(19)
(11) EP 2 070 694 B1

(12) EUROPEAN PATENT SPECIFICATION

(45) Mention of the grant of the patent:
13.04.2016 Bulletin 2016/15

(21) Application number: 08170902.4

(22) Date of filing: 08.12.2008
(51) International Patent Classification (IPC): 
B32B 3/12(2006.01)
B29D 24/00(2006.01)
E04C 2/36(2006.01)

(54)

Composite panel and method of manufacturing the same

Verbundpaneel und Verfahren zu dessen Herstellung

Panneau composite et son procédé de fabrication


(84) Designated Contracting States:
AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

(30) Priority: 13.12.2007 US 955959

(43) Date of publication of application:
17.06.2009 Bulletin 2009/25

(73) Proprietor: The Boeing Company
Chicago, IL 60606-1596 (US)

(72) Inventors:
  • Rapp, Robert A.
    O'Fallon, 63368 (US)
  • Ackermann, James F.
    Woodinville, Washington 98072 (US)
  • Gleason, Gregory R.
    Seattle, 98116-2421 (US)
  • Tanino, Ken M.
    Renton, 98058-8684 (US)

(74) Representative: Witte, Weller & Partner Patentanwälte mbB 
Postfach 10 54 62
70047 Stuttgart
70047 Stuttgart (DE)


(56) References cited: : 
EP-A- 0 786 330
EP-A- 1 897 680
US-A- 4 680 216
EP-A- 1 308 266
GB-A- 1 338 902
US-A1- 2005 161 154
   
       
    Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).


    Description

    BACKGROUND OF THE INVENTION



    [0001] This invention relates generally to composite materials, and more specifically to composite panels having a honeycomb core that are manufactured using a single-step curing process.

    [0002] Honeycomb core sandwich panels include composite laminate skins co-cured with adhesives to a honeycomb core are known. Such panels are utilized, for example, in the aerospace industry. Such honeycomb core sandwich panels are used at least partially due to their high stiffness-to-weight (i.e., specific stiffness) and strength-to-weight (i.e., specific strength) ratios. Current sandwich panels are processed, for example, using multiple cure cycles, or are co-cured in one step at low cure pressures in order to prevent deformation of the honeycomb core.

    [0003] When multiple cure cycles are used, either one or both of the composite skins are precured, then later bonded or cobonded onto the honeycomb core and/or the other skin. The multiple and complex steps increase production expenses and also increase the risk of defective panels due to, for example, bondline discrepancies, since the precured skin must match very closely with the contour-machined honeycomb core surface.

    [0004] A co-cure process refers to more than one skin simultaneously cured and bonded onto the machined honeycomb core pieces. A skin may include one ply of a composite material or a plurality of plies of a composite material. Numerous quality issues typically occur with a co-cure process such as, for example, distortion of the composite plies and/or dispersion of the composite resin into cells of the honeycomb core, as well as distortion of cells of the honeycomb core from their pre-processed core cell shape. Other quality issues due to known co-cure processes may also include formation of porous composite skins caused by curing at a less than optimum pressure, and also due to distortion of the composite skins into the cells of the core.

    [0005] Furthermore, quality inspections of composite panels formed using known co-cure processes are complicated because it may be difficult to accurately assess the quality of a composite panel formed using a known co-cure process using typical non-destructive inspection techniques, such as ultrasonic inspection methods.

    [0006] There are no current composite/honeycomb sandwich design and process schemes in which a one-step co-cure process produces a high strength structural part, with substantially porosity-free composite skins, minimal resin leakage into the honeycomb core, minimal honeycomb core distortion, minimal composite ply distortion into the honeycomb cells, and having composite skins that may be readily inspected by known ultrasonic inspection techniques to verify the co-cured skins are substantially porosity-free.

    [0007] U.S. Patent Publication 2005/0161154 discloses methods of stabilizing and/or sealing core material for manufacturing molded composite structures by applying a layer of roll-coated adhesive on the core, applying a layer of stabilizing material on the roll-coated adhesive layer, and applying a layer of thermoplastic barrier film on the stabilizing material.

    [0008] EP 1 897 680 A1 discloses a method for producing a sandwich component having a honeycomb core, wherein a barrier layer is provided between the core and the composite cover layers.

    [0009] EP 0 786 330 A2 discloses low-weight and water-resistant honeycomb sandwich panels which are made by a resin transfer molding process. A moisture barrier film is placed between the core and a fibrous reinforcement material.

    BRIEF DESCRIPTION OF THE INVENTION



    [0010] In one embodiment, a method of manufacturing a composite panel is provided. The method includes pre-stabilizing a honeycomb core by surrounding the honeycomb core with pre-stabilizing material and curing the pre-stabilizing material; positioning a laminate skin formed from one sheet of a composite material and folded along an edge thereof to surround said pre-stabilized honeycomb core; bonding said at least one laminate skin to opposite sides of said pre-stabilizing material surrounding said pre-stabilized honeycomb core; and curing said at least one laminate skin to opposite sides of said pre-stabilizing material substantially simultaneously.

    [0011] In another embodiment, a composite panel including a pre-stabilized honeycomb core and at least one laminate skin is provided. A composite panel comprising: a pre-stabilized honeycomb core surrounded by a cured pre-stabilizing material; and a laminate skin formed from one sheet of a composite material and folded along an edge thereof, said one laminate skin positioned to surround said pre-stabilized honeycomb core, characterized in that said laminate skin is bonded to opposite sides of said pre-stabilizing material surrounding said pre-stabilized honeycomb core and cured substantially simultaneously.

    BRIEF DESCRIPTION OF THE DRAWINGS



    [0012] 

    Figure 1 is an illustration of an exemplary composite panel

    Figure 2 is a cross-sectional view of the exemplary composite panel of Figure 1 taken generally along line 2-2.

    Figure 3 is a flow chart illustrating an exemplary method of manufacturing the composite panel of Figures 1 and 2.


    DETAILED DESCRIPTION OF THE INVENTION



    [0013] Figure 1 is an illustration of an exemplary composite panel 10. Exemplary composite panel 10 is a sandwich structure that includes two core portions (not shown in Figure 1), positioned between, and surrounded by, two layers of composite laminate skin, a first layer 16 and a second layer 18. In the exemplary embodiment, first laminate skin layer 16 and second laminate skin layer 18 may be two separate sheets of composite material. In an alternative embodiment, first laminate skin layer 16 and second laminate skin layer 18 are formed from one sheet of composite material, and folded along an edge, for example, but not limited to an edge 22 or an edge 24, such that first layer 16 is adjacent to one side of the core portions (not shown in Figure 1) and second layer 18 is adjacent to an opposite side of the core portions (not shown in Figure 1).

    [0014] Figure 2 is a cross-sectional view of exemplary composite panel 10 taken generally along line 2-2. As described above, composite panel 10 includes at least one core section 40, a pre-stabilizing composite material 42, and first and second composite laminate layers 16 and 18. Examples of composite materials may include, but are not limited to, fiberglass and carbon fiber in a resin matrix.

    [0015] Core section 40 may be, for example, a honeycomb structure. Core section 40 may be formed from, for example, but not limited to, paper, synthetic paper (e.g., NOMEX® brand fiber, manufactured by E.I du Pont de Nemours and Company), metal, composite, fiberglass, or the like, or any material that enables composite panel 10 to function as described herein. For example, core section 40 may be a chamfered-edge honeycomb core having a density of 3-8 pounds per cubic foot. In the exemplary embodiment, core section 40 is pre-stabilized with pre-stabilizing composite material 42, resulting in a pre-stabilized core 44. More specifically, core section 40 may be pre-stabilized by coupling composite material 42, such as, but not limited to, a ply of preimpregnated fiberglass, to core section 40. In the exemplary embodiment, composite material 42 is coupled to core section 40 using an adhesive 50, such as, but not limited to, a film adhesive, and curing by heating. In an alternative embodiment, composite material 42 is coupled directly to core section 40.

    [0016] First laminate skin layer 16 and second laminate skin layer 18 may include, but are not limited to including, composite laminate materials such as carbon fiber or fiberglass. First laminate skin layer 16 and second laminate skin layer 18 may be coupled to pre-stabilized core section 40 by respective adhesive layers 52 and 54.

    [0017] Figure 3 is a flow chart 60 illustrating an exemplary method of manufacturing the composite panel 10 illustrated in Figures 1 and 2. The method includes pre-stabilizing 64 a core. In the exemplary embodiment, pre-stabilizing 64 includes applying a pre-stabilizing composite material to the core and curing the pre-stabilizing composite material in an oven cure cycle under a pressure. The pressure may be applied using, for example, but not limited to, a vacuum bag or an autoclave. Pre-stabilizing 64 increases the strength of the core section 40 without substantially increasing its weight. In the exemplary embodiment, the core is machined to a desired shape and size prior to pre-stabilizing 64. In an alternative embodiment, the core is formed into a desired shape during pre-stabilizing 64. The applied heat facilitates changing the shape of the core and the pre-stabilizing composite material maintains the desired shape of the core.

    [0018] The method further includes positioning 66 the pre-stabilized core adjacent to at least a first skin layer and a second skin layer. As described above in regard to Figure 1, laminate skin layer 16 and laminate skin layer 18 may be formed from two separate sheets of composite material. In an alternative embodiment, laminate skin layer 16 and laminate skin layer 18 are formed from one sheet of composite material, and folded along an edge, for example, but not limited to edge 22 or edge 24, such that skin layer 16 is adjacent to one side of the cores and skin layer 18 is adjacent to an opposite side of the cores.

    [0019] Additionally, the method still further includes curing 68 the first skin layer 16 and the second skin layer 18 substantially simultaneously. In the exemplary embodiment, curing 68 is a high pressure (e.g., 3.44-8.27 bar (50-120 psi)), one-step co-cure process which cures both first skin layer 16 and second skin layer 18 while simultaneously bonding first skin layer 16 and second skin layer 18 to a core, for example, core section 40.

    [0020] In the exemplary embodiment, curing 68 enables production of cured skins including high-strength composite materials. Curing process 68, and more specifically the high pressure curing that is facilitated by pre-stabilizing the core, results in cured skins having a substantially low porosity, for example, a porosity of less than 2%, which is one indication of high structural performance and of a high level of quality. Curing 68 also enables production of cured skins that are inspectable by known non-destructive inspection techniques, including, but not limited to, ultrasonic inspection techniques. In the exemplary embodiment, the inspection techniques have a resolution sufficient to quantify the porosity of the cured skins.

    [0021] Furthermore, curing 68 and pre-stabilizing 64 facilitate prevention of core distortion and prevention of resin from the skins intruding into the core during the cure. Pre-stabilizing 64 enables a composite panel to include a lightweight core while also being cured at a high pressure, without the core being distorted. Curing 68 at a high pressure produces skins having a low porosity.

    [0022] The methods and apparatus described herein facilitate a one-step co-cure process which results in a high strength structural part, that includes substantially porosity-free composite skins, substantially no resin leakage into the honeycomb core, substantially no honeycomb core distortion, substantially no composite ply distortion into the honeycomb cells, while the sandwich skins are readily inspectable by known ultrasonic inspection techniques to verify the co-cured skins are substantially porosity-free.

    [0023] The methods and apparatus described herein facilitate cost-effective manufacturing of high strength toughened carbon/epoxy composites. Specifically, the methods and apparatus described herein facilitate increasing structural performance of composite panels, minimizing weight, improving part quality inspectability, while minimizing manufacturing cost (in part due to the one-step co-cure process described above).

    [0024] Exemplary embodiments of composite panels and methods of manufacturing composite panels are described above in detail. Neither the composite panels nor the methods of manufacturing the composite panels are limited to the specific embodiments described herein. Each component can also be used in combination with other components. More specifically, although the methods and apparatus herein are described with respect to aircraft components, it should be appreciated that the methods and apparatus can also be applied to a wide variety of components used within other structures, including, but not limited to, spacecraft, watercraft, and automobiles.


    Claims

    1. A composite panel (10) comprising:

    a pre-stabilized honeycomb core (44) surrounded by a cured pre-stabilizing material; and

    a laminate skin (16,18) formed from one sheet of a composite material and folded along an edge (22, 24) thereof, said one laminate skin (16, 18) positioned to surround said pre-stabilized honeycomb core, characterized in that

    said laminate skin (16, 18) is bonded to opposite sides of said pre-stabilizing material (42) surrounding said pre-stabilized honeycomb core (44) and cured substantially simultaneously.


     
    2. A composite panel (10) according to Claim 1 wherein said honeycomb core (44) is pre-stabilized by applying a composite material (42) to said honeycomb core and curing said composite material.
     
    3. A composite panel (10) according to Claim 1 wherein said pre-stabilizing material is coupled to said honeycomb core (44) using an adhesive (50).
     
    4. A composite panel (10) according to Claim 1 wherein said at least one laminate skin (16,18) is coupled to said pre-stabilized honeycomb core (44) using an adhesive (50).
     
    5. A composite panel (10) according to Claim 1 wherein said laminate skin (16,18) comprises at least one composite material (42).
     
    6. A method of manufacturing a composite panel (10) comprising:

    pre-stabilizing a honeycomb core (40) by surrounding the honeycomb core (40) with pre-stabilizing material (42) and curing the pre-stabilizing material;

    positioning a laminate skin (16,18) formed from one sheet of a composite material and folded along an edge (22, 24) thereof to surround said pre-stabilized honeycomb core (44);

    bonding said at least one laminate skin (16,18) to opposite sides of said pre-stabilizing material (42) surrounding said pre-stabilized honeycomb core (44); and curing said at least one laminate skin (16,18) to opposite sides of said pre-stabilizing material substantially simultaneously.


     
    7. A method of manufacturing a composite panel (10) according to Claim 6 wherein said laminate_skin (16, 18) of said composite panel is able to be inspected with at least one non-destructive inspection method to quantify porosity.
     
    8. A method of manufacturing a composite panel (10) according to Claim 7 wherein said at least one non-destructive inspection method comprises ultrasonic testing.
     


    Ansprüche

    1. Verbundplatte (10), die aufweist:

    einen vorstabilisierten Wabenkern (44), der von einem ausgehärteten vorstabilisierten Material umgeben ist; und

    eine Laminathaut (16, 18), die aus einer Schicht eines Verbundmaterials gebildet ist und die entlang eines Rands (22, 24) davon gefaltet ist, wobei die Laminathaut (16, 18) positioniert ist, den vorstabilisierten Wabenkern zu umgeben,

    dadurch gekennzeichnet, dass

    die Laminathaut (16, 18) an gegenüberliegende Seiten des vorstabilisierten Materials (42) gebunden ist, das den vorstabilisierten Wabenkern (44) umgibt, und im Wesentlichen gleichzeitig ausgehärtet wird.


     
    2. Verbundplatte (10) nach Anspruch 1, wobei der Wabenkern (44) vorstabilisiert wird, indem ein Verbundmaterial (42) auf den Wabenkern angewendet wird und indem das Verbundmaterial ausgehärtet wird.
     
    3. Verbundplatte (10) nach Anspruch 1, wobei das vorstabilisierte Material unter Verwendung eines Klebstoffs (50) an den Wabenkern (44) gekoppelt ist.
     
    4. Verbundplatte (10) nach Anspruch 1, wobei die zumindest eine Laminathaut (16, 18) unter Verwendung eines Klebstoffs (50) an den vorstabilisierten Wabenkern (44) gekoppelt ist.
     
    5. Verbundplatte (10) nach Anspruch 1, wobei die Laminathaut (16, 18) zumindest ein Verbundmaterial (42) aufweist.
     
    6. Verfahren zum Herstellen einer Verbundplatte (10), das aufweist:

    Vorstabilisieren eines Wabenkerns (40), indem der Wabenkern (40) mit einem vorstabilisierten Material (42) umgeben wird und indem das vorstabilisierte Material ausgehärtet wird;

    Positionieren einer Laminathaut (16, 18), die aus einer Schicht eines Verbundmaterials gebildet ist und die entlang eines Rands (22, 24) davon gefaltet ist, um den vorstabilisierten Wabenkern (44) zu umgeben;

    Binden der zumindest einen Laminathaut (16, 18) an gegenüberliegende Seiten des vorstabilisierten Materials (42), das den vorstabilisierten Wabenkern (44) umgibt; und

    im Wesentlichen gleichzeitiges Aushärten der zumindest einen Laminathaut (16, 18) an gegenüberliegenden Seiten des vorstabilisierten Materials.


     
    7. Verfahren zum Herstellen einer Verbundplatte (10) nach Anspruch 6, wobei die Laminathaut (16, 18) der Verbundplatte mit zumindest einem nicht zerstörerischen Inspektionsverfahren inspizierbar ist, um eine Porosität zu quantifizieren.
     
    8. Verfahren zum Herstellen einer Verbundplatte (10) nach Anspruch 7, wobei das zumindest eine nicht zerstörerische Verfahren eine Ultraschallüberprüfung aufweist.
     


    Revendications

    1. Panneau composite (10) comprenant :

    une âme en nid d'abeilles (44) pré-stabilisée entourée par un matériau pré-stabilisant durci ; et

    une peau stratifiée (16, 18) formée à partir d'une feuille d'un matériau composite et pliée le long d'un bord (22, 24) de celle-ci, ladite peau stratifiée (16, 18) étant positionnée de façon à entourer ladite âme en nid d'abeilles pré-stabilisée,

    caractérisé en ce que

    ladite peau stratifiée (16, 18) est assemblée à des côtés opposés dudit matériau pré-stabilisant (42) entourant ladite âme en nid d'abeilles (44) pré-stabilisée et durcie de façon essentiellement simultanée.


     
    2. Panneau composite (10) selon la revendication 1, dans lequel ladite âme en nid d'abeilles (44) est pré-stabilisée par application d'un matériau composite (42) à ladite âme en nid d'abeilles et durcissement dudit matériau composite.
     
    3. Panneau composite (10) selon la revendication 1, dans lequel ledit matériau pré-stabilisant est accouplé à ladite âme en nid d'abeilles (44) au moyen d'un adhésif (50).
     
    4. Panneau composite (10) selon la revendication 1, dans lequel ladite ou lesdites peaux stratifiées (16, 18) sont accouplées à ladite âme en nid d'abeilles (44) pré-stabilisée au moyen d'un adhésif (50).
     
    5. Panneau composite (10) selon la revendication 1, dans lequel ladite peau stratifiée (16, 18) comprend au moins un matériau composite (42).
     
    6. Procédé de fabrication d'un panneau composite (10) comprenant :

    pré-stabiliser une âme en nid d'abeilles (40) en entourant l'âme en nid d'abeilles (40) d'un matériau pré-stabilisant (42) et en durcissant le matériau pré-stabilisant; positionner une peau stratifiée (16, 18) formée à partir d'une feuille d'un matériau composite et pliée le long d'un bord (22, 24) de celle-ci de façon à entourer ladite âme en nid d'abeilles (44) pré-stabilisée ;

    assembler ladite ou lesdites peaux stratifiées (16, 18) à des côtés opposés dudit matériau pré-stabilisant (42) entourant ladite âme en nid d'abeilles (44) pré-stabilisée ; et

    durcir ladite ou lesdites peaux stratifiées (16, 18) sur des côtés opposés dudit matériau pré-stabilisant de façon essentiellement simultanée.


     
    7. Procédé de fabrication d'un panneau composite (10) selon la revendication 6, dans lequel ladite peau stratifiée (16, 18) dudit panneau composite peut être inspectée à l'aide d'au moins un procédé d'inspection non destructif afin de quantifier la porosité.
     
    8. Procédé de fabrication d'un panneau composite (10) selon la revendication 7, dans lequel ledit ou lesdits procédés d'inspection non destructifs comprennent l'auscultation dynamique.
     




    Drawing














    Cited references

    REFERENCES CITED IN THE DESCRIPTION



    This list of references cited by the applicant is for the reader's convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.

    Patent documents cited in the description