[0001] This invention relates to an elastomeric material which is conductive under pressure
and suitable for use in keyboards of data processing equipment.
[0002] Elastomeric materials (rubbers) are known which are rendered conductive by adding
materials such as carbon black or metal powders is the mix or composition. Some compositions
and processes for poducing conductive rubbers are given in the book: Conductive Rubbers
as Plastics, by R. H. Norman - Elsevier, Amsterdam, London, New York, 100.
[0003] Elements of conductive rubber are used as contact materials in

known types of keyboard.
[0004] For application in keyboards, piezoconductive rubbers are more interesting, that
is those rubbers which become conductive under the effect of applied pressure, because
they allow keyboards without contacts exposed to oxidation to be obtained, inasmuch
as contact takes place within the piezoconductive material.
[0005] 
piezoconductive elastomers are used for producing fixed contact. In the known materials
the piezoconductive effect disappears after a few thousand actuations of the elastomeric
element, for which reason these materials are not suitable for use in keyboards.
[0006] The ject of the invention is to provide an elastomer which becomes conductive under
the effect of pressure and preserves this characteric for a number of operations of
the order of at least some hundreds of nousands.
[0007] This prolem has been solved by means of the piezoconductive elastomerionterial according
to the invention, as claimed in claim 1.
[0008] The invention will be described in more detail, by way of example, with reference
to the accompanying drawings in which:
Fig. 1 is a front view of an apparatus for preparing an elastomer according to the
invention;
Fig. 2 shows a key employing the piezoc:nductive elastomer according to the invention;
Fig. 3 shows a detail of a keyboard employing the elastomer according to the invention;
Fig. 4 is a graph relating to the key of Fig. 2;
Fig. 5 is a diagram of a measuring cirotit used for the graph of Fig. 4.
[0009] Fig. 2 shows a key 10 which uses a path 11 of piezoconductive elastomer according
to the invention and can be employed to replace a normal contact-type key as an input
device for a data processing apparatus, with an interface towards semiconductor electronic
circuits of high input impedance.

[0010] assume a low resistance when this pressure is exceeded, and then to reacquire the
insulating properties on release of the key, presenting a certain hysteresis, but
with a negligible delay. It is moreover essential that the patch preserves these characteristics
for at least 100,000 operations of the same key, with a contact resistance always
below 10,000 ohms.
[0011] According to the known literature (B. E. Spingett: Conductivity of a system of metallic
particles dispersed in an insulating medium - J. A. Phys., Vol. 44, No. 6, June 73,
pp. 2925 - 26, and C. H. Kuist: Anisotropic conduction in elastomeric composites -
Proc. 7 Am. Conn. Symposium, June 1974, pp. 203 - 209), on varying the percentage
of metal powder in a matrix of insulating elastomer the conductivity of the whole
shows a distinct transition from insulating material to conductive material for a
well-defined percentage by volume (V ) of metal powder close to 0.2 and dependent
to a certain extent on the grain size and on the shape of the metal granules, presenting
piezoconductive characteristics for percentages by volume of metal powders a little
lower than V . m
[0012] In particular in the article by C. H. Kuist, percentages of metal (nickel) powder
by volume ranging between 0.08 and 0.18 are suggested for the piezoconductive rubbers.
[0013] It is known that the application of a magnetic field during the polymerization of
rigid epoxy plastics materials containing metal powders (see the said book Conductive
Rubbers and Plastics, page 82) brings a considerable increase in the conductivity
of the whole in the direction of the magnetic field; it could therefore be expected
from this that also with elastomers the application of a magnetic field during the
polymerization would lead to a lowering of the transition percentage V
m between the piezoconductive condition and the conductive condition in the preferred
direction established by the magnetic field.
[0014] Surprisingly, it has been found that on dispersing nickel powders in a matrix of
elastomeric binder, for example of the type Silastic E manufactured by Dow Corning,
and maintaining the composition under the effect of a magnetic field during the polymerization
of the binder, the rubber proves to be insulating in the absence of pressure even
with percentages of powder between 15 and 27%, which greatly exceed the indicated
limit values. On the other hand, the endurance of the piezoconductive characteristics
improves decisively and passes from a few thousand operations of the key to several
hundreds of thousands before irregularities of operation not tolerated by noraml electronic
utilization circuits are encountered.
[0015] It has also been found that on exceeding these percentages, the riezoconductive characteristics
become worse again and that the optimum value is found for percentages around 21%.
[0016] The preferred metal material is a nickel powder consisting of spnerical grains and
having the maximum hardness compatible with preservation of the magnetic characteristics.
More particularly, good results have been obtained with a nickel powder known by the
trade name of Alloy 79 GS, supplied by the Baudier Company, of Liancourt (France).
[0017] The powder consists of 93.94% of nickel, 3.5% of silicon, 1% of tron, 1.6% of boron
and 0.05% of carbon and has a Rockwell C hardness of 18-22; the spherical granules
have a diameter between 100 and 150µ.
[0018] A preferred composition of the piezoconductive elastomer is constituted by:
Silastic E silicone rubber from Dupont: by weight: 30 parts;
79 GS nickel powder from Baudier: 70 parts;
Silastic E hardener from Dupont: 3 parts.
[0019] Preparation of the piezoconductive elastomer requires careful mixing of the powder
and silicone rubber, addition of the hardener, a first degassing of the mix under
vacuum and casting in the mould followed by a second degassing under vacuum and introduction
into the magnetizer, which applies a magnetic field with a direction perpendicular
to the faces of the sheet during the polymerization of the binder.
[0020] The thickness of the sheet or film of piezoconductive elastomer may vary from 0.4
to 0.8 mm, the preferred thickness being 0.6 mm.
[0021] The intensity of the magnetic field during the polymerization is not critical, provided
that the field reaches an intensity of at least 500 oersteds. Above this value no
appreciable variations are found in the results.
[0022] The apparatus used for preparing the elastomer is shown diagrammatically in Fig.
1, in which a mould 31 of non-magnetic material, in which the elastomer mix 36 is
cast, is between two pole pieces 32 and 33 a magnetizer 37 which are interconnected
by an external magnetic circuit (not shown). The magnetic flux is maintained throughout
the time of polymerization of the elastomer by the current flowing in two windings
34 and 35. During the polymerization, the elastomer is kept at room temperature. Under
these conditions, complete polymerization requires about 18 hours.
[0023] The time required for preparing the piezoconductive elastomeric material can be reduced
to 10 minutes, still in a magnetic field, if the temperature of the mould 31 is brought
to 100°
C.
[0024] All the samples tested have exceeded the prescribed minimum life of 100,000 operations,
with peaks of more than 1,000,000 operaticns.
[0025] Fig. 5 shows a simple circuit used for detecting the characteristics of the key of
Fig. 2, comprising a DC voltage generator 41 producing 5 V and a 50 KΩ limiting resistor
42 in series with the key 10.
[0026] Fig. 4 is a graph of the voltage drop detected across the terminals 43 and 44 of
the resistor 42 as a function of the force F applied to the key. The phenomenon of
hysteresis between actuation and release of the key is obvious from the graph.
[0027] An alternative embodiment of a keyboard employing the piezoconductive rubber according
to the invention is shown in Fig. 3.
[0028] In.the keyboard 23, a single sheet 24 of piezoconductive material produced in a magnetic
field in accordance with the invention is used, instead of individual patches of piezoconductive
elastomer as in the key of Fig. 2. The sheet 24 is stuck by means of a conductive
adhesive to islands 26 of a printed circuit board 25 which constitute one of the contact
terminals of the keys 27.
[0029] A second, flexible, printed circuit board 28 is stuck by means of conductive adhesive
on top of the sheet 24 of piezoconductive material at islands 29 in line with the
islands 26. The islands 26 and 29 constitute contact terminals of the keys 27..
[0030] Springs 30, in combination with the movement of buttons 22, transmit the force applied
to the buttons 22 to the piezoconductive sheet 24, causing locally the formation of
passages of relatively low resistivity between the islands 26 and 29, while the material
of the piezoconductive sheet 24 interposed between the keys 27 and not subjected to
pressure maintains its insulating properties. The solution of Fig. 3, which is functionally
equivalent to the modular solution of Fig. 2, is more convenient for producing keyboards
with a large number of keys inasmuch as it drastically reduces the number of parts.
[0031] 
[0032] With this solution, it is possible to construct keys which simultaneously close a
plurality of independent circuits by using a plurality of separate and insulated patches
of piezoconductive material according to the invention or acting simultaneously on
different points of the same sheet of piezoconductive material by means of actuating
elements insulated from one another.
[0033] It is possible to make numerous variations in the solutions exemplified here as regards
the type of elastomer and of magnetic conductive material, the form of the key, the
level of modularity, that is the manner of grouping the keys, the actuating mechanism,
and the production of contact between the piezoconductive material and the encoding
circuit, without departing from the scope of the invention as claimed.
1. Piezoconductive elastomeric material containing a magnetic metal powder dispersed
in a matrix of polymerized elastomer, characterised in that the material is subjected
to the action of a magnetic field during the polymerization, whereby it becomes piezoconductive
in a preferred direction parallel to the direction of the magnetic field.
2. Material as in claim 1, characterised in that the percentage by volume of the powder
is between 15% and 27%.
3. Material as in claim 1 or 2, characterised in that the
magnetic metal material is substantially a hard nickel powder with spherical granules
having a diameter between 100 and 150µ.
4. Key for data processing equipment without movable contacts, characterised in that
the force of actuation of the key acts on a piezoconductive material according to
any one of the preceding claims.
5. Key as in claim 4, characterised in that the force of actuation acts on a patch
of piezoconductive material.
6. Key as in claim 5, characterised in that the force of actuation acts to establish
a contact at a predetermined point of a sheet of piezoconductive material.
7. Key as in claim 5 or 6, characterised in that the said force of actuation acts
simultaneously on a plurality of patches of piezoconductive material or at a plurality
of predetermined points of the sheet of piezoconductive material, cl7.osing a plurality of independent electric circuits.