[0001] The invention relates to the use of a composition as a lubricating oil additive to
improve the filtration of oils based on mineral oils.
[0002] Wear is the loss of metal between surfaces moving relative to each other. Wear occurs
in all equipment that has moving parts and if it continues, can lead to equipment
malfunction. Lubricant compositions are commonly applied to the metal surfaces of
mechanical equipment that features the movement and contact of metal surfaces, for
example, in the rolling-sliding contacts of hard steel surfaces. This reduces wear
and other damage such as micro-pitting (sometimes called "frosting", "greystaining"
or "peeling") which can occur in rolling element bearings and most often on gear teeth,
which can lead to significant practical problems such as scuffing, and even to tooth
fractures of gears.
[0003] The primary function of a gear lubricant is to protect both gears and axles against
micro-pitting, fatigue, scoring and wear and to provide a high degree of reliability
and durability in the service life of gear equipment. In the automotive industry gear
lubricants may also contribute to improving the fuel economy of vehicles by improving
the axle efficiency.
[0004] A large number of dewaxing aids are commercially available for use as oil additives.
One series of such aids is sold under the name Viscoplex®. Included in this series
of dewaxing aids are Viscoplex® 9-144, Viscoplex® 9-300, Viscoplex® 9-303 and Viscoplex®
9-305, each of which is described as a viscous concentrate of polyalkyl methacrylate
in a solvent-refined neutral oil. Each of these is for use in dewaxing oils as part
of the refining process for producing mineral oil base-stock, and each is also said
to have the properties of improving filtration speed and oil yield in the dewaxing
process, improving the low temperature properties of the resulting base stock, improving
the yield of dewaxed oil, increasing oil through-put, reducing the oil content in
wax produced and reducing the risk of slack-wax formation on filters. Viscoplex 9-305®
is used largely for the purpose of modifying the flow of crude oil through pipelines.
[0005] US 6,495,495 B1 discloses the use of a blend comprising from about 30 to about 70
% (preferably 50 %) of an alkyl ester polymer (preferably an ethylene-vinyl acetate
copolymer) and from about 70 to about 30 % (preferably 50 %) naphthenic oil as a filterability
improver.
[0006] Oil products based on mineral oil in the transportation industry generally contain
levels of dissolved paraffins (waxes), which are soft and flexible. At low temperatures,
these paraffins can begin to precipitate which causes an increase in the viscosity
of the product, reducing its ability to flow. In certain diesel engines, for example
those that feature a filter, this can also lead to blockages.
[0007] The present invention is based on the surprising appreciation that certain concentrations
of a particular C
12-20 polyalkyl methacrylate polymer, such as may be obtained from RohMax under Viscoplex
9-305®, may be included in a lubricating oil based on mineral oil, such as a gear
oil, with the result that a significant improvement in filtration performance is observed
when the composition is used as an additive to the lubricating oil based on mineral
oil.
[0008] Accordingly, the present invention provides for the use of a C
12-20 polyalkyl methacrylate polymer as a lubricating oil additive such that the C
12-20 polyalkyl methacrylate polymer accounts for 0.1 to 0.3 % by weight of the finished
lubricating oil, to improve the filtration of the lubricating oil based on mineral
oil. The C
12-20 polyalkyl methacrylate polymer may be used in the form of a composition comprising
a mineral carrier oil. In a preferred aspect the invention relates to the use of a
composition comprising a C
12-20 polyalkyl methacrylate polymer in a mineral carrier oil to improve the filtration
of a lubricating oil based on mineral oil. Preferably the composition accounts for
0.2 to 0.5 % by weight of the finished lubricating oil. Typically, the composition
comprises 40 to 50 % by weight of the C
12-20 polyalkyl methacrylate polymer and 50 to 60 % by weight of the mineral carrier oil.
Preferably, the composition consists of about 45 % by weight of the C
12-20 polyalkyl methacrylate polymer and about 55 % by weight of the mineral carrier oil.
The use according to the present invention results in a finished lubricating oil that
exhibits a significant improvement in filtration performance.
[0009] The present invention also provides for a finished lubricating oil that results from
use according to the invention as defined above, a composition for use according to
the invention as defined above, a method of lubricating a metal surface comprising
applying said finished lubricating oil to the metal surface, a gear or axle that has
been lubricated as defined in said method, and an additive pack comprising a composition
for use according to the invention as defined above.
[0010] In a preferred embodiment of the use according to the present invention the composition
comprising the C
12-20 polyalkyl methacrylate polymer has a viscosity of 500 to 1000 mm
2/s. More preferably, the composition has a viscosity of about 800 mm
2/s (ASTM D4052) at 100 °C.
[0011] In one preferred embodiment the present invention provides for the use of a C
12-20 polyalkyl methacrylate polymer as defined above wherein the lubricating oil based
on mineral oil is a gear oil. Accordingly, the finished lubricating oil that results
from use according to the present invention is preferably for use in gear oil formulation
applications.
[0012] In another preferred embodiment of the present invention, the finished lubricating
oil that results from use according to the present invention meets the specification
by Scania (STO 1:0). This specification requires that the oil to be tested is filtered
through a 5 micron (pore size) cellulose membrane in the CETOP RP 124H test, wherein
a minimum result of 90 % is required in stage 2 in order for the specification to
be met. CETOP stage 2 gives a measurement of filterability and provides the ratio
(expressed as a percentage) of the flow rates through the membrane at the end of and
at the beginning of the test. A filtration measurement may also be expressed as a
volume, wherein the volume represents the amount of oil filtered over a given period
of time. It should be noted that repeatability is not good (especially for particularly
low or high viscosity fluids) and therefore for each experiment at least three runs
are conducted. Accordingly, the finished lubricating oil that results from use according
to the present invention exhibits a mean of at least 3 CETOP stage 2 test values of
over 90 %. More preferably, this finished lubricating oil meets the specification
by Scania (STO 1:0).
[0013] In the present invention the finished lubricating oil that results from the use according
to the invention as defined above is for use as a lubricant. Preferably, it is a formulated
gear oil lubricant composition, for instance for transmissions such as automobile
rear axles and manual and automatic gear boxes. More preferably this gear oil composition
is formulated to meet the specification by Scania (STO 1:0) for the rear axle and
manual gear box of diesel engined automobiles.
[0014] Typical treat rates at which the C
12-20 polyalkyl methacrylate polymer is used include 0.09 % and above such as 0.14 and
0.18 %. In another preferred embodiment of the use according to the present invention,
the C
12-20 polyalkyl methacrylate polymer is used at a treat rate such that it accounts for
0.1 to 0.2 % by weight of the finished lubricating oil. Typically, the C
12-20 polyalkyl methacrylate polymer accounts for 0.1, 0.15 or 0.2 % by weight of the finished
lubricating oil. More preferably, the C
12-20 polyalkyl methacrylate polymer accounts for 0.15 or 0.2 % by weight of the finished
lubricating oil. The optimum treat rate will vary according to the nature of the mineral
base oil and may be determined on a case-by-case basis by use of the CETOP stage 2
test.
[0015] In another preferred embodiment the present invention provides for the use of a composition
of the invention as defined above wherein the composition is used at a treat rate
such that it accounts for 0.2 to 0.4 % by weight of the finished lubricating oil.
Typically, the composition accounts for 0.2, 0.3 or 0.4 % by weight of the finished
lubricating oil. More preferably, the composition accounts for 0.3 or 0.4 % by weight
of the finished lubricating oil. The optimum treat rate will vary according to the
nature of the mineral base oil and may be determined on a case-by-case basis by use
of the CETOP stage 2 test.
[0016] In another preferred embodiment of the use according to the present invention the
lubricating oil based on mineral oil is for automotive or industrial applications.
In another preferred embodiment of the use according to the present invention, the
lubricating oil based on mineral oil has a viscosity of 80W-90 or 85W-140. In another
preferred embodiment of the use according to the present invention the lubricating
oil based on mineral oil is a part synthetic base stock. In another preferred embodiment
of the use according to the present invention the lubricating oil based on mineral
oil comprises brightstock. Preferably, the lubricating oil based on mineral oil is
Kuwait Petroleum Company, Respol YPF, Total, Esso or SAFOR base stock. More preferably,
the lubricating oil based on mineral oil is a wax-containing base stock.
[0017] In another preferred embodiment of the use according to the present invention the
lubricating oil based on mineral oil and/or the finished oil comprises a further additive,
which further additive is added to the lubricating oil based on mineral oil or the
finished lubricating oil prior to, simultaneously with or subsequently to the C
12-20 polyalkyl methacrylate polymer.
[0018] The present invention also provides for a method of lubricating a metal surface comprising
applying to the metal surface a finished lubricating oil of the present invention
as defined above. Preferably the metal surface is that of a gear or axle. More preferably
the metal surface is that of a gear or rear axle. Typically, the method comprises
adding to and operating a transmission or axle a finished lubricating oil of the invention
as defined above.
[0019] The present invention also provides for an additive pack comprising a C
12-20 polyalkyl methacrylate polymer for use according to the invention as defined above.
The additive pack is added to a lubricating oil based on mineral oil such that the
C
12-20 polyalkyl methacrylate polymer accounts for 0.1 to 0.3 % by weight of the finished
lubricating oil. Preferably, the additive pack is added to the lubricating oil based
on mineral oil such that the contents of the additive pack account for up to 15 %
by weight of the finished lubricating oil. Typically, the additive pack is added to
the lubricating oil based on mineral oil such that the contents of the additive pack
account for 4 to 10 % by weight of the finished lubricating oil. Such an additive
pack may comprise any oil additive known to a person skilled in the art that does
not interfere with the performance of the C
12-20 polyalkyl methacrylate polymer when used accordance with the present invention as
defined above. Examples of appropriate additives are illustrated in the Examples below,
wherein a composition of the invention as defined above for use according to the present
invention is shown to work in a variety of blends with numerous different additives.
Other appropriate additives that may be used in conjunction with the present invention
will be evident to the person skilled in the art and include pour point depressants,
anti-wear additives, anti-oxidation additives, anti-rust additives, dispersants, boronated
dispersants, HiTEC 381 (a fully formulated gear package), viscosity index improvers,
detergents and friction modifiers.
[0020] The composition for use according to the invention as defined above is preferably
in the form of a concentrate. In another preferred embodiment this concentrate is
combined with a dispersant. Suitable dispersants will be evident to the person skilled
in the art.
[0021] The present invention additionally includes machines lubricated by the lubricating
oil described above. Although the machine may be any machine for which the inventive
lubricating oil would provide satisfactory lubrication, it is envisioned that such
machinery would include gas engines, diesel engines, turbine engines, automatic transmissions,
manual transmissions, hypoid axles, and gear boxes. Furthermore, the present invention
includes vehicles comprising the inventive oil soluble lubricant additive package
described above.
[0022] Further, the present invention provides a method for lubricating moving parts of
a machine comprising the step of: contacting at least one moving part with a lubricant
comprising the oil soluble lubricant additive package described above. Although the
method may be successfully employed on a wide variety of machines, it is envisioned
that such machinery would include: gas engines, diesel engines, turbine engines, automatic
transmissions, manual transmissions, hypoid axles, and gear boxes.
[0023] It is also useful herein that at least one dispersant used in the oil soluble lubricant
additive package described above has a molecular weight of from about 1,000 to about
20,000 amu. In one embodiment the at least one dispersant is a maleic anhydride functionalized
polyisobutylene polymer that has been reacted with a polyamine. Also the at least
one dispersant can be a product of a Mannich reaction. It is further equally possible
that the at least one dispersant is an ethylene-propylene type dispersant.
[0024] It is further preferred in one embodiment that the oil soluble lubricant additive
package described above additionally comprise at least one component selected from
the group consisting of: viscosity index improvers and pour point depressants.
[0025] The present invention also includes machines lubricated by the lubricating oil described
above. Although the inventive lubricating oil can be used on a wide variety of machines,
it is envisioned that the machines especially suited for lubrication include: gas
engines, diesel engines, turbine engines, automatic transmissions, manual transmissions,
hypoid axles, and gear boxes.
[0026] Additionally, the present invention includes vehicles comprising the oil soluble
lubricant additive package described above.
[0027] A method for lubricating moving parts of a machine is also provided comprising the
step of: contacting at least one moving part with a lubricant comprising the oil soluble
lubricant additive package described above. Although the method may be employed with
a wide variety of machines, it is believed that the method is especially suited for
use with: gas engines, diesel engines, turbine engines, automatic transmissions, manual
transmissions, hypoid axles, and gear boxes.
[0028] The present invention also includes machines lubricated by the lubricating oil described
above. Although a wide variety of machines may be lubricated by the present inventive
lubricating oil, it is preferred that the machine is selected from the group consisting
of: gas engines, diesel engines, turbine engines, automatic transmissions, manual
transmissions, hypoid axles, and gear boxes.
[0029] It is preferred that the lubricating oil additionally comprises at least one additive
selected from the group consisting of: detergents, dispersants, antioxidants, friction
modifiers, viscosity index improvers, and pour point depressants.
[0030] In accordance with the foregoing summary, the following presents a detailed description
of the preferred embodiment of the invention that is currently considered to be the
best mode.
[0031] The mineral oils useful in this invention can include but are not limited to all
common mineral oil base stocks. This would include oils that are naphthenic or paraffinic
in chemical structure. Oils that are refined by conventional methodology using acid,
alkali, and clay or other agents such as aluminum chloride, or be extracted oils produced,
for example, by solvent extraction with solvents such as phenol, sulfur dioxide, furfural,
dichlorodiethyl ether, etc. They may be hydrotreated or hydrorefined, dewaxed by chilling
or catalytic dewaxing processes, or hydrocracked. The mineral oil may be produced
from natural crude sources or be composed of isomerized wax materials or residues
of other refining processes. In one embodiment, the oil of lubricating viscosity is
a hydrotreated, hydrocracked and/or iso-dewaxed mineral oil having a Viscosity Index
(VI) of greater than 80, preferably greater than 90; greater than 90 volume % saturates
and less than 0.03 wt. % sulfur.
[0032] Group II and Group III basestocks are also particularly suitable for use in the present
invention, and are typically prepared from conventional feedstocks using a severe
hydrogenation step to reduce the aromatic, sulfur and nitrogen content, followed by
dewaxing, hydrofinishing, extraction and/or distillation steps to produce the finished
base oil. Group II and III basestocks differ from conventional solvent refined Group
I basestocks in that their sulfur, nitrogen and aromatic contents are very low. As
a result, these base oils are compositionally very different from conventional solvent
refined basestocks. The American Petroleum Institute has categorized these different
basestock types as follows: Group I, >0.03 wt. % sulfur, and/or <90 vol% saturates,
viscosity index between 80 and 120; Group II, ≤ 0.03 wt. % sulfur, and ≥ 90 vol% saturates,
viscosity index between 80 and 120; Group III, ≤ 0.03 wt. % sulfur, and ≥ 90 vol%
saturates, viscosity index > 120; Group IV, poly-alpha-olefins. Hydrotreated basestocks
and catalytically dewaxed basestocks, because of their low sulfur and aromatics content,
generally fall into the Group II and Group III categories.
[0033] There is no limitation as to the chemical composition of the various basestocks used
in the present invention. For example, the proportions of aromatics, paraffinics,
and naphthenics in the various Group I, Group II and Group III oils can vary substantially.
The degree of refining and the source of the crude used to produce the oil generally
determine this composition. In one embodiment, the base oil comprises a mineral oil
having a VI of at least 110.
[0034] The lubricating oils may be derived from refined, re-refined oils, or mixtures thereof.
Unrefined oils are obtained directly from a natural source or synthetic source (e.g.,
coal, shale, or tar sands bitumen) without further purification or treatment. Examples
of unrefined oils include shale oil obtained directly from a retorting operation,
petroleum oil obtained directly from distillation, or an ester oil obtained directly
from an esterification process, each of which is then used without further treatment.
Refined oils are similar to the unrefined oils except that refined oils have been
treated in one or more purification steps to improve one or more properties. Suitable
purification techniques include distillation, hydrotreating, dewaxing, solvent extraction,
acid or base extraction, filtration, and percolation, all of which are known to those
skilled in the art. Re-refined oils are obtained by treating used oils in processes
similar to those used to obtain the refined oils. These re-refined oils are also known
as reclaimed or reprocessed oils and are often additionally processed by techniques
for removal of spent additives and oil breakdown products:
VISCOSITY INDEX IMPROVERS
[0035] Viscosity index improvers impart high and low temperature operability to the lubricating
oil and permit it to remain relatively viscous at elevated temperatures and also exhibit
acceptable viscosity or fluidity at low temperatures. Viscosity index improvers are
generally high molecular weight hydrocarbon polymers including polyesters. The viscosity
index improvers may also be derivatized to include other properties or functions,
such as the addition of dispersancy properties. These oil soluble viscosity modifying
polymers will generally have number average molecular weights of from 10
3 to 10
6, preferably 10
4 to 10
6, as determined by gel permeation chromatography or osmometry.
[0036] The viscosity index improvers useful herein can include polymethacrylate-based ones,
olefin copolymer-based ones, (e.g., isobutylene-based and ethylene-propylene copolymer
based ones), polyalkyl styrene-based ones, hydrogenated styrene-butadiene copolymer-based
ones, and styrene-maleic anhydride ester copolymer-based ones.
[0037] Representative examples of suitable viscosity index improvers are found in U.S. Pat.
Nos. 5,075,383; 5,102,566; 5,139,688; 5,238,588; and 6,107,257. The above references
are incorporated herein by reference.
POUR POINT DEPRESSANTS
[0038] Pour point depressants are used to improve low temperature properties of oilbased
compositions. See, for example, page 8 of "Lubricant Additives" by C.V. Smalheer and
R. Kennedy Smith (Lezius Hiles Co. publishers, Cleveland, Ohio, 1967). Examples of
useful pour point depressants are polymethacrylates; polyacrylates; polyacrylamides;
condensation products of haloparaffin waxes and aromatic compounds; vinyl carboxylate
polymers; and ter-polymers of dialkylfumarates, vinyl esters of fatty acids and alkyl
vinyl ethers. Pour point depressants are described in U.S. Patent Nos. 2,387,501;
2,015,748; 2,655,479; 1,815,022; 2,191,498; 2,666,746; 2,721,877; 2,721,878; and 3,250,715,
which are herein incorporated by reference for their relevant disclosures.
DISPERSANTS
[0039] Dispersants used in the present invention may be ash-producing or ashless. Suitable
dispersants for use herein can typically comprise amine, alcohol, amide, or ester
polar moieties attached to the polymer backbone via a bridging group. The dispersant
may be, for example, selected from oil-soluble salts, esters, amino-esters, amides,
imides, and oxazolines of long chain hydrocarbon substituted mono- and dicarboxylic
acids or their anhydrides; thiocarboxylate derivatives of chain hydrocarbons; long
chain aliphatic hydrocarbons having a polyamine attached directly thereto; and Mannich
condensation products formed by condensing a long chain substituted phenol with formaldehyde
and polyalkylene polyamine, and Koch reaction products. The long chain aliphatic hydrocarbons
can be polymers such as polyalkylenes, including, for example, polyisobutylene, polyethylene,
polypropylene, and copolymers thereof and/or copolymers with other alpha-olefins.
Typical PIB molecular weights useful herein can range from about 950 to 6000.
[0040] Representative examples of dispersants suitable for use in the present invention
are found in U.S. Patent Nos. 5,075,383; 5,139,688; 5,238,588; and 6,107,257. Additional
representative examples are found in U.S. Patent Application Publication No. 2001/0036906A1.
The disclosures of the afore-mentioned references are incorporated herein by reference.
DETERGENTS
[0041] A detergent is an additive that reduces the formation of piston deposits, for example
high-temperature varnish and lacquer deposits, in engines. Detergents typically possess
acid-neutralizing properties and are capable of keeping finely divided solids in suspension.
Metal detergents are used preferably for improving the acid-neutralizing properties,
high-temperature detergency, and anti-wear properties of the resulting lubricating
oil composition.
[0042] Detergents used herein may be any detergent used in lubricating oil formulations,
and may be of the ash-producing or ashless variety. Detergents suitable for use in
the present invention include all of the detergents customarily used in lubricating
oils, including metal detergents. Specific examples of metal detergents are those
selected from alkali metal or alkaline earth metal sulfonates, alkali metal or alkaline
earth metal phenates, and alkali metal or alkaline earth metal salicylates. In an
embodiment, the lubricating oil formulation is essentially free of sulfurized phenate
detergent.
[0043] Representative examples of suitable detergents useful in the present invention are
found in U.S. Pat. Nos. 6,008,166. Additional representative examples of suitable
detergents are found in U.S. Patent Application Nos. 2002/0142922A1, 2002/0004069A1,
and 2002/0147115A1. The disclosures of the afore-mentioned references are incorporated
by reference herein.
ANTIOXIDANTS
[0044] Useful antioxidant materials include oil soluble phenolic compounds, oil soluble
sulfurized organic compounds, oil soluble amine antioxidants, oil soluble organo borates,
oil soluble organo phosphites, oil soluble organo phosphates, oil soluble organo dithiophosphates
and mixtures thereof. Such antioxidants can be metal free (that is, free of metals
which are capable of generating sulfated ash), and therefore are most preferably ashless
(having a sulfated ash value not greater than 1 wt. % SASH, as determined by ASTM
D874).
[0045] Representative examples of suitable antioxidants useful in the present invention
are found in U.S. Patent No. 5,102,566. Additional representative examples of suitable
antioxidants useful in the present invention are found in U.S. Patent Application
Publication No. 2001/0012821A1. The disclosures of the afore-mentioned references
are incorporated by reference herein.
FRICTION MODIFIERS
[0046] Friction modifiers serve to impart the proper friction characteristics to lubricating
oil compositions.
[0047] Friction modifiers include such compounds as aliphatic amines or ethoxylated aliphatic
amines, aliphatic fatty acid amines, aliphatic carboxylic acids, aliphatic carboxylic
esters of polyols such as glycerol esters of fatty acid as exemplified by glycerol
phenate, aliphatic carboxylic ester-amides, aliphatic phosphonates, aliphatic phosphates,
aliphatic thiophosphonates, aliphatic thiophosphates, etc., wherein the aliphatic
group usually contains above about eight carbon atoms so as to render the compound
suitably oil soluble. Also suitable are aliphatic substituted succinimides formed
by reacting one or more aliphatic succinic acids or anhydrides with ammonia. Additionally
suited for use in the present invention are friction modifiers containing molybdenum.
[0048] Representative examples of molybdenum-containing friction modifiers include those
found in U.S. Patent Nos. 5,650,381; RE37,363E; 5,628,802; 4,889,647; 5,412,130; 4,786,423;
4,812,246; 5,137,647; 5,364,545; 5,840,672; 5,925,600; 5,962,377; 5,994,277; 6,017,858;
6,150,309; 6,174,842; 6,187,723; 6,268,316; European Patent Nos. EP 222 143 B1; EP
281 992 B1; EP 719 314 B1; EP 719 315 B1; EP 874 040 A1; EP 892 037 A1; EP 931 827
A1; EP 1 041 134 A1; EP 1 041 135 A1; EP 1 087 008 A1; EP 1 088 882 A1; EP; Japanese
Patent No. JP 11035961; and International Publication Nos. WO 95/07965; WO 00/08120;
WO 00/71649.
[0049] Representative examples of suitable friction modifiers are found in U.S. Pat. Nos.
3,933,659; 4,105,571; 3,779,928; 3,778,375; 3,852,205; 3,879,306; 3,932,290; 3,932,290;
4,028,258; 4,344,853; 5,102,566; 6,103,674; 6,174,842; 6,500,786; 6,500,786; and 6,509,303.
Additional representative examples of suitable friction modifiers are found in U.S.
Patent Application Publication No. 2002/0137636 A1. The disclosures of the above references
are incorporated herein by reference.
EXAMPLES
[0050] The invention is illustrated by the following examples.
[0052] The results exemplified in the Tables 1 to 3 illustrate the significant improvement
in filtration performance exhibited by blends that comprise a C
12-20 polyalkyl methacrylate polymer at the appropriate concentrations. In conjunction
with Table 5 it is of note that the Shell base stocks meet the specification by Scania
without the addition of a C
12-20 polyalkyl methacrylate polymer at the appropriate concentrations. This is because
the Shell base stock is filtered to remove the wax during the manufacturing process.
In any case, the addition to this base stock of a C
12-20 polyalkyl methacrylate polymer at the appropriate concentrations did not result in
any detrimental effect to the filterability of the finished oil blend and the finished
lubricating oil resulting from the addition to the Shell base stock of a C
12-20 polyalkyl methacrylate polymer at the appropriate concentrations was shown to meet
the specification by Scania (STO 1:0).
[0053] The properties of certain components (as used in the above experiments and in the
industry in general) are as follows:
1. Use of a C12-20 polyalkyl methacrylate polymer as a lubricating oil additive such that the C12-20 polyalkyl methacrylate polymer accounts for 0.1 to 0.3 % by weight of the finished
lubricating oil, which use comprises the addition of said C12-20 polyalkyl methacrylate polymer to a lubricating oil based on mineral oil to improve
the filtration of said lubricating oil based on mineral oil.
2. Use according to claim 1 wherein the lubricating oil based on mineral oil is a gear
oil.
3. Use according to claim 1 or 2 wherein the mean CETOP filtration stage 2 test value
of the finished lubricating oil (the oil resulting from said use) is over 90 %.
4. Use according to claim 3 wherein the finished lubricating oil (the oil resulting from
said use) meets the specification by Scania (STO 1:0).
5. Use according to any one of claims 1 to 4 wherein the C12-20 polyalkyl methacrylate polymer accounts for 0.1 or 0.2 % by weight of the finished
lubricating oil.
6. Use according to any one of the preceding claims of a composition comprising the C12-20 polyalkyl methacrylate polymer.
7. Use according to claim 6 wherein the composition comprises about 45 % by weight of
the C12-20 polyalkyl methacrylate polymer and about 55 % by weight of a mineral carrier oil.
8. Use according to claim 7 wherein the composition has a viscosity of 800 mm2/s (ASTM D4052) at 100 °C.
9. Use according to any one of the preceding claims wherein the lubricating oil based
on mineral oil has a viscosity of 80W-90 or 85W-140.
10. Use according to any one of claims 1 to 8 wherein the lubricating oil based on mineral
oil is for automotive or industrial applications.
11. Use according to any one of the preceding claims wherein the lubricating oil based
on mineral oil is a part synthetic base stock.
12. Use according to any one of the preceding claims wherein the lubricating oil based
on mineral oil comprises brightstock.
13. Use according to any one of the preceding claims wherein the lubricating oil based
on mineral oil is Kuwait Petroleum Company, Repsol YPF, Total, Esso or SAFOR base
stock.
14. Use according to any one of the preceding claims wherein the lubricating oil based
on mineral oil and/or the finished lubricating oil comprises a further additive, which
further additive is added to the lubricating oil based on mineral oil or the finished
lubricating oil prior to, simultaneously with or subsequently to the composition comprising
a C12-20 polyalkyl methacrylate polymer in a mineral carrier oil.
15. Use according to any one of the preceding claims wherein the lubricating oil based
on mineral oil is a formulated gear lubricant composition.
16. A finished lubricating oil resulting from a use as defined in any one of claims 1
to 15.
17. A method of lubricating the metal surface of a gear or axle comprising applying to
the metal surface a finished lubricating oil as defined in claim 16.
18. A method according to claim 17 wherein the method comprises adding a finished lubricating
oil as defined in claim 16 to a transmission or axle and operating the transmission
or axle.
19. A gear or axle which has been lubricated in a method according to claim 17 or 18.
20. A composition comprising a C12-20 polyalkyl methacrylate polymer in a mineral carrier oil for use as defined in any
one of claims 1 to 15.
21. A gear additive package comprising a composition as defined in claim 20.