FIELD OF THE INVENTION
[0001] The present invention relates to a laundry treatment composition comprising 1,2-benzisothiazol-3(2
H)-one, methods of making said compositions, methods of using said composition and
use of 1,2-benzisothiazol-3(2
H)-one.
BACKGROUND OF THE INVENTION
[0002] Laundry treatment compositions are known and used by consumers. Such treatment compositions
can impart a number of different benefits to fabrics, including, but not limited to
freshness, malodour control, cleaning and softening.
[0003] During manufacture, transport and storage, it is preferably to minimise unwanted
microbial growth in such laundry treatment compositions. Therefore, there is an on-going
need to identify suitable anti-microbial materials to formulate into laundry treatment
compositions in order to minimise microbial growth therein. Preferably, the anti-microbial
material should be physically and chemically stable in the laundry treatment composition
and compatibility with other materials in laundry treatment composition. Such stability
should include colour stability, odour stability and enzyme stability. Additionally,
if the laundry treatment composition is comprised in a water-soluble unit dose article,
the anti-microbial should have no negative impact on the water-soluble film.
[0004] It was surprisingly found that formulation of 1,2-benzisothiazol-3(2
H)-one (BIT) into laundry treatment compositions minimised microbial growth in said
compositions. In addition, it was surprisingly found that laundry compositions comprising
1,2-benzisothiazol-3(2
H)-one and perfume are less prone to discoloration and had greater odour stability.
SUMMARY OF THE INVENTION
[0005] A first aspect of the present invention is a laundry treatment composition comprising
1,2-benzisothiazol-3(2
H)-one.
[0006] A second aspect of the present invention is a method of making a laundry treatment
composition according to the present invention wherein the method comprises;
- a. a step of directly mixing 1,2-benzisothiazol-3(2H)-one with other ingredients commonly used in liquid treatment compositions; or
- b. a step of preparing a perfume capsule premix, wherein the perfume capsule premix
comprises perfume core/shell capsules, wherein the perfume core/shell capsules comprise
perfume and a shell, wherein the shell is made from melamine formaldehyde, polyacrylate
or a mixture thereof, and wherein the perfume capsule premix comprises between 50ppm
and 100ppm, preferably between 60ppm and 80ppm of 1,2-benzisothiazol-3(2H)-one, and adding the perfume capsule premix to other ingredients commonly used in
laundry treatment compositions so that the laundry treatment composition comprises
between 0.1% and 5%, preferably between 0.2% and 2.5% by weight of the laundry treatment
composition of perfume core/shell capsules; or
- c. a step of preparing a structurant premix, wherein the thickener premix comprises
a structurant, preferably hydrogenated castor oil, and wherein the structurant premix
comprises between 80ppm and 120ppm, preferably between 90ppm and 100ppm of 1,2-benzisothiazol-3(2H)-one, and adding the structurant premix to other ingredients commonly used in laundry
treatment compositions so that the laundry treatment composition comprises between
0.01% and 1%, preferably between 0.03% and 0.5%, more preferably between 0.05% and
0.2% of the structurant, preferably of hydrogenated castor oil; or
- d. adding 1,2-benzisothiazol-3(2H)-one as a premix with one or more other materials typically used in the laundry treatment
composition; or
- e. a mixture thereof.
[0007] A third aspect of the present invention is a method of treating fabrics, comprising
the steps of diluting the fabric treatment composition according to the present invention
in water by between 100 and 3000, preferably between 100 and 800 fold to make a treatment
liquor and contacting fabrics with said treatment liquor.
[0008] A fourth aspect of the present invention is the use of 1,2-benzisothiazol-3(2
H)-one in a laundry treatment composition to reduce microbial growth in the laundry
treatment composition.
DETAILED DESCRIPTION OF THE INVENTION
Laundry treatment composition
[0009] A first aspect of the present invention is a laundry treatment composition comprising
1,2-benzisothiazol-3(2
H)-one which has the formula;
[0010] 1,2-benzisothiazol-3(2
H)-one minimizes microbial growth of gram positive bacteria, gram negative bacteria
and a mixture thereof.
[0011] By 'fabric treatment composition' we here mean any composition capable of providing
a benefit to a fabric upon contact of said treatment composition with said fabric.
For example, the benefit may be fabric cleaning, fabric softening, fabric conditioning
or a mixture thereof. Fabric conditioning includes fabric shape retention, fabric
restoration (e.g. colour restoration) or a mixture thereof.
[0012] Preferably, the fabric treatment composition is diluted in water to create a treatment
liquor and the fabric is contacted with said treatment liquor. A process of treating
the fabric is described in more detail below.
[0013] The laundry treatment composition may be selected from a laundry detergent composition,
a laundry softening composition, a laundry perfuming composition or a mixture thereof.
[0014] Laundry detergent compositions provide cleaning benefit to fabrics. Such cleaning
benefit include general soil removal, stain removal, whiteness benefit, colour restoration,
dye transfer inhibition or a mixture thereof.
[0015] Laundry softening compositions provide softening benefits to fabrics. Such softening
benefits include a perceived softness or silkiness feel to the fabric.
[0016] Laundry perfuming compositions provide fabric freshness benefits, fabric malodour
benefits or a mixture thereof.
[0017] The laundry treatment composition may be selected from a liquid, a gel, a powder
or a mixture thereof.
[0018] The laundry treatment composition preferably comprises between 0.5ppm and 200ppm,
more preferably between 1ppm and 110ppm of the 1,2-benzisothiazol-3(2
H)-one.
[0019] The laundry treatment composition may be a liquid laundry detergent composition.
The liquid laundry detergent composition preferably comprises between 40% and 80%,
more preferably between 50% and 75% by weight of the liquid laundry detergent composition
of water. The liquid laundry detergent composition preferably comprises between 25ppm
and 110ppm, more preferably between 30ppm and 105ppm of 1,2-benzisothiazol-3(2
H)-one.
[0020] The laundry treatment composition may be a liquid fabric softening composition. The
liquid fabric softening composition preferably comprises between 70% and 98%, more
preferably between 75% and 95% by weight of the liquid fabric softening composition
of water. Preferably, the liquid fabric softening composition comprises between 0ppm
and 2ppm, more preferably between 0.001ppm and 1.75ppm, even more preferably between
0.01ppm and 1.5ppm of 1,2-benzisothiazol-3(2
H)-one.
[0021] The laundry treatment composition may be a powder laundry detergent composition.
Preferably, the powder laundry detergent composition comprises between 0ppm and 2ppm,
more preferably between 0.001ppm and 1.75ppm, even more preferably between 0.01ppm
and 1.5ppm of 1,2-benzisothiazol-3(2
H)-one. The powder laundry detergent composition preferably is a granular laundry detergent
composition. The granular laundry detergent composition may comprise blown powder
granules, agglomerated granules, extruded granules or a mixture thereof.
[0022] The laundry treatment composition may be a compacted liquid laundry detergent composition.
The compacted liquid treatment composition preferably comprises between 1% and 50%,
more preferably between 1% and 40% by weight of the compacted liquid laundry detergent
composition of water. Preferably, the compacted liquid laundry detergent composition
comprises between 0.5ppm and 25ppm, more preferably between 0.5ppm and 20ppm, even
more preferably between 0.5ppm and 15ppm of 1,2-benzisothiazol-3(2
H)-one.
[0023] The compacted laundry treatment composition may be a high viscous liquid, such as
a gel.
[0024] The compacted liquid laundry detergent composition is preferably comprised in a water-soluble
unit dose article wherein the water-soluble unit dose article comprises a water-soluble
polyvinyl alcohol film, and wherein the compacted liquid laundry detergent composition
comprised in the water-soluble unit dose article comprises between 1% and 25%, preferably
between 2% and 13% by weight of the liquid laundry detergent composition of water.
[0025] The water-soluble unit dose article comprises the water-soluble film shaped such
that the unit-dose article comprises at least one internal compartment surrounded
by the water-soluble film. The unit dose article may comprise a first water-soluble
film and a second water-soluble film sealed to one another such to define the internal
compartment. The water-soluble unit dose article is constructed such that the laundry
treatment composition does not leak out of the compartment during storage. However,
upon addition of the water-soluble unit dose article to water, the water-soluble film
dissolves and releases the contents of the internal compartment into the wash liquor.
[0026] The compartment should be understood as meaning a closed internal space within the
unit dose article, which holds the laundry treatment composition. During manufacture,
a first water-soluble film may be shaped to comprise an open compartment into which
the laundry treatment composition is added. A second water-soluble film is then laid
over the first film in such an orientation as to close the opening of the compartment.
The first and second films are then sealed together along a seal region.
[0027] The unit dose article may comprise more than one compartment, even at least two compartments,
or even at least three compartments. The compartments may be arranged in superposed
orientation, i.e. one positioned on top of the other. In such an orientation the unit
dose article will comprise three films, top, middle and bottom. Alternatively, the
compartments may be positioned in a side-by-side orientation, i.e. one orientated
next to the other. The compartments may even be orientated in a 'tyre and rim' arrangement,
i.e. a first compartment is positioned next to a second compartment, but the first
compartment at least partially surrounds the second compartment, but does not completely
enclose the second compartment. Alternatively, one compartment may be completely enclosed
within another compartment.
[0028] Wherein the unit dose article comprises at least two compartments, one of the compartments
may be smaller than the other compartment. Wherein the unit dose article comprises
at least three compartments, two of the compartments may be smaller than the third
compartment, and preferably the smaller compartments are superposed on the larger
compartment. The superposed compartments preferably are orientated side-by-side.
[0029] In a multi-compartment orientation, the laundry treatment composition according to
the present invention may be comprised in at least one of the compartments. It may
for example be comprised in just one compartment, or may be comprised in two compartments,
or even in three compartments.
[0030] Each compartment may comprise the same or different compositions. The different compositions
could all be in the same form, or they may be in different forms.
[0031] The 1,2-benzisothiazol-3(2
H)-one may be present in one compartment, more than one compartment or all compartments.
Each compartment may comprise between 0.5ppm and 25ppm, more preferably between 0.5ppm
and 20ppm, even more preferably between 0.5ppm and 15ppm of 1,2-benzisothiazol-3(2
H)-one.
[0032] The water-soluble film is soluble in water. The water-soluble film preferably has
a thickness of from 20 to 150 micron, preferably 35 to 125 micron, even more preferably
50 to 110 micron, most preferably about 76 micron.
[0033] Preferably, the film has a water-solubility of at least 50%, preferably at least
75% or even at least 95%, as measured by the method set out here after using a glass-filter
with a maximum pore size of 20 microns:
5 grams ± 0.1 gram of film material is added in a pre-weighed 3L beaker and 2L ± 5ml
of distilled water is added. This is stirred vigorously on a magnetic stirrer, Labline
model No. 1250 or equivalent and 5 cm magnetic stirrer, set at 600 rpm, for 30 minutes
at 30°C. Then, the mixture is filtered through a folded qualitative sintered-glass
filter with a pore size as defined above (max. 20 micron). The water is dried off
from the collected filtrate by any conventional method, and the weight of the remaining
material is determined (which is the dissolved or dispersed fraction). Then, the percentage
solubility or dispersability can be calculated.
[0034] Preferred film materials are preferably polymeric materials. The film material can,
for example, be obtained by casting, blow-moulding, extrusion or blown extrusion of
the polymeric material, as known in the art.
[0035] Preferred polymers, copolymers or derivatives thereof suitable for use as pouch material
are selected from polyvinyl alcohols, polyvinyl pyrrolidone, polyalkylene oxides,
acrylamide, acrylic acid, cellulose, cellulose ethers, cellulose esters, cellulose
amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides,
polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides including
starch and gelatine, natural gums such as xanthum and carragum. More preferred polymers
are selected from polyacrylates and water-soluble acrylate copolymers, methylcellulose,
carboxymethylcellulose sodium, dextrin, ethylcellulose, hydroxyethyl cellulose, hydroxypropyl
methylcellulose, maltodextrin, polymethacrylates, and most preferably selected from
polyvinyl alcohols, polyvinyl alcohol copolymers and hydroxypropyl methyl cellulose
(HPMC), and combinations thereof. Preferably, the level of polymer in the pouch material,
for example a PVA polymer, is at least 60%. The polymer can have any weight average
molecular weight, preferably from about 1000 to 1,000,000, more preferably from about
10,000 to 300,000 yet more preferably from about 20,000 to 150,000.
[0036] Preferably, the water-soluble film comprises polyvinyl alcohol polymer or copolymer,
preferably a blend of polyvinylalcohol polymers and/or polyvinylalcohol copolymers,
preferably selected from sulphonated and carboxylated anionic polyvinylalcohol copolymers
especially carboxylated anionic polyvinylalcohol copolymers, most preferably a blend
of a polyvinylalcohol homopolymer and a carboxylated anionic polyvinylalcohol copolymer.
[0037] Preferred films exhibit good dissolution in cold water, meaning unheated distilled
water. Preferably such films exhibit good dissolution at temperatures of 24°C, even
more preferably at 10°C. By good dissolution it is meant that the film exhibits water-solubility
of at least 50%, preferably at least 75% or even at least 95%, as measured by the
method set out here after using a glass-filter with a maximum pore size of 20 microns,
described above.
[0038] Preferred films are those supplied by Monosol under the trade references M8630, M8900,
M8779, M8310.
[0039] The film may be opaque, transparent or translucent. The film may comprise a printed
area.
[0040] The area of print may be achieved using standard techniques, such as flexographic
printing or inkjet printing.
[0041] The film may comprise an aversive agent, for example a bittering agent. Suitable
bittering agents include, but are not limited to, naringin, sucrose octaacetate, quinine
hydrochloride, denatonium benzoate, or mixtures thereof. Any suitable level of aversive
agent may be used in the film. Suitable levels include, but are not limited to, 1
to 5000ppm, or even 100 to 2500ppm, or even 250 to 2000rpm.
[0042] The film may comprise 1,2-benzisothiazol-3(2
H)-one.
[0043] Preferably, the laundry treatment composition comprises less than 15ppm of 2-Methyl-1,2-thiazol-3(2
H)-one (MIT). Preferably the laundry treatment composition comprises no MIT. MIT has
the following structure;
[0044] The laundry treatment composition preferably comprises an adjunct material. The adjunct
material is preferably selected from linear alkylbenzene sulphonate, alkyl sulphate,
alkoxylated alkyl sulphate, fatty alcohol alkoxylates, oxo-synthesised alcohol alkoxylate,
Guerbet alcohol alkoxylates, alkyl phenol alcohol alkoxylates, amine oxide, fatty
acid, neutralised fatty acid salt, citric acid, ethoxylated polyethyleneimine, zwitterionic
polyamine, amphiphilic graft copolymer, polyester terephthalate, polysaccharides,
cationic polysaccharides, monoethanolamine, triethanolamine, ethanol, glycerol, dipropylene
glycol, 1,2-propanediol, hemicellulases, peroxidases, proteases, cellulases, xylanases,
lipases, phospholipases, esterases, cutinases, pectinases, keratanases, reductases,
oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases,
malanases, β-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, amylases,
brighteners, hydrogenated castor oil, perfumes, core/shell perfume capsules, silicones,
quaternary ammonium compounds, bleaches, carbonates, silicates, sulphates, polyethylene
glycol, dyes, hueing dyes, as ethylenediamine-N'N'-disuccinic acid (EDDS) and/or hydroxyethane
diphosphonic acid (HEDP), tetraacetylethylene diamine (TAED) and/or nonanoyloxybenzenesulphonate
(NOBS), or mixture thereof.
[0045] The polysaccharide may be carboxymethylcellulose.
[0046] The cationic polysaccharide may be selected from cationically modified hydroxyethyl
cellulose, cationically modified hydroxypropyl cellulose, cationically and hydrophobically
modified hydroxyethyl cellulose, cationically and hydrophobically modified hydroxypropyl
cellulose, or a mixture thereof, more preferably cationically modified hydroxyethyl
cellulose, cationically and hydrophobically modified hydroxyethyl cellulose, or a
mixture thereof.
[0047] The linear alkylbenzene sulphonate may be a C
10-C
16 linear alkylbenzene sulphonate or a C
11-C
14 linear alkylbenzene sulphonate or a mixture thereof.
[0048] The alkoxylated alkyl sulphate is preferably an ethoxylated alkyl sulphate, preferably
with an average degree of ethoxylation between 1 and 5, preferably between 1 and 3.
Preferably the alkyl chain of the alkoxylated alkyl sulphate is between 10 and 18
carbons, more preferably between 12 and 16 carbons.
[0049] Preferably the quaternary ammonium compound is selected from those having the formula;
[R
(4-m)-N
+-R
1m]X
-
wherein each R comprises either hydrogen, a short chain C
1-C
6 alkyl, preferably a C
1-C
3 alkyl or hydroxyalkyl group, for example methyl, ethyl, propyl, hydroxyethyl, poly(C
2-3 alkoxy), polyethoxy, benzyl, or mixtures thereof; each m is 1, 2 or 3 with the proviso
that the value of each m is the same; the sum of carbons in each R
1 may be C
12-C
22, with each R
1 being a hydrocarbyl, or substituted hydrocarbyl group; and X
- may comprise any softener-compatible anion. X
- may comprise chloride, bromide, methylsulfate, ethylsulfate, sulfate, and nitrate.
[0050] Non-limiting examples of suitable quaternary ammonium compounds include dialkylenedimethylammonium
salts such as dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride
dicanoladimethylammonium methylsulfate, and mixtures thereof. An example of commercially
available dialkylenedimethylammonium salts usable in the present invention is dioleyldimethylammonium
chloride available from Witco Corporation under the trade name Adogen® 472 and dihardtallow
dimethylammonium chloride available from Akzo Nobel Arquad 2HT75.
[0051] The hueing dyes may comprise polymeric or non-polymeric dyes, pigments, or mixtures
thereof. Preferably the hueing dye comprises a polymeric dye, comprising a chromophore
constituent and a polymeric constituent. The chromophore constituent is characterized
in that it absorbs light in the wavelength range of blue, red, violet, purple, or
combinations thereof upon exposure to light. In one aspect, the chromophore constituent
exhibits an absorbance spectrum maximum from about 520 nanometers to about 640 nanometers
in water and/or methanol, and in another aspect, from about 560 nanometers to about
610 nanometers in water and/or methanol.
[0052] Although any suitable chromophore may be used, the dye chromophore is preferably
selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole,
napthoquinone, anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and
phthalocyanine dye chromophores. Mono and di-azo dye chromophores are preferred.
[0053] The hueing dye may comprise a dye polymer comprising a chromophore covalently bound
to one or more of at least three consecutive repeat units. It should be understood
that the repeat units themselves do not need to comprise a chromophore. The dye polymer
may comprise at least 5, or at least 10, or even at least 20 consecutive repeat units.
[0054] The repeat unit can be derived from an organic ester such as phenyl dicarboxylate
in combination with an oxyalkyleneoxy and a polyoxyalkyleneoxy. Repeat units can be
derived from alkenes, epoxides, aziridine, carbohydrate including the units that comprise
modified celluloses such as hydroxyalkylcellulose; hydroxypropyl cellulose; hydroxypropyl
methylcellulose; hydroxybutyl cellulose; and, hydroxybutyl methylcellulose or mixtures
thereof. The repeat units may be derived from alkenes, or epoxides or mixtures thereof.
The repeat units may be C2-C4 alkyleneoxy groups, sometimes called alkoxy groups,
preferably derived from C2-C4 alkylene oxide. The repeat units may be C2-C4 alkoxy
groups, preferably ethoxy groups.
[0055] For the purposes of the present invention, the at least three consecutive repeat
units form a polymeric constituent. The polymeric constituent may be covalently bound
to the chromophore group, directly or indirectly via a linking group. Examples of
suitable polymeric constituents include polyoxyalkylene chains having multiple repeating
units. In one aspect, the polymeric constituents include polyoxyalkylene chains having
from 2 to about 30 repeating units, from 2 to about 20 repeating units, from 2 to
about 10 repeating units or even from about 3 or 4 to about 6 repeating units. Non-limiting
examples of polyoxyalkylene chains include ethylene oxide, propylene oxide, glycidol
oxide, butylene oxide and mixtures thereof.
[0056] The shell of the core/shell perfume capsule may comprise polyacrylate polymer. The
shell may include from about 50% to about 100%, or from about 70% to about 100%, or
from about 80% to about 100% of a polyacrylate polymer. The polyacrylate may include
a polyacrylate cross linked polymer.
[0057] The shell material may include a material selected from the group consisting of a
polyacrylate, a polyethylene glycol acrylate, a polyurethane acrylate, an epoxy acrylate,
a polymethacrylate, a polyethylene glycol methacrylate, a polyurethane methacrylate,
an epoxy methacrylate, and mixtures thereof.
[0058] The shell material of the capsules may include a polymer derived from a material
that comprises one or more multifunctional acrylate moieties. The multifunctional
acrylate moiety may be selected from the group consisting of tri-functional acrylate,
tetra- functional acrylate, penta-functional acrylate, hexa-functional acrylate, hepta-functional
acrylate and mixtures thereof. The multifunctional acrylate moiety is preferably hexa-functional
acrylate. The shell material may include a polyacrylate that comprises a moiety selected
from the group consisting of an acrylate moiety, methacrylate moiety, amine acrylate
moiety, amine methacrylate moiety, a carboxylic acid acrylate moiety, carboxylic acid
methacrylate moiety and combinations thereof, preferably an amine methacrylate or
carboxylic acid acrylate moiety.
[0059] The shell material may include a material that comprises one or more multifunctional
acrylate and/or methacrylate moieties. The ratio of material that comprises one or
more multifunctional acrylate moieties to material that comprises one or more methacrylate
moieties may be from about 999:1 to about 6:4, preferably from about 99:1 to about
8:1, more preferably from about 99:1 to about 8.5:1.
[0060] The core/shell capsule may comprise an emulsifier, wherein the emulsifier is preferably
selected from anionic emulsifiers, nonionic emulsifiers, cationic emulsifiers or mixtures
thereof, preferably nonionic emulsifiers.
[0061] The core/shell capsule may comprise from 0.1 % to 1.1% by weight of the core/shell
capsule of polyvinyl alcohol.
[0062] Polyacrylate perfume capsules can be purchased from Encapsys, (825 East Wisconsin
Ave, Appleton, WI 54911), and are made as follows: a first oil phase, consisting of
37.5 g perfume, 0.2 g tert-butylamino ethyl methacrylate, and 0.2 g beta hydroxyethyl
acrylate is mixed for about 1 hour before the addition of 18 g CN975 (Sartomer, Exter,
PA). The solution is allowed to mix until needed later in the process.
[0063] A second oil phase consisting of 65 g of the perfume oil, 84 g isopropyl myristate,
1 g 2,2'-azobis(2-methylbutyronitrile), and 0.8 g 4,4'-azobis[4-cyanovaleric acid]
is added to a jacketed steel reactor. The reactor is held at 35°C and the oil solution
in mixed at 500 rpm's with a 2" flat blade mixer. A nitrogen blanket is applied to
the reactor at a rate of 300cc/min. The solution is heated to 70°C in 45 minutes and
held at 70°C for 45 minutes, before cooling to 50°C in 75 minutes. At 50°C, the first
oil phase is added and the combined oils are mixed for another 10 minutes at 50°C.
[0064] The shell may comprise polyurea or polyurethane and may be prepared using one or
more polyisocyanates and one or more cross-linker agents.
[0065] A polyisocyanate is a molecule having two or more isocyanate groups, i.e., O=C=N-,
wherein said polyisocyanate can be aromatic, aliphatic, linear, branched, or cyclic.
In certain aspects, the polyisocyanate contains, on average, 2 to 4 -N=C=O groups.
In particular aspects, the polyisocyanate contains at least three isocyanate functional
groups. In certain aspects, the polyisocyanate is water-insoluble.
[0066] The polyisocyanate can be an aromatic or aliphatic polyisocyanate. Desirable aromatic
polyisocyanates each have a phenyl, tolyl, xylyl, naphthyl or diphenyl moiety or a
combination thereof as the aromatic component. The aromatic polyisocyanate may be
a polymeric methylene diphenyl diisocyanate ("PMDI"), a polyisocyanurate of toluene
diisocyanate, a trimethylol propane-adduct of toluene diisocyanate or a trimethylol
propane-adduct of xylylene diisocyanate. Suitable aliphatic polyisocyanates include
trimers of hexamethylene diisocyanate, trimers of isophorone diisocyanate or biurets
of hexamethylene diisocyanate. Additional examples include those commercially available,
e.g., BAYHYDUR N304 and BAYHYDUR N305, which are aliphatic water-dispersible polyisocyanates
based on hexamethylene diisocyanate; DESMODUR N3600, DESMODUR N3700, and DESMODUR
N3900, which are low viscosity, polyfunctional aliphatic polyisocyanates based on
hexamethylene diisocyanate; and DESMODUR 3600 and DESMODUR N100 which are aliphatic
polyisocyanates based on hexamethylene diisocyanate, each of which is available from
Bayer Corporation (Pittsburgh, Pa.).
[0067] Specific examples of polyisocyanates include 1,5-naphthylene diisocyanate, 4,4'-diphenylmethane
diisocyanate (MDI), hydrogenated MDI (H12MDI), xylylene diisocyanate (XDI), tetramethylxylol
diisocyanate (TMXDI), 4,4'-diphenyldimethylmethane diisocyanate, di- and tetraalkyldiphenylmethane
diisocyanate, 4,4'-dibenzyl diisocyanate, 1,3-phenylene diisocyanate, 1,4-phenylene
diisocyanate, the isomers of tolylene diisocyanate (TDI), optionally in a mixture,
1-methyl-2,4-diisocyanatocyclohexane, 1,6-diisocyanato-2,2,4-trimethylhexane, 1,6-diisocyanato-2,4,4-trimethylhexane,
1-isocyanatomethyl-3-isocyanato-1 ,5,5-trimethylcyclohexane, chlorinated and brominated
diisocyanates, phosphorus-containing diisocyanates, 4,4'-diisocyanatophenylperfiuoroethane,
tetramethoxybutane 1,4-diisocyanate, butane 1,4-diisocyanate, hexane 1,6-diisocyanate
(HDI), dicyclohexylmethane diisocyanate, cyclohexane 1,4-diisocyanate, ethylene diisocyanate,
phthalic acid bisisocyanatoethyl ester, also polyisocyanates with reactive halogen
atoms, such as 1-chloromethylphenyl 2,4-diisocyanate, 1-bromomethylphenyl 2,6-diisocyanate,
3,3-bischloromethyl ether 4,4'-diphenyldiisocyanate.
[0068] Other suitable commercially-available polyisocyanates include LUPRANATE M20 (PMDI,
commercially available from BASF containing isocyanate group "NCO" 31.5 wt %), where
the average n is 0.7; PAPI 27 (PMDI commercially available from Dow Chemical having
an average molecular weight of 340 and containing NCO 31.4 wt %) where the average
n is 0.7; MONDUR MR (PMDI containing NCO at 31 wt % or greater, commercially available
from Bayer) where the average n is 0.8; MONDUR MR Light (PMDI containing NCO 31.8
wt %, commercially available from Bayer) where the average n is 0.8; MONDUR 489 (PMDI
commercially available from Bayer containing NCO 30-31.4 wt %) where the average n
is 1.0; poly [(phenylisocyanate)-co-formaldehyde] (Aldrich Chemical, Milwaukee, Wis.),
other isocyanate monomers such as DESMODUR N3200 (poly(hexamethylene diisocyanate)
commercially available from Bayer), and TAKENATE D110-N (xylene diisocyanate adduct
polymer commercially available from Mitsui Chemicals corporation, Rye Brook, N.Y.,
containing NCO 11.5 wt %), DESMODUR L75 (a polyisocyanate base on toluene diisocyanate
commercially available from Bayer), DESMODUR IL (another polyisocyanate based on toluene
diisocyanate commercially available from Bayer), and DESMODUR RC (a polyisocyanurate
of toluene diisocyanate).
[0069] The average molecular weight of certain suitable polyisocyanates varies from 250
to 1000 Da and preferable from 275 to 500 Da. In general, the range of the polyisocyanate
concentration varies from 0.1% to 10%, preferably from 0.1% to 8%, more preferably
from 0.2 to 5%, and even more preferably from 1.5% to 3.5%, all based on the weight
of the core/shell perfume capsule.
[0070] Cross-linkers or cross-linking agents suitable for use with polyisocyanates each
contain multiple (i.e., two or more) functional groups (e.g., -NH-, -NH2 and -OH)
that can react with polyisocyanates to form polyureas or polyurethanes. Examples include
polyfunctional amines containing two or more amine groups (e.g., polyamines), polyfunctional
alcohols containing two or more hydroxyl groups (e.g., polyols), epoxy cross-linkers,
acrylate crosslinkers, and hybrid cross-linking agents containing one or more amine
groups and one or more hydroxyl groups. Amine groups in the cross-linking agents include
-NH2and R*NH, R* being substituted and unsubstituted C
1-C
20 alkyl, C
1-C
20 heteroalkyl, C
1-C
20 cycloalkyl, 3- to 8-membered heterocycloalkyl, aryl, and heteroaryl.
[0071] Two classes of such polyamines include polyalkylene polyamines. Examples of the first
class of polyalkylene polyamines include ethylene diamine, 1,3-diaminepropane, diethylene
triamine, triethylene tetramine, 1,4-diaminobutane, hexaethylene diamine, hexamethylene
diamine, pentaethylenehexamine, melamine and the like. Exemplary amines of the second
class of polyalkylene polyamines also include diethylenetriamine, bis(3-aminopropyl)amine,
bis(3-aminopropyl)-ethylenediamine, bis(hexanethylene)triamine.
[0072] Another class of amine that can be used in the invention is polyetheramines. They
contain primary amino groups attached to the end of a polyether backbone. The polyether
backbone is normally based on either propylene oxide (P0), ethylene oxide (EO), or
mixed P0/EQ. Exemplary polyetheramines include 2,2-(ethylenedioxy)-bis (ethylamine)
and 4,7,10-trioxa- 1, 13-tridecanediamine.
[0073] Other suitable amines include, but are not limited to, tris(2-aminoethyl)amine, triethylenetetramine,
N,N'-bis (3-aminopropyl)- 1,3-propanediamine, tetraethylene pentamine, 1,2-diaminopropane,
1,2-diaminoethane, N,N,N',N'-tetrakis(2-hydroxyethyl) ethylene diamine, N,N,N',N'-tetrakis(2-hydroxypropyl)ethylene
diamine, N,N, N',N'-tetrakis(3-aminopropyl)-1,4-butanediamine, 3,5-diamino-1,2,4-triazole,
branched polyethylenimine, 2,4-diamino-6-hydroxypyrimidine and 2,4,6-triaminopyrimidine.
[0074] Branched polyethylenimines useful as cross-linking agents typically have a molecular
weight of 200 to 2,000,000 Da (e.g., 800 to 2,000,000 Da, 2,000 to 1,000,000 Da, 10,000
to 200,000 Da, and 20,000 to 100,000 Da).
[0075] Amphoteric amines, i.e., amines that can react as an acid as well as a base, are
another class of amines of use in this invention.
[0076] Guanidine amines and guanidine salts are yet another class of multi-functional amines
of use in this invention.
[0077] Commercially available examples of amines include JEFFAMINE EDR-148 having a structure
shown above (where n=2), JEFFAMINE EDR-176 (where n=3) (from Huntsman). Other polyether
amines include the JEFFAMINE ED Series, JEFFAMINE TRIAMINES, polyethylenimines from
BASF (Ludwigshafen, Germany) under LUPASOL grades (e.g., LUPASOL FG, LUPASOL G20 waterfree,
LUPASOL PR 8515, LUPASOL WF, LUPASOL FC, LUPASOL G20, LUPASOL G35, LUPASOL G100, LUPASOL
G500, LUPASOL HF, LUPASOL PS, LUPASOL HEO 1, LUPASOL PNSO, LUPASOL PN6O, LUPASOL PO100
and LUPASOL SK). Other commercially available polyethylenimines include EPOMIN P-1000,
EPOMIN P-1050, EPOMIN RP18W and EPOMIN PP-061 from NIPPON SHOKUBAI (New York, N.Y).
Polyvinylamines such as those sold by BASF under LUPAMINE grades can also be used.
A wide range of polyetheramines may be selected by those skilled in the art. In certain
embodiments, the cross-linking agent is hexamethylene diamine, polyetheramine or a
mixture thereof.
The range of polyfunctional amines, polyfunctional alcohols, or hybrid cross-linking
agents can vary from 0.1% to 5% (e.g., 0.2% to 3%, 0.2% to 2%, 0.5% to 2%, or 0.5%
to 1%) by weight of the core/shell perfume capsule. The cross-linking agent may be
added to the capsule reaction at a temperature of 0-55° C (e.g., 10-50° C, 15-45°
C, 20-40° C, or 22-35° C).
[0078] The perfume composition comprised in the core comprises perfume raw materials. The
encapsulated benefit agent may further comprise essential oils, malodour reducing
agents, odour controlling agents, silicone, and combinations thereof.
[0079] The perfume raw materials are typically present in an amount of from 10% to 95%,
preferably from 20% to 90% by weight of the capsule.
[0080] The perfume composition may comprise from 2.5% to 30%, preferably from 5% to 30%
by weight of perfume composition of perfume raw materials characterized by a logP
lower than 3.0, and a boiling point lower than 250°C.
[0081] The perfume composition may comprise from 5% to 30%, preferably from 7% to 25% by
weight of perfume composition of perfume raw materials characterized by having a logP
lower than 3.0 and a boiling point higher than 250°C. The perfume composition may
comprise from 35% to 60%, preferably from 40% to 55% by weight of perfume composition
of perfume raw materials characterized by having a logP higher than 3.0 and a boiling
point lower than 250°C. The perfume composition may comprise from 10% to 45%, preferably
from 12% to 40% by weight of perfume composition of perfume raw materials characterized
by having a logP higher than 3.0 and a boiling point higher than 250°C.
[0082] Preferably, the core also comprises a partitioning modifier. Suitable partitioning
modifiers include vegetable oil, modified vegetable oil, propan-2-yl tetradecanoate
and mixtures thereof. The modified vegetable oil may be esterified and/or brominated.
The vegetable oil comprises castor oil and/or soy bean oil. The partitioning modifier
may be propan-2-yl tetradecanoate. The partitioning modifier may be present in the
core at a level, based on total core weight, of greater than 20%, or from greater
than 20% to about 80%, or from greater than 20% to about 70%, or from greater than
20% to about 60%, or from about 30% to about 60%, or from about 30% to about 50%.
[0083] Preferably the core/shell capsule have a volume weighted mean particle size from
0.5 microns to 100 microns, preferably from 1 micron to 60 microns, even more preferably
from 5 microns to 30 microns.
Method of making the laundry treatment composition
[0084] An aspect of the present invention is a method of making a laundry treatment composition
according to the present invention wherein the method comprises;
- a. a step of directly mixing 1,2-benzisothiazol-3(2H)-one with other ingredients commonly used in liquid treatment compositions; or
- b. a step of preparing a perfume capsule premix, wherein the perfume capsule premix
comprises perfume core/shell capsules, wherein the perfume core/shell capsules comprise
perfume and a shell, wherein the shell is made from melamine formaldehyde, polyacrylate
or a mixture thereof, and wherein the perfume capsule premix comprises between 50ppm
and 100ppm, preferably between 60ppm and 80ppm of 1,2-benzisothiazol-3(2H)-one, and adding the perfume capsule premix to other ingredients commonly used in
laundry treatment compositions so that the laundry treatment composition comprises
between 0.1% and 5%, preferably between 0.2% and 2.5% by weight of the laundry treatment
composition of perfume core/shell capsules; or
- c. a step of preparing a structurant premix, wherein the thickener premix comprises
a structurant, preferably hydrogenated castor oil, and wherein the structurant premix
comprises between 80ppm and 120ppm, preferably between 90ppm and 100ppm of 1,2-benzisothiazol-3(2H)-one, and adding the structurant premix to other ingredients commonly used in laundry
treatment compositions so that the laundry treatment composition comprises between
0.01% and 1%, preferably between 0.03% and 0.5%, more preferably between 0.05% and
0.2% of the structurant, preferably of hydrogenated castor oil; or
- d. adding 1,2-benzisothiazol-3(2H)-one as a premix with one or more other materials typically used in the laundry treatment
composition; or
- e. a mixture thereof.
[0085] Those skilled in the art will be aware of suitable means to mix the relevant ingredients
to make a laundry treatment composition. Commonly used off the shelf mixing apparatus
known to the skilled person can be used.
[0086] Preferably, the structurant premix comprises between 2% and 7% by weight of the premix
of hydrogenated castor oil, between 10% and 20% by weight of the premix of hydrogenated
castor oil, between 1% and 5% by weight of the premix of monoethanolamine, and the
remainder being water.
[0087] Those skilled in the art will be aware of suitable methods to manufacture water-soluble
unit dose articles according to the present invention. Commonly known methods include
thermoforming and extrusion. Water-soluble films may be sealed together using heat,
solvents or a mixture thereof.
Method of treating fabrics
[0088] An aspect of the present invention is a method of treating fabrics, comprising the
steps of diluting the fabric treatment composition in water by between 100 and 3000
fold, preferably between 100 and 800 fold to make a treatment liquor and contacting
fabrics with said treatment liquor.
[0089] The fabrics may be added to the treatment liquor once the treatment liquor is made.
Alternatively, the treatment liquor may be made whilst the fabrics are present. For
example, the treatment liquor may be made in the drum of a washing machine once the
fabrics have been added to said drum.
[0090] The treatment liquor maybe made for use in a hand wash operation, in an automatic
washing machine or a mixture thereof.
[0091] The treatment liquor may be a wash liquor, a rinse liquor or a mixture thereof.
Use
[0092] A further aspect of the present invention is the use of 1,2-benzisothiazol-3(2
H)-one in a laundry treatment composition to reduce microbial growth in the laundry
treatment composition. Preferably, an aspect of the present invention is the use of
1,2-benzisothiazol-3(2
H)-one in a laundry treatment composition according to the present invention to reduce
microbial growth in the laundry treatment composition. "Microbial growth" herein means
growth of microorganisms. Microorganisms include fungi, bacteria or a mixture thereof.
Bacteria include gram positive bacteria, gram negative bacteria or a mixture thereof.
[0093] The dimensions and values disclosed herein are not to be understood as being strictly
limited to the exact numerical values recited. Instead, unless otherwise specified,
each such dimension is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension disclosed as "40
mm" is intended to mean "about 40 mm."
EXAMPLES
Example 1
[0094] Liquid laundry detergent compositions according to the present invention:
|
Ex. 1A |
Ex. 1B |
Ex. 1C |
Ex. 1D |
|
wt% |
wt% |
wt% |
wt% |
C12-14 EO3 alkyl ethoxylated sulfate |
9.8 |
4.0 |
0.6 |
9.0 |
C12-15 linear alkylbenzene sulfonic acid |
14.5 |
9.2 |
5.9 |
12.0 |
C12-15 EO8 ethoxylated alcohol |
2.0 |
4.0 |
3.0 |
0 |
C12-14 EO7 ethoxylated alcohol |
0 |
0 |
0 |
6.0 |
Dodecydimethylamine-N-oxide |
0 |
0.5 |
1.0 |
0 |
Citric Acid |
4.8 |
2.8 |
1.9 |
3.0 |
C12-18 Fatty Acid |
3.3 |
1.7 |
1.2 |
8.0 |
Sodium Cumene Sulfonate |
0 |
1.7 |
0.2 |
0 |
Zwitterionic polyamine1 |
0.7 |
0 |
0.3 |
2.1 |
Diethylenetriamine penta(methylene phosphonic acid), Sodium salt (DTPMP) |
0 |
0.5 |
0.2 |
0 |
1-hydroxyethane 1,1-diphosphonic acid (HEDP) |
0.6 |
0 |
0 |
1.5 |
Mannanase2 |
0.003 |
0.002 |
0 |
0 |
Amylase3 |
0.013 |
0.004 |
0.0016 |
0.0032 |
Protease4 |
0.039 |
0.02 |
0.018 |
0.036 |
Cellulase5 |
0 |
0 |
0.006 |
0.012 |
Pectate Lyase6 |
0.005 |
0.002 |
0 |
0 |
Lipase7 |
0 |
0 |
0.010 |
0 |
PEG-PVAc Polymer8 |
1.9 |
1.3 |
0 |
0 |
Di-ethoxylated poly (1,2 propylene terephtalate) short block soil release polymer9 |
0 |
0 |
0.9 |
0.9 |
Ethoxylated Polyethylenimine10 |
0.5 |
0 |
0.9 |
0 |
Brightener 49 |
0.08 |
0 |
0.05 |
0.2 |
Bis azo or azo thiophene hueing dye11 |
0 |
0 |
0.02 |
0 |
Hydrogenated castor oil12 |
1 |
0.30 |
0.0 |
0.75 |
2-propylheptanol |
5 |
0 |
0 |
0 |
Diethylene glycol |
0 |
0 |
3 |
4.0 |
1, 2 propanediol |
8.3 |
1.3 |
1.0 |
7.0 |
Ethanol |
0 |
0 |
0.5 |
0 |
Glycerine |
0 |
0.1 |
0 |
0 |
Sodium formate |
0 |
0.03 |
0.3 |
0 |
Calcium Chloride |
0.03 |
0.01 |
0.006 |
0 |
Boric acid |
0 |
0 |
1.1 |
1.5 |
Monoethanolamine |
8.8 |
0 |
0.35 |
8.5 |
Triethanolamine |
0 |
0.58 |
0 |
0 |
Sodium hydroxide |
to pH 7.4 |
to pH 7.9 |
to pH 8.0 |
to pH 8.0 |
1,2-benzisothiazol-3(2H)-one |
0.003 |
0.001 |
0.001 |
0.003 |
Silicone suds suppressor |
0 |
0.003 |
0.003 |
0.005 |
Perfume microcapsules |
0 |
0.25 |
0 |
0 |
Perfume |
1.5 |
0.9 |
0.6 |
1.7 |
Dye |
0.009 |
0.005 |
0.004 |
0.004 |
Water |
to 100% |
to 100% |
to 100% |
to 100% |
1 Zwitterionic ethoxylated quaternized sulfated hexamethylene diamine, supplied by
BASF, Germany
2 Mannanase enzyme originating from Bacillus sp. I633 available from Novozymes, Denmark
3 Termamyl® Ultra, available from Novozymes, Denmark
4 Protease enzyme from Bacillus Amyloliquefaciens as described in EP 0 130 756 B1 published January 9, 1985
5 Carezyme® available from Novozymes, Denmark
6 Pectawash® 20L, supplied by Novozymes, Denmark
7 Lipex®, supplied by Novozymes, Denmark
8 Polyvinyl acetate grafted polyethylene oxide copolymer having a polyethylene oxide
backbone and multiple polyvinyl acetate side chains, supplied by BASF, Germany.
9 TexCare® SRN-100, supplied by Clariant, Germany
10 Polyethyleneimine (MW = 600) with 20 ethoxylate groups per -NH, supplied by BASF
11 Supplied by Milliken, USA
12 prepared as an aqueous premix comprising 4wt% of hydrogenated castor oil, 16 wt%
of C12-15 linear alkylbenzene sulfonic acid and sufficient 1,2-benzisothiazol-3(2H)-one
to preserve the composition. The levels of the ingredients in the table include the
amounts of the three ingredients that are added as part of the premix. |
Example 2
[0095] Liquid laundry fabric softener compositions according to the present invention:
summarized in the following table.
|
Wt % in the Composition |
|
3A |
3B |
3C |
3D |
3E |
3F |
3G |
3H |
31 |
3J |
FSA a |
14 |
16.47 |
14 |
12 |
12 |
16.47 |
--- |
--- |
5 |
5 |
FSA b |
|
|
|
|
--- |
|
3.00 |
--- |
--- |
--- |
FSA c |
|
|
|
|
--- |
|
--- |
6.5 |
--- |
--- |
Ethanol |
2.18 |
2.57 |
2.18 |
1.95 |
1.95 |
2.57 |
--- |
--- |
0.81 |
0.81 |
Isopropyl Alcohol |
--- |
--- |
--- |
--- |
--- |
--- |
0.33 |
1.22 |
--- |
--- |
Starch d |
1.25 |
1.47 |
2.00 |
1.25 |
--- |
2.30 |
0.5 |
0.70 |
0.71 |
0.42 |
Phase Stabilizing Polymer f |
0.21 |
0.25 |
0.21 |
0.21 |
0.14 |
--- |
--- |
0.14 |
--- |
--- |
Calcium Chloride |
0.15 |
0.176 |
0.15 |
0.15 |
0.30 |
0.176 |
--- |
0.1-0.15 |
--- |
--- |
DTPA h |
0.017 |
0.017 |
0.017 |
0.017 |
0.007 |
0.007 |
0.20 |
--- |
0.002 |
0.002 |
Preservative |
5 |
5 |
5 |
5 |
5 |
5 |
--- |
250 j |
5 |
5 |
(ppm) i,j |
|
|
|
|
|
|
|
|
|
|
Antifoamk |
0.015 |
0.018 |
0.015 |
0.015 |
0.015 |
0.015 |
--- |
0.1 |
0.015 |
0.015 |
Dye (ppm) |
40 |
40 |
40 |
40 |
40 |
40 |
11 |
30-300 |
30 |
30 |
Ammonium Chloride |
0.100 |
0.118 |
0.100 |
0.100 |
0.115 |
0.115 |
--- |
--- |
--- |
--- |
HCl |
0.012 |
0.014 |
0.012 |
0.012 |
0.028 |
0.028 |
0.016 |
0.025 |
0.011 |
0.011 |
Structurantl |
0.01 |
0.01 |
0.01 |
0.01 |
0.01 |
0.01 |
0.01 |
0.01 |
0.01 |
0.01 |
Perfume |
0.8 |
0.7 |
0.9 |
0.5 |
1.2 |
0.5 |
1.1 |
0.6 |
1.0 |
0.9 |
Deionized Water |
* |
* |
* |
* |
* |
* |
* |
* |
* |
* |
* Balance
a N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
b Methyl bis(tallow amidoethyl)2-hydroxyethyl ammonium methyl sulfate.
c Compound of Fatty acid with Methyldiethanolamine in a molar ratio 1.5:1, quaternized
with Methylchloride, resulting in a 1:1 molar mixture of N,N-bis(stearoyl-oxy-ethyl)
N,N-dimethyl ammonium chloride and N-(stearoyl-oxy-ethyl) N,-hydroxyethyl N,N dimethyl
ammonium chloride.
d Cationic high amylose maize starch available from National Starch under the trade
name CATO®.
f Copolymer of ethylene oxide and terephthalate.
g SE39 from Wacker
h Diethylenetriaminepentaacetic acid.
i KATHON® CG available from Rohm and Haas Co. "PPM" is "parts per million."
j Gluteraldehyde
k Silicone antifoam agent available from Dow Corning Corp. under the trade name DC2310.
l Hydrophobically-modified ethoxylated urethane available from Rohm and Haas under
the tradename Aculan 44. |
Example 3
[0096] A water-soluble unit dose article according to the present invention comprising an
anionically charged polyvinyl alcohol film, preferably wherein the film is a blend
of polyvinylalcohol polymers and/or polyvinylalcohol copolymers, preferably selected
from sulphonated and carboxylated anionic polyvinylalcohol copolymers especially carboxylated
anionic polyvinylalcohol copolymers, most preferably a blend of a polyvinylalcohol
homopolymer and a carboxylated anionic polyvinylalcohol copolymer, and a liquid laundry
detergent comprising;
Ingredients |
Wt% of composition unless stated otherwise |
Linear C9-C15 Alkylbenzene sulfonic acid |
18-23 |
C12-15 ethoxylated alkyl sulphate with an average degree of ethoxylation of 3 |
8-16 |
C12-14 fatty alcohol ethoxylate having an average degree of ethoxylation of 7 |
2-5 |
Citric Acid |
0.5-1 |
Fatty acid |
4-7 |
Chelants |
0.75-2.25 |
Cleaning polymers (selected from CMC, polyester terephthalate (preferably anionically
modified), amphiphilic graft copolymer, ethoxylated polyethyleneimine or a mixture
thereof) |
4-9 |
Enzymes (selected from amylase, protease, lipase, xyloglucanase or a mixture thereof) |
0.01-1 |
Brightener 49 |
0.05-1 |
Structurant (preferably hydrogenated castor oil) |
0.05-0.5 |
Solvent system (selected from propanediol, glycerol, ethanol, dipropyleneglycol, tripropyleneglycol,
polyetheyleneglycol, polypropyleneglycol) |
15-25 |
Water |
8-13 |
Perfume |
0.5-2 |
Perfume capsule |
0.5-2 |
Aesthetic dye, opacifier or a mixture thereof |
0.5-2 |
Mono-ethanolamine, NaOH or mixture thereof |
5-15 |
1,2-benzisothiazol-3(2H)-one |
0.5ppm - 25ppm |
Other laundry adjuncts / minors |
To 100 |
Example 4
[0097] A powder laundry detergent composition according to the present invention;
Component |
Wt % in the Composition |
4A |
4B |
4C |
4D |
4E |
4F |
9G |
Brightener |
0.1 |
0.1 |
0.1 |
0.2 |
0.1 |
0.2 |
0.1 |
Soap |
0.6 |
0.6 |
0.6 |
0.6 |
0.6 |
0.6 |
0.6 |
Ethylenediamine disuccinic acid |
0.1 |
0.1 |
0.1 |
0.1 |
0.1 |
0.1 |
0.1 |
Acrylate/maleate copolymer |
1.5 |
1.5 |
1.5 |
1.5 |
1.5 |
1.5 |
1.5 |
Hydroxyethane di(methylene phosphonic acid) |
0.4 |
0.4 |
0.4 |
0.4 |
0.4 |
0.4 |
0.4 |
Mono-C12-14 alkyl, di-methyl, mono-hydroxyethyl quaternary ammonium chloride |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
Linear alkyl benzene |
0.1 |
0.1 |
0.2 |
0.1 |
0.1 |
0.2 |
0.1 |
Linear alkyl benzene sulphonate |
10.3 |
10.1 |
19.9 |
14.7 |
10.3 |
17 |
10.5 |
Magnesium sulphate |
0.4 |
0.4 |
0.4 |
0.4 |
0.4 |
0.4 |
0.4 |
Sodium carbonate |
19.5 |
19.2 |
10.1 |
18.5 |
29.9 |
10.1 |
16.8 |
Sodium sulphate |
29.6 |
29.8 |
38.8 |
15.1 |
24.4 |
19.7 |
19.1 |
Sodium Chloride |
0.1 |
0.1 |
0.1 |
0.1 |
0.1 |
0.1 |
0.1 |
Zeolite |
9.6 |
9.4 |
8.1 |
18 |
10 |
13.2 |
17.3 |
Photobleach particle |
0.1 |
0.1 |
0.2 |
0.1 |
0.2 |
0.1 |
0.2 |
Blue and red carbonate speckles |
1.8 |
1.8 |
1.8 |
1.8 |
1.8 |
1.8 |
1.8 |
Ethoxylated Alcohol AE7 |
1 |
1 |
1 |
1 |
1 |
1 |
1 |
Tetraacetyl ethylene diamine agglomerate (92wt% active) |
0.9 |
0.9 |
0.9 |
0.9 |
0.9 |
0.9 |
0.9 |
Citric acid |
1.4 |
1.4 |
1.4 |
1.4 |
1.4 |
1.4 |
1.4 |
PDMS/clay agglomerates (9.5% wt% active PDMS) |
10.5 |
10.3 |
5 |
15 |
5.1 |
7.3 |
10.2 |
Polyethylene oxide |
0.2 |
0.2 |
0.2 |
0.2 |
0.2 |
0.2 |
0.2 |
Enzymes e.g. Protease (84mg/g active), Amylase (22mg/g active) |
0.2 |
0.3 |
0.2 |
0.1 |
0.2 |
0.1 |
0.2 |
Suds suppressor agglomerate (12.4 wt% active) |
0.2 |
0.2 |
0.2 |
0.2 |
0.2 |
0.2 |
0.2 |
Sodium percarbonate (having from 12% to 15% active AvOx) |
7.2 |
7.1 |
4.9 |
5.4 |
6.9 |
19.3 |
13.1 |
Perfume oil |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
0.5 |
Solid perfume particles |
0.4 |
0 |
0.4 |
0.4 |
0.4 |
0.4 |
0.6 |
Balance Water* |
* |
* |
* |
* |
* |
* |
* |
1. A laundry treatment composition comprising 1,2-benzisothiazol-3(2H)-one.
2. The laundry treatment composition according to claim 1, wherein the laundry treatment
composition is selected from a laundry detergent composition, a laundry softening
composition, a laundry conditioning composition, a laundry perfuming composition or
a mixture thereof.
3. The laundry treatment composition according to any preceding claims wherein the laundry
treatment composition is selected from a liquid, a gel, a powder or a mixture thereof.
4. The laundry treatment composition according to any preceding claims comprising between
0.5ppm and 200ppm, preferably between 1ppm and 110ppm of the 1,2-benzisothiazol-3(2H)-one.
5. The laundry treatment composition according to any preceding claims, wherein the laundry
treatment composition is a liquid laundry detergent composition and comprises between
40% and 80%, preferably between 50% and 75% by weight of the liquid laundry detergent
composition of water, and wherein the liquid laundry detergent composition comprises
between 25ppm and 110ppm, preferably between 30ppm and 105ppm of 1,2-benzisothiazol-3(2H)-one.
6. The laundry treatment composition according to claims 1-4, wherein the laundry treatment
composition is a liquid fabric softening composition and comprises between 70% and
98%, preferably between 75% and 95% by weight of the liquid fabric softening composition
of water, and wherein the liquid fabric softening composition comprises between 0ppm
and 2ppm, preferably between 0.001ppm and 1.75ppm, even more preferably between 0.01ppm
and 1.5ppm of 1,2-benzisothiazol-3(2H)-one.
7. The laundry treatment composition according to claims 1-4, wherein the laundry treatment
composition is a powder laundry detergent composition and wherein the powder laundry
detergent composition comprises between 0ppm and 2ppm, preferably between 0.001ppm
and 1.75ppm, even more preferably between 0.01ppm and 1.5ppm of 1,2-benzisothiazol-3(2H)-one.
8. The laundry treatment composition according to claims 1-4, wherein the laundry treatment
composition is a compacted liquid laundry detergent composition and wherein the compacted
liquid treatment composition comprises between 1% and 50%, preferably between 1% and
40% by weight of the compacted liquid laundry detergent composition of water, and
wherein the compacted liquid laundry detergent composition comprises between 0.5ppm
and 25ppm, preferably between 0.5ppm and 20ppm, even more preferably between 0.5ppm
and 15ppm of 1,2-benzisothiazol-3(2H)-one;
preferably, wherein the compacted liquid laundry detergent composition is comprised
in a water-soluble unit dose article wherein the water-soluble unit dose article comprises
a water-soluble polyvinyl alcohol film, and wherein the compacted liquid laundry detergent
composition comprised in the water-soluble unit dose article comprises between 1%
and 25%, preferably between 2% and 13% by weight of the liquid laundry detergent composition
of water.
9. The laundry treatment composition according to any preceding claims, wherein the laundry
treatment composition comprises less than 15ppm of 2-Methyl-1,2-thiazol-3(2H)-one.
10. The laundry treatment composition according to any preceding claims wherein the laundry
treatment composition comprises an adjunct material, wherein the adjunct material
is preferably selected from linear alkylbenzene sulphonate, alkyl sulphate, alkoxylated
alkyl sulphate, fatty alcohol ethoxylates, amine oxide, fatty acid, neutralised fatty
acid salt, citric acid, ethoxylated polyethyleneimine, zwitterionic polyamine, amphiphilic
graft copolymer, polyester terephthalate, monoethanolamine, triethanolamine, ethanol,
glycerol, dipropylene glycol, 1,2-propanediol, hemicellulases, peroxidases, proteases,
cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases,
keratanases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases,
tannases, pentosanases, malanases, β-glucanases, arabinosidases, hyaluronidase, chondroitinase,
laccase, amylases, brighteners, hydrogenated castor oil, perfumes, core/shell perfume
capsules, silicones, ester quaternary ammonium compounds, bleaches, carbonates, silicates,
sulphates, polyethylene glycol, dyes, hueing dyes, as ethylenediamine-N'N'-disuccinic
acid (EDDS) and/or hydroxyethane diphosphonic acid (HEDP), tetraacetylethylene diamine
(TAED) and/or nonanoyloxybenzenesulphonate (NOBS), or mixture thereof.
11. A method of making a laundry treatment composition according to any preceding claims
wherein the method comprises;
a. a step of directly mixing 1,2-benzisothiazol-3(2H)-one with other ingredients commonly used in liquid treatment compositions; or
b. a step of preparing a perfume capsule premix, wherein the perfume capsule premix
comprises perfume core/shell capsules, wherein the perfume core/shell capsules comprise
perfume and a shell, wherein the shell is made from melamine formaldehyde, polyacrylate
or a mixture thereof, and wherein the perfume capsule premix comprises between 50ppm
and 100ppm, preferably between 60ppm and 80ppm of 1,2-benzisothiazol-3(2H)-one, and adding the perfume capsule premix to other ingredients commonly used in
laundry treatment compositions so that the laundry treatment composition comprises
between 0.1% and 5%, preferably between 0.2% and 2.5% by weight of the laundry treatment
composition of perfume core/shell capsules; or
c. a step of preparing a structurant premix, wherein the thickener premix comprises
a structurant, preferably hydrogenated castor oil, and wherein the structurant premix
comprises between 80ppm and 120ppm, preferably between 90ppm and 100ppm of 1,2-benzisothiazol-3(2H)-one, and adding the structurant premix to other ingredients commonly used in laundry
treatment compositions so that the laundry treatment composition comprises between
0.01% and 1%, preferably between 0.03% and 0.5%, more preferably between 0.05% and
0.2% of the structurant, preferably of hydrogenated castor oil; or
d. adding 1,2-benzisothiazol-3(2H)-one as a premix with one or more other materials typically used in the laundry treatment
composition; or
e. a mixture thereof.
12. A method of treating fabrics, comprising the steps of diluting the fabric treatment
composition according to any preceding claims in water by between 100 and 3000, preferably
between 100 and 800 fold to make a treatment liquor and contacting fabrics with said
treatment liquor.
13. The use of 1,2-benzisothiazol-3(2H)-one in a laundry treatment composition to reduce microbial growth in the laundry
treatment composition.