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EP 0 368 559 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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01.03.1995 Bulletin 1995/09 |
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Date of filing: 02.11.1989 |
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International Patent Classification (IPC)6: C11D 3/12 |
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Glass cleaning preparation
Glasreinigungsmittel
Composition pour le nettoyage du verre
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Designated Contracting States: |
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BE DE ES FR IT |
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Priority: |
10.11.1988 GB 8826338
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Date of publication of application: |
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16.05.1990 Bulletin 1990/20 |
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Proprietor: TRICO-FOLBERTH LIMITED |
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Brentford
Middlesex TW8 9HP (GB) |
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Inventor: |
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- Huber, Hermann Joseph
Teddington
Middlesex (GB)
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Representative: Pedder, James Cuthbert |
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J.C. Pedder & Co.
38 Norbury Cross Norbury
London SW16 4JQ Norbury
London SW16 4JQ (GB) |
(56) |
References cited: :
EP-A- 0 030 986
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FR-A- 2 235 994
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Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
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[0001] This invention relates to a glass cleaning preparation and more particularly to a
preparation for cleaning the windscreens of motor or like vehicles.
[0002] In motor vehicles, the ability to see clearly through the windscreen is critical
not only for the safety of the driver and his passengers but also for the safety of
other road users. For this reason, all motor vehicles travelling on public highways
are fitted with windscreen wipers whose job is to clear the windscreen of any rain
thereon and, to a limited extent, with the help of washers, to remove mud and grime
from the windscreen.
[0003] However, for the windscreen wipers to work satisfactorily, it is essential that grease
and other matter which sticks to the windscreen be removed at regular intervals as
otherwise the wipe becomes streaky and visibility is impaired.
[0004] There are a number of glass cleaning preparations on the market with generally non
specialised application. However, they are far from satisfactory for a number of reasons.
For example, many glass cleaning compositions are good at cleaning glass such as house
windows, but they leave a surface coating on the glass which interferes with the correct
operation of the windscreen wipers. Other preparations require to be washed off after
use or dry in such a way as to leave smears on the glass.
[0005] This invention seeks to provide a glass cleaning preparation in which some or all
of the above disadvantages are removed or substantially reduced and which is eminently
suitable for cleaning the windscreens of motor and like vehicles.
[0006] According to the invention, a glass cleaning preparation comprises a light abrasive,
finely divided silica, water and alcohol in proportions suitable to produce a cream
and a wetting agent.
[0007] The finely divided silica may be fumed, precipitated or in colloidal form.
[0008] Preferably, the light abrasive comprises calcium carbonate in precipitated form suitably
in the form known commercially as "light calcium carbonate". The alcohol is preferably
ethanol but may suitably include methanol and isopropanol. The wetting agent may be
propylene glycol-ethylene glycol fatty alcohol polymer.
[0009] In a particular formulation of the glass cleaning preparation in accordance with
the invention, the preparation comprises, by weight, 4 - 17% precipitated calcium
carbonate, 1.7 - 6% fumed silica, 47 - 77% water, 8 - 38% ethanol and 0.5 - 4% wetting
agent.
[0010] The invention will now be described in greater detail by way of example.
[0011] In a particular example of a batch of glass cleaning preparation, the preparation
comprised:-
100 g calcium carbonate (light)
50 g fumed silica
800 ml water
250 ml ethanol
24 ml propylene glycol-ethylene glycol fatty alcohol polymer
To formulate the preparation, 50 g fumed silica powder was placed in a mixing vessel
to which 800 cc. water was then added. The contents of the mixing vessel were stirred
to a smooth creamy consistency. Then the calcium carbonate powder was added to the
mixing vessel and the contents were again stirred to a smooth creamy consistency.
[0012] At this point, 250 ml ethanol and 24 ml propylene glycol-ethylene glycol fatty alcohol
polymer were added as a mixture and the the final preparation was again stirred to
a smooth consistency. The preparation was then ready for bottling.
[0013] The proportions used could suitably be varied in the ranges:-
50-200 g calcium carbonate
20-70 g fumed silica
6 -48 ml propylene glycol-ethylene glycol fatty alcohol polymer
The amount of water and ethanol used would depend on the amount of powder present,
the liquid being in sufficient quantities to provide a creamy smooth substance. While
it is desirable that the ratio of ethanol to water should be of the order of 5 : 16
parts by volume, this ratio could be varied over a wide range, e. g. between 1 : 8
and 1 : 1.
[0014] Other alcohols may be used instead of ethanol, for example methanol and isopropanol.
The finely divided silica could be obtained by precipitation or used in colloidal
form. Other forms of calcium carbonate, such as heavy chalk, could be used. Talc,
Kaolin or other suitable light abrasives may be used instead of the calcium carbonate.
Other wetting agents could be used, but these should all be low foaming.
[0015] In use, the glass cleaning preparation above described may suitably be dispensed
directly onto the windscreen to be cleaned from a squeeze bottle. The preparation
is rubbed into the glass with a tissue or soft cloth and allowed to dry. After a short
time a residual dry powder is left and this can be removed by wiping with a soft dry
cloth leaving a clean dry windscreen.
[0016] In the action of the material, the calcium carbonate and the fumed silica provide
a light abrasive action. The fumed silica, which is a thixotropic material, acts to
adhere the preparation to the glass and prevent it from running off before it has
been rubbed in. The water and ethanol enable the ingredients to be emulsified into
a smooth cream, the ratio of the two determining the drying time required after application.
The use of a wetting agent ensures that no residue of the preparation is left adhered
to the screen.
[0017] While the above preparation has been particularly formulated for windscreen cleaning,
it will be understood that it is equally suitable for cleaning other glass surfaces.
1. A glass cleaning preparation characterised in that the preparation comprises a light abrasive, finely divided silica, water and alcohol
in proportions suitable to produce a cream and a wetting agent.
2. A preparation as claimed in claim 1, characterised in that the finely divided silica is fumed.
3. A preparation as claimed in claim 1, characterised in that the finely divided silica comprises precipitated silica or colloidal silica.
4. A preparation as claimed in any one of claims 1 to 4, characterised in that the light abrasive comprises precipitated calcium carbonate.
5. A preparation as claimed in claim 4, characterised in that the calcium carbonate comprises the material known commercially as "light calcium
carbonate".
6. A preparation as claimed in any one of claims 1 to 5, characterised in that the alcohol comprises ethanol.
7. A preparation as claimed in any preceding claim, characterised in that the alcohol includes methanol and/or isoopropanol.
8. A preparation as claimed in any preceding claim, characterised in that the wetting agent comprises propylene glycolethylene glycol fatty alcohol polymer.
9. A preparation as claimed in claim 1, characterised in that the preparation comprises, by weight, 4 - 17% precipitated calcium carbonate, 1.7
- 6% fumed silica, 47 - 77% water, 8 - 38% ethanol and 0.5 - 4% wetting agent.
10. A preparation as claimed in claim 1, characterised in that the preparation has the following proportionate values:-
100 g calcium carbonate (light)
50 g fumed silica
800 ml water
250 ml ethanol
24 ml propylene glycol-ethylene glycol fatty alcohol polymer
1. Präparat zum Reinigen von Glas, dadurch gekennzeichnet, daß das Präparat eine leicht
abtragbare Substanz, fein verteilte Kieselerde, Wasser und Alkohol in einem Verhältnis
enthält, das geeignet ist, eine Creme und eine Befeuchtungssubstanz zu erzeugen.
2. Präparat nach Anspruch 1, dadurch gekennzeichnet, daß die feinzerteilte Kieselerde
abgeraucht ist.
3. Präparat nach Anspruch 1, dadurch gekennzeichnet, daß die feinzerteilte Kieselerde
niedergeschlagene Kieselerde oder Kolloidkieselerde enthält.
4. Präparat nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die leichtabtragbare
Substanz niedergeschlagenes Calciumcarbonat enthält.
5. Präparat nach Anspruch 4, dadurch gekennzeichnet, daß das Calciumcarbonat dasjenige
Material enthält, das kommerziell als "light calcium carbonate" bekannt ist.
6. Präparat nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß der Alkohol
Äthanol enthält.
7. Präparat nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß der
Alkohol Methanol und/oder Isopropanol enthält.
8. Präparat nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die
Befeuchtungssubstanz ein Propylen-Glykolethylen-Glykol fetthaltiges Alkoholpolymer
enthält.
9. Präparat nach Anspruch 1, dadurch gekennzeichnet, daß das Präparat die folgenden Gewichtsprozente
enthält: 4 - 17 % niedergeschlagenes Calciumcarbonat,
1,7 - 6 % abgerauchte Kieselerde,
47 - 77 % Wasser,
8 - 38 % Äthanol und
0,5 - 4 % Befeuchtungssubstanz.
10. Präparat nach Anspruch 1, dadurch gekennzeichnet, daß es das folgende Mischverhältnis
aufweist:
100 g Calciumcarbonat (light calcium carbonate)
50 g abgerauchte Kieselerde
800 ml Wasser
250 ml Äthanol
24 ml Propylen-Glykol-Ethylen-Glykol fetthaltiges Alkohol- polymer.
1. Préparation pour le nettoyage des vitres, caractérisée en ce que la préparation comprend
une silice finement divisée et légèrement abrasive, de l'eau et de l'alcool, en proportions
appropriées pour obtenir une crème et un agent mouillant.
2. Préparation selon la revendication 1, caractérisée en ce que la silice finement divisée
est fumée.
3. Préparation selon la revendication 1, caractérisée en ce que la silice finement divisée
comprend de la silice précipitée ou de la silice colloïdale.
4. Préparation selon l'une quelconque des revendications 1 a 3, caractérisée en ce que
l'abrasif léger comprend du carbonate de calcium précipité.
5. Préparation selon la revendication 4, caractérisée en ce que le carbonate de calcium
comprend la substance appelée dans le commerce "carbonate de calcium léger".
6. Préparation selon l'une quelconque des revendications 1 a 5, caractérisée en ce que
l'alcool comprend de l'éthanol.
7. Préparation selon l'une quelconque des revendications précédentes, caractérisée en
ce que l'alcool comprend du méthanol et/ou de l'isopropanol.
8. Préparation selon l'une quelconque des revendications précédentes, caractérisée en
ce que l'agent mouillant comprend un polymère d'un alcool gras, du propylèneglycol
et de l'éthylèneglycol.
9. Préparation selon la revendication 1, caractérisée en ce que la préparation comprend,
en poids, de 4 à 17% de carbonate de calcium précipité, de 1,7 a 6% de silice fumée,
de 47 a 77% d'eau, de 8 à 38% d'éthanol et de 0,5 a 4% d'agent mouillant.
10. Préparation selon la revendication 1, caractérisée en ce que la préparation comprend
les proportions suivantes :
100 g de carbonate de calcium (léger)
50 g de silice fumée
800 ml d'eau
250 ml d'éthanol
24 ml de polymère d'alcool gras et de propylène-glycol-éthylèneglycol.