[0001] The present invention relates to a malodor and pesticide counteractant agent and
the fabrication method thereof, particularly to a counteractant agent including its
fabrication method that can effectively decompose pesticides, malodors, and smokes.
[0002] To prevent pest attacks, farmers usually spray pesticides on crops, such as vegetables,
fruits, and tea trees. However, most pesticides, such as Malathion, Iprodine (an organonitrogen/heterocyclic
pesticide widely used for strawberries), and Pyridaben (widely used for tea trees)
are hazardous toward human health. Because pesticides are often organic compounds
and water insoluble, it is difficult to remove them with water. As a result, a portion
of pesticide residues usually remains on the surface of the vegetables, fruits, and
tea leaves. Overdose of pesticide makes farmers sick, vomit, or harmful to their cranial
nerve. The pesticides accumulated in the body induce genetic mutations and could lead
to cancer. The phenomenon of "Cancer Village" appearing in Mainland China results
from the residual pesticides in the foods, which were eaten by the villagers over
a long period of time.
[0003] For crops not harvested by farmers in the safe dates, the problem of pesticide residues
may become serious. As a consequence, the consumers would be harmed seriously. For
example, the residual pesticides in tea leaves may be partially dissolved into hot
water and thus jeopardize consumer's health. Consumers usually rinse vegetables and
fruits with water; yet the cleaning efficiency is poor. Sometimes, consumers wash
vegetables and fruits with saline water; however, the efficacy is lack of a scientific
proof and thus its effect is uncertain. For vegetables and fruits washed with a detergent,
the surfactants and other chemicals in the detergent may remain on the surface of
vegetables and fruits. They could bring about an odd smell and cause a secondary contamination.
[0004] Unpleasant smells often come from malodors and smokes. The sources of malodors are
usually nitrogen- or sulfur-containing compounds, such as amine (body odor and perspiration
odor), trimethylamine (fish odor), hydrogen sulfide (rotten egg smell), and methyl
mercaptan (kitchen garbage odor). The smoke often comes from cigarette. The deodorants
on the market generally function on the basis of the principles of covering malodor
with good odor, absorbing malodor, or neutralizing the acidic/basic molecules of malodors.
The odor-covering type deodorants can cover malodors, but they cannot decompose malodor
molecules; therefore, the malodor still remains partially. The absorption type deodorants
are limited by their absorption capacity. When malodor is too intense or after the
deodorants have been used for a long period of time, the absorption capability of
deodorants may be exhausted. The acid-base neutralizing type deodorants can only be
applied to the compounds that possess acidic or basic property. Some special types
of deodorants, such as citric acid and maleic acid, cannot be used to eliminate mercaptan-based
odors.
[0005] Smoke pollution includes cigarette, barbecue, kitchen smokes, etc. The primary constituent
for cigarette smoke is nicotine, for barbecue smoke is acrylamide, imidazole, and
quinoline as well as for kitchen smoke is usually indene, naphthalene, and phenanthrene.
For further information, please refer to:
Borgerding, M.; Klus, H. Experimental and Toxicologic Pathology 2005, 57, 43-73;
Brage, C.; Yu, Q.; Chen, G.; Sjostrom, K. Biomass and Bioenergy 2000, 18, 87-91;
Preuss, R.; Angerer, H.; Drexler, H. Int. Arch. Occup. Environ. Health 2003, 76, 556-576. All of the smokes mentioned above are hazardous to human body; however, so far on
the market, there is no appropriate agent that can effectively decompose the primary
constituents of smokes.
[0006] A few current technology can effectively decompose pesticides, malodors, or smokes,
the heath of people is being threatened thereby. Accordingly, the present invention
discloses a malodor and pesticide counteractant agent and a fabrication method thereof,
whereby the molecules of pesticides, malodors, and smokes can be decomposed as soon
as those molecules contact the agent of the present invention.
[0007] The primary objective of the present invention is to provide a malodor and pesticide
counteractant agent and a fabrication method thereof, wherein the agent of the present
invention can be fabricated into an aerosol, a detergent, or an additive and used
to decompose pesticides, malodors, and smokes.
[0008] Another objective of the present invention is to provide a malodor and pesticide
counteractant agent and a fabrication method thereof, wherein the detergent fabricated
according to the present invention can be used to clean the residual pesticides on
crops, particularly vegetables and unpeeled fruits.
[0009] The other objective of the present invention is to provide a malodor and pesticide
counteractant agent and a fabrication method thereof, wherein the aerosol fabricated
according to the present invention can effectively decompose the residual pesticides
on crops. The aerosol of the present invention can be used to eliminate body odors,
such as underarm odor, perspiration odor, sole odor, bad breath, hair odor, menstrual
odor as well as odors of animals and pets. The aerosol of the present invention can
be applied directly on daily necessities, air filters, clothes, respirators, masks,
gloves, protective clothes, condoms, and medical devices. The aerosol can also be
applied to the spaces polluted by odors or smokes, such as the interior and exterior
of living rooms, vehicle compartments, fish bowls, bathrooms, restaurants, hotels,
kitchens, barbecues, cybercafés, and smoking areas.
[0010] The malodor and pesticide counteractant agent of the present invention comprises:
a catalytic ionic compound, a buffering agent, and a mixture of a reducing coenzyme
and an oxidizing agent/an ionic compound/a sulfide, and the proportion of these constituents
by weight is 1: 40~4,000 : 2~200. The general formula of the catalytic ionic compound
is M
+aX
-b, wherein a = 1~6 and b = 1~6; M is selected from the group consisting of Ni, Co,
Mg, Fe, Cu, Mn, Cr, Ca, Ti, Al, Sb, Sn, Pb, Zn, Pt, Pd, Os, Ru, Cd, Rh, Ir, and NH
4; X is selected from the group consisting of chloride, bromide, iodide, nitrate, sulfate,
sulfite, acetate, oxalate, carboxylate, succinate, phosphate, pyrophosphate, perchlorate,
gluconate, ascorbate, ethylenediamine tetraacetate, fumarate, and lactate. The general
formula of the buffering agent is RY
z, wherein z=1 or 2; R is selected from the group consisting of Li, Na, K, Mg, Ca,
and Zn; Y is selected from the group consisting of chloride, nitrate, sulfate, carboxylate,
hydrogen carbonate, phosphate, dihydrogen phosphate, hydrogen phosphate, and oxalate.
Among the mixture of a reducing coenzyme and an oxidizing agent/an ionic compound/a
sulfide, the reducing coenzyme is selected from the group consisting of FMNH
2 (reduced flavin mononucleotide), FADH
2 (reduced flavin adenine dinucleotide), NADH (reduced nicotinamide adenine dinucleotide),
and NADPH (reduced nicotinamide adenine dinucleotide phosphate); the oxidizing agent
is selected from the group consisting of hydrogen peroxide and quinone-based compounds,
such as azulenequinone and its derivatives.; the general formula of the ionic compound
is NX, wherein N is selected from the group consisting of Li, Na, and K, and X is
selected from the group consisting of chloride, bromide, iodide, sulfite, acetate,
succinate, pyrophosphate, perchlorate, gluconate, ascorbate, ethylenediamine tetraacetate,
fumarate, and lactate; the general formula of the sulfide is RSH, wherein R is an
aryl group, an alkyl group, or an aralkyl group with R = C
1~C
6, such as cysteine, reduced glutathione, dithiothreitol, and homocysteine.
[0011] These and other objects and advantages of the present invention will no doubt become
obvious to those of ordinary skill in the art after having read the following detailed
description of the preferred embodiment, which is illustrated in the various drawing
figures.
- Fig. 1
- is a diagram showing the relationship between the reaction time and the decomposition
extents of pesticides, including Terbufos, Acephate, and Hexaconazole by tap water,
10% salt solution, and the agent of the present invention ;
- Fig. 2
- is a bar graph showing the relationship between the reaction time and the destruction
extents of the nitrogen- or sulfur-containing odor compounds-Fenobucard, Hexaconazole,
Terbufos, and Diazinon-by the agent of the present invention;
- Fig. 3
- is a bar graph showing the relationship between the destruction extents of the primary
constituents of smokes-nicotine, indene, and naphthalene-and the dilution factors
of the agent of the present invention with the initial concentration thereof being
0.5%; and
- Fig. 4
- is a diagram showing the relationship between the reaction time and the destruction
extents of nicotine by different concentrations of the agent of the present invention.
[0012] The present invention discloses a malodor and pesticide counteractant agent and a
fabrication method thereof. The agent of the present invention may be fabricated into
an aerosol, a detergent, or an additive for decomposing pesticides, malodors, and
smokes. As a detergent, it can be used to remove the pesticide residues on the surface
of fruits and vegetables. As an aerosol, it can be sprayed on the unharvested crops
to decompose the residual pesticides. In addition, the aerosol can be applied on daily
usage products, air filters, clothes, respirators, masks, gloves, protective clothes,
condoms, and medical devices. Moreover, the aerosol can be sprayed on various areas
of the human body to eliminate body odors, such as the hands, feet, head, underarms,
reproductive organ, and oral cavity. The aerosol is also able to eliminate the odors
of animals and pets. Furthermore, one can apply the aerosol to the spaces polluted
by odors or smokes, such as the interior and exterior of living rooms, vehicle compartments,
fish bowls, bathrooms, restaurants, hotels, kitchens, barbecues, cybercafés, and smoking
areas.
[0013] The malodor and pesticide counteractant agent is prepared by use of three primary
constituents, which are mixed in different concentrations and proportions and then
fabricated into different forms. The constituents of the malodor and pesticide counteractant
agents of the present invention include: (A) a catalytic ionic compound, (B) a buffering
agent, and (C) a mixture of a reducing coenzyme and an oxidizing agent/an ionic compound/a
sulfide. The proportion of the abovementioned constituents by weight is (A) : (B)
: (C) = 1 : 40~4,000 : 2-200, and the preferable proportion is (A) : (B) : (C) = 1:
1,200~1,500 : 10~50. Those constituents are to be described in detail below.
- (A) Catalytic ionic compound: The general formula thereof is M+aX-b, wherein a = 1~6 and b = 1~6; M is selected from the group consisting of Ni, Co,
Mg, Fe, Cu, Mn, Cr, Ca, Ti, Al, Sb, Sn, Pb, Zn, Pt, Pd, Os, Ru, Cd, Rh, Ir, and NH4; X is selected from the group consisting of chloride, bromide, iodide, nitrate, sulfate,
sulfite, acetate, oxalate, carboxylate, succinate, phosphate, pyrophosphate, perchlorate,
gluconate, ascorbate, ethylenediamine tetraacetate, fumarate, and lactate.
- (B) Buffering agent: The general formula thereof is RYz, wherein z =1 or 2; R is selected from the group consisting of Li, Na, K, Mg, Ca,
and Zn; Y is selected from the group consisting of chloride, nitrate, sulfate, carboxylate,
hydrogen carbonate, phosphate, dihydrogen phosphate, hydrogen phosphate, and oxalate.
- (C) Mixture of a reducing coenzyme and an oxidizing agent/an ionic compound/a sulfide:
The reducing coenzyme thereof is selected from the group consisting of FMNH2, FADH2, NADH, and NADPH. The oxidizing agent thereof is selected from the group consisting
of hydrogen peroxide, quinone-based compounds, such as azulenequinone and its derivatives.
The general formula of the ionic compound is NX, wherein N is selected from the group
consisting of Li, Na, and K; X is selected from the group consisting of chloride,
bromide, iodide, sulfite, acetate, succinate, pyrophosphate, perchlorate, gluconate,
ascorbate, ethylenediamine tetraacetate, fumarate, and lactate. The general formula
of the sulfide is RSH, wherein R is an aryl group, an alkyl group, or an aralkyl group
with R=C1~C6, such as cysteine, reduced glutathione, dithiothreitol, and homocysteine.The malodor
and pesticide counteractant agent of the present invention is obtained by fully mixing
the aforementioned three constituents in the proportion mentioned above.
[0014] The malodor and pesticide counteractant agent of the present invention can be used
to decompose the molecules of pesticides, odors, and smokes. The agent of the present
invention can be fabricated into an aerosol and sprayed onto the surface of the objects
or to the air of the surroundings, and the agent can instantly react with oxygen and
then decompose the chemical components contained in pesticides, odors, and smokes.
The agent of the present invention can be fabricated into a detergent or an additive
and used to decompose the molecules of pesticides or odors in solutions.
[0015] The active time of the agent of the present invention correlates closely with the
proportion, concentration, and dosage of the agent. The active time of the agent sprayed
on the surface of crops lasts as long as 3~7 days. The active time of the agent sprayed
on the objects or to the air of the surroundings depends on the characteristics of
the surroundings and may reach to 12~72 hours. After the agent is sprayed on daily
usage products, clothes, respirators, masks, gloves, protective clothes, condoms,
or medical devices, the active time is 6~12 hours. When the agent is used to eliminate
the underarm odor, perspiration odor, sole odor, bad breath, hair odor, or menstrual
odor of the human body, the active time is 4~8 hours.
[0016] Below, an embodiment is used to exemplify the fabrication method of the agent of
the present invention. Thereby, the person skilled in the art would fully understand
and make use of the present invention according to those described in the specification.
However, the scope of the present invention is not to be limited by the exemplification
anyhow.
[0017] The fabrication method of the present invention includes the following steps:
Step 1, preparing Constituent (A): 0.50 grams of ammonium nickel sulfate is added
into 500 mL of Reverse Osmosis (R.O.) water, and the solution is stirred for 15 min
at the ambient temperature until the solution is clear and does not contain any deposition.
Step 2, preparing Constituent (B): 15 grams of sodium hydrogen phosphate and 15 grams
of sodium dihydrogen phosphate are sequentially added into 9.0 L of R.O. water, and
the solution is fully stirred; then, 120 g of sodium chloride, 40 g of potassium hydrogen
carbonate, 5.0 g of calcium sulfate, and 5.0 g of magnesium chloride are sequentially
added into the solution, which is quickly stirred for 60 min at the ambient temperature
until no suspended matter appears.
Step 3, preparing Constituent (C): 10 mL of 3.0% hydrogen peroxide is added into 500
mL of R.O. water, and then 5.0 g of a quinone derivative is added into the solution;
the solution is stirred for 30 min at the ambient temperature until the solution is
homogeneous; 2.0 g of coenzyme NADPH is added into the solution, and the solution
is stirred for 20 min until the solution is clear.
Step 4: Constituent (A) is added into Constituent (C), and the solution is stirred
for 15 min at the ambient temperature; subsequently, Constituent (B) is added into
the solution of Constituent (A) and Constituent (C), and the solution is fully stirred
for 20 min; thus, the agent of the present invention is obtained. The agent should
be packed in airtight containers, which have a cap or a jet nozzle, and it is preferred
that no air exists in the container. The agent of the present invention can be sprayed
onto the surface of objects or into the 3-dimensional space of the surroundings, and
the concentration of the agent in the aerosol solution is preferred to be 10-4~10-6 wt%. When the agent of the present invention is used as a detergent or an additive,
the concentration in the washing solution is higher than that in the aerosol solution
and is preferred to be 10-1~10-4 wt%.
[0018] The technical contents have been stated above. Three experiments for verifying the
efficacies of the agent of the present invention in decomposing pesticides, odors,
and smokes are to be described in detail below.
Experiment 1
[0019] Experiment 1 is to verify the efficacy of the agent fabricated according to the abovementioned
embodiment in decomposing pesticides; tap water and a 10% salt solution are used for
comparison of the decomposing rate in the this experiment. The pesticides tested in
this experiment include seven groups of pesticides with the total number thereof amounting
to 17 compounds. The pesticides tested in this experiment include: organophosphorous
pesticides, such as Diazinon, Terbufos, Acephate, Glyphosate, Phosmet, and Mevinphos;
organonitrogen/heterocyclic pesticides, such as Benomyl, Metalaxyl, and Pymetrozine;
carbamate pesticides, such as Methomyl, Fenobucard, and Carbendazim; urea-type pesticides
(herbicides), such as Pencycuron; triazole pesticides, such as Hexaconazole; dithiocarbamates
pesticides (germicides), such as Thiophanate-methyl and Cartap; and other type pesticides,
such as Thiabendazole.
[0021] In this experiment, 10 mL of the agent of the present invention and 10 mL of a 10
ppm solution of each abovementioned pesticide are mixed to react for 5.0 min. Then,
High Performance Liquid Chromatography (HPLC) is used to determine the extents of
the pesticide decomposition. Tap water and a 10% salt solution are also allowed to
react with the same pesticide solutions. The experimental results of tap water and
the 10% salt solution are used to compare with the experimental results of the agent
of the present invention. From the experimental results, it shows that the agent of
the present invention has a superior decomposing effect on pesticides. The decomposing
rate of the agent of the present invention is 2,300~14,000 times than that of tap
water and is 1,900~11,000 times than that of 10% salt solution. Therefore, the effect
of the present invention in decomposing pesticides is much greater than other conventional
methods.
[0022] Fig. 1 and Table 1 indicate that the agent of the present invention can indeed decompose
pesticides. Among these seventeen pesticides, the agent of the present invention exhibits
the best decomposition results on Terbufos, Acephate, and Hexaconazole.
Table 1. The experimental results of the agent of the present invention decomposing
Terbufos, Acephate, and Hexaconazole.
Pesticides |
The proportion of the decomposed pesticide after 5 min of reaction |
Rate ratio |
PIa |
Tap water |
10% Salt solution |
PIa/ Tap water |
PIa/ Salt solution |
Terbufos |
93.4% |
0.007% |
0.008% |
13,343 |
11,675 |
Acephate |
83.7% |
0.009% |
0.010% |
9,300 |
8,370 |
Hexaconazole |
73.1% |
0.007% |
0.007% |
10,443 |
10,443 |
aPI = the present invention |
Experiment 2
[0023] Experiment 2 is to verify efficacy of the agent fabricated according to the abovementioned
embodiment in destroying the molecules of malodors. The decomposing rates are compared
in this experiment. The nitrogen- and sulfur-containing compounds, which have strong
odor, are used as targeting samples, such as Terbufos, Diazinon, Hexaconazole, and
Fenobucard. The structural formula of these odor compounds are shown below:
[0024] In this experiment, 7.5 mL of a 10 ppm solution of the nitrogen-or sulfur-containing
odor compound is allowed to react with 2.5 mL of the agent of the present invention
for 1.0 min, 3.0 min, and 5.0 min, respectively. HPLC is used to determine the destruction
extents of odor compounds and the results are shown in Fig. 2.
[0025] Fig. 2 shows that the agent of the present invention can effectively decompose the
nitrogen- or sulfur-containing odor molecules of Terbufos, Diazinon, Hexaconazole,
and Fenobucard in 1.0 min, 3.0 min, and 5.0 min, respectively. After 5.0 min of the
reaction time, the agent of the present invention destroyed 91% of Terbufos, 87% of
Diazinon, 85% of Hexaconazole, and 76% of Fenobucard. Therefore, the agent of the
present invention can indeed decompose odor molecules in an efficient way.
Experiment 3
[0026] Experiment 3 is to verify the efficiency of the agent fabricated according to the
abovementioned embodiment in destroying the primary molecules of smokes, and the decomposing
rates are compared. In this experiment, nicotine, indene, and naphthalene are used
as the testing samples. They respectively represent the major components in cigarette
smoke, barbecue smoke, and kitchen smoke. The solutions with different concentrations
of the agent of the present invention are used to react with nicotine-the primary
constituent of cigarette-in order to obtain the destruction rates of different concentrations
of the agent.
[0028] In this experiment, 9.9 mL of a 100 ppm solution of each abovementioned smoke constituent
is allowed to react with 0.10 mL of the twenty times dilution and one hundred times
dilution, respectively, of the agent of the present invention for 3.0 min; then Gas
Chromatography (GC) was used to determine the extents of the remaining primary constituents
of smokes. The experimental results are shown in Figs. 3 and 4.
[0029] Fig. 3 shows that the agent of the present invention decomposed the primary constituents
of cigarette smoke (i.e., nicotine), barbecue smoke (i.e., indene), and kitchen smoke
(i.e., naphthalene). The twenty times dilution of the agent of the present invention
destroyed >90% the primary constituents of the abovementioned smokes in 3.0 min; especially,
the destruction extent of the primary constituent of cigarette smoke-nicotine-was
as high as 99%. Furthermore, Fig. 4 indicates that the agent of the present invention
effectively decomposed nicotine in 2.0 min when the concentration of the agent of
the present invention is twenty times diluted. Its destruction extent is >99%. Therefore,
the agent of the present invention can indeed decompose the molecules of smokes efficiently.
[0030] In summary, when the molecules of pesticides, malodors, and smokes react with the
malodor and pesticide counteractant agent of the present invention, these molecules
were rapidly decomposed by the constituents of the agent of the present invention.
Therefore, the present invention achieves the objectives of eliminating pesticides,
malodors, and smokes.
[0031] These embodiments described above are to clarify the present invention to enable
the persons skilled in the art to understand, to make, and to use the present invention.
However, it is not intended to limit the scope of the present invention, and any equivalent
modification and variation according to the scope of the present invention is to be
also included within the scope of the claims of the present invention.
1. A malodor and pesticide counteractant agent, comprising:
(A) a catalytic ionic compound having a general formula M+aX-b, wherein a = 1~6 and b = 1~6; M is selected from the group consisting of Ni, Co,
Mg, Fe, Cu, Mn, Cr, Ca, Ti, Al, Sb, Sn, Pb, Zn, Pt, Pd, Os, Ru, Cd, Rh, Ir, and NH4; X is selected from the group consisting of chloride, bromide, iodide, nitrate, sulfate,
sulfite, acetate, oxalate, carboxylate, succinate, phosphate, pyrophosphate, perchlorate,
gluconate, ascorbate, ethylenediamine tetraacetate, fumarate, and lactate;
(B) a buffering agent having a general formula RYz, wherein z =1 or 2; R is selected from the group consisting of Li, Na, K, Mg, Ca,
and Zn; Y is selected from the group consisting of chloride, nitrate, sulfate, carboxylate,
hydrogen carbonate, phosphate, dihydrogen phosphate, hydrogen phosphate, and oxalate;
and
(C) a mixture of a reducing coenzyme and an oxidizing agent/an ionic compound/a sulfide;
wherein a proportion by weight of constituents is (A) : (B) : (C) = 1: 40~4,000 :
2~200.
2. The malodor and pesticide counteractant agent according to Claim 1, wherein said proportion
by weight of said constituents is preferred to be (A) : (B) : (C) = 1: 1,200~1,500
: 10~50.
3. The malodor and pesticide counteractant agent according to Claim 1, wherein said reducing
coenzyme is selected from the group consisting of FMNH2 (reduced flavin mononucleotide), FADH2 (reduced flavin adenine dinucleotide), NADH (reduced nicotinamide adenine dinucleotide),
and NADPH (reduced nicotinamide adenine dinucleotide phosphate); said oxidizing agent
is selected from the group consisting of hydrogen peroxide and quinone-based compounds.
4. The malodor and pesticide counteractant agent according to Claim 1, wherein the general
formula of said ionic compound is NX; N is selected from the group consisting of Li,
Na, and K; X is selected from the group consisting of chloride, bromide, iodide, sulfite,
acetate, succinate, pyrophosphate, perchlorate, gluconate, ascorbate, ethylenediamine
tetraacetate, fumarate, and lactate.
5. The malodor and pesticide counteractant agent according to Claim 1, wherein the general
formula of said sulfide is RSH, and R is an aryl group, an alkyl group, or an aralkyl
group with R = C1~C6.
6. The malodor and pesticide counteractant agent according to Claim 1, wherein said sulfide
is selected from the group consisting of cysteine, reduced glutathione, dithiothreitol,
and homocysteine.
7. The malodor and pesticide counteractant agent according to Claim 1, which may be fabricated
into a detergent, an additive, or an aerosol.
8. The malodor and pesticide counteractant agent according to Claim 7, wherein said detergent
may be used to clean fruits and vegetables; said aerosol may be sprayed onto unharvested
crops; said aerosol may also be sprayed to the interior and exterior of living rooms,
vehicle compartments, fish bowls, bathrooms, restaurants, hotels, hospitals, kitchens,
barbecues, cybercafés, and smoking areas; said aerosol may also be sprayed to daily
usage products, air filters, clothes, respirators, masks, gloves, protective clothes,
condoms, and medical devices; said aerosol may also be sprayed to pets and various
areas of the human body.
9. A fabrication method of a malodor and pesticide counteractant agent, including the
following steps:
providing a catalytic ionic compound, a buffering agent, and a mixture of a reducing
coenzyme and an oxidizing agent/ionic compound/sulfide, wherein the general formula
of said catalytic ionic compound is M+aX-b; a = 1~6 and b = 1~6; M is selected from the group consisting of Ni, Co, Mg, Fe,
Cu, Mn, Cr, Ca, Ti, Al, Sb, Sn, Pb, Zn, Pt, Pd, Os, Ru, Cd, Rh, Ir, and NH4; X is selected from the group consisting of chloride, bromide, iodide, nitrate, sulfate,
sulfite, acetate, oxalate, carboxylate, succinate, phosphate, pyrophosphate, perchlorate,
gluconate, ascorbate, ethylenediamine tetraacetate, fumarate, and lactate; the general
formula of said buffering agent is RYz, and z=1 or 2; R is selected from the group consisting of Li, Na, K, Mg, Ca, and
Zn; Y is selected from the group consisting of chloride, nitrate, sulfate, carboxylate,
hydrogen carbonate, phosphate, dihydrogen phosphate, hydrogen phosphate, and oxalate;
and
fully mixing said catalytic ionic compound, said buffering agent, and said mixture
of a reducing coenzyme and an oxidizing agent/ionic compound/sulfide according to
a proportion by weight of 1: 40~4,000 : 2~200.
10. The fabrication method of a malodor and pesticide counteractant agent according to
Claim 9, wherein the preferable proportion by weight of said catalytic ionic compound,
said buffering agent, and said mixture of a reducing coenzyme and an oxidizing agent/ionic
compound/sulfide is 1: 1,200~1,500 : 10~50.
11. The fabrication method of a malodor and pesticide counteractant agent according to
Claim 9, wherein said reducing coenzyme is selected from the group consisting of FMNH2, FADH2, NADH, and NADPH; and said oxidizing agent is selected from the group consisting
of hydrogen peroxide and quinone-based compounds.
12. The fabrication method of a malodor and pesticide counteractant agent according to
Claim 9, wherein the general formula of said ionic compound is NX; N is selected from
the group consisting of Li, Na, and K; X is selected from the group consisting of
chloride, bromide, iodide, sulfite, acetate, succinate, pyrophosphate, perchlorate,
gluconate, ascorbate, ethylenediamine tetraacetate, fumarate, and lactate.
13. The fabrication method of a malodor and pesticide counteractant agent according to
Claim 9, wherein the general formula of said sulfide is RSH, and R is an aryl group,
an alkyl group, or an aralkyl group with R = C1~C6.
14. The fabrication method of a malodor and pesticide counteractant agent according to
Claim 9, wherein said sulfide is selected from the group consisting of cysteine, reduced
glutathione, dithiothreitol, and homocysteine.