[0001] The present invention relates to an operating method and an operation control apparatus
for a gasification-melting furnace for disposal of such wastes as municipal solid
wastes and industrial wastes as well as a method and an apparatus for regulating the
basicity of slag discharged from the gasification-melting furnace.
[0002] As means for disposal of wastes, there is conventionally known a fluidized-bed gasification-melting
furnace, for example, described in Patent Document 1 for example. This fluidized-bed
gasification-melting furnace comprises a fluidized-bed gasification furnace having
a fluidized bed formed by a fluidization gas, and a melting furnace disposed downstream
therefrom. The aforementioned fluidized-bed gasification furnace produces pyrolysis
gases through partial combustion of wastes thrown into the fluidized bed. The aforementioned
melting furnace further combusts the pyrolysis gases produced by the fluidized-bed
gasification furnace and melts ash contained in the gases, thus producing slag. Provided
at the top of this melting furnace is an auxiliary burner for maintaining temperature
in the furnace.
[0003] This kind of gasification-melting furnace has below-mentioned problems to be solved
with respect to operation of the furnace.
1) About burner operation
[0004] In a state where the internal temperature of the aforementioned gasification-melting
furnace has already reached about 1300°C, even if the auxiliary burner is turned off
in that state, spontaneous combustion of unburned components will keep the in-furnace
temperature high for a while. This causes a desire of a appropriate rest of the operation
of the burner for fuel savings and environmental issues (especially in view of restrictions
on CO
2 emissions).
[0005] However, after the burner is brought to rest as mentioned above, there can occur
a case where the burner fails resume successful combustion when reignited. If the
burner is reignited at a point when unburned gases existing in the proximity of the
burner have reached a temperature equal to or lower than a spontaneous ignition temperature
as a result of a rapid drop in in-furnace temperature near the burner for one reason
or another after the stoppage of operation of the burner, for example, abnormal combustion
can arise.
2) About slag fluidity
[0006] For maintaining stable discharge of slag through a slag outlet of the aforementioned
gasification-melting furnace, it is important to maintain fluidity of the slag. Leaving
the slag fluidity low can occur a risk that the slag might clog the slag outlet to
hinder continuous furnace operation.
[0007] There exist parameters dominating the slag fluidity, including the temperature and
the basicity (CaO/SiO
2) of the slag. To maintain the slag fluidity, the slag temperature must be higher
than a fluxing point thereof, while the fluxing point has a significant correlation
with the slag basicity. Specifically, it is known that the slag basicity exceeding
a value of approximately 0.7 involves a rise of the fluxing point of the slag with
an increase of the basicity. For example, the basicity of the slag of 1 is known to
bring up a fluxing point of the slag to 1200°C.
[0008] Adjustment of the slag basicity is therefore important for efficient and stable continuous
operation of the gasification-melting furnace. Even though the melting furnace is
operated to keep an internal temperature thereof generally constant, the actual fluidity
of the slag is influenced by changes in the basicity thereof. This means that stable
operation is difficult without maintaining the slag basicity within a proper range.
Meanwhile, if the in-furnace temperature is set at a higher level in anticipation
of changes in the basicity mentioned above, low operating efficiency cannot be avoided.
For example, with the slag basicity of 1, the stable discharge of the slug through
the slag outlet requires a temperature thereof to be 1200°C or above. Moreover, considering
that the temperature of the discharged slag tends to be lower than the temperature
in the melting furnace by approximately 100-150°C, the temperature in the melting
furnace should be set at 1350°C or above for stable discharge of the slag. Continuing
such a high temperature operation for long periods of time not only involves requirement
of increasing the amount of external fuel for in-furnace temperature maintenance and
increase in running cost, but also would involve an increase in environmental load
as well as in repair cost due to damages to refractory materials.
[0009] Under such circumstances, conventionally performed is to supply basicity adjusters
into a system. Specifically, quartz sand (SiO
2) or the like is supplied to the system for decreasing the basicity, whereas calcium
hydroxide (Ca(OH)
2) or the like is supplied to the system for increasing the basicity. This supply of
the basicity adjusters in appropriate quantities into the system enables the slag
basicity to be maintained within a preferable range. In short, determination of appropriate
amounts of the basicity adjusters supply is essential to proper adjustment of the
slag basicity.
[0010] As a method for determining the amounts of the aforementioned basicity adjusters
supply, Patent Document 2 proposes a measurement of the actual slag basicity by use
of analyzing equipment. The method disclosed in this Document includes a step of analyzing
the composition of slag actually discharged from a furnace by using a simplified X-ray
fluorescence spectrometer and so on, and a step of determining the amount of each
basicity adjuster addition based on results of the analysis.
[0011] This method, however, involves complicated management of operation. Specifically,
it requires installment of a specialized analyzer and regular analyzing operation
for calculation of the slag basicity. Moreover, the analyzer is generally installed
in a dedicated organization far away from a site, which requires transportation of
slag samples from a waste disposal plant including the gasification-melting furnace.
This causes a considerable time lag from a slag sampling to a determination of the
slag basicity.
[0012] Furthermore, in this method, the reliability of analysis results is difficult to
verify. In this method, generally used is an analyzing equipment installed outside
the disposal facility as mentioned above, which can perform only a periodic analysis
at relatively long intervals. The analysis results obtained at such infrequent intervals
is extremely difficult to assess whether it is worthy of adoption or to be excluded
as erratically occurred peculiar values. A failure in this assessment prevents determination
of the appropriate amount of each basicity adjuster.
Patent Document 1: Japanese Unexamined Patent Publication No. 2006-29678
Patent Document 2: Japanese Unexamined Patent Publication No. 2001-182924
[0013] US-patent 4,013,023 discloses ways and means for incinerating organic wastes in a multiple hearth furnace
equipped with an afterburner.
JP-A-2004-353944 provides a refuse disposal facility capable of supplying proper quantity of combustion
air.
[0014] An object of the invention is to provide a technology for carrying out highly efficient
operation of a gasification-melting furnace by rest of the burner while reliably resuming
successful combustion at reignition of the burner.
[0015] To achieve this object, after a stop of operation of a burner for auxiliary combustion
of the melting furnace, the burner is reignited under the following condition: if
the temperature in a melting furnace drops to a certain extent, the burner is reignited
followed by increasing oxygen concentration in gases supplied from a gasification
furnace to the melting furnace by stopping charging of waste material; or the burner
is reignited during a period when the temperature in the melting furnace remains still
rather high. This method prevents the burner reignition under unsuitable conditions
(e.g., conditions where spontaneous ignition of unburned gas hardly occurs) in advance
to thereby enable the burner to be properly reignited, while carrying out highly efficient
operation by rest of the burner.
[0016] Also, in the course of the present invention another object was to provide a technology
for facilitating a proper basicity adjustment in operation of a gasification-melting
furnace, with no need of special analyzer for analysis of slag composition. To achieve
this object, the inventors undertook an intensive study of the basicity adjustment
aforementioned, resulting in discovery of a significant correlation between the calorific
value per unit weight of the waste material charged into the gasification-melting
furnace and the basicity of slag discharged from the gasification-melting furnace.
This correlation can be used to enable the actual basicity of the slag to be quickly
and properly determined without a special analyzer or the like.
[0017] According, in the course of the present invention, there is provided a method for
adjusting basicity of slag in operating a gasification-melting furnace which brings
waste material charged therein into pyrolysis and melts ash in pyrolysis gases produced
by the pyrolysis to produce slag, the gasification-melting furnace having a slag discharging
port for discharging the slag. This method comprises: a step of supplying a basicity
adjuster for adjusting the basicity of the slag discharged through the slag discharging
port to a position upstream therefrom; a step of detecting the weight of the waste
material charged into the gasification-melting furnace per unit time; a step of detecting
a parameter corresponding to the calorific value of the waste material per unit weight;
a step of calculating an expected value of the basicity of the slag produced inside
the gasification-melting furnace, based on a detected value of the parameter; and
a step of regulating the amount of the basicity adjuster supply so as to make the
basicity of the slag approach a preset target value of the basicity, based on the
calculated expected value of the basicity.
[0018] This method makes use of a correlation between the parameter corresponding to the
calorific value of the waste material per unit weight and the actual basicity of the
slag, the use allowing the expected value of the actual slag basicity to be obtained
without a complicated analysis of the slag composition. Specifically, the expected
value of the basicity can be calculated, based on the detected value of the parameter
and the aforementioned correlation. Then, based on the expected value of the basicity
of the slag, a proper amount of the basicity adjuster addition is determined.
[0019] This method can be realized by an apparatus for adjusting the basicity of the slag,
the apparatus comprising: a basicity adjuster feeder for supplying a basicity adjuster
for adjusting the basicity of the slag discharged through a slag discharging port
at a position upstream from the slag discharging port; a waste material charging quantity
detector for detecting the weight of waste material charged into the gasification-melting
furnace per unit time; a parameter detector for detecting a parameter corresponding
to the calorific value of the waste material per unit weight; an expected basicity
value calculator for calculating an expected value of the basicity of the slag produced
inside the gasification-melting furnace based on a detected value of the parameter,
and a basicity adjuster quantity regulator for regulating the amount of the basicity
adjuster supply so as to make the basicity of the slag approach a preset target value
of the basicity, based on the expected value of the basicity.
FIG. 1 is an overall configuration diagram of a waste disposal plant provided with
a gasification-melting furnace according to an embodiment achieved in the course of
the present Application;
FIG. 2 is a cross-sectional diagram showing the structure of the gasification-melting
furnace;
FIG. 3 is a cross-sectional diagram showing an example of arrangement of a thermometer
of the gasification-melting furnace;
FIG. 4 is a flowchart showing an example of a control process for determining burner
reignition timing based on oxygen concentration in gas in an operation control process
of the gasification-melting furnace;
FIG. 5 is a flowchart showing an example of a control process for determining the
burner reignition timing based on furnace-top temperature in an operation control
process of the gasification-melting furnace;
FIG. 6 is a diagram showing an example of a facility for executing a control process
for determining the burner reignition timing based on a cumulative value of the amount
of air in an operation control process of the gasification-melting furnace;
FIG. 7 is a flowchart showing an example of the control process for determining the
burner reignition timing based on the oxygen concentration in gases in the operation
control process of the gasification-melting furnace;
FIG. 8 is a diagram showing the overall configuration of a waste disposal plant according
to an embodiment achieved in the course of the present invention;
FIG. 9 is a graph showing an example of annual changes in the calorific value of refuse
and basicity of slag;
FIG. 10 is a graph showing an example of a correlation between the calorific value
of refuse and the basicity of the slag; and
FIG. 11 is a graph showing an example of setting the amount of basicity adjuster to
be supplied based on an expected value of the basicity of the slag.
[0020] There is described a preferred embodiment of the invention with reference to FIGS.
1 to 7.
[0021] FIG. 1 shows an example of a waste disposal plant provided with a fluidized-bed gasification-melting
furnace. The present invention is widely applicable to operation of a gasification-melting
furnace having a gasification furnace and a melting furnace. The overall configuration
of the waste disposal plant adopting the gasification-melting furnace is not particularly
limited.
[0022] Referring to FIG. 1, waste materials, that is, items of refuse are once placed in
a refuse pit 1 and thrown into a hopper 2a of a refuse feeder 2 which serves as a
waste feeder by an unillustrated crane. The refuse feeder 2 feeds the refuse into
a fluidized-bed gasification furnace 3 in prescribed quantities.
[0023] This gasification furnace 3 performs a partial combustion process under conditions
of an air ratio, for instance, of 0.2 to 0.4, that is, a pyrolysis process or primary
combustion, with a fluidized bed including a layer of sand maintained at a temperature
of 450°C to 650°C. Noncombustible material contained in the refuse thrown into the
refuse feeder 2 is withdrawn from a furnace bottom and carried via a screw conveyer
5, a vibrating screen 6 and an unillustrated magnetic separator to be separated into
noncombustible objects, nonferrous metals, ferrous metals and fluidized sand. The
fluidized sand among them is returned to the layer of sand in the gasification furnace
3 for reuse.
[0024] Pyrolysis gases produced in the gasification furnace 3 are led to a melting furnace
4 to be further combusted therein under conditions of an air ratio of 1.3, for instance.
Performed in this melting furnace 4 is a high-temperature combustion process at about
1300°C with a spiral flow produced therein. This high-temperature combustion generates
heat, which melts ash contained in the pyrolysis gases to separate the ash as slag
from the pyrolysis gases while decomposing hazardous substances like dioxins contained
in the gases. The molten slag is drawn out from the bottom of the melting furnace
4, carried out by a slag removing unit 7 including a conveyer, cooled in a slag cooling
unit 8 provided therebelow, and then collected.
[0025] The exhaust gases discharged from the swirling-flow melting furnace 4 are led through
an air heater 9 and a waste heat boiler 10, where heat within the pyrolysis gases
is recovered. The exhaust gases after the heat-recovery are further cooled in a gas
cooling unit 11 and dedusted by a bag filter 12. The exhaust gases thus cleaned are
led by an induced draft fan 13 through a denitration unit 14 to be exausted through
a chimney 15.
[0026] FIG. 2 shows details of the structure of the gasification-melting furnace configured
with the gasification furnace 3 and the melting furnace 4.
[0027] Referring to Fig. 2, there is provided a dispersion plate 20 having a large number
of gas injection orifices 22 at a bottom of the gasification furnace 3, a wind box
24 formed below the dispersion plate 20. From the wind box 24 is ejected fluidization
gas for example upward through the gas injection orifices 22 in the dispersion plate
20, thus forming a fluidized bed 26 of sand particles above the dispersion plate 20.
The middle of the dispersion plate 20 is provided with a noncombustible material outlet
28, through which the noncombustible material is withdrawn to be led to the screw
conveyer 5 and the vibrating screen 6.
[0028] Above the fluidized bed 26 is provided a refuse input port 30 connected to the refuse
feeder 2. In a path between the refuse input port 30 and the refuse feeder 2 is provided
a dumper 32 for opening and closing off the path. At about the same height as the
refuse input port 30 is provided a gasification furnace heat-up burner 34. Further
above the gasification furnace heat-up burner 34 is formed a free board 36 for secondary
combustion. At a furnace top is provided a pyrolysis gas output port 38.
[0029] The pyrolysis gases discharged through the pyrolysis gas output port 38 are fed into
an upper portion of the melting furnace 4. At an appropriate location (a furnace top
in the illustrated example) of the swirling-flow melting furnace 4, there is downwardly
provided a burner 40 for auxiliary combustion. Immediately below this burner 40 is
provided a pyrolysis gas input port 42, which is connected to the pyrolysis gas output
port 38 of the gasification furnace 3 via a duct 44 serving as a pyrolysis gas channel.
The burner 40 is used to raise and maintain the temperature of the melting furnace
4 (e.g. to maintain a state at a temperature of 1300°C or above). Operation of this
burner 40 will be described later in detail.
[0030] Besides, the melting furnace 4 is provided with a slag discharging port 43 at the
bottom thereof, to which the slag removing unit 7 is connected.
[0031] The duct 44 is provided with an oxygen analyser 45, which detects the concentration
of oxygen contained in the gases fed from the gasification furnace 3 to the melting
furnace 4. In the vicinity of the burner 40 (i.e., at a location close to the top
of the swirling-flow melting furnace 4 in this embodiment), there is provided a thermometer
46 for detecting in-furnace temperature at the location (i.e., the temperature at
the furnace top in this embodiment).
[0032] The oxygen analyser 45 preferably has superior durability. Specifically, preferable
is, for example, a zirconia-type oxygen analyzer.
[0033] The thermometer 46 preferably has superb durability and excellent sensing accuracy
in a high-temperature range. Specifically, a radiation pyrometer (especially an infrared
radiation pyrometer) or the like is preferable. The location of this thermometer 46,
though possibly determined as appropriate within a detectable range for the furnace-top
temperature, is preferably determined so as to allow as stable a monitoring as possible
to be made. For example, in case that a combustion air feeding nozzle 48 for the melting
furnace shown in FIG. 3 is provided close to the pyrolysis gas input port 42 of the
melting furnace 4, the thermometer 46 is preferably disposed at a position upstream
from the nozzle 48, from which the thermometer 46 can monitor the inside of the top
of the melting furnace 4 through the nozzle 48, as illustrated. This location of the
thermometer 46 enables a combustion air flow from the nozzle 48 to the inside of the
melting furnace 4a to be used for prevention of the ash or the like in the melting
furnace 4 from clogging a detection window of the thermometer 46, thereby realizing
a temperature monitoring in a stable manner.
[0034] The position of the thermometer 46 may be chosen within a range close to the burner
40, specifically so near a range to the burner 40 that the ignition of the burner
40 can cause combustion of unburned gases.
[0035] This gasification-melting furnace is further provided with a control system 50 shown
in FIG. 2, into which output signals (sensing signals) from the oxygen analyser 45
and the thermometer 46 are individually input.
[0036] This control system 50 is configured with a computer and so on, functionally including
a burner control section 52 and a refuse feeder control section 54. The burner control
section 52 outputs command respective signals for making temporary shutdown and reignition
of the burner 40. The refuse feeder control section 54 outputs respective command
signals for making temporary shutdown and restart of the refuse feeder 2.
[0037] Described next is the working of this gasification-melting furnace and an operation
control process performed by the control system 50 referring also to a flowchart of
FIG. 4.
[0038] In a "normal operating state" (step S1) shown in FIG. 4, the refuse feeder 2 is
activated and the burner 40 of the melting furnace 4 has been ignited. In this normal
operating state, the refuse feeder 2 feeds refuse like municipal solid wastes into
the gasification furnace 3 through the refuse input port 30 of the furnace 3. The
refuse is brought into a primary combustion in the fluidized bed 26 within the furnace
3, thereby producing pyrolysis gases. The pyrolysis gases are fed from the pyrolysis
gas output port 38 at the furnace top to the pyrolysis gas input port 42 of the melting
furnace 4 through the duct 44 and introduced into the upper portion of the furnace
4 through the input port 42. In the melting furnace 4, combustible constituents in
the pyrolysis gases further combust at a high temperature, thus producing heat which
melts ash contained in the gas into slag. This slag adheres to a furnace wall, and
further flows down into the slag discharging port 43 at a furnace bottom to be withdrawn
to the exterior of the furnace.
[0039] The temperature at the top of the melting furnace 4 is held high by the burner 40
already ignited. However, with the furnace top temperature already reached 1300°C,
spontaneous combustion of unburned components can keep the in-furnace temperature
high for a while, even if operation of the auxiliary burner is stopped. Accordingly,
from a viewpoint of fuel savings and environmental issues (especially in view of restrictions
on CO
2 emissions), an appropriate rest of the burner operation is desirable.
[0040] For the reason, when a current operating state coincides with a preset burner stop
condition (step S2), the control system 50 outputs a burner stop command signal (step
S3) for stopping the operation of the burner 40.
[0041] The burner stop conditions may be set in various ways. For example, the condition
may preferably include the following.
[0042]
- 1) There has been maintained a state in which the furnace-top temperature detected
by the thermometer 46 is equal to or higher than a preset burner stop temperature
(e.g., 1100°C), for a specific period of time (e.g., 30 minutes). A judgment on the
"furnace-top temperature" may be made by checking an instantaneous value at appropriate
sampling intervals or based on a moving average value of the furnace-top temperature
for an appropriate period of time (e.g., the aforementioned specific period of time).
Setting this 1) as a condition has an advantage of allowing the thermometer 46 for
ascertaining fulfillment of the condition to be used also as means for taking a timing
of stopping later-described refuse charge or reigniting the burner.
- 2) A moving average value of low calorific values is equal to or larger than a preset
calorific value (e.g., 2000 kcal/kg). The "low calorific value" referred to herein
means the amount of heat possessed by the refuse fed by the refuse feeder 2 into the
gasification furnace 3 per unit time, corresponding to the amount of heat of waste
material.
[0043] The amount of heat possessed by the refuse, possibly calculated from heat balance
of the waste disposal plant, for example as disclosed in Japanese Unexamined Patent
Publication No.
2004-37049, may be approximately regarded as being equal to exhaust gas heat output Q calculated
based on exhaust gas flow rate Fe (Nm
3/h) detected by an exhaust gas flow meter provided at a location downstream from the
bag filter 12 and exhaust gas temperature Te (°C) detected by an exhaust gas temperature
sensor provided at a like location. Specifically, given the specific heat cE of the
exhaust gas, the exhaust gas heat output Q (kcal/h) is expressed in the following
equation:
[0044] For more precise calorific calculation, preferably taken into consideration are a
heat input by other media (e.g., air, water and auxiliary fuel of the burner 40) and
a heat output by these media, in addition to the exhaust gas heat output Q, for calculation
of the calorific value.
[0045] Only one or both of 1) and 2) mentioned above may be employed as the burner stop
condition. Specifically, the burner 40 may be caused to stop when at least one of
1) and 2) is satisfied or when both of 1) and 2) are satisfied.
[0046] The burner stop command signal output in step S3 may be directly used as a control
signal, or utilized as a notification signal for an operator. In the former case,
the burner stop command signal can realize automatic control of the burner 40, when
input into an actuator of the burner 40. In the latter case, the burner stop command
signal can be input into for instance an operating panel to light an indicator on
the operating panel, thus notifying the operator of a proper burner stop timing to
enable him to stop the operation of the burner 40, by manual intervention, at a proper
timing.
[0047] After thus stopping the operation of the burner 40, the burner 40 is reignitioned
at a proper timing. If the burner 40 is reignited at a temperature equal to or lower
than a spontaneous ignition temperature of the unburned gases after the furnace-top
temperature has become equal to or lower than the spontaneous ignition temperature
for one reason or another following the temporary shutdown of the burner 40, the reignition
of the burner 40 may potentially induce an explosion depending on the concentration
of the unburned gases.
[0048] Accordingly, the control system 50 of this embodiment outputs the refuse charging
stop command signal for stopping refuse charging operation of the refuse feeder 2
(step S5) at a point in time when the furnace-top temperature detected by the thermometer
46 drops down to a preset waste charging stop temperature (900°C in this embodiment)
(Yes in step S4). Similarly to the burner stop command signal, the refuse charging
stop command signal also may be directly input into, for example, a driving portion
of the refuse feeder 2 to function as a signal for automatically stopping the refuse
charging operation of the refuse feeder 2, or may be input into the operating panel
and the like for lighting the indicator thereof to function as a signal for notifying
the operator of a proper refuse charging stop timing.
[0049] In step S4 above, the refuse charging stop command signal may be output immediately
upon the drop down of the furnace-top temperature to the waste charging stop temperature.
However, in order to exclude the risk of the reignition at a point in time when the
furnace-top temperature has suddenly dropped for one reason or another, preferable
is that the refuse charging stop command signal be output after a state where the
furnace-top temperature is lowered to the waste charging stop temperature has been
continued for a specific period of time (e.g., 2 to 20 seconds).
[0050] The aforementioned stoppage of the refuse charging operation increases the concentration
of oxygen contained in the gases fed from the gasification furnace 3 to the melting
furnace 4 to make a safe state for the reignition of the burner 40 in the interior
of the melting furnace 4. In view of this, the control system 50 monitors the oxygen
concentration in the gases detected by the oxygen analyser 45 and outputs a burner
reignition command signal (step S8) at a point in time when the oxygen concentration
has reached a preset burner reignition concentration (10% in this embodiment) (Yes
in step S6).
[0051] If the oxygen concentration has not increased up to the burner reignition concentration,
the control system 50 outputs the burner reignition command signal at a point in time
when the furnace-top temperature reaches a specific temperature (950°C in this embodiment)
higher than the burner reignition temperature due to an increase in the furnace-top
temperature for one reason or another (Yes in step S7). Like the burner stop signal,
this signal also may be directly input into the actuator of the burner 40 to automatically
reignite the burner 40, or may be input into the operating panel to indicate a proper
burner reignition timing to the operator.
[0052] Thereafter, verifying that the refuse feeder 2 is ready to restart (Yes in step S9),
the control system 50 outputs a restart command signal to the refuse feeder 2 to restart
it (step S10). This restarting step may also be performed manually by the operator.
[0053] The above-described operation ensures a high degree of safety of restarting the burner
40 while intending fuel savings and suppression of CO
2 emissions by rest of the burner 40 at a proper timing.
[0054] Another example of operation to ensure such a high degree of safety is shown in FIG.
5. The operation control process shown in this Figure includes operation up to a point
of outputting the burner reignition command signal (step S3) which is equal to what
shown in FIG. 4. After the output of that signal, the control system 50 outputs the
burner reignition command signal (step S12) at a point in time when the furnace-top
temperature has dropped down to a preset burner reignition temperature (1000°C in
this embodiment) (Yes in step S11).
[0055] The burner reignition temperature is set at so high a temperature as to reliably
prevent abnormal combustion of the unburned gases due to reignition of the burner
40 at that temperature to thereby ensure a high degree of safety. In general, desirably
employed is a temperature at which safety has been assured by testing or the like,
the temperature being obtained by multiplying the spontaneous ignition temperature
of the unburned gases (approximately 680°C in the case of natural gas, for example)
by a sufficient safety factor.
[0056] This kind of operation can also prevent excessive cooling of the interior of the
melting furnace 4 in advance and assure a high degree of safety of burner reignition,
by reigniting the burner 40 during the in-furnace temperature drops little after temporary
shutdown of the burner 40.
[0057] This operation may be performed in combination with the operation shown in FIG. 4,
that is, the operation of stopping the refuse charge to increase the oxygen concentration
in the gases at the output port of the gasification furnace, for providing a fail-safe
feature in case the burner 40 is not shut down even when the burner reignition command
signal is output in step S12 or it becomes impossible to output this signal.
[0058] The operation control process shown in FIG. 4 includes determining the burner reignition
timing based on the oxygen concentration in the gas after stopping the refuse charging
operation; however, as a parameter directly affecting the oxygen concentration, according
to the present invention, the cumulative value of the amount of air supplied to an
side upstream from the melting furnace 4 after stoppage of the refuse charging operation
is monitored to determine the burner reignition timing based on this cumulative value.
An example of this will be described with reference to FIGS. 6 and 7.
[0059] A facility shown in FIG. 6 is provided with a blower 60 and a flowmeter 62. The blower
60 is for supplying air to the gasification furnace 3, which air is supplied to the
inside of the wind box 24 of the gasification furnace 3 as fluidization gas, and further
delivered to the inside of the free board 36 as purging air in some cases. The pyrolysis
gas output port 38 is provided at furnace top. The flowmeter 62 is provided on an
outlet side of the blower 60 to detect the flow rate of air supplied from the blower
60 to the gasification furnace 3 and output a sensing signal concerning the detected
flow rate. This sensing signal is input into the control system 50.
[0060] FIG. 7 shows control operation of the control system 50. FIG. 7 shows operation up
to a point of outputting the refuse charging stop command signal (steps S1-S5) which
is equal to the operation performed in the control process shown in FIG. 4. After
the output of the refuse charging stop command signal, the burner control section
52, from a point in time when the refuse charging operation is stopped, accumulates
the amount of air supplied to the gasification furnace 3 based on the aforementioned
sensing signal (step S6A), and outputs the burner reignition command signal (step
S8) at a point in time when the cumulative value thus obtained reaches a preset fixed
value (Yes in step S6B).
[0061] This control operation also enables the burner 40 to be reignited at a timing when
the oxygen concentration in the vicinity of the burner 40 can be assumed to have increased
to a certain extent as a result of air supply from the blower 60 after the temporary
shutdown of the burner 40. This serves to assure a high degree of safety at the time
of restarting the burner 40.
[0062] The air subject to the aforementioned accumulating step includes either air which
is so supplied to the side upstream from the melting furnace 4 as to contribute to
an increased oxygen concentration inside the melting furnace 4. This air is therefore
not limited to the air supplied to the inside of the gasification furnace 3. For example,
the purging air, if supplied to the duct 44 provided between the gasification furnace
3 and the melting furnace 4, is also included in the air subject to the accumulating
step.
[0063] As thus far described, in the course of the invention there is provided an operating
method for operating a gasification-melting furnace provided with a gasification furnace
for gasifying input waste material, a melting furnace configured to burn combustible
constituents contained in pyrolysis gas produced in said gasification furnace and
introduced in the melting furnace and melt ash in the pyrolysis gas, and a burner
for auxiliary combustion provided in the melting furnace. This operating method comprises:
stopping operation of the burner when an operating state of the gasification-melting
furnace satisfies a specific burner stop condition; stopping charge of the waste material
into the gasification furnace at a point in time when the temperature within the melting
furnace in the vicinity of r the burner drops down to a preset waste charging stop
temperature after the operation of the burner has stopped; reigniting the burner at
a point in time when oxygen concentration in the gas delivered from the gasification
furnace to the melting furnace increases up to a preset burner reignition concentration
after the charge of the waste material is stopped.
[0064] The position where the "temperature within the melting furnace in the vicinity of
the burner" is detected, may be appropriately determined within a range where the
burner reignition can cause a combustion of unburned gas.
[0065] The expression "stopping charge of the waste material into the gasification furnace
at a point in time when the temperature within the melting furnace in the vicinity
of the burner drops down to a preset waste charging stop temperature" includes not
only stopping the charge of the waste material at the moment when the temperature
within the gasification furnace has dropped the waste charging stop temperature, but
also stopping the charge of the waste material after a state in which the furnace-top
temperature remains lowered to the waste charging stop temperature has been continued
for a preset period of time, to exclude a case of sudden drop of the furnace-top temperature.
[0066] According to this operating method, at a point in time when the temperature within
the melting furnace in the vicinity of the burner drops down to the preset waste charging
stop temperature (e.g., on the occurrence of a temperature state in which spontaneous
combustion of the unburned gas has become difficult) after the burner is stopped operating,
at first, stopping the charge of the waste material into the gasification furnace
can increase the oxygen concentration in the gas delivered from the gasification furnace
to the melting furnace, and thereafter, the burner reignition at a point in time when
the oxygen concentration has increased up to the preset burner reignition concentration
can ensure prevention of abnormal combustion of the unburned gas due to the reignition,
thus ensuring successful combustion.
[0067] Meanwhile, at a point in time when the temperature within the melting furnace in
the vicinity of the burner increases up to a preset temperature higher than the waste
charging stop temperature (e.g., a temperature sufficiently high to prevent the abnormal
combustion of the unburned gas) after the burner has stopped operating, the burner
may be reignited regardless of the oxygen concentration.
[0068] In this operating method, after the operation of the burner is stopped when the operating
state of the gasification furnace satisfies a specified burner stop condition, the
burner may be reignited at a point in time when the temperature within the melting
furnace in the vicinity of the burner has dropped down to the preset waste charging
stop temperature. This approach also can prevent reignition of the burner in an excessively
low temperature range thereof (e.g., an temperature range in which spontaneous combustion
of the unburned gas hardly occurs), thus assuring successful combustion.
[0069] The burner stop condition may be set as appropriate. However, if this burner stop
condition is such a condition that the temperature within the melting furnace in the
vicinity of the burner or a moving average value thereof has been kept equal to or
higher than a preset burner stop temperature for a specific period of time, means
for detecting the aforementioned temperature can be used to take the waste charging
stop timing or the burner reignition timing as well to make a judgment on the burner
stop condition.
[0070] In the operating method according to the present invention, after stopping the operation
of the burner when the operating state of the gasification-melting furnace satisfies
the specific burner stop condition and stopping charge of the waste material into
the gasification furnace at a point in time when the temperature within the melting
furnace in the vicinity of the burner drops down to the preset waste charging stop
temperature after the burner has stopped operating, the operation for reigniting the
burner is performed when the cumulative value of the amount of air supplied to the
side upstream from the melting furnace from a point in time when the charging of the
waste material is stopped reaches a fixed value. This performance allows a reignition
while ensuring a sufficient oxygen concentration in a combustion range of the burner,
thus assuring successful combustion.
[0071] Provided in the course of the invention as an operation control apparatus for performing
the above-described operating method is an apparatus comprising: a waste feeder for
charging the waste material into the gasification furnace; a thermometer for detecting
the temperature within the melting furnace in the vicinity of the burner; an oxygen
analyser for detecting oxygen concentration in the gas fed from the gasification furnace
to the melting furnace; and a control system for controlling operation of the gasification
furnace based on detection results of the thermometer and the oxygen analyser. The
aforementioned control system includes a burner controller which outputs a burner
stop command signal for stopping the operation of the burner when an operating state
of the gasification-melting furnace satisfies a specific burner stop condition, and
a waste charging controller which outputs a waste charging stop command signal for
stopping the waste charge from charging the waste material into the gasification furnace
at a point in time when the temperature detected by the thermometer drops down to
a preset waste charging stop temperature after the burner has stopped operating. The
burner controller outputs a burner reignition command signal for reigniting the burner
at a point in time when the oxygen concentration detected by the oxygen analyser increases
up to a preset burner reignition concentration after the waste feeder has stopped
charging the waste material.
[0072] In this apparatus, after the burner has stopped operating, the burner controller
may output the burner reignition signal regardless of the oxygen concentration at
a point in time when the temperature within the melting furnace in the vicinity of
the burner detected by the thermometer increases up to a preset temperature higher
than the waste charging stop temperature.
[0073] Also provided as another operation control apparatus for performing the above-described
operating method is an apparatus comprising: a waste feeder for charging waste material
into a gasification furnace; a thermometer for detecting the temperature within a
melting furnace in the vicinity of a burner; and a control system for controlling
operation of the burner based on detection results of the thermometer; wherein the
control system outputs a burner stop signal for stopping the operation of the burner
when an operating state of the gasification-melting furnace satisfies a specific burner
stop condition as well as a burner reignition signal for restarting the operation
of the burner at a point in time when the temperature detected by the thermometer
drops down to a preset burner reignition concentration after the burner has stopped
operating.
[0074] It is preferable that the burner stop condition of the above-described apparatus
includes that the temperature detected by the thermometer or a moving average value
thereof has been kept equal to or higher than a preset burner stop temperature for
a specific period of time.
[0075] Provided as an operation control apparatus for performing the above-described operating
method according to the present invention is an apparatus comprising: a burner controller
which outputs a burner stop signal for stopping operation of a burner when an operating
state of a gasification-melting furnace satisfies a specific burner stop condition;
and a waste charging controller which outputs a waste charging stop command signal
for stopping a waste feeder from charging the waste material into a gasification furnace
at a point in time when the temperature detected by a thermometer drops down to a
preset waste charging stop temperature after the burner has stopped operating, wherein
the burner controller accumulates the amount of air detected by the air quantity detector
from a point in time when the waste feeder has stopped charging the waste material
and outputs a burner reignition signal for restarting the operation of the burner
at a point in time when a cumulative value thus obtained reaches a preset fixed value.
[0076] Each of the above-described operation control apparatuses can configure an excellent
gasification-melting furnace in combination with a gasification furnace for gasifying
input waste material, a waste feeder for charging the waste material into the gasification
furnace, a melting furnace configured to burn combustible constituents contained in
pyrolysis gas produced in said gasification furnace and introduced in the melting
furnace and melt ash in the pyrolysis gas, and a burner for combustion provided in
the melting furnace.
[0077] Next described is an embodiment achieved in the course of the present invention with
reference to FIG. 8.
[0078] FIG. 8 shows the overall configuration of a waste disposal plant including a gasification-melting
furnace to which this embodiment is applied. This plant is provided with a gasification-melting
furnace 110, a refuse feeding section 112 for feeding waste materials, that is, items
of refuse to the gasification-melting furnace 110 and a gas treatment section 114
for treating gases discharged from the gasification-melting furnace 110.
[0079] The refuse feeding section 112 is equipped with a refuse pit 116, a refuse mover
118 and a refuse feeder 120. The refuse pit 116 receives and once stores the items
of refuse to be treated that are carried in from outside the plant. The refuse mover
118, provided with a crane, grasps the refuse in the refuse pit 116 and moves the
same to the refuse feeder 120. The refuse feeder 120 has a hopper 122, which receives
the refuse fed from the refuse mover 118. The amount of charged refuse corresponds
to a refuse charging quantity fed into the gasification-melting furnace 110. The refuse
feeder 120, incorporating a screw conveyer, supplies the refuse thrown into the hopper
122 to the gasification-melting furnace 110.
[0080] The gasification-melting furnace 110 has a gasification furnace 124 and a melting
furnace 126. The gasification furnace 124 performs pyrolytisis of the refuse charged
from the refuse feeder 120, thereby producing pyrolysis gases. As the gasification
furnace 124, can be employed, for example, a known fluidized-bed furnace or kiln.
The melting furnace 126 combusts combustible constituents in the pyrolysis gases at
a high temperature to melt ash contained in the gases into slag. The slag adheres
to a furnace wall of the melting furnace 126, for instance. The melting furnace 126
is provided with a slag discharging port 128 at a furnace bottom. The slag discharging
port 128 is for discharging the slag that adheres to the furnace wall and flows down
therefrom to the exterior of the furnace. In this melting furnace 126, combustion
of auxiliary fuel by an unillustrated burner for adjusting in-furnace temperature
is performed as required.
[0081] The gas treatment section 114 is provided with a waste heat boiler 130, a cooling
chamber 132, a dust collector 134, an induced draft fan 136 and a chimney 138.
[0082] The waste heat boiler 130 is for recovering heat from high-temperature exhaust gas
discharged from the melting furnace 126, specifically for producing steam by using
the heat possessed by the exhaust gas and discharging the steam. The flow rate of
the discharged steam, i.e., the amount of steam produced in the waste heat boiler
130 per unit time, serves as a parameter corresponding to the calorific value of the
refuse charged into the gasification-melting furnace 110 per unit time.
[0083] The cooling chamber 132 is equipped with a tower structure into which gas discharged
from the waste heat boiler 130 is introduced, a sprayer for spraying cooling water
into the tower structure, a temperature sensor for detecting gas temperature at an
outlet of the tower structure and a controller for regulating the flow rate of the
cooling water supplied by the sprayer so as to make the outlet gas temperature detected
by the temperature sensor keep constant.
[0084] The dust collector 134 captures dust or the like contained in the gas discharged
from the cooling chamber 132. The dust-removed gas from the dust collector 134 is
discharged through the chimney 138 via the induced draft fan 136.
[0085] This plant further includes a basicity adjusting unit 140. The basicity adjusting
unit 140, for adjusting the basicity of the slag discharged through the slag discharging
port 128 of the melting furnace 126, comprises a basicity adjuster feeder 142, a steam
flowmeter 144, a refuse charging quantity output portion 146 and a controller 150.
[0086] The basicity adjuster feeder 142, for supplying a basicity adjuster into the refuse
charged into the gasification furnace 124, comprises a screw conveyer 147 which serves
as transport means for supplying the basicity adjuster and a motor 148 for turning
the screw conveyer 147. The basicity adjuster is appropriately selected. This embodiment
is intended only to excessively high basicity of the discharged slag, so that quartz
sand (SiO
2) for decreasing the basicity of the slag is selected as the basicity adjuster.
[0087] The steam flowmeter 144 measures the flow rate of the discharged steam, that is,
the amount of steam produced in the waste heat boiler 130 per unit time.
[0088] The refuse charging quantity output portion 146 outputs an information signal concerning
the weight of the refuse charged into the gasification furnace 124 per unit time.
Specifically, the refuse charging quantity output portion 146 is additionally provided
to the refuse mover 118 to calculate the amount of refuse convey based on the weight
load applied to the refuse mover 118 and the number of moving operations, and to provide
it to the controller 150 as information regarding the amount of refuse charge into
the gasification-melting furnace 110.
[0089] The controller 150, configured with a microcomputer and so on, has a function of
totally controlling the entirety of the plant, including an expected basicity value
calculator 152 and a basicity adjuster quantity regulator 154 to serve a function
of adjusting the basicity of the slag.
[0090] The expected basicity value calculator 152 calculates a predicted value of the basicity
of the slag discharged from the slag discharging port 128, based on the information
signal concerning the weight of the refuse charged into the gasification furnace 124
per unit time and the flow rate of the steam measured by the steam flowmeter 144.
Calculation of this expected value is accomplished by a step of calculating the calorific
value of refuse per unit weight based on the amount of refuse charged per unit time
and the flow rate of the discharged steam and a step of calculating the predicted
value of the basicity based on the calorific value of refuse per unit weight.
[0091] There is a correlation between the flow rate of the discharged steam or the calorific
value of the refuse per unit weight and the slag basicity. This correlation can be
predetermined by actual measurements. Specifically, measuring the actual slag basicity
corresponding to the flow rate of the steam by an analyzer for a particular period
of time enables the correlation to be estimated, as shown in later-discussed Examples.
The correlation can be approximately expressed for example in a first-degree equation
(a linear equation).
[0092] The expected basicity value calculator 152 stores the correlation and calculates
the expected value of the basicity based on the correlation and the flow rate of the
steam actually measured by the steam flowmeter 144.
[0093] As a value of the flow rate of the discharged steam on which the calculation of the
expected value of the basicity is based, adopted is an average value of values by
the steam flowmeter 144 during a specific period of time. This period of time can
be set as appropriate, preferably at about 6 to 24 hours in general terms.
[0094] The basicity adjuster quantity regulator 154 determines the amount of the basicity
adjuster supply for making the basicity approach a preset target value (e.g., 0.5),
based on the expected value of the slag basicity calculated by the expected basicity
value calculator 152 and the information signal concerning the weight of the charged
refuse input from the refuse charging quantity output portion 146. Then, to obtain
the determined amount of supply, the basicity adjuster quantity regulator 154 outputs
a control signal to the motor 148 of the basicity adjuster feeder 142 to control the
rotation speed thereof. In advance can be prepared a relationship between the expected
value and the actual amount of the basicity adjuster supply, based on theory or simulation.
[0095] In the above-described apparatus and method of adjusting the slag basicity performed
in this apparatus, with a focus on the parameter (flow rate of the steam discharged
from the waste heat boiler 130 herein) concerning the calorific value of the refuse
which is closely related to the basicity, the expected value of the basicity is calculated
based on detected values of that parameter and the relationship. This allows the amount
of the basicity adjuster to be supplied to be properly and quickly determined with
a simple configuration using an existing plant, unlike a conventional method in which
operation is carried paralleling measurement of the actual slag basicity by an analyzer.
[0096] This method can be carried out even within a plant not including the aforementioned
waste heat boiler 130. In this case, as a parameter concerning the calorific value
of the refuse can be selected, for example, a flow rate of the cooling water supply
in the cooling chamber 132. Since this cooling chamber 132, as previously described,
is provided with the temperature sensor for detecting gas temperature at the outlet
of the tower structure and the controller for regulating the flow rate of the cooling
water supply by the sprayer so as to keep constant the outlet gas temperature detected
by the temperature sensor, the flow rate of the cooling water supply corresponds to
the calorific value of the refuse charged into the gasification-melting furnace 110
per unit time.
[0097] A feeding position of the basicity adjuster is not limited to an inlet side of the
gasification furnace 124, permitted to be appropriately determined in a range upstream
from the slag discharging port 128. For example, the position may be determined within
a range between the gasification furnace 124 and the melting furnace 126 or inside
a combustion chamber of the melting furnace 126 upstream from the slag discharging
port 128 thereof.
EXAMPLES (not part of the present invention)
[0098] Here are described examples concerning adjustment of the basicity of the slag in
the waste disposal plant shown in FIG. 8.
[0099]
- 1) About correlation between calorific value of refuse per unit weight and basicity
of slag
There exists a correlation between the calorific value of the refuse per unit weight
and the basicity of the slag, which correlation can be approximately assumed to be
a first-degree function.
FIG. 9 shows annual changes in the calorific value of refuse per unit weight (kcal/kg)
and basicity of slag in a certain waste disposal plant. This Figure clearly indicates
that the calorific value of the refuse and the basicity vary similarly to each other.
FIG. 10 is a graphical representation of respective relationships between the calorific
value of refuse and basicity of slag determined by actual measurements in two waste
disposal plants (plant A and plant B). As shown in this Figure, either of plants A
and B has a specific relationship between the calorific value of refuse and basicity
of slag. The two plants A and B are so different from each other in components of
the refuse charged into the gasification-melting furnaces thereof that the respective
relationships between the calorific value of refuse and the basicity of slag in the
plants A and B differ from each other, while both of the relationships can be approximately
assumed to be first-degree functions. Accordingly, each relationship, when input and
stored into the expected basicity value calculator 152 in advance, enables the calculator
152 to quickly calculate an expected value of the slag basicity based on the parameter
corresponding to the calorific value of the refuse (e.g., flow rate of the steam discharged
from the waste heat boiler 30).
- 2) About relationship between expected value of basicity of slag and amount of basicity
adjuster
It is possible to determine the relationship between the expected value of the slag
basicity and the amount of the basicity adjuster supply in advance based on theory
or simulation. For example, under the assumption of only down adjustment of the slag
basicity, a relationship between the amount of the basicity adjuster (e.g., quartz
sand) to be supplied (the amount of supply corresponding to the amount of refuse charged
per unit time) and the expected value of the basicity is preferably set as shown in
FIG. 11. According to this setting, when the expected value of the basicity exceeds
a target value (e.g., 0.5), the basicity adjuster is supplied in a quantity corresponding
to an excess amount of the expected value.
[0100] As thus far described, this embodiment provides a method of adjusting basicity of
slag in operating a gasification-melting furnace which brings charged waste material
into pyrolysis and melts ash in pyrolysis gas produced by the pyrolysis, the gasification-melting
furnace having a slag discharging port for discharging the slag produced by melting
the ash. The basicity adjusting method comprising: a step of supplying a basicity
adjuster for adjusting the basicity of the slag discharged through the slag discharging
port at a position upstream therefrom; a step of detecting the weight of the waste
material charged into the gasification-melting furnace per unit time; a step of detecting
a parameter corresponding to the calorific value of the waste material per unit weight;
a step of calculating an expected value of the basicity of the slag produced inside
the gasification-melting furnace based on a detected value of the parameter, and a
step of regulating the amount of the basicity adjuster supply toward a preset target
value of the basicity, based on the calculated expected value of the basicity.
[0101] In this basicity adjusting method, utilizing a correlation between the parameter
corresponding to the calorific value of the waste material per unit weight and the
actual slag basicity allows the expected value of the actual slag basicity to be obtained
without a complicated analysis of the slag composition. In short, the expected value
of the basicity can be calculated based on the detected value of the parameter and
the correlation. Based on the expected value of the slag basicity, a proper amount
of the basicity adjuster addition is determined.
[0102] Specifically, as the parameter corresponding to the calorific value of the waste
material per unit weight is effectively detected an amount of steam produced in a
waste heat boiler per unit time by use of heat of gas discharged from the gasification-melting
furnace. The amount of steam production is easily detected. Moreover, based on the
amount of steam thus produced and the amount of the waste material charged into the
gasification-melting furnace per unit time, the calorific value of the waste material
per unit weight can be properly calculated.
[0103] As specific means for calculating the expected value of the basicity, for example,
effective is a method including a step of determining a relationship between the parameter
and the actual slag basicity by actual measurement, in advance of the step of calculating
the expected value of the basicity of the slag produced in the gasification-melting
furnace, wherein the expected value of the basicity of the slag produced in the gasification-melting
furnace is calculated based on the relationship and the detected value of the parameter.
In this method, a proper expected value of the basicity of the slag is quickly calculated
based on the relationship between the predetermined parameter and the actual slag
basicity.
[0104] Also provided is a basicity adjusting apparatus of a gasification-melting furnace
for performing the above-described basicity adjusting method. This apparatus comprises:
a basicity adjuster feeder for supplying a basicity adjuster for adjusting basicity
of slag discharged through a slag discharging port at a position upstream therefrom;
a waste material charging quantity detector for detecting the weight of waste material
charged into the gasification-melting furnace per unit time; a parameter detector
for detecting a parameter corresponding to the calorific value of the waste material
per unit weight; an expected basicity value calculator for calculating an expected
value of the basicity of the slag produced inside the gasification-melting furnace
based on a detected value of the parameter; and a basicity adjuster quantity regulator
for regulating the amount of the basicity adjuster supply so as to make the slag basicity
approach a preset target value of the basicity, based on the expected value of the
basicity.
[0105] The parameter detector of this apparatus, for example, preferably detects the amount
of steam produced in a waste heat boiler per unit time by use of heat of gas discharged
from the gasification-melting furnace. In this case, the expected basicity value calculator
can calculate the calorific value of the waste material per unit weight based on the
parameter detected by the parameter detector and the amount of the waste material
charged into the gasification-melting furnace per unit time.
[0106] Also, the basicity adjuster quantity regulator, for example, preferably stores a
relationship between the parameter determined by actual measurement and the actual
basicity of the slag, and determines the amount of the basicity adjuster supply based
on the relationship thus stored and the detected value of the parameter.