposited electrostatically on a metallic
part to be decorated, such as for example an aluminium or iron part. Likewise in a
conventional manner, this first powder paint is subjected to a heat treatment.
[0015] The innovation of the invention resides in the application by means of screen printing
of a second powder paint with a particle size less than 40 microns, in contrast to
habitual practice in these techniques, and all this with the object of achieving a
very high definition in the reproduction of the decorative motif through the use of
a very fine powder. In this way it is possible to reproduce details, like for example
the grain of wood, with a precision that would not be possible with the procedures
known at the present time.
[0016] Subsequently this second powder paint with a selected grain size, is subjected to
a heat treatment in localised areas to fix it on the first paint. The heat treatment
consists of the application of radiation, preferably an infrared radiation, with the
object of heating the second paint until the same reaches a gelled state which produces
its adherence on the first coat of base paint, and which in this way allows the manipulation
of the metallic piece to be decorated without the risk of the particles of the second
paint moving and deforming the decorative design.
[0017] Finally the metallic part with the first base paint and the second paint, is subjected
to a final and joint heat treatment whereby the first and the second coat of paint
are polymerised together, the final decoration of the product being obtained.
[0018] The process of the present invention achieves in this way levels of definition in
the reproduction of a decorative motif much superior to those obtained by means of
conventional decoration techniques.
DESCRIPTION OF THE DRAWINGS
[0019] To complete the description that is being made and with the object of assisting in
a better understanding of the characteristics of the invention, in accordance with
a preferred example of practical embodiment thereof, attached as an integral part
of said description, is a single figure wherein by way of illustration and not restrictively,
the following has been represented:
Figure 1 shows schematically the elliptic reflector employed preferably in the heat
treatment of the second paint participant in the procedure.
PREFERRED EMBODIMENT OF THE INVENTION
[0020] According to that explained above, the procedure for decoration object of the present
invention comprises the following stages:
1. - Application of a first base paint of powdered polyester which is deposited electrostatically
on the aluminium or iron piece which it is desired to decorate.
2. - Heat treatment of said first base paint by conventional means during a period
of time lasting between 4 and 6 minutes at a temperature of 130° C.
3. - Application by means of screen printing of a second powder paint on said first
base paint, forming a distribution of this second paint in accordance with the decorative
motif it is desired to obtain, like for example wood, marble or any other design.
With the object of obtaining a high degree of accuracy in the reproduction of the
decorative design, the application of this second paint is carried out by means of
a screen printing mesh of 40 microns mesh pitch, and the particles of this second
powder paint are selected with a size less than 40 microns, since particles of greater
size would not pass through the mesh and would block the pores thereof, losing definition
therefore in the reproduction of the decorative motif. In a preferred embodiment of
the invention the grain size of the particles of this second paint is of between 5
and 30 microns.
4. - Thereafter a heat treatment is carried out localised in the areas (A) where said
second paint has been deposited, with the object that the same acquires a gelled state
which allows its adherence on the first base paint. This heat treatment consists of
the application of an infrared radiation with a short wavelength having its maximum
energy located between 1000 and 1200 nm, being focussed and directed by an elliptic
reflector (2), with which, according to the arrangement shown in figure 1, the maximum
concentration of radiation is obtained at a distance (C) lying at between 10 and 30
mm from the surface of the metal (1). In a preferred embodiment this distance is of
between 15 and 17 mm.
The short wavelength is obtained by means of a quartz lamp working at 2400° C, and
the time of application of maximum radiation is of between 1 and 10 seconds, preferably
between 2 and 4 seconds. With these working parameters it is achieved that the time
necessary to complete this heat treatment by application of infrared radiation, is
very short, and therefore does not influence the total time in which the decoration
of a metallic piece is completed.
The object of applying the infrared radiation in a localised form in the areas where
the second paint has been applied, is in order not to affect the first base paint,
so that the state is not altered which this base paint has reached during its heat
treatment described in point 2.
This second paint can have a different hue or colour to that of the first base paint,
with the object of obtaining the desired decorative design.
At this point, the metallic piece to be treated can be manipulated, for example its
position can be changed in order to apply paint on another of its faces, without risk
that the particles of the second paint applied by screen printing move from the precise
point in which they have been deposited by means of the screen printing mesh.
The working parameters described for this stage of the procedure, were selected to
attain, in a certain time, a particular gelled state of the second paint, which without
delaying excessively the time necessary to complete the heat treatment, allow that
the gelled state reached is sufficient to impede the displacement of the particles
of the second paint.
5. - Finally after the application of the first and the second coat of paint with
their respective heat treatments, that is, the lacquering of the first base paint
and the adherence of the second paint, the whole undergoes a final heat treatment
for polymerising jointly the two coats of paint. This final treatment is carried out
at a temperature of between 160° C and 220° C (temperature of the metal) during a
period of 8 to 20 minutes.
1. Process for decorating metallic parts by means of the application of powder paint,
intended to achieve a high degree of definition in the reproduction of the decorative
design, in which the following stages intervene: application of a first powder paint
by means of electrostatic deposition on the metallic surface to be decorated, heat
treatment of said first paint, application in selected areas of the first paint by
means of a screen printing mesh of a second powder paint to obtain a decorative design,
and a final heat treatment of said first and second paint to achieve the joint polymerisation
of both paints, characterised in that the size of the particles which constitute the second powder paint is less than 40
microns, and in that said second paint after its application by means of the screen printing mesh and
prior to said final heat treatment, is subjected to a heat treatment by means of the
application of infrared radiation in localised areas, with the object of bringing
this second powder paint to a gelled state which results in its adherence on the first
paint, with the object of facilitating the manipulation of the metallic part without
a displacement of the particles of the second paint taking place.
2. Process according to claim 1, characterised in that the size of the particles of the second powder paint is of between 5 and 30 microns.
3. Process according to claim 1, characterised in that the heat treatment to which the first paint is subjected initially is carried out
at a temperature of 130° C during a period of time of between 4 and 6 minutes.
4. Process according to claims 1 and 2, characterised in that the screen printing mesh only allows the passage of powder particles of less than
40 microns.
5. Process according to claim 1, characterised in that the infrared radiation is of a short wavelength with its maximum energy at between
1000 and 1200 nm.
6. Process according to claims 1 and 5, characterised in that the infrared radiation is focussed by means of an elliptic reflector, located in
such a way that the maximum concentration of radiation is obtained at a distance of
between 10 and 30 mm from the surface of the metal piece.
7. Process according to claim 6, characterised in that the distance at which the maximum radiation is obtained is at between 15 and 17 mm.
8. Process according to claims 1, 5, 6 or 7, characterised in that the time of application of the infrared radiation is of between 1 and 10 seconds,
preferably between 2 and 4 seconds.
9. Process according to claim 1, characterised in that the final and joint heat treatment of the first and the second paint is carried out
at a temperature of between 160° and 220° C of metal temperature and during a time
of between 8 and 20 minutes.
1. Verfahren zum Dekorieren von metallischen Teilen mittels Auftragen eines Pulverlacks
mit dem Ziel, einen hohes Maß an Präzision bei der Reproduktion der dekorativen Formgebung
zu erreichen, in welchem die folgenden Schritte ablaufen: Auftragen eines ersten Pulverlacks
mittels einer elektrostatischen Beschichtung auf der zu dekorierenden metallischen
Oberfläche, Wärmebehandlung des ersten Lacks, Auftragen eines zweiten Pulverlacks
in ausgewählten Bereichen des ersten Lacks mittels eines Siedrucknetzes, um eine dekorative
Form zu erhalten, und eine abschließende Wärmebehandlung des ersten und zweiten Lacks,
um die Verbundpolymerisation beider Lacke zu erreichen, dadurch gekennzeichnet, dass die Größe der Teilchen, welche den zweiten Pulverlack bilden, kleiner als 40 Mikrometer
ist, und dass der zweite Lack nach seinem Auftragen mit Hilfe des Siedrucknetzes und
vor der abschließenden Wärmebehandlung einer Wärmebehandlung durch Einsatz einer Infrarotstrahlung
in lokalisierten Bereichen ausgesetzt wird, mit dem Ziel, diesen zweiten Pulverlack
in einen gelierten Zustand zu versetzen, welcher sein Anhaften an dem ersten Lack
zur Folge hat, mit dem Ziel, das Handhaben des metallischen Teils zu erleichtern,
ohne dass es zu einer Verschiebung der Teilchen des zweiten Lackes kommt.
2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Größe der Teilchen des zweiten Pukverlackes zwischen 5 und 30 Mikrometern liegt.
3. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Wärmebehandlung, welcher der erste Lack zu Beginn ausgesetzt wird, bei einer
Temperatur von 130 °C während eines Zeitraums zwischen 4 und 6 Minuten ausgeführt
wird.
4. Verfahren nach den Ansprüchen 1 und 2, dadurch gekennzeichnet, dass das Siebdrucknetz nur den Durchgang von Pulverteilchen kleiner als 40 Mikrometer
erlaubt.
5. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Infrarotstrahlung eine kurze Wellenlänge aufweist, wobei ihre Maximalenergie
zwischen 1000 und 1200 nm vorliegt.
6. Verfahren nach den Ansprüchen 1 und 5, dadurch gekennzeichnet, dass die Infrarotstrahlung mit Hilfe eines elliptischen Reflektors fokussiert wird, der
derart angeordnet ist, dass die maximale Strahlenkonzentration bei einer Entfernung
zwischen 10 und 30 mm von der Oberfläche des Metallstücks erhalten wird.
7. Verfahren nach Anspruch 6, dadurch gekennzeichnet, dass der Abstand, bei dem die Maximalstrahlung erhalten wird, zwischen 15 und 17 mm liegt.
8. Verfahren nach den Ansprüchen 1, 5, 6 oder 7, dadurch gekennzeichnet, dass die Einwirkungszeit der Infrarotstrahlung zwischen 1 und 10 Sekunden, vorzugsweise
zwischen 2 und 4 Sekunden, liegt.
9. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Abschluß- und Verbundwärmebehandlung des ersten und zweiten Lacks bei einer Temperatur
zwischen 160 und 220 °C der Metalltemperatur und während einer Zeit zwischen 8 und
20 Minuten ausgeführt wird.
1. Procédé de décoration de pièces métalliques par des moyens d'application de peinture
en poudre, en vue d'atteindre un haut degré de définition dans la reproduction de
dessins décoratifs, et comprenant les étapes suivantes :
- application d'une première peinture en poudre au moyen du dépôt électrostatique
sur la surface métallique destinée à être décorée,
- traitement thermique de la première peinture,
- dans des zones sélectionnées de la première peinture, application au moyen d'un
grillage de sérigraphie d'une seconde peinture en poudre pour obtenir un dessin décoratif,
et
- traitement thermique final de la première et de la seconde peinture pour obtenir
la polyxnérisation jointe des deux peintures,
caractérisé en ce que
la taille des particules qui constituent la seconde peinture en poudre est inférieure
à 40 microns, et la seconde peinture, après son application au moyen du grillage de
sérigraphie et avant le traitement thermique final, est soumise à un traitement thermique
par application d'un rayonnement infrarouge dans des zones localisées, avec l'objectif
d'amener cette seconde peinture en poudre à un état gélifié qui entraîne son adhérence
sur la première peinture, dans le but de faciliter la manipulation de la pièce métallique
sans causer de déplacement des particules de la seconde peinture.
2. Procédé selon la revendication 1,
caractérisé en ce que
la taille des particules de la seconde peinture en poudre est comprise entre 5 et
30 microns.
3. Procédé selon la revendication 1,
caractérisé en ce que
le traitement thermique auquel la première peinture est soumise est exécuté initialement
à une température d'environ 130 °C pendant un intervalle de temps compris entre 4
et 6 minutes.
4. Procédé selon les revendications 1 et 2,
caractérisé en ce que
le grillage de sérigraphie permet uniquement le passage de particules de poudre de
moins de 40 microns.
5. Procédé selon la revendication 1,
caractérisé en ce que
le rayonnement infrarouge est de longueur d'onde courte et son énergie maximum est
située entre 1 000 et 1 200 nm.
6. Procédé selon les revendications 1 et 5,
caractérisé en ce que
le rayonnement infrarouge est focalisé au moyen d'un réflecteur elliptique, situé
de sorte que la concentration maximale du rayonnement est obtenue à une distance comprise
entre 10 et 30 mm de la surface de la pièce en métal.
7. Procédé selon la revendication 6,
caractérisé en ce que
la distance à laquelle le rayonnement maximal est obtenu est entre 15 et 17 mm.
8. Procédé selon les revendications 1, 5, 6 ou 7,
caractérisé en ce que
le temps d'application du rayonnement infrarouge est compris entre 1 et 10 secondes,
de préférence entre 2 et 4 secondes.
9. Procédé selon la revendication 1,
caractérisé en ce que
le traitement thermique final et conjoint de la première et de la seconde peinture
est exécuté à une température comprise entre 160° et 220°C de température du métal
et pendant un temps compris entre 8 et 20 minutes.