[0001] The present invention relates to improving fluoroelastomer seal compatibility and
dispersancy in an internal combustion engine. Moreover, the present invention relates
to the use of a carboxylated detergent-dispersant to render nitrogen-containing dispersants
contained in lubricating oils compatible with fluoroelastomer seals used in internal
combustion engines.
BACKGROUND OF THE INVENTION
[0002] It is known to employ nitrogen-containing dispersants and/or detergents in the formulation
of crankcase lubricating oil compositions. Many of the known dispersant/detergent
compounds are based on the reaction of an alkenylsuccinic acid or anhydride with an
amine or polyamine to produce an alkenylsuccinimide or an alkenylsuccinamic acid as
determined by selected conditions of reaction.
[0003] A continuing problem in the art of lubrication is to provide lubricating oil compositions
which satisfy the demands imposed upon them by the original equipment manufacturers.
One such requirement is that lubricants not contribute to premature deterioration
of seals, clutch face plates or other parts made from elastomers such as fluoro, acrylic,
silicone, nitrile and the like. Elastomers are increasingly being used in fabricating
the flexible seals which are used in internal combustion engines. These seals are
used, for example, to prevent leakage of lubricants at the point where moving parts,
such as a crankshaft, leave the engine. Any substantial leakage of lubricant from
the engine is obviously undesirable. Unfortunately, elastomer seals are subject to
discoloration and mechanical deterioration when used in engines which are lubricated
with lubricating oils containing polyamine dispersants, i.e., nitrogen-containing
dispersants. The polyamine dispersants interact with the elastomer seals, causing
the seals to swell and to lose mechanical and dimensional integrity. The rate of attack
of the elastomer seals by a polyamine dispersant appears to be directly proportional
to the concentration of polyamine dispersant and to the operating temperature of the
engine. As the engine operating temperature rises, the rate of decomposition of the
seal rises proportionately. As interaction of the dispersant with the seal continues,
the mechanical strength and dimensional integrity of the seal increasingly deteriorates
until the seal fails to prevent the leakage of lubricant from the engine.
[0004] Accordingly, qualification tests have been established whereby the effect of a lubricant
composition on seal-type materials is measured under a particular set of controlled
laboratory bench test conditions. Contemporary test methods for evaluating elastomer
compatibility of lubricants and functional fluids include, but not limited to, the
Volkswagen PV 3344 Elastomer Compatibility Test, the ACEA Oil-Elastomer Seal Test
(CEC L-39-T-87), the DaimlerChrysler Oil-Elastomer Seal Test (VDA 675301-"Closed Test
Cup") and the API Cl-4 Elastomer test.
[0005] Generally, known succinimides useful as dispersants and/or detergents are not always
compatible with elastomer seals when present in lubricating oil compositions at concentration
levels necessary to be effective in controlling engine deposits. Of the nitrogenated
components normally used in lubricants, bis-succinimides with dispersant action have
proved particularly critical towards elastomers, either when used alone or in combination
with, for example, viscosity index improvement polymers of dispersant action containing
nitrogenated monomers. In this respect, both these classes of additive contain strongly
basic amino groups (primary and/or secondary and/or tertiary).
[0006] The literature describes various processes which can be used to overcome the aforesaid
drawback. Many known process involve post-treating various nitrogen-containing dispersants
with various substances to reduce reactivity with elastomer seals.
[0007] U.S. Patent No. 4,379,064 teaches mild oxidation of nitrogenated dispersants to make the dispersant unreactive
towards fluoroelastomers. However, the process results in an excessive decrease (50-90%)
in the initial TBN (Total Base Number).
[0008] U.S. Patent No. 4,873,009 is also concerned, in part, with the use of succinimides as lube oil additives. This
patent teaches in Col. 2, lines 28 et seq. that lube additives prepared from "long
chain aliphatic polyamines", i.e., succinimides, "are excellent lube oil additives".
It teaches such succinimides are "inferior to additives where the alkylene polyamine
is hydroxyalkylated" (Col. 2, lines 31-32). Such hydroxyalkylated polyamine- based
succinimides, however, "have the drawback that they tend to attack engine seals particularly
those of the fluorocarbon polymer type" (Col. 2, lines 35-37). This patent solves
the fluoroelastomer seal compatibility problem by directly borating the hydroxylated
polyamine-based succinimide.
[0009] Furthermore,
U.S. Patent No. 4,873,009 teaches it would be desirable for the additive to have a relatively high concentration
of N-hydroxyalkyl moieties because the more N-hydroxyalkyl substituents, the cleaner
the engine. However, it also teaches that the more amino groups in the polyamine,
the greater the degradation of fluoroelastomer seal, and that alkylene amines containing
more than 2 amino groups cannot be utilized (Col. 2, lines 50-62).
[0010] U.S. Patent No. 4,940,552 relates to polyamine dispersants passivated toward fluorohydrocarbon compositions.
The dispersants described comprise the reaction product of a Mannich polyamine dispersant
with an amount of maleic anhydride sufficient to reduce the reactivity with fluorohydrocarbons
of the dispersant.
[0011] U.S. Patent No. 5,356,552 teaches succinimide additives post-treated with a cyclic carbonate having fluoroelastomer
seal compatibility and for concentration levels at which fluoroelastomer seal compatibility
is achieved, possess improved dispersancy and/or detergency.
[0012] U.S. Patent No. 6,124,247 teaches that dispersants of mono-succinimides or bis-succinimides are even more effective
if their relative basic nitrogen content is high, i.e. insofar as the number of nitrogen
atoms of the polyamine is larger than the number of succinic anhydride groups substituted
by a polyisobutenyl group. However, the higher the basic nitrogen content of these
dispersants, the more they favor the attack of the fluoroelastomer seal used in modern
engines, because the basic nitrogen tends to reach with the acidic hydrogen atoms
of this type of seal, and this attack results in the formation of cracks in the elastomer
surface and the loss of other physical properties sought in this type of material.
The patent provides that by using lubricating oil compositions containing a dispersant
of mono-succinimide or bis-succinimide type, post-treated or not, in combination with
a borated glycerol ester, one obtains a composition compatible with fluorocarbon elastomers.
[0013] U.S. Patent No. 6,162,770 (and the related
US-B-6262001 and
EP-A-0933417) teaches a process for preparing an unsulfurized, alkali metal-free, detergent-dispersant
composition having from 40% to 60% alkylphenol, from 10% to 40% alkaline earth alkylphenate,
and from 20% to 40% alkaline earth single aromatic-ring alkylsalicylate. This composition
may have an alkaline earth double aromatic-ring alkylsalicylate as long as the mole
ratio of single-ring alkylsalicylate to double aromatic-ring alkylsalicylate is at
least 8:1. This composition may be produced by the three-step process involving neutralization
of alkylphenols, carboxylation of the resulting alkylphenate, and filtration of the
product of the carboxylation step. The detergent-dispersant produced by the method
can be used in an engine lubricating composition to improve antioxidant properties,
high temperature deposit control, and black sludge control. The patent does not mention
that the detergent-dispersant produced provides improved elastomer seal compatibility.
[0014] Clearly, a need exists to provide highly effective nitrogen-containing dispersants
which provide dispersancy to the lubricating oil while at the same time not causing
the deterioration of elastomer seals, such as, for example, fluoro, acrylic, silicone,
nitrile and the like, and the associated leak of lubricant.
SUMMARY OF THE INVENTION
[0015]
The present invention is directed to the use of a carboxylated detergent-dispersant
obtained by:
- (i) neutralizing alkylphenols using an alkaline earth base in the presence of at least
one carboxylic acid that contains from one to four carbon atoms but in the absence
of alkali base, dialcohol, and monoalcohol, forming an intermediate product; and
- (ii) carboxylating the intermediate product using carbon dioxide so that at least
20 mole percent of the original alkylphenol starting material has been converted to
alkaline earth metal single aromatic-ring hydrocarbyl salicylate; and
[0016] in a lubricating oil composition comprising a major amount of a base oil of lubricating
oil viscosity and a nitrogen-containing dispersant which is an alkyl or alkenyl succinimide,
or mixtures of such dispersants to improve seal compatibility in a lubricating oil
composition in an internal combustion engine.
[0017] Alkenyl succinimides are preferred. Bis-succinimides are more preferred.
[0018] Among other factors, the present invention is based on the discovery that a certain
carboxylated detergent-dispersant improves fluoroelastomer seal compatibility of lubricating
oil compositions containing nitrogen-containing dispersants.
DETAILED DESCRIPTION OF THE INVENTION
DEFINITIONS
[0019] Prior to discussing the present invention in detail, the following terms will have
the following meanings unless expressly stated to the contrary.
[0020] The term "alkylphenol" means a phenol group having one or more alkyl substituents;
at least one of which has a sufficient number of carbon atoms to impart oil solubility
to the phenol.
[0021] The term "alkaline earth metal" means calcium, barium, magnesium, strontium, potassium,
sodium, and lithium.
[0022] The term "alkaline earth alkylphenate" means an alkaline earth metal salt of an alkylphenol.
[0023] The term "alkaline earth alkylsalicylate" means an alkaline earth metal salt of an
alkyl salicylic acid.
[0024] The term "alkaline earth single aromatic-ring alkylsalicylate" means an alkaline
earth alkylsalicylate having only one alkyl salicylic anion per each alkaline earth
metal base cation. Thus one mole of alkaline earth single aromatic-ring alkylsalicylate
will contain one mole of aromatic ring and one mole of alkaline earth base cation.
Thus, a calcium single aromatic-ring alkylsalicylate would have one aromatic ring
for each calcium ion.
[0025] The term "alkaline earth double aromatic-ring alkylsalicylate" means an alkaline
earth alkylsalicylate having two alkyl salicylic anions per each alkaline earth metal
base cation. Thus one mole of alkaline earth double aromatic-ring alkylsalicylate
will contain two moles of aromatic rings and one mole of alkaline earth base cation.
Thus, a calcium double aromatic-ring alkylsalicylate would have two aromatic rings
for each calcium ion.
[0026] The term "succinimide" is understood in the art to include imide species which are
formed by the reaction of a succinic anhydride with an amine and is so used herein.
The predominant product, is succinimide and this term has been generally accepted
as meaning the product of a reaction of an alkenyl- or alkylsubstituted succinic acid
or anhydride with a polyamine.
[0027] The term "Total Base Number" or "TBN" refers to the amount of base equivalent to
milligrams of KOH in l gram of sample. Thus, higher TBN numbers reflect more alkaline
products and therefore a greater alkalinity reserve. The TBN of a sample can be determined
by ASTM D 2896 or any other equivalent procedure.
[0028] Unless otherwise specified, all percentages are in weight percent and all molecular
weights are number average molecular weights.
BASE OIL OF LUBRICATING VISCOSITY
[0029] The base oil of lubricating viscosity may be mineral oils or synthetic oils. A base
oil having a viscosity of at least about 2.5 cSt at about 40°C and a pour point below
about 20°C, preferably at or below 0°C is desirable. The base oils may be derived
from synthetic or natural sources. Mineral oils for use as the base oil in this invention
include, for example, paraffinic, naphthenic and other oils that are ordinarily used
in lubricating oil compositions. Synthetic oils include, for example, both hydrocarbon
synthetic oils and synthetic esters and mixtures thereof having the desired viscosity.
[0030] Hydrocarbon synthetic oils may include, for example, oils prepared from the polymerization
of alpha olefins, i.e., polyalphaolefin or PAO, or from hydrocarbon synthesis procedures
using carbon monoxide and hydrogen gases such as in a Fisher-Tropsch process. Useful
synthetic hydrocarbon oils include liquid polymers of alpha olefins having the proper
viscosity. Especially useful are the hydrogenated liquid oligomers of about C
6 to about C
12 alpha olefins such as 1-decene trimer. Likewise, alkyl benzenes of proper viscosity,
such as didodecyl benzene, can be used. Useful synthetic esters include the esters
of monocarboxylic acids and polycarboxylic acids, as well as mono-hydroxy alkanols
and polyols. Typical examples are didodecyl adipate, pentaerythritol tetracaproate,
di-2-ethylhexyl adipate, dilaurylsebacate, and the like. Complex esters prepared from
mixtures of mono and dicarboxylic acids and mono and dihydroxy alkanols can also be
used. Blends of mineral oils with synthetic oils are also useful.
CARBOXYLATED DETERGENT-DISPERSANT ADDITIVE
[0031] The lubricating oil composition comprises a carboxylated detergent-dispersant additive
(also referred to herein as "carboxylate" or "carboxylated detergent") made by the
following process.
A. Neutralization Step
[0032] In the first step, alkylphenols are neutralized using an alkaline earth base in the
presence of at least one C
1 to about C
4 carboxylic acid. This reaction is carried out in the absence of alkali base, and
in the absence of dialcohol or monoalcohol.
[0033] The alkylphenols contain up to 98% of linear alkylphenol (preferably up to 35% linear
alkylphenol) in mixture with up to 15% of branched alkylphenol. Preferably, the linear
alkyl radical contains about 12 to about 40 carbon atoms, more preferably about 18
to about 30 carbon atoms. The branched alkyl radical contains at least nine carbon
atoms, preferably about 9 to about 24 carbon atoms, more preferably about 10 to about
15 carbon atoms.
[0034] The use of an alkylphenol containing up to 35% of long linear alkylphenol (from about
18 to about 30 carbon atoms) is particularly attractive because a long linear alkyl
chain promotes the compatibility and solubility of the additives in lubricating oils.
However, the presence of relatively heavy linear alkyl radicals in the alkylphenols
makes the latter less reactive than branched alkylphenols, hence the need to use harsher
reaction conditions to bring about their neutralization by an alkaline earth base.
[0035] Branched alkylphenols can be obtained by reaction of phenol with a branched olefin,
generally originating from propylene. They consist of a mixture of monosubstituted
isomers, the great majority of the substituents being in the para position, very few
being in the ortho position, and hardly any in the meta position. That makes them
relatively reactive towards an alkaline earth base, since the phenol function is practically
devoid of steric hindrance.
[0036] On the other hand, linear alkylphenols can be obtained by reaction of phenol with
a linear olefin, generally originating from ethylene. They consist of a mixture of
monosubstituted isomers in which the proportion of linear alkyl substituents in the
ortho, para, and meta positions is much more uniformly distributed. This makes them
much less reactive towards an alkaline earth base since the phenol function is much
less accessible due to considerable steric hindrance, due to the presence of closer
and generally heavier alkyl substituents.
[0037] The alkaline earth bases that can be used for carrying out this step include the
oxides or hydroxides of calcium, magnesium, barium, or strontium, and particularly
of calcium oxide, calcium hydroxide, magnesium oxide, and mixtures thereof. In one
embodiment, slaked lime (calcium hydroxide) is preferred.
[0038] The C
1 to about C
4 carboxylic acids used in this step include formic, acetic, propionic and butyric
acid, and may be used alone or in mixture. Preferably, a mixture of acids is used,
most preferably a formic acid/acetic acid mixture. The molar ratio of formic acid/acetic
acid should be from about 0.2:1 to about 100:1, preferably between about 0.5:1 and
about 4:1, and most preferably 1:1. The carboxylic acids act as transfer agents, assisting
the transfer of the alkaline earth bases from a mineral reagent to an organic reagent.
[0039] The neutralization operation is carried out at a temperature of at least 200 °C.,
preferably at least 215 °C., and, more preferably, at least 240 °C. The pressure is
reduced gradually below atmospheric in order to distill off the water of reaction.
Accordingly the neutralization should be conducted in the absence of any solvent that
may form an azeotrope with water. Preferably, the pressure is reduced to no more than
7,000 Pa (70 mbars). The quantities of reagents used should correspond to the following
molar ratios:
- (1) alkaline earth base/alkyl phenol of about 0.2:1 to about 0.7:1, preferably about
0.3:1 to about 0.5:1; and
- (2) carboxylic acid/alkylphenol of about 0.01:1 to about 0.5:1, preferably from about
0.03:1 to about 0.15:1.
[0040] Preferably, at the end of this neutralization step the alkylphenate obtained is kept
for a period not exceeding fifteen hours at a temperature of at least 215 °C. and
at an absolute pressure of between 5,000 and 105 Pa (between 0.05 and 1.0 bar). More
preferably, at the end of this neutralization step the alkylphenate obtained is kept
for between two and six hours at an absolute pressure of between 10,000 and 20,000
Pa (between 0.1 and 0.2 bar).
[0041] By providing that operations are carried out at a sufficiently high temperature and
that the pressure in the reactor is reduced gradually below atmospheric, the neutralization
reaction is carried out without the need to add a solvent that forms an azeotrope
with the water formed during this reaction.
B. Carboxylation Step
[0042] The carboxylation step is conducted by simply bubbling carbon dioxide into the reaction
medium originating from the preceding neutralization step and is continued until at
least 20 mole % of the alkylphenate to alkylsalicylate (measured as salicylic acid
by potentiometric determination). It must take place under pressure in order to avoid
any decarboxylation of the alkylsalicylate that forms.
[0043] Preferably, at least 22 mole % of the starting alkylphenols is converted to alkylsalicylate
using carbon dioxide at a temperature of between 180 ° and 240 °C., under a pressure
within the range of from above atmospheric pressure to 15 x 105 Pa (15 bars) for a
period of one to eight hours.
[0044] According to one variant, at least 25 mole % of the starting alkylphenols is converted
to alkylsalicylate using carbon dioxide at a temperature equal to or greater than
200 °C. under a pressure of 4 x 105 Pa (4 bars).
[0045] The product of the carboxylation step is then filtered. The purpose of the filtration
step is to remove sediments, and particularly crystalline calcium carbonate, which
might have been formed during the preceding steps, and which may cause plugging of
filters installed in lubricating oil circuits.
[0046] The carboxylated detergent-dispersant formed by this process can be characterized
by its unique composition, with much more alkylphenol and alkaline earth metal single
aromatic-ring hydrocarbyl salicylate than produced by other routes. The reaction product
will typically have the following composition:
- a) from about 1 % to about 40 % alkylphenol,
- b) from about 10 % to about 40 % alkaline earth metal alkylphenate, and
- c) from about 30 % to about 70 % alkaline earth metal single aromatic-ring alkylsalicylate.
[0048] Unlike alkaline earth alkylsalicylates produced by other processes, this detergent-dispersant
composition can be characterized by having only minor amounts of an alkaline earth
double aromatic-ring alkylsalicylates. The mole ratio of single aromatic-ring alkylsalicylate
to double aromatic-ring alkylsalicylate is at least 8:1.
[0049] Preferably, the TBN of the detergent-dispersant should be from about 100 to about
250, more preferably from about 150 to about 200.
[0050] In the lubricating oil composition employed , the carboxylated detergent-dispersant
will typically range from 0.5 to 15 wt %, preferably from 1 to 12 wt % and more preferably
1 to 8 wt %, based on the weight of the total lubricating oil composition.
NITROGEN-CONTAINING DISPERSANT
[0051] The nitrogen-containing dispersant employed in the lubricating oil composition of
the present invention is an ashless dispersant such as an alkenyl or alkyl succinimide,
or mixture of such dispersants.
[0052] Ashless dispersants are broadly divided into several groups. One such group is directed
to copolymers which contain a carboxylate ester with one or more additional polar
function, including amine, amide, imine, imide, hydroxyl carboxyl, and the like. These
products can be prepared by copolymerization of long chain alkyl acrylates or methacrylates
with monomers of the above function. Such groups include alkyl methacrylate-vinyl
pyrrolidinone copolymers, alkyl methacrylate-dialkylaminoethy methacrylate copolymers
and the like. Additionally, high molecular weight amides and polyamides or esters
and polyesters such as tetraethylene pentamine, polyvinyl polysterarates and other
polystearamides may be employed. Preferred dispersants are N-substituted long chain
alkenyl succinimides.
[0053] Alkenyl succinimides are usually derived from the reaction of alkenyl succinic acid
or anhydride and alkylene polyamines. These compounds are generally considered to
have the formula:
wherein R
1 is a substantially hydrocarbon radical having a molecular weight from about 400 to
about 3000, that is, R
1 is a hydrocarbyl radical, preferably an alkenyl radical, containing about 30 to about
200 carbon atoms; Alk is an alkylene radical of about 2 to about 10, preferably about
2 to about 6, carbon atoms, R
2, R
3, and R
4 are selected from a C
1 to about C
4 alkyl or alkoxy or hydrogen, preferably hydrogen, and x is an integer from 0 to about
10, preferably 0 to about 3. The actual reaction product of alkylene succinic acid
or anhydride and alkylene polyamine will comprise the mixture of compounds including
succinamic acids and succinimides. However, it is customary to designate this reaction
product as a succinimide of the described formula, since this will be a principal
component of the mixture. See, for example,
U.S. Patent Nos, 3,202,678;
3,024,237; and
3,172,892. Reduction of the alkenyl substituted succinic anhydride produces the corresponding
alkyl derivative. The mono alkenyl succinimide and bis alkenyl succinimide produced
may depend on the charge mole ratio of polyamine to succinic groups and the particular
polyamine used. Charge mole ratios of polyamine to succinic groups of about 1:1 may
produce predominately mono alkenyl succinimide. Charge mole ratios of polyamine to
succinic group of about 1:2 may produce predominately bis alkenyl succinimide.
[0054] Particularly, advantageous results with the present invention are obtained when the
alkenyl or alkyl succinimide is a mono- or bis-succinimide prepared from a succinic
anhydride substituted by polyisobutene of a polyalkylene polyamine as discussed in
further detail below. Bis-succinimides are preferred.
[0055] These N-substituted alkenyl succinimides can be prepared by reacting maleic anhydride
with an olefinic hydrocarbon followed by reacting the resulting alkenyl succinic anhydride
with the alkylene polyamine. The R
1 radical of the above formula, that is, the alkenyl radical, is preferably derived
from a polymer prepared from an olefin monomer containing from about 2 to about 5
carbon atoms. Thus, the alkenyl radical is obtained by polymerizing an olefin containing
from about 2 to about 5 carbon atoms to form a hydrocarbon having a molecular weight
ranging from about 400 to about 3,000. Such olefin monomers are exemplified by ethylene,
propylene, 1-butene, 2-butene, isobutene, and mixtures thereof.
[0056] The preferred polyalkylene amines used to prepare the succinimides are of the formula:
wherein z is an integer of from 0 to about 10 and Alk, R
2, R
3, and R
4 are as defined above.
[0057] The alkylene amines include principally methylene amines, ethylene amines, butylene
amines, propylene amines, pentylene amines, hexylene amines, heptylene amines, octylene
amines, other polymethylene amines and also the cyclic and the higher homologs of
such amines as piperazine and amino alkyl-substituted piperazines. They are exemplified
specifically by ethylene diamine, triethylene tetraamine, propylene diamine, decamethyl
diamine, octamethylene diamine, diheptamethylene triamine, tripropylene tetraamine,
tetraethylene pentamine, trimethylene diamine, pentaethylene hexamine, ditrimethylene
triamine, 2-heptyl-3-(2-aminopropyl)-imidazoline, 4-methyl imidazoline, N,N-dimethyl-1
,3-propane diamine, 1,3-bis(2-aminoethyl)imidazoline, 1-(2-aminopropyl)-piperazine,
1,4-bis(2-aminoethyl)piperazine and 2-methyl-1-(2-aminobutyl)piperazine. Higher homologs
such as are obtained by condensing two or more of the above-illustrated alkylene amines
likewise are useful.
[0059] The term "ethylene amine" is used in a generic sense to denote a class of polyamines
conforming for the most part to the structure:
H
2N(CH
2CH
2NH)
aH
wherein a is an integer from 1 to about 10.
[0060] Thus, it includes, for example, ethylene diamine, diethylene triamine, triethylene
tetraamine, tetraethylene pentamine, pentaethylene hexamine, and the like.
[0061] Also included within the term "alkenyl succinimides" are post-treated succinimides
such as post-treatment processes involving ethylene carbonate and boric acid disclosed
by Wollenberg, et al.,
U.S. Patent No. 4,612,132; Wollenberg, et al.,
U.S. Patent No. 4,746,446; and the like as well as other post-treatment processes.
[0062] Preferably, the nitrogen-containing dispersant is a polyalkylene succinimide, preferably
a polyisobutylene succinimide. More preferably, the nitrogen-containing dispersant
is a polyisobutylene bis-succinimide. The nitrogen-containing dispersant employed
in the present invention will be present in sufficient quantity to impart the desired
dispersant properties to the lubricating oil composition in order to prevent the deposit
of contaminants formed in oil during operation of the internal combustion engine.
In general, in the lubricating oil composition, the nitrogen-containing dispersant
will typically range from 2 to 13 wt %, preferably from 4 to 8 wt % and more preferably
6 to 7.5 wt %, based on the weight of the total lubricating oil composition.
OTHER ADDITIVES
[0063] The following additive components are examples of some of the components that can
be favorably employed in the present invention. These examples of additives are provided
to illustrate the present invention, but they are not intended to limit it:
- 1. Metal detergents: sulfurized or unsulfurized alkyl or alkenyl phenates, alkyl or
alkenyl aromatic sulfonates, sulfurized or unsulfurized metal salts of multi-hydroxy
alkyl or alkenyl aromatic compounds, alkyl or alkenyl hydroxy aromatic sulfonates,
sulfurized or unsulfurized alkyl or alkenyl naphthenates, metal salts of alkanoic
acids, metal salts of an alkyl or alkenyl multiacid, and chemical and physical mixtures
thereof.
- 2. Anti-oxidants: Anti-oxidants reduce the tendency of mineral oils to deteriorate
in service which deterioration is evidenced by the products of oxidation such as sludge
and varnish-like deposits on the metal surfaces and by an increase in viscosity. Examples
of anti-oxidants useful in the present invention include, but are not limited to,
phenol type (phenolic) oxidation inhibitors, such as 4,4'-methylene-bis(2,6-di-tert-butylphenol),
4,4'-bis(2,6-di-tert-butylphenol), 4,4'-bis(2-methyl-6-tert-butylphenol), 2,2'-methylene-bis(4-methyl-6-tert-butyl-phenol),
4,4'-butylidene-bis(3-methyl-6-tert-butylphenol), 4,4'-isopropylidene-bis(2,6-di-tert-butylphenol),
2,2'-methylene-bis(4-methyl-6-nonylphenol), 2,2'-isobutylidene-bis(4,6-dimethylphenol),
2,2'-methylene-bis(4-methyl-6-cyclohexylphenol), 2,6-di-tert-butyl-4-methylphenol,
2,6-di-tert-butyl-4-ethylphenol, 2,4-dimethyl-6-tert-butyl-phenol, 2,6-di-tert-I-dimethylamino-p-cresol,
2,6-di-tert-4-(N,N'-dimethylaminomethylphenol), 4,4'-thiobis(2-methyl-6-tert-butylphenol),
2,2'-thiobis(4-methyl-6-tert-butylphenol), bis(3-methyl-4-hydroxy-5-tert-butylbenzyl)-sulfide,
and bis(3,5-di-tert-butyl-4-hydroxybenzyl). Other types of oxidation inhibitors include
metal dithiocarbamate (e.g., zinc dithiocarbamate), and methylenebis(dibutyldithiocarbamate).
- 3. Anti-wear agents: As their name implies, these agents reduce wear of moving metallic
parts. Examples of such agents include, but are not limited to, phosphates, phosphites,
carbamates, esters, sulfur containing compounds, and molybdenum complexes.
- 4. Rust inhibitors (Anti-rust agents)
- a) Nonionic polyoxyethylene surface active agents: polyoxyethylene lauryl ether, polyoxyethylene
higher alcohol ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene octyl phenyl
ether, polyoxyethylene octyl stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene
sorbitol monostearate, polyoxyethylene sorbitol mono-oleate, and polyethylene glycol
mono-oleate.
- b) Other compounds: stearic acid and other fatty acids, dicarboxylic acids, metal
soaps, fatty acid amine salts, metal salts of heavy sulfonic acid, partial carboxylic
acid ester of polyhydric alcohol, and phosphoric ester.
- 5. Demulsifiers: addition product of alkylphenol and ethylene oxide, polyoxyethylene
alkyl ether, and polyoxyethylene sorbitan ester.
- 6. Extreme pressure agents (EP agents): zinc dialkyldithiophosphate (primary alkyl,
secondary alkyl, and aryl type), sulfurized oils, diphenyl sulfide, methyl trichlorostearate,
chlorinated naphthalene, fluoroalkylpolysiloxane, and lead naphthenate.
- 7. Friction modifiers: fatty alcohol, fatty acid, amine, borated ester, and other
esters.
- 8. Multifunctional additives: sulfurized oxymolybdenum dithiocarbamate, sulfurized
oxymolybdenum organo phosphorodithioate, oxymolybdenum monoglyceride, oxymolybdenum
diethylate amide, amine-molybdenum complex compound, and sulfur-containing molybdenum
complex compound.
- 9. Viscosity index improvers: polymethacrylate type polymers, ethylenepropylene copolymers,
styrene-isoprene copolymers, hydrated styrene-isoprene copolymers, polyisobutylene,
and dispersant type viscosity index improvers.
- 10. Pour point depressants: polymethyl methacrylate.
- 11. Foam inhibitors: alkyl methacrylate polymers and dimethyl silicone polymers.
EXAMPLES
[0064] The invention will be further illustrated by following examples, which set forth
particularly advantageous method embodiments. While the Examples are provided to illustrate
the present invention, they are not intended to limit it.
EXAMPLE 1
CARBOXYLATED DETERGENT-DISPERSANT
[0065] A carboxylated detergent-dispersant was prepared as follows:
A. Neutralization:
[0066] A charge of 875 g of branched dodecylphenol (DDP) having a molecular mass of 270,
(i.e. 3.24 moles) and 875 g of linear alkylphenol having a molecular mass of about
390 (i.e. 2.24 moles) was placed in a four-necked 4 liter glass reactor above which
was a heat-insulated Vigreux fractionating column. The isomeric molar distribution
of para versus ortho alkylphenol was:
DDP: 89% para and 5.5% ortho
Linear alkylphenol: 39% para and 53% ortho.
[0067] The agitator was started up and the reaction mixture was heated to 65°C, at which
temperature 158 grams of slaked lime Ca(OH)
2 (i.e. 2.135 moles) and 19 g of a mixture (50/50 by weight) of formic acid and acetic
acid were added. The reaction medium underwent further heating to 120°C at which temperature
the reactor was placed under a nitrogen atmosphere, then heated up to 165°C and then
the nitrogen introduction was stopped. Distillation of water commenced at this temperature.
[0068] The temperature was increased to 240°C and the pressure was reduced gradually below
atmospheric until an absolute pressure of 5,000 Pa (50 mbars) was obtained. The reaction
mixture was kept for five hours under the preceding conditions. The reaction mixture
was allowed to cool to 180°C, then the vacuum was broken under a nitrogen atmosphere
and a sample was taken for analysis. The total quantity of distillate obtained was
about 120 cm
3; demixing took place in the lower phase (66 cm
3 being water).
B. Carboxylation:
[0069] The product obtained in Step (A) was transferred to a 3.6-liter autoclave and heated
to 180°C. At this temperature, scavenging of the reactor with carbon dioxide (CO
2) was commenced and continued for ten minutes. The amount of CO
2 used in this step was in the order of 20 grams.
[0070] After the temperature had been raised to 200°C, the autoclave was closed, leaving
a very small leak, and the introduction of CO
2 was continued so as to maintain a pressure of 3.5 x 10
5 Pa (3.5 bars) for 5 hours at 200°C. The amount of CO
2 introduced was in the order of 50 grams. After the autoclave had been cooled to 165°C,
the pressure was restored to atmospheric and the reactor was then purged with nitrogen.
[0071] A total quantity of 1,912 grams of product was recovered prior to filtration. The
product was then filtered.
EXAMPLE 2
[0072] The present invention was evaluated for compatibility with elastomer seals in a bench
test (PV 3344) by suspending a fluorocarbon test piece (AK 6) in an oil-based solution
heated to 150 °C. for 282 hours, the oil being renewed every 92 hours, then by measuring
the variation in the physical properties of the sample, in particular the tensile
strength break (TSB) and the elongation at break (ELB), in accordance with procedure
DIN 53504, by observing whether any cracks had formed at 100% elongation. The passing
test criteria included the following: no evidence of crack development; a tensile
strength break greater than 8N/mm2 and an elongation at break greater than 160%. This
test procedure will be designated above and later simply as the "VW Bench Test".
[0073] The formulation tested comprised a polyisobutenyl (PIB) bis-succinimide (the PIB
having a molecular weight of 2300 and the bis-succinimide having been post-treated
with ethylene carbonate)(6.5 wt %), low overbased (LOB) calcium sulfonate (0.68 wt
%), carboxylated detergent, prepared in the manner described in Example 1, (2.45 wt
%), high overbased (HOB) calcium alkylphenate (1.13 wt %), zinc dithiophosphate (0.69
wt %), a molybdenum-based anti-oxidant (0.05 wt %), a diphenylamine-based antioxidant
(0.3 wt %), a friction modifier (0.25 wt %), a foam inhibitor (0.0025 wt %), a pour
point depressant (0.15 wt %), a viscosity index improver (6.4 wt %), and a base oil
of lubricating viscosity (80.8 wt %).
COMPARATIVE EXAMPLE A
[0074] Comparative Example A was conducted as described in Example 2 except that 1.97 wt
% of a commercial medium overbased (MOB) calcium phenate was substituted for the carboxylate
and 0.5 wt % of the friction modifier was used instead of 0.25 wt %.
[0075] The results of the Example 2 and Comparative Example A are presented below in Table
1.
Table 1.
Volkswagen PV 3344 Seal Test |
Test |
VW EAM Acrylate Seals |
VW ACM Acrylate Seals |
VW AK-6 Fluoroelastomer Seals |
Result |
|
Tensile Strength, %
(Limit ≥ -40) |
Elongation, %
(Limit ≥ -40) |
Cracks in Seal
(Limit: None) |
|
Example 2 |
-36 |
-31.4 |
None |
Pass |
Comparative Example A |
-48.3 |
-45.1 |
Cracks |
Fail |
[0076] The results in Table 1 indicate that the detergent-dispersant employed in the present
invention enables you to pass the seal tests whereas a comparable commercial detergent,
on an equal molar basis, fails these tests. Example 2 showed no seal cracks and were
well within the passing limits of the Volkswagen VW seal test.
EXAMPLE 3
[0077] The evaluation of Oil-Elastomer Compatibility, either by CEC-L-39-T-97 plus DaimlerChrysler
requirement for AEM or by complete DaimlerChrysler requirements plus CEC elastomer
RE3, is aimed at determining the degree of compatibility of lubricating oils and cured
elastomers used in the automotive industry. Elastomer test pieces are immersed in
the test oil for a given period of time and a given temperature. The size, the volume,
the hardness, and the stress-strain properties are determined before and after immersion.
The compatibility of the oil and the elastomer is estimated by the change in these
characteristics.
[0078] The materials and test temperatures are provided in the following Table A. Immersion
duration 168 hours (7 days), in fresh oil with no elastomer pre-aging.
Table A.
Material Designation |
General Elastomer Type |
Test Temperature |
CEC RE 1 or DC FPM |
Fluoro-elastomer |
150°C |
CEC RE 2 or DC FPM |
Acrylic |
150°C |
CEC RE 3 |
Silicone |
150°C |
CEC RE 4 or DC NBR |
Nitrile |
100°C |
DC AEM |
Vamac |
150°C |
[0079] The formulations tested and their results are presented in Table 2.
Table 2.
CEC-L-39-T-97 or DaimlerChrysler Seal Test |
Component |
Weight % of Componenta |
Test Limit |
Formulation 1 |
Formulation 2 |
Formulation 3 |
Borated Bis-Succinimide |
1.5 |
2.5 |
3 |
|
Ethylene-Carbonated Bis-Succinimide |
5.0 |
5.0 |
5.0 |
|
Carboxylate |
4.72 |
4.72 |
4.72 |
|
|
Test Results |
|
Tensile Strength |
-37.7 |
-40 |
-45 |
-45 |
Elongation |
-36.1 |
-36 |
-41 |
-50 |
Hardness |
2.7 |
2 |
3 |
-5/+5 |
Volume |
0.9 |
0.6 |
0.6 |
0/+5 |
|
Pass |
Pass |
Borderline Pass |
|
aOther components: Phenate-salicylate (0.69 wt %), Zinc dithiophosphate (1.03 wt %),
Molybdenum-based anti-oxidant (0.17 wt %), Foam inhibitor (0.0025 wt %), Viscosity
index improver (5.55 wt %), and a base oil of lubricating viscosity (80.7 wt %). |
EXAMPLE 4
[0080] The test in Example 3 was repeated with a lubricating oil composition containing
the carboxylated detergent-dispersant (Formulation 4) employed in the present invention
and compared with a lubricating oil composition containing a comparable commercially
available detergent (Formulation 5) without the detergent-dispersant. The results
are shown in Table 3.
Table 3.
CEC-L-39-T-97 or DaimlerChrysler Seal Test |
Component |
Weight % of Componenta |
Test Limit |
Formulation 4 |
Formulation 5 |
Ethylene-Carbonated Bis-Succinimide |
8 |
8 |
|
Carboxylate |
4.8 |
- |
|
Commercial Detergent |
0.69 |
2.83 |
|
|
Test Results |
|
Tensile Strength (%) |
-40.7 |
-48.6 |
-45 |
Elongation |
-40.3 |
-45.7 |
-50 |
Hardness |
3.3 |
2.6 |
-5/+5 |
Volume 0.8 |
0.4 |
0/+5 |
|
|
Pass |
Fail |
|
aOther components: Zinc dithiophosphate (1.0 wt %), Molybdenum-based anti-oxidant (0.17
wt %), Foam inhibitor (0.0025 wt %), Viscosity index. improver (5.55 wt %), and a
base oil of lubricating viscosity (79 wt %). |
[0081] The results in Table 3 indicate that in a direct comparison between carboxylate and
a commercial detergent, seal compatibility can be maintained with the carboxylate
(Formulation 4). Comparatively, in Formulation 5 containing no carboxylate and with
a commercial detergent, the seal compatibility is lost.
[0082] The overall conclusion in the above examples clearly indicates that elastomer compatability
can be maintained at high dispersant levels. Switching to conventional detergent technology
with identical dispersant levels will result in failure.