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EP 1 052 186 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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01.02.2006 Bulletin 2006/05 |
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Date of filing: 20.04.2000 |
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International Patent Classification (IPC):
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Multilayer structure for reclosable container closure
Mehrschichtige Struktur für wiederverschliessbaren Behälterverschluss
Structure multicouche pour fermeture de récipient pouvant être refermée
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Designated Contracting States: |
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AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
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Priority: |
26.04.1999 IT MI990881
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Date of publication of application: |
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15.11.2000 Bulletin 2000/46 |
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Proprietor: Di Mauro Officine Grafiche S.p.A. |
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84013 Cava dei Tirreni,
(Prov. of Salerno) (IT) |
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Inventor: |
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- Celano, Clemente
84013 Cava dei Tirreni (Salerno) (IT)
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Representative: Modiano, Micaela Nadia et al |
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Dr. Modiano & Associati S.p.A.
Via Meravigli 16 20123 Milano 20123 Milano (IT) |
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References cited: :
EP-A- 0 306 982 EP-A- 0 905 048 FR-A- 2 741 605
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EP-A- 0 554 152 FR-A- 2 669 607
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Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
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[0001] The present invention relates to a multilayer structure for closing containers, suitable
for providing containers which can be re-closed several times after their initial
opening.
[0002] It is known that many food and non-food products are packaged in containers, for
example trays, pouches or similar containers, which are sealed.
[0003] Tray-like containers are constituted by a lower thermoformed portion, designed to
contain the product, and by an upper portion, designed to close the container. The
lower portion and the upper portion designed for closure can both be flexible or rigid
and be of the single-layer or multilayer type. In some cases, the lower portion is
produced on-line by the packaging machine by thermoforming a film made of flat synthetic
material. In other cases, the lower portion is already preformed when it is introduced
in the packaging machine. In many cases, the container is closed by thermal bonding
performed along the perimeter of the tray where the two portions overlap.
[0004] In the case of pouch-type containers, the production and packaging method is similar,
except that the lower portion is not subjected to thermoformation.
[0005] Due to economic and environmental requirements, products are packaged in a plurality
of doses in said containers. The consumer must therefore be able to easily and effectively
re-close the container in order to preserve the part of the product that has not been
consumed. Especially in the case of food products, after the initial opening of the
container it would be convenient to be able to re-close it in order to avoid spreading
odors into the surrounding environment, avoid dehydration of the packaged product
or its alteration, and avoid other drawbacks arising from poor preservation of the
product.
[0006] In order to meet this requirement, various mechanical and chemical-physical re-closure
systems have been devised for these containers.
[0007] One of the re-closure systems currently in use is based on using, in order to close
tray-like containers, a multilayer structure comprising at least three layers: a first
layer, constituted by a film of material which allows thermal bonding and is designed
to be subjected to thermal bonding at the rim of the opening of the container, a second
outer layer; and a third layer of permanent adhesive interposed between the first
layer and the second layer.
[0008] In this multilayer structure, the bonding force between the adhesive layer and the
first layer is weaker than the resistance to separation of the thermal bonding performed
in order to apply the multilayer structure to the tray-like container.
[0009] In this way, during the first opening of the container the first layer tears at the
thermal bonding region and this tearing exposes the layer of permanent adhesive, which
can be used to re-close the container by pressing.
[0010] This multilayer structure requires a large amount of permanent adhesive, since the
layer of permanent adhesive that is used, besides allowing to re-close the container,
also mutually couples the first layer and the second layer.
[0011] Moreover, in the above-described multilayer structure it is necessary to use a permanent
adhesive having a strong bonding force, necessarily greater than the force required
to tear the first layer, in order to prevent the first layer and the second layer
from uncoupling during the initial opening of the container, when it is necessary
to apply to the multilayer structure a force sufficient to tear the first layer at
the thermal bonding region.
[0012] This requirement in practice limits the choice of the permanent adhesive to be used.
[0013] FR-A-2 669 607 discloses a re-closure system of the above-described type having a
layer of permanent adhesive which mutually couples to the first and second layers
at the entire extension of the multilayer structure.
[0014] EP-A-0 554 152 discloses another re-closure system of the above described type. In
some embodiments the layer of permanent adhesive is arranged along the whole perimeter
of the opening of the container, in other embodiments the layer of permanent adhesive
is limited exclusively at only a part of the perimeter of said opening. However, in
the latter case there are zones where the first layer is not attached to the container.
[0015] The aim of the present invention is to solve the above-described problems, by providing
a multilayer structure for closing containers which is adapted for forming containers
which can be re-closed several times after their initial opening and allows to reduce
the use of permanent adhesives with respect to conventional multilayer structures.
[0016] Within the scope of this aim, an object of the present invention is to provide a
multilayer structure which can be manufactured at a lower cost than conventional multilayer
structures.
[0017] A further object of the present invention is to provide a multilayer structure which
allows to also use permanent adhesives with reduced bonding force for reclosing the
containers after their first opening.
[0018] In accordance with the invention, there is provided a mutilayer structure for closing
containers as defined in the appended claims.
[0019] Further characteristics and advantages of the invention will better appear from the
following detailed description of a preferred but not exclusive embodiment of the
multilayer structure according to the invention, illustrated only by way of non-limitative
example in the accompanying drawings, wherein:
Figure 1 is an exploded perspective view of the multilayer structure according to
the invention;
Figure 2 is a highly enlarged sectional view of the multilayer structure;
Figure 3 is a sectional view of the multilayer structure according to the invention
applied to a tray-type container;
Figure 4 is a sectional view, similar to Figure 3, but showing the behavior of the
multilayer structure according to the invention during the first opening of the container.
[0020] With reference to the above figures, the multilayer structure according to the invention,
generally designated by the reference numeral 1, comprises at least two layers: a
first layer 2, constituted by a film of material which is adapted for thermal bonding,
designed to be subjected to thermal bonding along the whole perimeter of the opening
3 of a container 4, and a second layer 5, which is coupled to the first layer 2 on
the face thereof that lies opposite the face designed to be coupled to the container
4 by thermal bonding.
[0021] A third layer 6 of permanent adhesive is interposed between the first layer 2 and
the second layer 5. The presence of the third layer 6 is limited exclusively at only
a part of the region of the first layer 2 designed to be coupled to the container
4 by thermal bonding, i.e. the third layer 6 is omitted at certain portions of the
region 10 for the thermal bonding of the first layer 2 on the container 4.
[0022] For example, as shown, if the container 4 has a substantially rectangular opening,
it is possible to provide the third layer 6 only at three of the four sides along
which thermal bonding is performed, so that the container 4 can be opened, so as to
allow re-closure, by removing the multilayer structure 1 only along said three sides.
[0023] The tear resistance of the first layer 2 is weaker than the bonding force between
the first layer 2 and the second layer 5, where the third layer 6 is not present,
and is weaker than the resistance to separation of the thermal bonding 10 to be performed
between the first layer 2 and the container 4. The resistance to separation of the
thermal bonding 10 is greater than the cohesion and/or bonding force of the permanent
adhesive of the third layer 6, so that during the first opening of the container 4
the first layer 2 tears, exposing the third layer 6, which can thus be used to re-close
the container 4 several times.
[0024] The first layer 2 can be constituted by a film made of synthetic material suitable
for thermal bonding, such as polyethylene.
[0025] The second layer 5 can be constituted by a flexible or rigid synthetic material,
such as an oriented polymer or polyvinyl chloride (PVC) or polyethylene or other synthetic
materials.
[0026] The third layer 6 can be constituted, for example, by an acrylic polymer.
[0027] The second layer 5 can be constituted by a barrier film or by a film which bears
printing or can be substantially of the same material used for the first layer 2 and
can optionally be coupled to one or more additional films with the face that lies
opposite the face directed toward the first layer 1.
[0028] Moreover, the second layer 5 can be constituted by a rigid thermoformable film or
can be coupled to a thermoformable rigid film with its side that faces away from the
first layer 2.
[0029] The first layer 2 and the second layer 5 can be mutually coupled by heat calendering,
or each one of the two layers 2 and 5 can be provided, according to the method known
as extrusion coating, on the other layer.
[0030] Alternatively, the layer 2 and the layer 5 can be coupled one another with the method
known as extrusion lamination.
[0031] The layer 6 of permanent adhesive is interposed on the side of the first layer 2
that faces the second layer 5 or, alternatively, on the side of the second layer 5
that faces the first layer 2, before their coupling, or alternatively before the coating
of one of the two layers on the other layer, at the region designed to be affected
by the thermal bonding 10 on the perimeter of the opening of the container 4.
[0032] During the subsequent step for coupling the layers 2 and 5, the presence of the layer
6 of permanent adhesive prevents permanent coupling between the layers 2 and 5 only
in the regions where said layer 6 has been applied. The layer 6 in any case provides
a bonding between the layers 2 and 5 which assuredly seals the package.
[0033] It should be observed that the layers 2 and 5 are mutually coupled also outside the
region of the first layer 2 designed to be coupled to the container 4 by thermal bonding
and occupied by the third layer 6.
[0034] Preferably, the cohesion force between the third layer 6 and the second layer 5 is
stronger than the cohesion force between the third layer 6 and the first layer 2,
so that during the separation of the layer 5 from the layer 2, at the layer 6, the
layer 6 remains bonded to the layer 5. This can be achieved by appropriately selecting
the materials of the layers 2 and 5 or by means of a different degree of roughness
on the faces of the layers 2 and 5 that couple to the layer 6.
[0035] In order to facilitate the opening of the container, in one or more regions along
the perimeter of the opening of the container 4 the thermal bonding can affect only
partially the region where the multilayer structure according to the invention overlaps
the perimeter of the opening 3 of the container.
[0036] It should be observed that the container 4 can be constituted by a tray or even simply
by a substantially flat structure constituted by a single film or by a plurality of
coupled films, as in the case of pouch-type containers.
[0037] The container closed by means of the multilayer structure according to the invention
is opened by lifting a flap of the multilayer structure 1 that lies outside the thermal
bonding 10, as shown in Figure 4.
[0038] Said free flap, designed to be gripped in order to open the container 4, is provided
in a region of the multilayer structure 1 that is adjacent to the region in which
the layer 6 of permanent adhesive is present.
[0039] The lifting of said free flap continues without hindrance until it reaches the region
affected by the thermal bonding 10. At the beginning of said region, since the coupling
force between the first layer 2 and the second layer 5 is greater than the tearing
resistance of the first layer 2, the first layer 2 tears and remains bonded to the
container 4 due to the thermal bonding 10. As the lifting of the multilayer structure
1 continues, the region where the first layer 2 is coupled to the second layer 5 inside
the region affected by the thermal bonding 10 is reached. At said region, owing to
the fact that the bonding force between the first layer 2 and the second layer 5 is
greater than the tearing resistance of the first layer 2, an additional tearing of
the first layer 2 occurs.
[0040] The tearing of the first layer 2 at the region affected by the thermal bonding 10
exposes the layer 6, which can be used to re-close the container, even several times,
after its initial opening.
[0041] It should be observed that if the second layer 5 is constituted by a rigid film which
is thermoformable or is coupled to a thermoformable rigid film, the multilayer structure
according to the invention can be thermoformed and can optionally replace the container
without thereby abandoning the scope of the protection of the present invention. In
this case, the container constituted by the thermoformed multilayer structure can
be closed with a conventional film by thermal bonding.
[0042] In practice it has been observed that the multilayer structure according to the invention
fully achieves the intended aim and objects, since it allows to re-close containers
after their first opening despite using a reduced amount of permanent adhesive.
[0043] Another advantage of the multilayer structure according to the invention is that
it is also possible to use permanent adhesives having a reduced bonding force.
[0044] The multilayer structure thus conceived is susceptible of numerous modifications
and variations, all of which are within the scope of the inventive concept; all the
details may further be replaced with other technically equivalent elements.
[0045] In practice, the materials employed, as well as the dimensions, may be any according
to requirements and the state of the art.
[0046] Where technical features mentioned in any claim are followed by reference signs,
those reference signs have been included for the sole purpose of increasing the intelligibility
of the claims and accordingly, such reference signs do not have any limiting effect
on the interpretation of each element identified by way of example by such reference
signs.
1. A multilayer structure for closing containers provided with an opening, comprising
at least two layers, namely, a first layer (2) adapted for thermal bonding along the
whole perimeter of said opening (3) of the container (4) and a second layer (5) which
is coupled to said first layer (2); a third layer (6) of permanent adhesive being
interposed between said first layer (2) and said second layer (5), the tearing resistance
of said first layer (2) being weaker than the bonding force between said first layer
(2) and said second layer (5), where said third layer (6) is not present, and being
weaker than the resistance to separation of the thermal bonding (10) to be provided
between said first layer (2) and the container (4); the resistance to separation of
said thermal bonding (10) being greater than the bonding and/or cohesion force of
said permanent adhesive, so that said first layer (2) tears during the first opening
of the container (4), exposing said third layer (6), which can be used to re-close
the container (4), characterized in that said third layer (6) is limited exclusively at only a part of the region (10) of
said first layer (2) forseen to be coupled to said container (4) by thermal bonding.
2. The multilayer structure according to claim 1, characterized in that said first layer (2) and said second layer (5) are mutually coupled also outside
the region of said first layer (2) forseen to be coupled to said container (4) by
thermal bonding and occupied by said third layer (6).
3. The multilayer structure according to claim 1, characterized in that the cohesion force between said third layer (6) and said second layer (5) is greater
than the cohesion force between said third layer (6) and said first layer (2).
4. The multilayer structure according to one or more of the preceding claims, characterized in that said second layer (5) is coupled to one or more layers on its side that faces away
from said first layer (2).
5. The multilayer structure according to one or more of the preceding claims, characterized in that said second layer (5) is constituted by a film of oriented polymer.
6. The multilayer structure according to one or more of the preceding claims, characterized in that said second layer (5) is constituted by a barrier film.
7. The multilayer structure according to one or more of the preceding claims, characterized in that said second layer (5) is constituted by a thermoformable rigid film.
8. The multilayer structure according to one or more of the preceding claims, characterized in that said second layer (5) is coupled to a thermoformable rigid film at its side that
faces away from said first layer (2).
9. A method for producing a multilayer structure according to one or more of the preceding
claims, consisting in mutually coupling said at least two layers (2,5), one of which
is adapted for thermal bonding, and in interposing said layer (6) of permanent adhesive
between said two layers (2,5), before their coupling, characterized in that said layer (6) is limited exclusively at only a part of the region (10) of said layer
adapted for thermal bonding forseen to be coupled to a container (4) by thermal bonding.
10. The method according to claim 9, characterized in that said two layers (2,5) are mutually coupled by hot calendering.
11. The method according to claim 9, characterized in that said two layers (2,5) are mutually coupled by the method known as extrusion lamination.
12. The method according to claim 9, characterized in that said two layers (2,5) are mutually coupled by making one of said two layers, with
the method known as extrusion coating, on the other one of said two layers (2,5).
1. Mehrlagige Struktur zum Verschließen von mit einer Öffnung versehenen Behältern, mit
wenigstens zwei Lagen, d. h. einer ersten Lage (2), die für eine thermische Haftung
längs des gesamten Umfangs der Öffnung (3) des Behälters (4) geeignet ist, und einer
zweiten Lage (5), die mit der ersten Lage (2) gekoppelt ist; wobei zwischen die erste
Lage (2) und die zweite Lage (5) eine dritte Lage (6) aus einem dauerhaften Klebstoff
eingefügt ist; wobei der Reißwiderstand der ersten Lage (2) geringer ist als die Haftkraft
zwischen der ersten Lage (2) und der zweiten Lage (5), wo die dritte Lage (6) nicht
vorhanden ist, und geringer ist als der Widerstand gegenüber einer Trennung der thermischen
Haftung (10), die zwischen der ersten Lage (2) und dem Behälter (4) geschaffen werden
soll; wobei der Widerstand gegenüber der Trennung der thermischen Haftung (10) größer
ist als die Haftungs- und/oder Kohäsionskraft des dauerhaften Klebstoffs, so dass
die erste Lage (2) während des ersten Öffnens des Behälters (4) zerreißt und die dritte
Lage (6), die zum Wiederschließen des Behälters (4) verwendet werden kann, freilegt,
dadurch gekennzeichnet, dass die dritte Lage (6) ausschließlich nur auf einen Teil des Bereichs (10) der ersten
Lage (2), der dazu vorgesehen ist, mit dem Behälter (4) durch thermische Haftung gekoppelt
zu werden, begrenzt ist.
2. Mehrlagige Struktur nach Anspruch 1, dadurch gekennzeichnet, dass die erste Lage (2) und die zweite Lage (5) auch außerhalb jenes Bereichs der ersten
Lage (2), der durch thermische Haftung mit dem Behälter (4) gekoppelt werden soll
und durch die dritte Lage (6) belegt ist, miteinander gekoppelt sind.
3. Mehrlagige Struktur nach Anspruch 1, dadurch gekennzeichnet, dass die Kohäsionskraft zwischen der dritten Lage (6) und der zweiten Lage (5) größer
ist als die Kohäsionskraft zwischen der dritten Lage (6) und der ersten Lage (2).
4. Mehrlagige Struktur nach einem oder mehreren der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die zweite Lage (5) auf ihrer Seite, die von der ersten Lage (2) wegweist, mit einer
oder mehreren Lagen gekoppelt ist.
5. Mehrlagige Struktur nach einem oder mehreren der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die zweite Lage (5) durch eine Schicht aus einem orientierten Polymer gebildet ist.
6. Mehrlagige Struktur nach einem oder mehreren der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die zweite Lage (5) durch eine Sperrschicht gebildet ist.
7. Mehrlagige Struktur nach einem oder mehreren der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die zweite Lage (5) durch eine wärmeformbare starre Schicht gebildet ist.
8. Mehrlagige Struktur nach einem oder mehreren der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die zweite Lage (5) auf ihrer Seite, die von der ersten Lage (2) wegweist, mit einer
wärmeformbaren starren Schicht gekoppelt ist.
9. Verfahren zum Herstellen einer mehrlagigen Struktur nach einem oder mehreren der vorhergehenden
Ansprüche, das darin besteht, die wenigstens zwei Lagen (2, 5), wovon eine für eine
thermische Haftung geeignet ist, miteinander zu koppeln und zwischen die zwei Lagen
(2, 5) die Lage (6) aus einem dauerhaften Klebstoff einzufügen, bevor sie gekoppelt
werden, dadurch gekennzeichnet, dass diese Lage (6) ausschließlich nur auf einen Teil des Bereichs (10) der für die thermische
Haftung geeigneten Lage, der dazu vorgesehen ist, mit einem Behälter (4) durch thermische
Haftung gekoppelt zu werden, begrenzt ist.
10. Verfahren nach Anspruch 9, dadurch gekennzeichnet, dass die zwei Lagen (2, 5) durch Heißkalandrieren miteinander gekoppelt sind.
11. Verfahren nach Anspruch 9, dadurch gekennzeichnet, dass die zwei Lagen (2, 5) durch das als Extrusionsiaminierung bekannte Verfahren miteinander
gekoppelt sind.
12. Verfahren nach Anspruch 9, dadurch gekennzeichnet, dass die zwei Lagen (2, 5) dadurch gekoppelt werden, dass eine der zwei Lagen durch das
als Extrusionsbeschichtung bekannte Verfahren auf der anderen der zwei Lagen (2, 5)
hergestellt wird.
1. Structure multi-couches pour la fermeture de récipients munis d'une ouverture, comprenant
au moins deux couches, à savoir, une première couche (2) adaptée pour la liaison thermique
le long de tout le périmètre de ladite ouverture (3) du récipient (4) et une deuxième
couche (5) qui est accouplée à la dite première couche (2); une troisième couche (6)
d'adhésif permanent étant interposé entre ladite première couche (2) et ladite deuxième
couche (5); la résistance à la déchirure de ladite première couche (2) étant plus
faible que la force de liaison (10) entre ladite première couche (2) et ladite deuxième
couche (5), là où ladite troisième couche (6) n'est pas présente, et étant plus faible
que la résistance à la séparation de la liaison thermique (10) qui doit être prévue
entre ladite première couche (2) et le récipient (4); la résistance à la séparation
de la liaison thermique (10) étant plus grande que la force de liaison et/ou de cohésion
dudit adhésif permanent, de sorte que ladite première couche (2) se déchire au moment
de la première ouverture du récipient (4), exposant ladite troisième couche (6), et
peut être utilisée pour refermer le récipient (4), caractérisée en ce que ladite troisième couche (6) est limitée exclusivement au niveau d'une partie de la
zone (10) de ladite première couche (2) prévue pour être accouplée audit récipient
(4) par liaison thermique.
2. Structure multi-couches selon la revendication 1, caractérisée en ce que ladite première couche (2) et ladite deuxième couche (5) sont mutuellement accouplées
également hors de la zone de ladite première couche (2) prévue pour être accouplée
audit récipient (4) par liaison thermique et occupée par ladite troisième couche (6).
3. Structure multi-couches selon la revendication 1, caractérisée en ce que la force de cohésion entre ladite troisième couche (6) et ladite deuxième couche
(5) est plus grande que la force de cohésion entre ladite troisième couche (6) et
ladite première couche (2).
4. Structure multi-couches selon l'une ou plusieurs des revendications précédentes, caractérisée en ce que ladite deuxième couche (5) est accouplée à une ou plusieurs couches sur son coté
ne faisant pas face à ladite première couche (2).
5. Structure multi-couches selon l'une ou plusieurs des revendications précédentes, caractérisée en ce que ladite deuxième couche (5) est constitué d'une pellicule en polymère orienté.
6. Structure multi-couches selon l'une ou plusieurs des revendications précédentes, caractérisée en ce que ladite deuxième couche (5) est constitué d'une pellicule barrière.
7. Structure multi-couches selon l'une ou plusieurs des revendications précédentes, caractérisée en ce que ladite deuxième couche (5) est constitué d'une pellicule rigide thermoformable.
8. Structure multi-couches selon l'une ou plusieurs des revendications précédentes, caractérisée en ce que ladite deuxième couche (5) est accouplée avec une pellicule rigide thermoformable
sur son coté ne faisant pas face à ladite première couche (2).
9. Méthode pour produire une structure multi-couche selon l'une ou plusieurs des revendications
précédentes, consistant en l'accouplement mutuel desdites au moins deux couches (2,
5), l'une d'elles étant adaptée pour la liaison thermique, et en l'interposition de
ladite couche (6) d'adhésif permanent entre lesdites deux couches (2, 5), avant leur
accouplement, caractérisée en ce que ladite couche (6) est limitée exclusivement au niveau d'une seule partie de la zone
(10) de ladite couche adaptée pour la liaison thermique prévue pour être accouplée
par liaison thermique à un récipient (4).
10. Méthode selon la revendication 9, caractérisée en ce que lesdites deux couches (2, 5) sont accouplées mutuellement par laminage à chaud.
11. Méthode selon la revendication 9, caractérisée en ce que lesdites deux couches (2, 5) sont accouplées mutuellement par la méthode connue comme
lamination par extrusion.
12. Méthode selon la revendication 9, caractérisée en ce que lesdites deux couches (2, 5) sont accouplées mutuellement en réalisant l'une desdites
deux couches, avec la méthode connue comme enduisage par extrusion, sur l'autre desdites
deux couches (2, 5).