TECHNICAL FIELD
[0001] The present invention relates to a fiber structure suitably usable as a bandage or
the like, and a method for manufacturing the same.
BACKGROUND ART
[0002] Conventionally, in the fields of medicine, sports, and the like, tapes such as various
bandages and supporters have been used for the purpose of appropriately pressing,
fixing, and protecting application sites such as limbs and affected parts. These tapes
are required to have fixing ability by self-adhesion or adhesion in addition to stretchability,
followability, sweat absorption, air permeability, and the like.
[0003] In general, a soft component such as a rubber or acrylic latex is applied to the
surface of a bandage for the purpose of fulfilling stretchability and fixing ability
(PTL 1 to 5). These soft components, however, are not preferable from the viewpoint
of safety because they may possibly cause irritation to the skin and stuffiness due
to loss of air permeability, and may even cause allergy.
[0004] For the purpose of reducing skin irritation, a medical material containing a low-protein
natural rubber latex as a pressure-sensitive adhesive (PTL 6), and a self-adhesive
bandage containing a specific acrylic polymer as a pressure-sensitive adhesive (PTL
7) have been proposed. These medical material and self-adhesive bandage, however,
still contain a pressure-sensitive adhesive, and do not provide a fundamental solution.
[0005] As a nonwoven fabric that can be self-adhesive without any pressure-sensitive adhesive
applied thereto, there have been proposed a nonwoven fabric including a latently thermally
crimpable conjugated fiber, which has stretchability and can be easily cut by hand
(PTL 8), and a stretchable nonwoven fabric that is of a high-stress type and can be
used repeatedly (PTL 9).
CITATION LIST
PATENT LITERATURE
SUMMARY OF INVENTION
TECHNICAL PROBLEMS
[0007] It was found that the nonwoven fabric described in PTL 8, however, is easily torn
when tightly wound. It was also found that although the nonwoven fabric described
in PTL 9 has, owing to the high stress of the fabric, a property of being hardly torn
even when tightly wound, the nonwoven fabric tends to have high stress even at low
extension, and there is room for improvement of the initial conformity.
[0008] Therefore, an object of the present invention is to provide a fiber structure that
is easy to extend but is hardly torn, which has very high stress at high extension
and can be tightly wound while having very low stress at low extension and being excellent
in the initial conformity.
SOLUTIONS TO PROBLEMS
[0009] The present inventors found that the nonwoven fabric described in PTL 8 has low strength
because the crimps that have been expressed are entangled with each other, and the
nonwoven fabric is easy to extend but is likely to break. The present inventors also
found that in the nonwoven fabric described in PTL 9, which is obtained by entanglement
by the spunlace method or needle punch method and then treated with high-speed steam,
the sheet itself is entangled and the expressed crimps cannot be used, and the nonwoven
fabric hardly exhibits shrinkability.
[0010] The present inventors have conducted intensive studies to achieve the above-described
object. As a result, they found that a fiber structure described below can achieve
the above-described object: a fiber structure having an entangled part (A) including
coil-shaped crimped fibers (a) and two or more entangled parts (B) including non-coil-shaped
crimped fibers (b), at least one distance between the entangled parts (B) in a machine
direction of the fiber structure being less than the apparent average fiber length
of the coil-shaped crimped fibers (a).
[0011] More specifically, the present invention includes the following.
- [1] A fiber structure including coil-shaped crimped fibers (a) and non-coil-shaped
crimped fibers (b), the fiber structure having an entangled part (A) including the
coil-shaped crimped fibers (a) and two or more entangled parts (B) including the non-coil-shaped
crimped fibers (b), at least one distance between the entangled parts (B) in a machine
direction of the fiber structure being less than the apparent average fiber length
of the coil-shaped crimped fibers (a).
- [2] The fiber structure according to [1], wherein, in a surface of the fiber structure,
the area rate of the entangled part (A) to the surface area of the fiber structure
is 20 to 85%.
- [3] The fiber structure according to [1] or [2], wherein a thickness (TA) of the entangled part (A) and a thickness (TB) of the entangled parts (B) have a ratio of TA/TB = 1.1 to 10.
- [4] The fiber structure according to any one of [1] to [3], having, in the machine
direction of the fiber structure, a stress at 50% extension of less than or equal
to 15 N/5 cm, and a stress at 80% extension of greater than or equal to 20 N/5 cm.
- [5] The fiber structure according to any one of [1] to [4], having, in the machine
direction of the fiber structure, a ratio between a stress at 50% extension and a
stress at 80% extension, that is, stress at 80% extension/stress at 50% extension
of greater than or equal to 2.7.
- [6] The fiber structure according to any one of [1] to [5], wherein the coil-shaped
crimped fibers (a) include a conjugated fiber in which a plurality of resins having
different thermal shrinkage factors form a phase structure.
- [7] The fiber structure according to any one of [1] to [6], having a basis weight
of 50 to 200 g/m2,
- [8] A bandage including the fiber structure according to any one of [1] to [7].
- [9] A method for manufacturing the fiber structure according to any one of [1] to
[8], the method including:
- 1) forming a fiber into a web;
- 2) entangling part of the web by spraying or injection of water to form the entangled
parts (B); and
- 3) heating the web with high-temperature steam to form the entangled part (A).
ADVANTAGEOUS EFFECTS OF INVENTION
[0012] The fiber structure according to the present invention is excellent in the initial
conformity and can be tightly wound, so that the fiber structure can be suitably used
as a bandage or the like.
BRIEF DESCRIPTION OF DRAWINGS
[0013]
Fig. 1 is an outline diagram showing an arrangement pattern of entangled parts (B)
in a machine direction of a fiber structure obtained in Example 1.
Fig. 2 is a schematic diagram showing a method of preparing a sample for measuring
curved surface sliding stress.
Fig. 3 is a cross-sectional schematic diagram showing the sample for measuring the
curved surface sliding stress.
Fig. 4 is a schematic diagram showing a method of measuring the curved surface sliding
stress.
DESCRIPTION OF EMBODIMENTS
[Fiber structure]
[0014] The fiber structure according to the present invention (hereinafter also simply referred
to as a "fiber structure") has an entangled part (A) including coil-shaped crimped
fibers (a) and entangled parts (B) including non-coil-shaped crimped fibers (b). The
fiber structure according to the present invention has, in the entangled part (A),
a structure in which the coil-shaped crimped fibers (a) are entangled with each other
at their crimped coil portions and bound or hooked. Meanwhile, in the entangled parts
(B), the entangled parts are formed not by the crimp of the non-coil-shaped crimped
fibers (b) but by the packing of the fibers. The coil-shaped crimped fibers (a) and
the non-coil-shaped crimped fibers (b) are preferably oriented in the machine direction
of the fiber structure, and the coil-shaped crimped fibers (a) are preferably crimped
into a coil shape along the orientation axis.
[0015] The "machine direction" of the fiber structure is a machine direction of the fiber
structure in a production process (that is, MD direction). When the fiber structure
has, for example, a length direction and a width direction like a bandage, the machine
direction is preferably the length direction. In this case, the fiber structure as
a bandage can be wrapped around an application site while being extended along the
length direction thereof. When the fiber structure has a length direction and a width
direction, a CD direction orthogonal to the MD direction is preferably the width direction.
[0016] In the fiber structure according to the present invention, fibers are relatively
weakly entangled with each other in the entangled part (A), so that the fiber structure
has very low stress at low extension and is excellent in the initial conformity. Further,
since fibers are strongly entangled with each other in the entangled parts (B), the
fiber structure has very high stress at high extension and can be tightly wound.
[0017] In the fiber structure according to the present invention, at least one distance
between the entangled parts (B) in the machine direction of the fiber structure (hereinafter,
the distance is also simply referred to as a "distance between the entangled parts
(B)") is less than the apparent average fiber length of the coil-shaped crimped fibers
(a). The "distance between the entangled parts (B) in the machine direction of the
fiber structure" refers to the shortest distance in the machine direction between
any one of the entangled parts (B) of the fiber structure and another one of the entangled
parts (B) that is present closest to the above-described entangled part (B) in the
machine direction. If the distance between the entangled parts (B) is greater than
or equal to the apparent average fiber length of the coil-shaped crimped fibers (a),
the entangled parts (B) are entangled with each other only by the crimped coil portions
of the coil-shaped crimped fibers (a), and the entangled coil portions are extended
and finally unwrapped at high extension, so that the fiber structure tends to be broken
at the coil portions. On the contrary, when the distance between the entangled parts
(B) is less than the apparent average fiber length of the coil-shaped crimped fibers
(a), at least one ends of the coil-shaped crimped fibers (a) are entangled at the
entangled parts (B), so that the coil-shaped crimped fibers (a) do not unwrap even
at high extension, and the fiber structure tends to easily exhibit high stress at
high extension. From the above-described viewpoint, it is preferable that in at least
part of the coil-shaped crimped fibers (a), both ends thereof are entangled at the
entangled parts (B).
[0018] It is preferable that pairs of the entangled parts (B) constituting the distances
between the entangled parts (B) are arranged so that at least part thereof can be
entangled with the coil-shaped crimped fibers (a) oriented in the machine direction.
When the entangled parts (B) are entangled with the coil-shaped crimped fibers (a),
high stress tends to be easily obtained at high extension. As the number of the coil-shaped
crimped fibers (a) entangled with the entangled parts (B) is larger, strong entanglement
between the entangled parts (B) and the coil-shaped crimped fibers (a) tends to occur
easily. When the fiber structure has a sheet shape, the entangled parts (B) may be
formed regularly in the sheet plane, and it is preferable that the entangled part
(A) and the entangled parts (B) are arranged in a border pattern in which the entangled
part (A) and the entangled parts (B) are alternately arranged in the machine direction,
or a plane lattice pattern in which the entangled parts (B) having a specific shape
are regularly arranged, such as a square lattice pattern, an orthorhombic lattice
pattern, or a rectangular lattice pattern. Fig. 1 shows, as for a fiber structure
1 having an orthorhombic lattice pattern and obtained in Example 1 described later,
entangled parts (B) 2, an entangled part (A) 3, and a distance 4 between the entangled
parts (B).
[0019] When the entangled parts (B) are arranged in a border pattern, the width (length
in the machine direction) of one entangled part (B) may be, for example, 0.5 to 30
mm, and is preferably 1 to 20 mm, more preferably 2 to 10 mm, still more preferably
3 to 8 mm.
[0020] When the entangled parts (B) are arranged in a plane lattice pattern, the interval
in a direction perpendicular to the machine direction (the interval in a direction
perpendicular to the "distance between the entangled parts (B)") may be, for example,
0.5 to 30 mm, and is preferably 1 to 20 mm, more preferably 2 to 10 mm, still more
preferably 3 to 8 mm.
[0021] When the entangled parts (B) are arranged in a plane lattice pattern, the shape of
the entangled parts (B) is not particularly limited, but may be, for example, an oval
shape, an elliptical shape, a circular shape, a square shape, or a rectangular shape,
and is preferably an oval shape. When the entangled parts (B) have an oval shape,
the length in the major axis direction may be, for example, 1 to 80 mm, and is preferably
5 to 60 mm, more preferably 10 to 40 mm, and the length in the minor axis direction
is, for example, 1 to 80 mm, and is preferably 3 to 50 mm, more preferably 5 to 30
mm.
[0022] In the fiber structure, the higher the percentage of the distances between the entangled
parts (B) that are less than the apparent average fiber length of the coil-shaped
crimped fibers (a) is, the easier it tends to be for the fiber structure to exhibit
high stress at high extension. Therefore, in the fiber structure, for example, greater
than or equal to 10% of the distances between the entangled parts (B) in the machine
direction of the fiber structure are less than the apparent average fiber length of
the coil-shaped crimped fibers (a). Preferably greater than or equal to 30%, more
preferably greater than or equal to 60%, still more preferably greater than or equal
to 90%, particularly preferably greater than or equal to 95% of the distances between
the entangled parts (B) present in the machine direction of the fiber structure are
less than the apparent average fiber length of the coil-shaped crimped fibers (a).
[0023] The apparent average fiber length of the coil-shaped crimped fibers (a) (hereinafter
also simply referred to as an "apparent average fiber length") is not the fiber length
obtained by unwinding the coil-shaped crimped fibers into straight lines (actual fiber
length) but the average of lengths of fibers crimped into a coil shape (apparent fiber
length). Therefore, the apparent average fiber length is measured as being shorter
than the actual fiber length. The apparent average fiber length was obtained by observing
a surface of the fiber structure with an electron microscope, measuring the apparent
fiber lengths of 100 fibers arbitrarily selected from the coil-shaped crimped fibers
(a) present per any 1 cm
2 of a surface of the entangled part (A) of the fiber structure, and calculating the
average of the apparent fiber lengths.
[0024] The apparent average fiber length may be, for example, greater than or equal to 10
mm, and is preferably greater than 10 mm, more preferably greater than or equal to
11 mm, still more preferably greater than or equal to 12 mm, particularly preferably
greater than or equal to 13 mm. Meanwhile, the apparent average fiber length may be,
for example, less than or equal to 70 mm, and is preferably less than or equal to
55 mm, more preferably less than or equal to 40 mm, still more preferably less than
or equal to 30 mm, particularly preferably less than or equal to 21 mm.
[0025] The distance between the entangled parts (B) may be, for example, greater than or
equal to 2.5 mm, and is preferably greater than or equal to 3 mm, more preferably
greater than or equal to 3.5 mm. In addition, at least one of the distances between
the entangled parts (B) may be, for example, less than or equal to 20 mm, and is preferably
less than 20 mm, more preferably less than or equal to 15 mm, still more preferably
less than or equal to 10 mm. When at least one of the distances between the entangled
parts (B) is between the above-described upper and lower limits, the entangled parts
(B) are entangled with each other by the coil-shaped crimped fibers (a), and the fiber
structure has high stress at high extension and tends to be hardly torn even when
tightly wound.
[0026] In the present invention, the entangled parts (B) may include a small amount of the
coil-shaped crimped fibers (a), for example, up to 3% by mass of the coil-shaped crimped
fibers (a) based on the total mass of the entangled parts (B), and the entangled part
(A) may include a small amount of the non-coil-shaped crimped fibers (b), for example,
up to 3% by mass of the non-coil-shaped crimped fibers (b) based on the total mass
of the entangled part (A). Further, one fiber may have a coil-shaped crimped portion
and a non-coil-shaped crimped portion.
[0027] In the fiber structure, in a surface of the fiber structure, the area rate of the
entangled part (A) to the surface area of the fiber structure may be, for example,
20 to 85%, and is preferably 30 to 83%, more preferably 40 to 81%. The area of the
entangled part (A) is a value determined by a measurement method described in examples
described later. When the area rate of the entangled part (A) is within the above-described
range, the fiber structure tends to have low stress at low extension, and excellent
conformity tends to be easily obtained.
[0028] In the fiber structure, the thickness (T
A) of the entangled part (A) and the thickness (T
B) of the entangled parts (B) may have, for example, a ratio T
A/T
B of 1.1 to 10, and the ratio is preferably 2 to 7, more preferably 3 to 5. When the
ratio between the thickness (T
A) of the entangled part (A) and the thickness (T
B) of the entangled parts (B), T
A/T
B, is within the above-described range, it is advantageous in that the fiber structure
has a good balance between softness and strength.
[0029] The thickness (T
A) of the entangled part (A) may be, for example, 1 to 10 mm, and is preferably 1.5
to 7 mm, more preferably 2 to 5 mm.
[0030] The thickness (T
B) of the entangled parts (B) may be, for example, 0.2 to 1 mm, and is preferably 0.3
to 0.9 mm, more preferably 0.4 to 0.8 mm.
[0031] The thickness (T
A) of the entangled part (A) and the thickness (T
B) of the entangled parts (B) were measured in accordance with the "Test methods for
nonwovens" specified in JIS L 1913.
[0032] The fiber structure preferably has a basis weight of 50 to 200 g/m
2, and the basis weight is more preferably 70 to 180 g/m
2.
[0033] When the basis weight and the thickness are within the above-described ranges, the
fiber structure has a good balance among stretchability, flexibility, touch feeling,
and cushioning property. The densities (bulk densities) of the entangled parts (A)
and (B) of the fiber structure can each be a value corresponding to the above-described
basis weight and thickness. The density (bulk density) of the entangled part (A) of
the fiber structure may be, for example, 0.03 to 0.15 g/cm
3, and is preferably 0.04 to 0.1 g/cm
3. The density (bulk density) of the entangled parts (B) of the fiber structure can
be a value corresponding to the above-described basis weight and thickness, and is,
for example, 0.15 to 1.5 g/cm
3, preferably 0.2 to 1 g/cm
3.
[0034] The fiber structure may have, in the machine direction of the fiber structure, a
stress at 50% extension of, for example, less than or equal to 15 N/5 cm, and the
stress at 50% extension is preferably less than or equal to 13 N/5 cm, more preferably
less than or equal to 12 N/5 cm. When the stress at 50% extension in the machine direction
of the fiber structure is less than or equal to the above-described upper limit, the
fiber structure tends to have low stress at low extension, and tends to be excellent
in the initial conformity. The lower limit of the stress at 50% extension in the machine
direction of the fiber structure is not particularly limited, but may be, for example,
greater than or equal to 1 N/5 cm.
[0035] The fiber structure may have, in the machine direction of the fiber structure, a
stress at 80% extension of, for example, greater than or equal to 20 N/5 cm, and the
stress at 80% extension is preferably greater than or equal to 25 N/5 cm, more preferably
greater than or equal to 30 N/5 cm. When the stress at 80% extension in the machine
direction of the fiber structure is greater than or equal to the above-described value,
the fiber structure tends to have high stress at high extension, and tends to be hardly
torn even when tightly wound. The upper limit of the stress at 80% extension in the
machine direction of the fiber structure is not particularly limited, but is, for
example, usually less than or equal to 50 N/5 cm.
[0036] The fiber structure may have, in the machine direction of the fiber structure, a
ratio between the stress at 50% extension and the stress at 80% extension, that is,
stress at 80% extension/stress at 50% extension of, for example, greater than or equal
to 2.7, and stress at 80% extension/stress at 50% extension is preferably greater
than or equal to 3.0, more preferably greater than or equal to 3.2. When the ratio
between the stress at 50% extension and the stress at 80% extension in the machine
direction of the fiber structure is greater than or equal to the above-described lower
limit, the fiber structure tends to have low stress at low extension, to have high
stress at high extension while being excellent in the initial conformity, and to be
hardly torn even when tightly wound. The ratio between the stress at 50% extension
and the stress at 80% extension, that is, stress at 80% extension/stress at 50% extension
in the machine direction of the fiber structure is not particularly limited, but may
be, for example, less than or equal to 10, and is preferably less than or equal to
8, more preferably less than or equal to 5.
[0037] The stress at 50% extension and the stress at 80% extension in the machine direction
of the fiber structure respectively mean stresses at extension immediately after extension
at extension rates of 50% and 80% in the machine direction of the fiber structure,
and can be measured by a tensile test in accordance with the "Test methods for nonwovens"
specified in JIS L 1913. The stress at 50% extension and the stress at 80% extension
in the machine direction of the fiber structure according to the present invention
are values obtained using AG-IS manufactured by Shimadzu Corporation as a constant
rate extension tensile tester.
[0038] The fiber structure may have a recovery rate after 50% extension in at least one
direction (hereinafter also referred to as a "recovery rate after 50% extension")
of, for example, greater than or equal to 70%, and the recovery rate after 50% extension
is preferably greater than or equal to 80%, more preferably greater than or equal
to 90%. The upper limit of the recovery rate after 50% extension is not particularly
limited, but is usually less than or equal to 100%. When the recovery rate after 50%
extension is within the above-described range, the followability to extension is enhanced.
For example, when the fiber structure is used as a bandage, the bandage satisfactorily
follows the shape of a portion around which the bandage is wrapped, and at the same
time, it is advantageous for improvement of the self-adhesiveness due to friction
between the overlapped fiber structures. If the extension recovery rate is excessively
small, the fiber structure cannot follow movement of a portion around which the fiber
structure is wrapped in the case where the portion has a complex shape or moves during
use of the fiber structure, and a portion deformed by body movement does not return
to its original shape, thus weakening fixation of the wrapped fiber structure.
[0039] The above-described "at least one direction" is preferably the above-described machine
direction of the fiber structure. When the fibrous sheet has, for example, a length
direction and a width direction like a bandage, the at least one direction is preferably
the length direction of the fibrous sheet.
[0040] The recovery rate after 50% extension is defined by the following formula:
wherein X is a residual strain (%) after a tensile test in accordance with the "Test
methods for nonwovens" specified in JIS L 1913 when a load is removed immediately
after the extension rate reaches 50%.
[0041] The recovery rate after 50% extension in a direction other than the at least one
direction of the fiber structure, for example, in the CD direction or, when the fiber
structure has a length direction and a width direction like a bandage, in the width
direction may be, for example, greater than or equal to 70% (less than or equal to
100%), and is preferably greater than or equal to 80%.
[0042] The fiber structure preferably exhibits self-adhesiveness. In the present specification,
the "self-adhesiveness" refers to a property allowing fibers on a fiber structure
surface to engage with each other or come into close contact with each other due to
superposition (contact) of the fibers and to be hooked or fixed. The fiber structure
having self-adhesiveness is advantageous when the fiber structure is a bandage or
the like. For example, in the case where the fiber structure is a bandage, after the
bandage is wrapped around an application site, the wrapped fibrous sheets are pressed
against each other while being extended by such an operation that an end of the bandage
is overlapped on a bandage surface located under the end, so that the fiber structures
are joined and fixed to each other, thereby expressing self-adhesiveness.
[0043] When the fiber structure has self-adhesiveness, it is unnecessary to form a layer
formed of a self-adhesive agent such as an elastomer or a pressure-sensitive adhesive
on a surface of the fiber structure or to prepare separately a fastener for fixing
the tip after wrapping. It is preferable that the fiber structure is constituted only
of a non-elastomer material. More specifically, it is preferable that the fiber structure
is constituted only of fibers. For example, Japanese Patent Laying-Open No.
2005-095381 (PTL 7, claim 1, paragraphs [0004] to [0006]) describes that an acrylic polymer or
a latex is caused to adhere as a self-adhesive agent to at least one side of a bandage
base material. However, when such a layer formed of an elastomer is formed on the
fibrous sheet surface, this may cause problems such as blood circulation disturbance
and pain when the sheet is wrapped around an application site for a long time. The
layer formed of an elastomer may induce skin irritation and allergy when wrapped around
an application site.
[0044] The self-adhesiveness of the fiber structure can be evaluated by a curved surface
sliding stress. The fiber structure may have a curved surface sliding stress of, for
example, greater than or equal to 1 N/50 mm, and the curved surface sliding stress
is preferably greater than or equal to 3 N/50 mm. Moreover, the curved surface sliding
stress is preferably higher than the breaking strength. Since it is relatively easy
to unwrap the wrapped fiber structure if desired, the curved surface sliding stress
is preferably less than or equal to 30 N/50 mm, more preferably less than or equal
to 25 N/50 mm. The curved surface sliding stress can be measured using a tensile tester
in accordance with the method described in the section of EXAMPLES (Figs. 2 to 4).
[0045] The fiber structure preferably has a hand cut property. In the present specification,
the "hand cut property" refers to a property enabling breakage (cutting) by hand tension.
The hand cut property of the fiber structure can be evaluated by breaking strength.
When the fiber structure has a sheet shape, the breaking strength in at least one
direction in the sheet plane is preferably 5 to 100 N/50 mm, more preferably 8 to
60 N/50 mm, still more preferably 10 to 40 N/50 mm from the viewpoint of hand cut
property. When the breaking strength is within the above range, it is possible to
impart a good hand cut property enabling relatively easy breakage (cutting) by hand.
If the breaking strength is too large, the hand cut property deteriorates, and it
tends to be difficult to cut the fiber structure with one hand, for example. Meanwhile,
if the breaking strength is too small, the strength of the fiber structure is insufficient
to cause easy breakage of the fiber structure, and durability and handleability tend
to be lowered. The breaking strength can be measured by a tensile test in accordance
with the "Test methods for nonwovens" specified in JIS L 1913.
[0046] The at least one direction in the sheet plane is a tensile direction when the fiber
structure is cut by hand, and is preferably the above-described machine direction
of the fiber structure. When the fiber structure has, for example, a length direction
and a width direction like a bandage, the at least one direction is preferably the
length direction of the fiber structure. That is, when the fiber structure is used
as a bandage, it is usual to break the bandage in the length direction after the bandage
is wrapped around an application site while being extended along the length direction
thereof, and therefore the machine direction is preferably the length direction as
the tensile direction.
[0047] The breaking strength in a direction other than the at least one direction in the
sheet plane, for example, in the CD direction or, when the fibrous sheet has a length
direction and a width direction like a bandage, in the width direction may be, for
example, 0.1 to 300 N/50 mm, and is preferably 0.5 to 100 N/50 mm, more preferably
1 to 20 N/50 mm.
[0048] From the viewpoint of the hand cut property, it is preferable that the fiber structure
is constituted only of a non-elastomer material. More specifically, it is preferable
that the fiber structure is constituted only of fibers. If a layer formed of an elastomer
or the like is formed on the fiber structure surface, the hand cut property may be
lowered.
[0049] The fiber structure may have an elongation at break in at least one direction in
the sheet plane of, for example, greater than or equal to 50%, and the elongation
at break is preferably greater than or equal to 60%, more preferably greater than
or equal to 80%. When the elongation at break is within the above-described range,
it is advantageous for enhancing the stretchability of the fiber structure. Moreover,
in the case where the fiber structure is used as a bandage, the followability can
be enhanced when the fiber structure is applied to a site with large movement, such
as a joint. The elongation at break in at least one direction in the sheet plane is
usually less than or equal to 300% and preferably less than or equal to 250%. The
elongation at break can also be measured by a tensile test in accordance with the
"Test methods for nonwovens" specified in JIS L 1913.
[0050] At least one direction in the sheet plane is preferably the above-described first
direction. The first direction may be the MD direction, and when the fiber structure
has, for example, a length direction and a width direction like a bandage, the first
direction is preferably the length direction of the fiber structure.
[0051] The elongation at break in a direction other than the at least one direction in the
sheet plane, for example, in the CD direction, or when the fiber structure has a length
direction and a width direction like a bandage, in the width direction may be, for
example, 10 to 500%, and is preferably 100 to 350%.
[0052] The coil-shaped crimped fibers (a) can include a latently thermally crimpable conjugated
fiber (hereinafter also simply referred to as a "conjugated fiber").
[0053] The conjugated fiber is a conjugated fiber in which a plurality of resins having
different thermal shrinkage factors or thermal expansion coefficients form a phase
structure. The conjugated fiber is a fiber having an asymmetric or layered (so-called
bimetal) structure crimped by heating due to a difference in thermal shrinkage factor
or thermal expansion coefficient. The plurality of resins usually have mutually different
softening points or melting points. The plurality of resins may be selected from thermoplastic
resins such as polyolefin-based resins (e.g., poly-C
2-4 olefin-based resins such as low-density, medium-density, or high-density polyethylene
and polypropylene); acrylic resins (e.g., acrylonitrile-based resins having an acrylonitrile
unit, such as acrylonitrile-vinyl chloride copolymers); polyvinyl acetal-based resins
(e.g., polyvinyl acetal resins); polyvinyl chloride-based resins (e.g., polyvinyl
chloride, vinyl chloride-vinyl acetate copolymers, and vinyl chloride-acrylonitrile
copolymers); polyvinylidene chloride-based resins (e.g., vinylidene chloride-vinyl
chloride copolymers and vinylidene chloride-vinyl acetate copolymers); styrene-based
resins (e.g., heat-resistant polystyrene); polyester-based resins (e.g., poly-C
2-4 alkylene arylate-based resins such as polyethylene terephthalate resins, polytrimethylene
terephthalate resins, polybutylene terephthalate resins, and polyethylene naphthalate
resins); polyamide-based resins (e.g., aliphatic polyamide-based resins such as polyamide
6, polyamide 66, polyamide 11, polyamide 12, polyamide 610, and polyamide 612, semi-aromatic
polyamide-based resins, and aromatic polyamide-based resins such as polyphenylene
isophthalamide, polyhexamethylene terephthalamide, and poly-p-phenyleneterephthalamide);
polycarbonate-based resins (e.g., bisphenol A-type polycarbonate); polyparaphenylene
benzobisoxazole resins; polyphenylene sulfide resins; polyurethane-based resins; and
cellulose-based resins (e.g., cellulose esters). These thermoplastic resins may contain
other copolymerizable units.
[0054] Among the thermoplastic resins, non thermal adhesive resins under moisture (or heat-resistant
hydrophobic resins or nonaqueous resins) having a softening point or melting point
greater than or equal to 100°C, such as polypropylene-based resins, polyester-based
resins, and polyamide-based resins are preferable from the viewpoint that fibers are
not melted or softened to be fused even when subjected to heating treatment with high-temperature
steam. Particularly, aromatic polyester-based resins and polyamide-based resins are
more preferable because they are excellent in the balance among heat resistance, fiber
formability, and the like. In the present invention, the resin exposed on the surface
of the conjugated fiber is preferably a non thermal adhesive fiber so that the fibers
constituting the fiber structure may not be fused even when treated with high-temperature
steam.
[0055] The plurality of resins forming the conjugated fiber may have different thermal shrinkage
factors, and may be a combination of resins of the same kind, or a combination of
different kinds of resins.
[0056] In the present invention, it is preferable that the conjugated fiber is formed from
a combination of resins of the same kind from the viewpoint of adhesion. In the case
where the conjugated fiber is formed from a combination of resins of the same kind,
usually a combination of a component (A) forming a homopolymer and a component (B)
forming a modification polymer (copolymer) is used. That is, for example, a copolymerizable
monomer for reducing the crystallization degree, the melting point, the softening
point, or the like may be copolymerized with a homopolymer to perform modification,
whereby the crystallization degree may be reduced as compared to that of the homopolymer,
or the polymer may be made noncrystalline to reduce the melting point or softening
point as compared to that of the homopolymer. As described above, a difference in
thermal shrinkage factor can be provided by changing the crystallinity, the melting
point, or the softening point. The difference in melting point or softening point
may be, for example, 5 to 150°C, preferably 50 to 130°C, more preferably about 70
to 120°C. The rate of the copolymerizable monomer used for the modification may be,
for example, 1 to 50 mol%, and is preferably 2 to 40 mol%, more preferably about 3
to 30 mol% (particularly 5 to 20 mol%) based on the whole amount of monomers. While
the composite ratio (mass ratio) between the component forming a homopolymer and the
component forming a modification polymer can be selected according to the structure
of fibers, the ratio of homopolymer component (A)/modification polymer component (B)
may be, for example, 90/10 to 10/90, and is preferably 70/30 to 30/70, more preferably
about 60/40 to 40/60.
[0057] The conjugated fiber may be a combination of aromatic polyester-based resins, in
particular, a combination of a polyalkylene arylate-based resin (a) and a modified
polyalkylene arylate-based resin (b) from the viewpoint of ease of production of the
latently crimpable conjugated fiber. The polyalkylene arylate-based resin (a) may
be a homopolymer of an aromatic dicarboxylic acid (e.g., a symmetric aromatic dicarboxylic
acid such as terephthalic acid or naphthalene-2,6-dicarboxylic acid) and an alkanediol
component (e.g., a C
2-6 alkanediol such as ethylene glycol or butylene glycol). Specifically, a poly-C
2-4 alkylene terephthalate-based resin such as polyethylene terephthalate (PET) or polybutylene
terephthalate (PBT) is used, and usually, PET for use in general PET fibers having
an intrinsic viscosity of about 0.6 to 0.7 is used.
[0058] Meanwhile, as for the modified polyalkylene arylate-based resin (b), a copolymerization
component for reducing the melting point, the softening point, or the crystallization
degree of the polyalkylene arylate-based resin (a), for example, dicarboxylic acid
components such as an asymmetric aromatic dicarboxylic acid, an alicyclic dicarboxylic
acid, and an aliphatic dicarboxylic acid; an alkanediol component having a chain length
longer than that of the alkanediol of the polyalkylene arylate-based resin (a); and/or
an ether bond-containing diol component can be used.
[0059] These copolymerization components may be used singly, or in combination of two or
more kinds thereof. Among these components, as the dicarboxylic acid component, asymmetric
aromatic dicarboxylic acids (e.g., isophthalic acid, phthalic acid, and 5-sodium sulfoisophthalic
acid), aliphatic dicarboxylic acids (C
6-12 aliphatic dicarboxylic acids such as adipic acid), or the like are generally used.
As the diol component, alkanediols (e.g., C
3-6 alkanediols such as 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, and neopentyl
glycol), polyoxyalkylene glycols (e.g., polyoxy-C
2-4 alkylene glycols such as diethylene glycol, triethylene glycol, polyethylene glycol,
and polytetramethylene glycol), or the like are generally used. Among them, asymmetric
aromatic dicarboxylic acids such as isophthalic acid, and polyoxy-C
2-4 alkylene glycols such as diethylene glycol are preferable. The modified polyalkylene
arylate-based resin (b) may be an elastomer having a C
2-4 alkylene arylate (e.g., ethylene terephthalate or butylene terephthalate) as a hard
segment and a (poly)oxyalkylene glycol or the like as a soft segment.
[0060] In the modified polyalkylene arylate-based resin (b), the rate of the dicarboxylic
acid component (e.g., isophthalic acid) for reducing the melting point or softening
point may be, for example, 1 to 50 mol%, and is preferably 5 to 50 mol%, more preferably
about 15 to 40 mol% based on the whole amount of dicarboxylic acid components. The
rate of the diol component (e.g., diethylene glycol) for reducing the melting point
or softening point may be, for example, less than or equal to 30 mol%, and is preferably
less than or equal to 10 mol% (for example, about 0.1 to 10 mol%) based on the whole
amount of diol components. If the rate of copolymerization components is too low,
sufficient coil-shaped crimps are not expressed, and thus the form stability and stretchability
of the fiber structure after expression of crimps are lowered. Meanwhile, if the rate
of copolymerization components is too high, although the performance of expressing
coil-shaped crimps is improved, it is difficult to stably perform spinning.
[0061] The modified polyalkylene arylate-based resin (b) may contain, as monomer components,
polyvalent carboxylic acid components such as trimellitic acid and pyromellitic acid,
polyol components such as glycerol, trimethylolpropane, trimethylolethane, and pentaerythritol,
and the like as necessary.
[0062] The transverse cross-sectional shape of the conjugated fiber (that is, the shape
of a cross section perpendicular to the length direction of the fiber) is not limited
to a general solid cross-sectional shape such as a circular cross-sectional shape
or an irregular cross-sectional shape [flat shape, elliptical shape, polygonal shape,
3 to 14-foliated shape, T-shape, H-shape, V-shape, dog-bone (I-shape) or the like],
and it may be a hollow cross-sectional shape or the like. Usually, the transverse
cross-sectional shape of the conjugated fiber is a circular cross-sectional shape.
[0063] Examples of the transverse cross-sectional structure of the conjugated fiber include
phase structures formed of a plurality of resins, such as structures of core-sheath
type, sea-island type, blend type, parallel type (side-by-side type or multilayer
lamination type), radial type (radial lamination type), hollow radial type, block
type, and random composite type. Among these transverse cross-sectional structures,
a structure in which phase parts neighbor each other (so-called bimetal structure),
and a structure in which a phase structure is asymmetric, such as a structure of eccentric
core-sheath type or parallel type are preferable from the viewpoint of ease of expression
of spontaneous crimps by heating.
[0064] In the case where the conjugated fiber has a structure of core-sheath type such as
a structure of eccentric core-sheath type, the core part may be made from a thermal
adhesive resin under moisture (e.g., a vinyl alcohol-based polymer such as an ethylenevinyl
alcohol copolymer or polyvinyl alcohol), or a thermoplastic resin having a low melting
point or softening point (e.g., polystyrene or low-density polyethylene) as long as
the resin of the core part has a difference in thermal shrinkage from the non thermal
adhesive resin under moisture of the sheath part situated at the surface, and thus
the fiber can be crimped.
[0065] The conjugated fibers may have an average fineness of, for example, 1 to 5 dtex,
and the average fineness is preferably 1.3 to 4 dtex, more preferably 1.5 to 3 dtex.
If the fineness is too small, it is difficult to produce fibers themselves, and, in
addition, it is difficult to secure fiber strength. Further, it is difficult to express
fine coil-shaped crimps in a process of expressing crimps. Meanwhile, if the fineness
is too large, fibers are rigid, so that it is difficult to express sufficient crimps.
[0066] The conjugated fibers may have an average fiber length (actual fiber length) of,
for example, 20 to 70 mm, and the average fiber length is preferably 25 to 65 mm,
more preferably 40 to 60 mm. If the fiber length is too short, it is difficult to
form a fibrous web, and, in addition, entanglement of fibers is insufficient in a
process of expressing crimps, so that it may be difficult to secure the strength and
stretchability. Meanwhile, if the fiber length is too long, it is difficult to form
a fibrous web with a uniform basis weight, and further, a large number of entanglements
of fibers are expressed at the time of forming the web, so that fibers may obstruct
one another at the time of expressing crimps, resulting in difficulty in expression
of stretchability. Further, in the present invention, when the fiber length is within
the above-described range, part of the crimped fibers at the surface of the fiber
structure are moderately exposed on the surface of the fiber structure, so that the
self-adhesiveness of the fiber structure can be improved.
[0067] When the conjugated fibers are heat-treated, crimps are expressed (or appear), and
thus fibers having substantially coil-shaped (helical or spiral spring-shaped) three-dimensional
crimps are obtained.
[0068] The number of crimps (number of mechanical crimps) before heating may be, for example,
0 to 30 crimps/25 mm, and is preferably 1 to 25 crimps/25 mm, more preferably 5 to
20 crimps/25 mm. The number of crimps after heating may be, for example, 20 to 120
crimps/25 mm, and is preferably 25 to 120 crimps/25 mm.
[0069] As described above, the coil-shaped crimped fibers (a) have substantially coil-shaped
crimps. The average curvature radius of the circles formed by the coils of crimped
fibers can be selected, for example, from a range of about 10 to 250 µm, and is, for
example, 20 to 200 µm (for example, 50 to 200 µm), preferably 50 to 160 µm (for example,
60 to 150 µm), more preferably about 70 to 130 µm. Herein, the average curvature radius
is an index expressing the average size of circles formed by the coils of crimped
fibers. In the case where this value is large, the formed coil has a loose shape,
i.e., a shape having a small number of crimps. If the number of crimps is small, the
number of entanglements of fibers is also small, so that it tends to be disadvantageous
for expressing sufficient stretching performance. Conversely, if coil-shaped crimps
having too small an average curvature radius are expressed, the fibers are not sufficiently
entangled with each other, and it is not only difficult to secure the web strength,
but also the production of latently crimped fibers that express such crimps tends
to be very difficult.
[0070] In the coil-shaped crimped fibers (a), the average pitch of the coils is preferably
0.03 to 0.5 mm, more preferably 0.03 to 0.3 mm, still more preferably 0.05 to 0.2
mm.
[0071] The non-coil-shaped crimped fibers (b) may include the conjugated fiber used in the
above-described coil-shaped crimped fibers (a), or may include another fiber other
than the conjugated fiber (a non-conjugated fiber). Use of the same conjugated fibers
in the coil-shaped crimped fibers (a) and the non-coil-shaped crimped fibers (b) tends
to be advantageous in view of simplicity of the production process. Further, the fiber
structure may include, irrespective of the type of the fibers constituting the coil-shaped
crimped fibers (a) and the non-coil-shaped crimped fibers (b), another fiber (non-conjugated
fiber) in the entangled part (A) and/or the entangled parts (B) in such an amount
that the object of the present invention is achieved.
[0072] Examples of the non-conjugated fiber include, in addition to fibers containing the
above-described non thermal adhesive resin under moisture or thermal adhesive resin
under moisture, cellulose-based fibers [e.g., natural fibers (e.g., cotton, wool,
silk, and hemp), semi-synthetic fibers (e.g., acetate fibers such as triacetate fibers),
and regenerated fibers (e.g., rayon, polynosic, cupra, and lyocell (e.g., registered
trademark "Tencel"))]. The average fineness and average fiber length of the non-conjugated
fibers are the same as those of the conjugated fibers. These non-conjugated fibers
may be used singly, or in combination of two or more kinds thereof. Among these non-conjugated
fibers, regenerated fibers such as rayon, semi-synthetic fibers such as acetate, polyolefin-based
fibers such as polypropylene fibers and polyethylene fibers, polyester fibers, and
polyamide fibers are preferable. In particular, from the viewpoint of blending properties
and the like, a fiber of the same type as the conjugated fiber may be used. For example,
when the conjugated fiber is a polyester-based fiber, the non-conjugated fiber may
also be a polyester-based fiber.
[0073] When the fiber structure includes a conjugated fiber and a non-conjugated fiber in
the entangled part (A) and/or the entangled parts (B), the ratio (mass ratio) between
the conjugated fiber and the non-conjugated fiber may be, for example, conjugated
fiber/non-conjugated fiber = 80/20 to 100/0 (for example, 80/20 to 99/1), and is preferably
90/10 to 100/0, more preferably about 95/5 to 100/0. Blending of the non-conjugated
fiber can adjust the strength of the fiber structure. However, if the ratio of the
conjugated fiber (latently crimped fiber) is too small, when the crimped fiber is
extended and shrinks after the expression of crimps, particularly when the crimped
fiber shrinks after extension, the non-conjugated fiber may serve as a resistance
to shrinkage, and it tends to be difficult to secure the recovery stress.
[0074] The fiber structure (fibrous web) may further contain commonly used additives, such
as stabilizers (e.g., thermal stabilizers such as copper compounds, ultraviolet absorbers,
light stabilizers, and antioxidants), antibacterial agents, deodorants, fragrances,
colorants (dyes and pigments), fillers, antistatic agents, flame retardants, plasticizers,
lubricants, and crystallization speed retardants. These additives may be used singly,
or in combination of two or more kinds thereof. The additives may be supported on
the fiber surface or may be contained in the fibers.
[Method for manufacturing fiber structure]
[0075] A method for manufacturing the fiber structure according to the present invention
includes: 1) forming a fiber into a web (hereinafter also referred to as a "web formation
step"); 2) entangling part of the web by spraying or injection of water to form the
entangled parts (B) (hereinafter also referred to as an "entangling step 1"); and
3) heating the web with high-temperature steam to form the entangled part (A) (hereinafter
also referred to as an "entangling step 2").
[0076] As a method of forming the web in the web formation step, it is possible to use a
commonly used method, such as a direct method including a spunbond method and a melt-blow
method, a carding method using melt-blown fibers, staple fibers, or the like, or a
dry method such as an air-lay method. Among these methods, a carding method using
melt-blown fibers or staple fibers, particularly, a carding method using staple fibers
is commonly used. Examples of the web obtained by using staple fibers include a random
web, a semi-random web, a parallel web, and a cross-wrap web.
[0077] Next, in the entangling step 1, part of the obtained fibrous web is entangled by
spraying or injection of water to form the entangled parts (B). Although the water
to be sprayed or injected may be blown from one or both sides of the fibrous web,
it is preferable to blow water from both sides from the viewpoint of efficiently performing
strong entanglement. The portion blown with water turns into the entangled parts (B),
and the portion not blown with water turns into the entangled part (A) in the subsequent
entangling step 2.
[0078] Examples of a method of forming the entangled parts (B) include a method of injecting
water with a spray nozzle or the like through a plate-like object (porous plate, slit
plate, or the like) or a drum (porous drum, slit drum, or the like) having a regular
spray area or spray pattern formed with a plurality of holes, a method of forming
the entangled parts (B) by switching on and off of the injection of water from the
spray nozzle, and a combination method of these. These methods can be performed by
appropriately selecting a manner of continuously or periodically moving the spray
nozzle, a manner of continuously or periodically transferring the fibrous web using
a belt conveyor such as an endless conveyor, or a combination manner of these in accordance
with the shape and size of the fibrous web, the shape and arrangement pattern of the
entangled parts (B) to be formed, and the like. The entangled parts (B) can be continuously
formed, for example, by installing a spray nozzle in the above-described drum, and
rotating the drum to transfer the fibrous web while injecting water. The material
constituting the plate-like object or the drum may be, for example, metals, plastics,
or wood.
[0079] When a border pattern in which the entangled part (A) and the entangled parts (B)
are alternately arranged in the machine direction is to be formed, the entangled parts
(B) can be formed, for example, by injecting water to the fibrous web using a spray
nozzle through a plate-like object or a drum having slits of a specific width in a
direction perpendicular to the machine direction. The slit width may be, for example,
0.5 to 30 mm, and is preferably 1 to 20 mm, more preferably 2 to 10 mm, still more
preferably 3 to 8 mm. The pitch of the slits is, for example, greater than or equal
to 2.5 mm, preferably greater than or equal to 3 mm, more preferably greater than
or equal to 3.5 mm. Meanwhile, the pitch of the slits may be, for example, less than
or equal to 20 mm, and is preferably less than 20 mm, more preferably less than or
equal to 15 mm, still more preferably less than or equal to 10 mm.
[0080] In the case of forming the border pattern, the entangled parts (B) can also be formed,
for example, by injecting water from spray nozzles arranged linearly in the machine
direction by switching on/off of the spray nozzles while continuously moving the fibrous
web.
[0081] When a plane lattice pattern in which the entangled parts (B) having a specific shape
are regularly arranged is to be formed, the entangled parts (B) can, for example,
be formed by injecting water from a spray nozzle onto the fibrous web through a plate-like
object or a drum having a plurality of regularly formed holes.
[0082] The shape of the hole is not particularly limited, but may be, for example, an oval
shape, an elliptical shape, a circular shape, a square shape, or a rectangular shape,
and is preferably an oval shape. When the hole has an oval shape, the length in the
major axis direction is, for example, 1 to 80 mm, and is preferably 5 to 60 mm, more
preferably 10 to 40 mm, and the length in the minor axis direction is, for example,
1 to 80 mm, and is preferably 3 to 50 mm, more preferably 5 to 30 mm. The plurality
of holes can be arranged in a plane lattice pattern, for example, a square lattice
pattern, an orthorhombic lattice pattern, or a rectangular lattice pattern. The pitch
of the holes may be, for example, greater than or equal to 2.5 mm, and is preferably
greater than or equal to 3 mm, more preferably greater than or equal to 3.5 mm. Meanwhile,
the pitch of the holes may be, for example, less than or equal to 20 mm, and is preferably
less than 20 mm, more preferably less than or equal to 15 mm, still more preferably
less than or equal to 10 mm.
[0083] The jetting pressure of water may be, for example, greater than or equal to 4 MPa,
and is preferably 8 MPa, more preferably greater than or equal to 10 MPa, still more
preferably greater than or equal to 15 MPa, particularly preferably greater than 15
MPa. When the jetting pressure of water is greater than or equal to the above-described
lower limit, the fibers come into a state of being packed, and even if a steam jet
is applied to the fibers in the subsequent entangling step 2, the fibers are fixed
and do not move and hardly express coil-shaped crimps, so that the entangled parts
(B) tend to be easily formed. Meanwhile, the upper limit of the jetting pressure of
water may be, for example, less than or equal to 20 MPa.
[0084] The temperature of water is preferably 5 to 50°C, more preferably 10 to 40°C, still
more preferably 15 to 35°C (normal temperature).
[0085] As a method of spraying or injecting water, preferred is a method of injecting water
with use a nozzle or the like having a regular spray area or spray pattern, from the
viewpoint of convenience and the like. Specifically, water can be injected onto a
fibrous web transferred by a belt conveyor such as an endless conveyor, while the
fibrous web is placed on a conveyor belt. The conveyor belt may be water-permeable,
and water may pass through the water-permeable conveyor belt from the back side of
the fibrous web to be injected onto the fibrous web. When water is injected also from
the back side of the fibrous web, it is preferable to inject water onto the fibrous
web through a plate-like object or a drum having a spray area or a spray pattern also
on the back side of the fibrous web. In order to suppress scattering of fibers due
to water injecting, the fibrous web may be wetted with a small amount of water in
advance. When the fibrous web is transferred by a conveyor, the transfer speed may
be, for example, 5 to 40 m/minute, and is preferably 10 to 20 m/minute.
[0086] As the nozzle for spraying or injecting water, it is possible to use a plate or die
having predetermined orifices successively arranged in the width direction thereof
in accordance with the pattern of the entangled parts (B) to be formed. The plate
or die may be disposed to arrange the orifices in the width direction of the fibrous
web to be conveyed. The number of orifice lines may be at least one, and a plurality
of orifice lines may be arranged in parallel. A plurality of nozzle dies each having
one orifice line may be installed in parallel. The nozzle pitch may be, for example,
1.0 to 2.5 mm. The nozzle diameter may be, for example, 0.2 to 0.5 mm.
[0087] In the entangling step 2, the fibrous web is heated with high-temperature steam,
and a portion of the conjugated fiber not blown with water in the above-described
entangling step is crimped into a coil shape to form the entangled part (A). In the
method of treating the fibrous web with high-temperature steam, the fibrous web is
exposed to a high-temperature or superheated steam (high-pressure steam) flow, whereby
coil-shaped crimps are formed in the conjugated fibers (latently crimped fibers).
The fibrous web has air permeability. Accordingly, high-temperature steam permeates
into the fibrous web even in treatment from one direction, substantially uniform crimps
are expressed in the thickness direction, and the fibers are uniformly entangled with
each other. The temperature of the high-temperature steam may be, for example, 50
to 150°C, and is preferably 40 to 130°C, more preferably 60 to 120°C.
[0088] The portion of the conjugated fiber not blown with water in the entangling step 1
of the fibrous web shrinks simultaneously with the high-temperature steam treatment.
Accordingly, it is desirable that the fibrous web to be supplied is overfed according
to the area shrinkage rate of an intended fiber structure immediately before the fibrous
web is exposed to high-temperature steam. The rate of overfeeding is preferably 110
to 250% based on the length of the intended fiber structure.
[0089] In order to supply the fibrous web with steam, a commonly used steam injecting apparatus
may be used. The steam injecting apparatus is preferably an apparatus capable of generally
uniformly blowing steam over the whole width of the fibrous web with a desired pressure
and amount. The steam injecting apparatus may be provided only on one surface side
of the fibrous web, or in order to treat the front and back of the fibrous web with
steam at a time, the steam injecting apparatus may be further provided on the other
surface side.
[0090] Since the high-temperature steam injected from the steam injecting apparatus is a
gas flow, the high-temperature steam enters inside the fibrous web without significantly
moving the fibers in the fibrous web, unlike the water flow entanglement treatment
and the needle punching treatment. By virtue of the entry action of the steam flow
into the fibrous web, the steam flow efficiently covers a surface of each fiber existing
in the fibrous web, and enables uniform thermal crimping. Since heat can be satisfactorily
conducted inside the fibrous web, as compared with the dry heat treatment, the degree
of crimping is almost uniform in the plane direction and the thickness direction.
[0091] Similarly to the nozzle for water flow entanglement, as a nozzle for injecting high-temperature
steam, a plate or die having predetermined orifices successively arranged in a width
direction thereof is used, and the plate or die may be disposed to arrange the orifices
in the width direction of the fibrous web to be conveyed. The number of orifice lines
may be at least one, and a plurality of orifice lines may be arranged in parallel.
A plurality of nozzle dies each having one orifice line may be installed in parallel.
[0092] The pressure of the high-temperature steam to be used can be selected from the range
of 0.1 to 2 MPa (for example, 0.2 to 1.5 MPa). If the pressure of the steam is too
high, the fibers forming the fibrous web may move more than required to cause disturbance
of the texture, or the fibers may be entangled more than required. When the pressure
is too weak, it becomes impossible to give the quantity of heat required for expression
of crimps of the fibers to the fibrous web, or the steam cannot penetrate the fibrous
web and expression of crimps of the fibers in the thickness direction tends to be
nonuniform. Although depending on materials of the fibers and the like, the temperature
of the high-temperature steam can be selected from the range of 70 to 180°C (for example,
80 to 150°C). The treatment speed with high-temperature steam can be selected from
the range of less than or equal to 200 m/minute (for example, 0.1 to 100 m/minute).
[0093] After thus causing expression of crimps of the conjugated fiber in the fibrous web,
there may be a case where water remains in the fiber structure, and therefore, a drying
step of drying the fiber structure may be provided as necessary. Examples of the drying
method may include a method using a drying apparatus such as a cylinder dryer or a
tenter; a non-contact method such as far infrared ray irradiation, microwave irradiation,
or electron beam irradiation; and a method of blowing hot air or passing the fiber
structure through hot air.
[0094] The fiber structure according to the present invention is excellent in the initial
conformity, can be tightly wound, does not contain a pressure-sensitive adhesive,
and has self-adhesiveness. Therefore, the fiber structure is suitable for applications
in contact with the human body, for example, tapes such as bandages and supporters
used in the medical and sports fields. Another gist of the present invention is a
bandage including the fiber structure.
[0095] Hereinafter, the present invention will be described more specifically with reference
to examples, but the present invention is not limited by these examples.
EXAMPLES
[0096] Physical property values of fiber structures obtained in Examples and Comparative
Examples were measured by the following methods.
- (1) Apparent average fiber length
The apparent average fiber length was obtained by observing a surface of the fiber
structure with an electron microscope, measuring the apparent fiber lengths of 100
fibers arbitrarily selected from the coil-shaped crimped fibers (a) present per any
1 cm2 of a surface of the entangled part (A) of the fiber structure, and calculating the
average of the apparent fiber lengths.
- (2) Number of crimps
The number of crimps was evaluated in accordance with JIS L 1015 "Chemical fiber staple
test method" (8.12.1).
- (3) Basis weight
The basis weight was measured in accordance with the "Test methods for nonwovens"
specified in JIS L 1913.
- (4) Thickness (TA) of entangled part (A) (height of protrusion)
The thickness was measured in accordance with the "Test methods for nonwovens" specified
in JIS L 1913.
- (5) Thickness (TB) of entangled parts (B) (base height)
The thickness was measured in accordance with the "Test methods for nonwovens" specified
in JIS L 1913.
- (6) Density of entangled part (A)
The density was calculated from the basis weight measured in the item (3) and the
thickness measured in the item (4).
- (7) Density of entangled parts (B)
The density was calculated from the basis weight measured in the item (3) and the
thickness measured in the item (5).
- (8) Area rate of entangled part (A)
The area rate of the entangled part (A) present per 0.5 cm2 of the fiber structure was determined as follows. A surface of the fiber structure
was observed over 0.5 cm2 at a magnification of 300 using an electron microscope. As for one visual field observed
with the electron microscope, a case where only crimped fibers were visible was defined
as "1", a case where crimped fibers and other fibers were mixed was defined as "0.5",
and a case where no crimped fibers were present was defined as "0". The total of the
scores was determined, and the rate of the calculated total to the number of observed
visual fields was defined as the area rate of the entangled part (A).
- (9) As a method of measuring the distance between the entangled parts (B), a ruler
was used to measure the distance between two points that were farthest from each other
at the center of the entangled parts.
- (10) Recovery rate after 50% extension
The recovery rate after 50% extension was measured in accordance with the "Test methods
for woven and knitted fabrics" specified in JIS L 1096. In the evaluation in the present
invention, however, the recovery rate was uniformly defined as that after 50% extension,
and after the fiber structure returned to its original position subsequent to the
50% extension, the next operation was performed without any standby time. Note that
the measurement was performed in the machine (MD) direction of the fiber structure.
AG-IS manufactured by Shimadzu Corporation was used as a constant rate extension tensile
tester.
- (11) Stress at extension
The stress at extension was measured in accordance with the "Test methods for woven
and knitted fabrics" specified in JIS L 1096. Stresses at 50% extension and at 80%
extension were measured. AG-IS manufactured by Shimadzu Corporation was used as a
constant rate extension tensile tester.
- (12) Self-adhesiveness
The curved surface sliding stress (N/50 mm) was measured by the following method.
When the curved surface sliding stress was greater than or equal to 1 N/50 mm, it
was determined that the fiber structure has self-adhesiveness.
[0097] First, a fibrous sheet was cut into a size of 50 mm in width and 600 mm in length
so that the MD direction was the length direction, to obtain a sample 5. Then, as
shown in Fig. 2(a), one end of sample 5 was fixed to a winding core 7 (a pipe roll
formed of a polypropylene resin and having an outer diameter of 30 mm and a length
of 150 mm) with a single-sided adhesive tape 6. Then, with use of an alligator clip
8 (the gripping width was 50 mm, and a rubber sheet having a thickness of 0.5 mm had
been fixed on the inside of the clip with a double-sided adhesive tape before use),
a weight 9 of 150 g was attached to the other end of sample 5 to apply the load to
the whole width of sample 5 evenly.
[0098] Then, while winding core 7 to which sample 5 was fixed was lifted up such that sample
5 and weight 9 were suspended, winding core 7 was rotated for five rounds so that
weight 9 did not significantly swing, to wind up sample 5 and thus to lift up weight
9 (see Fig. 2(b)). In this state, a contact between a cylindrical portion at an outermost
peripheral portion of sample 5 wrapped around winding core 7 and a planar portion
of sample 5 not wrapped around winding core 7 was defined as a base point 10 (the
contact was a border line between an area of sample 5 wrapped around winding core
7 and an area of sample 5 rendered vertical by the gravity of weight 9), and alligator
clip 8 and weight 9 were slowly removed so as not to move and shift base point 10.
Then, the outermost peripheral portion of sample 5 wound around winding core 7 was
cut with a razor at a point 11 that was located a half-circle away (180°) from base
point 10 along sample 5, paying attention to avoid cutting underlying sample 5, to
provide a cut 12 (see Fig. 3).
[0099] A curved surface sliding stress between an outermost layer portion of sample 5 and
an inner layer portion placed under the outermost layer portion (inner layer) and
wrapped around winding core 7 was measured. For this measurement, a tensile tester
("Autograph" manufactured by Shimadzu Corporation) was used. Winding core 7 was fixed
on a jig 13 installed on a chuck base on a fixed side of the tensile tester (see Fig.
4), and the end of sample 5 (the end to which alligator clip 8 had been attached)
was gripped by a chuck 14 on a load cell side to stretch sample 5 at a tensile speed
of 200 mm/minute. When sample 5 was removed (separated) at cut 12, the measured value
(tensile strength) was regarded as the curved surface sliding stress.
<Example 1>
[0100] As a latently crimpable fiber, a side-by-side type composite staple fiber ["Sofit
PN780" manufactured by Kuraray Co., Ltd., 1.7 dtex × 51 mm long, number of mechanical
crimps: 29 crimps/25 mm, number of crimps after heat treatment at 130°C for 1 minute:
29 crimps/25 mm] was prepared that was constituted of a polyethylene terephthalate
resin having an intrinsic viscosity of 0.65 [component (A)] and a modified polyethylene
terephthalate resin [component (B)] in which 20 mol% of isophthalic acid is copolymerized
with 5 mol% of diethylene glycol. Using 100% by mass of this side-by-side type composite
staple fiber, a carded web having a basis weight of 30 g/m
2 was provided by a carding method.
(Entangling step 1)
[0101] This carded web was moved on a conveyor net, and allowed to pass between the conveyor
net and a porous drum with pores (oval shape) having a major axis dimension of 50
mm, a minor axis dimension of 5 mm, and a pitch of 15 mm and being arranged in an
orthorhombic lattice pattern. Through the porous drum, a water flow was injected in
a spray form at 10 MPa toward the web and the conveyor net, and thus an entangling
step of fibers was conducted.
[0102] Then, the carded web was transferred to an entangling step 2 while the web was overfed
at about 200% so as not to prevent shrinkage in the subsequent entangling step 2 performed
by steam.
(Entangling step 2)
[0103] Then, the carded web was introduced to a steam injecting apparatus provided in a
belt conveyor, and steam at 0.5 MPa and a temperature of about 160°C was ejected to
the carded web perpendicularly from the steam injecting apparatus to treat the web
with steam, so that coil-shaped crimps of the latently crimped fibers were expressed,
and at the same time, the fibers were entangled. In this steam injecting apparatus,
nozzles were installed in one of the conveyors so as to blow steam toward the carded
web through the conveyor belt. Each of the steam injecting nozzles had a pore diameter
of 0.3 mm, and an apparatus in which the nozzles were arranged in a line at a pitch
of 2 mm in the width direction of the conveyor was used. The processing speed was
8.5 m/minute, and the distance between each nozzle and the conveyor belt on a suction
side was 7.5 mm. Finally, the web was dried with hot air at 120°C for 1 minute to
obtain stretchable sheet-shaped fiber structure 1.
[0104] Obtained fiber structure 1 was subjected to various measurements. The results are
shown in Table 1. An outline diagram of an arrangement pattern of entangled parts
(B) 2 in a machine direction of obtained fiber structure 1 is shown in Fig. 1.
<Example 2>
[0105] A fiber structure was produced in the same manner as in Example 1 except that in
the entangling step 1, a water flow was injected at a water pressure of 20 MPa. The
evaluation results are shown in Table 1.
<Example 3>
[0106] A fiber structure was produced in the same manner as in Example 1 except that in
the entangling step 1, the carded web was allowed to pass between the conveyor net
and a porous drum with pores (oval shape) having a major axis dimension of 50 mm,
a minor axis dimension of 10 mm, and a pitch of 10 mm and being arranged in an orthorhombic
lattice pattern. The evaluation results are shown in Table 1.
<Example 4>
[0107] A fiber structure was produced in the same manner as in Example 1 except that in
the entangling step 1, the carded web was allowed to pass between the conveyor net
and a porous drum with pores having a major axis dimension of 400 mm, a minor axis
dimension of 5 mm, and a pitch of 15 mm and being arranged in a border pattern. The
evaluation results are shown in Table 1.
<Comparative Example 1>
[0108] A fiber structure was produced in the same manner as in Example 1 except that the
entangling step 1 was not conducted. The evaluation results are shown in Table 1.
<Comparative Example 2>
[0109] A fiber structure was produced in the same manner as in Example 1 except that instead
of the entangling step 1, the carded web was moved on a conveyor net, and allowed
to pass between the conveyor net and a porous drum with pores (circular shape) having
a diameter of 2 mmϕ and a pitch of 2 mm and being arranged in an orthorhombic lattice
pattern, that a water flow was injected in a spray form at 0.8 MPa from the inside
of the porous drum toward the web and the conveyor net, and thus an uneven distribution
step of periodically forming a low-density region and a high-density region of fibers
was conducted, and that then water was injected at a water pressure of 4 MPa while
the web was transferred to a belt conveyor equipped with a 76 mesh, 500 mm width resin
endless belt, using a nozzle having orifices having a diameter of 0.1 mm arranged
in a line at 0.6 mm intervals in the width direction of the web. The evaluation results
are shown in Table 1.
[Table 1]
|
Example 1 |
Example 2 |
Example 3 |
Example 4 |
Comparative Example 1 |
Comparative Example 2 |
Average fineness (dtex) |
1.7 |
1.7 |
1.7 |
1.7 |
1.7 |
1.7 |
Average fiber length (mm) |
51 |
51 |
51 |
51 |
51 |
51 |
Apparent average fiber length (mm) |
17 |
17 |
17 |
17 |
17 |
17 |
Number of mechanical crimps (crimps) |
29 |
29 |
29 |
29 |
29 |
29 |
Basis weight (g/m2) |
138.6 |
142.8 |
147.0 |
140.4 |
90.0 |
88.5 |
Thickness (TB) of entangled parts (B) [Base height] (mm) |
0.77 |
0.78 |
0.75 |
0.77 |
- |
- |
Thickness (TA) of entangled part (A) [Height of protrusion] (mm) |
2.8 |
2.79 |
2.81 |
2.80 |
- |
- |
TA/TB |
3.64 |
3.58 |
3.75 |
3.64 |
- |
- |
Density of entangled part (A) (g/cm3) |
0.05 |
0.05 |
0.06 |
0.05 |
0.06 |
0.11 |
Density of entangled parts (B) (g/cm3) |
0.18 |
0.18 |
0.20 |
0.18 |
|
|
Area rate of entangled area (A) (%) |
81 |
68 |
55 |
77 |
100 |
100 |
Distance between entangled parts (B) [mm] |
7.5 |
5.0 |
3.5 |
7.5 |
- |
- |
Rate of distances between entangled parts (B) that are less than apparent average
fiber length (%) |
100 |
100 |
100 |
100 |
- |
- |
Stress at 50% extension (N/50 mm) |
7.5 |
9.4 |
11.8 |
7.7 |
4.2 |
19.0 |
Stress at 80% extension (N/50 mm) |
31.5 |
34.0 |
38.0 |
32.1 |
8.5 |
48.6 |
Stress at 80% extension/stress at 50% extension |
4.2 |
3.6 |
3.2 |
4.2 |
2.0 |
2.6 |
Recovery rate after 50% extension (%) |
93.8 |
94.6 |
95.3 |
93.1 |
93.9 |
96.4 |
Self-adhesiveness |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
[0110] The fiber structures of Examples 1 to 3 were smaller in stress at 50% extension,
excellent in the initial conformity, and excellent in the recovery rate after 50%
extension compared to the fiber structure of Comparative Example 2. Further, the fiber
structures of Examples 1 to 3 had higher stress at 80% extension than the fiber structure
of Comparative Example 1 did, and can be tightly wound. That is, the fiber structures
of Examples 1 to 3 had the performance required at low extension and at high extension
in a balanced manner as compared with Comparative Examples 1 and 2.
REFERENCE SIGNS LIST
[0111] 1: fiber structure, 2: entangled part (B), 3: entangled part (A), 4: distance between
entangled parts (B), 5: sample, 6: single-sided adhesive tape, 7: winding core, 8:
alligator clip, 9: weight, 10: base point, 11: point located half-circle away from
base point, 12: cut, 13: jig, 14: chuck