BACKGROUND OF THE INVENTION
1. Field of the Invention
[0001] This invention relates to gem stones and other display objects and, more particularly,
to multiplet gem stones, such as doublets and triplets, which incorporate pleochroic
materials.
2. Description of the Prior Art
[0002] Many of the well-known gem minerals are pleochroic. That is, a single piece of such
a material will exhibit various colors, depending on the direction of viewing and/or
the polarization direction of the illuminating light. The fundamental effect is due
to the polarization direction of the light. The viewing angle dependence in unpolarized
light arises due to the elimination of light polarized parallel to the viewing direction,
since light waves are purely transverse excitations. Such effects occur in non-cubic,
optically uniaxial and biaxial crystals due to the influence of the anisotropic host
crystal structure on the transitions between electron energy levels of the impurity
ions which give rise to the color.
[0003] Some well-known gem crystals which exhibit pleo- chroism to a greater or lesser extent
include alexandrite, andalusite, axinite, beryl, chrosoberyl, cordierite, emerald,
epidot, kyanite, peridote, ruby, sinnalide, spodumene, tourmaline and zoisite.
[0004] In the course of cutting crystals of these minerals to obtain faceted gem stones,
it is well-known that one must often control the crystallographic orientation of the
stone to obtain the desired color in the finished gem stone, or alternatively, that
the color of the finished gem may be varied to some extent by varying the crystallographic
orientation. This is particularly important, for example, in the faceting of certain
types of tourmaline which, if cut with the table (top) facet terallel to the "c" plane,
may appear nearly opaque or blact, while the same stone, if cut with the table facet
perpendicular to the "c" plane, would exhibit a desirable blue or green color. Similarly,
certain cordierites may appear nearly colorless in certain orientations and deep blue
in others.
[0005] Multiplet element gem stones have been used in the past for various purposes. For
example, D'Esposito in U.S. Patent 1,745,607, issued February 4, 1930, describes doublet
stones in which two components made of natural beryl are cemented together with a
transparent cement incorporating an appropriate coloring agent so as to produce a
composite stone exhibiting the color of emerald. In this case, the refractive properties
of beryl, which resemble those of emerald, are combined with the color properties
of the central colored film. Other doublet constructions may combine the hardness
properties of a material, such as sapphire, with the refractive and dispersive properties
of a soft material, such as strontium titanate, to produce a robust composite stone
visually resembling a diamond. See, e.g., Jones, U.S. Patents 3,528,261 and 3,808,836,
issued Sept. 15, 1970 and May 7, 1974, respectively. Or, a hard colorless cap may
be used to mechanically protect a fragile but visually attractive stone such as opal.
[0006] Other attempts to alter or control the optical properties of gem stones have also
been employed. For example, in highly doped natural or synthetic alexandrite, the
daylight green color is often obscured by red overtones, especially in thicker sections.
Cline et al. in U.S. Patent 3,912,521, issued Oct. 14, 1975, disclose addition of
iron as an impurity as a means of improving the daylight green coloration of highly
doped synthetic crystals of larger size. However, we have observed that this method
is not totally effective.
SUMMARY OF THE INVENTION
[0007] The present invention is directed to the improvement or modification of the color
displayed by certain of the above-mentioned
pleochroic materials, either alone or in various combinations, by constructing multiple
element display objects, including gem stones, in such a way as to exploit the natural
pleochroic behavior of the material. As used herein, pleochroic material refers to
either natural or synthetic mineral, that is, a crystalline, inorganic oxide, for
example, which evidences pleochroic behavior.'
[0008] In accordance with one aspect of the invention, a display object is disclosed comprising
at least two optically oriented elements of at least one pleochroic material, said
elements either fixed or disposed in continuously variable rotational configuration
with respect to each other. Such display objects may be used to provide a varying
range of colors pleasing to the eye, the particular colors depending on the particular
pleochroic materials and optical orientations selected.
[0009] In accordance with another aspect of the invention, a multi-element transparent gem
stone is disclosed comprising at least two optically oriented elements of at least
one pleochroic material, said oriented elements being either physically rotated with
respect to each other over a range of about 20° to 160° or separated by an optically
active rotator plate.
[0010] The gem stones of the invention evidence enhanced colors and other unusual optical
properties over those obtained in singlet construction. In the case of either synthetic
or natural alexandrite, the red overtones which obscure the daylight green color are
substantially eliminated by rotating two alexandrite stones, which have been cut parallel
to the "c" crystal plane, by, e.g., 90° to produce a clear intense blue-green color.
The stones are then cemented together to produce a doublet having a color pleasing
to the eye. Alternatively, triplet constructions
[0011] comprising an optical rotator plate sandwiched by at least one pleochroic material
may be used to obtain the enhanced colc=s and other unusual optical properties.
BRIEF DESCRIPTION OF THE DRAWING
[0012]
FIG. 1, on coordinates of absorption in cm-1 and wavelength in µm, is a plot of the absorption spectrum of synthetic alexandrite
in polarized light; and
FIG. 2 is a diagrammatic sectional view of a doublet gem stone construction.
DETAILED DESCRIPTION OF THE INVENTION
[0013] One of the most spectacular of the pleochroic minerals is alexandrite, BeAl
2O
4, containing chromium (Cr
3+) as an impurity. It is one of the few trichroic minerals, that is, exhibiting three
distinct colors corresponding to the three possible polarization directions of light
traveling through its orthorhombic crystal structure. These will be described here
for later reference. We use the crystal lattice parameter assignment of Farrell et
al. in American Minerologist, 48, 804-810 (1963), where a = 9.404 0 0 0 A, b = 5.476
A and c = 4.427 A. A polished cube of alexandrite containing about 0.05 to 0.1 atomic
percent chromium substituted for aluminum and having dimensions of about 1 cm on an
edge, when viewed in transmission in unpolarized daylight, will appear blue or purplish-blue
in the "a" direction, orange or reddish-orange in the "b" direction and green or reddish-green
in the "c" direction. If the same cube is viewed in transmission, illuminated by linearly
polarized white light, it will appear a clear yellow color for light polarized with
the electric vector parallel to the "a" direction (i.e., Ella) for all directions
of viewing except, of course, "a", since as mentioned above, light is a purely transverse
disturbance and therefore light traveling along a certain direction can have no component
of polarization in that direction. Similarly, for E||b, the color is blue-green and
for E||c, the color is violet. Thus, when viewing, for example, through the "c" direction
in unpolarized light, both the E||a (yellow) and E|| b (blue-green) beams are seen
simultaneously, and the resulting color is green.
[0014] The polarized absorption spectra which give rise to these observed colors are shown
for a typical piece of synthetic alexandrite in FIG. 1.
[0015] In the present invention, as it applies to a multiplet gem stone which incorporates
pleochroic materials, the function of the pleochroic materials is to act as spectrally
selective polarizers by absorbing light of particular polarizations and in particular
spectral regions in order to modify aspects of the color of the resulting gem. In
certain instances of the invention, all of the elements of the multiplet are of the
same material, while in other instances, it is desirable to combine elements of different
pleochroic materials in the same gem.
[0016] Display objects incorporating the teachings herein are also contemplated. Such display
objects, like the gem stones of the invention, comprise at least two optically oriented
elements of at least one pleochroic material. The doublet and triplet constructions
set forth below may be advantageously employed to produce display objects having colors
pleasing to the eye. The optically oriented elements of the display objects may be
fixed with respect to each other in a manner similar to that described below for gem
stones. For example, a simple cube comprising appropriately cut and oriented plates
which are then cemented together may be fabricated. Alternatively, the elements of
the display objects may be disposed in continuously variable rotational configuration
with respect to each other. For example, two single cubes comprising appropriately
cut and oriented elements rotationally mounted on the same axis may be fabricated.
l. Doublet Gem Stones
[0017] A doublet gem stone is schematically depicted in FIG. 2, which shows, in cross-section,
a top or crown portion 1 which is disposed in effectively permanent secured relation,
as by cementing, to a lower or pavillion member 2. Interface or mating surfaces 3
of parts 1 and 2 are first lapped and polished prior to cementing or otherwise bonding
portions 1 and 2 together. The actual gem cut may be any of the type usually employed,
such as brilliant-cut, emerald-cut, and the like, or other cuts employing facets producing
a stone pleasing to the eye.
[0018] One useful application of the present invention is the enhancement of the color change
properties of the gem alexandrite. In highly doped natural or synthetic alexandrite,
the daylight green color is often obscured by red overtones, especially in thicker
sections.
[0019] In accordance with one aspect of the invention, the alexandrite crystal section (natural
or synthetic) to be fabricated into a facet gem, say an optically dense, highly doped
crystal, is first oriented by means of visual inspection, optical methods or X-ray
diffraction so that the three crystal directions, "a", "b" and "c", are known. The
crystal is then sawed in half parallel to the "c" crystal plane (i.e., perpendicular
to the "c" direction). The mating sawed surfaces are polished flat and placed in contact
in their original orientation. The stone, now in two pieces, is viewed in transmission
in a direction perpendicular to the saw cut. One of the pieces is then rotated with
respect to the other. It will be found that this rotation produces a dramatic change
in the color displaced from a reddish or reddish-green color with no rotation to a
clear blue-green color which will be most intense with a rotation of 90°. The stone
is then rotated by some angle 6 so as to produce the desired degree of color change
in the composite, and the two mating polished surfaces are cemented together using
a suitable bonding agent. This may be any transparent, colorless, strong glue, such
as epoxy, Canada balsam, polymethyl methacrylate, cyanoacrylate or other satisfactory
material. Other agents requiring the application of heat, such as low melting point
glasses or polymers, may also be used. The angle 8 producing the blue-green color
may range from about 20° to 160°. The most intense coloration is produced over the
range of about 60° to 120°, and accordingly, such rotation angle is preferred.
[0020] The doublet crystal so formed is then fabricated into the desired finished form by
conventional methods of lapidary art. The faceting is done in such a way that the
planar glue joint generally lies in the stone parallel to the table facet and at a
position near the firgle of the stone. Some care may be required during facet grinding
and polishing to avoid damage to the glue joint from excessive heat or mechanical
force, since the joint may not in general be as strong or heat resistant as the original
material.
[0021] Alternatively, the separation of the stone into two components may be made parallel
to the "a" crystal plane, in which case a relative rotation of the two halves around
an axis normal to the "a" plane will produce a deep pure blue color. The angle of
rotation again may vary from about 20° to 160°. The most intense coloration is produced
over the range of about 60° to l20°, and accordingly, such rotation angle is preferred.
However, if the same method is followed by separating the stone parallel to the "b"
plane,' little or no color change will result from rotation, an observation which
will be explained below.
[0022] In general, the two components of a pleochroic doublet gem, namely, the crown (the
upper or top) component and the pavillion (the lower or back) component, are best
made from crystals containing different levels of doping. This is because in most
standard gem cuts, to which the present invention is primarily addressed, the crown
section of the stone is thinner than the pavillion section and therefore requires
deeper coloring to produce an optimum balanced coloring of the finished gem stone.
[0023] It is also sometimes desirable to combine "a" and "c" axis plates in the same stone.
In this case, the color will vary between blue-green, when the "b" directions of the
two plates are at 90° from each other, to violet, when the "b" directions are parallel.
[0024] The daylight green color of alexandrite can be enhanced most effectively by using
two natural or synthetic "c" axis alexandrite plates as described above, in which
the upper or crown plate contains from 1 to 5 times as much chromium as the bottom
plate, and the angle of relative rotation, e (measured between similar crystallographic
directions in the upper and lower plates) lies between 20° and 160°. The chromium
concentration of the alexandrite crystals should, in general, be in the range of from
about 0.005 to 1.0 atomic percent substitution of chromium for aluminum ions. The
preferred concentrations for gems with final dimensions of about 0.2 to 2 cm in diameter
are about 0.02 to 0.2 atomic percent chromium in the pavillion element and about 0.06
to 0.6 atomic percent in the crown element. In general, the smaller stones require
the higher chromium concentration to produce intense colors.
[0025] Natural or synthetic alexandrite doublet gem stones constructed according to the
method of the present invention exhibit a strikingly pure daylight green coloration
while still possessing the characteristic raspberry or columbine red color of alexandrite
when illuminated by incandescent light or light from a wood fire, oil lamp or candle.
[0026] Furthermore, high doping levels, up to 1.0 atom percent and higher (substitution
of Cr
3+ for
A13+in BeA1
20
4) can be used to obtain very deep green colors. Such high concentration levels inevitably
cause serious or complete degradation of the green color in conventional singlet alexandrite
gems.
[0027] Thus, the method of the present invention can be used to produce natural or synthetic
alexandrite gems possessing unprecedented color change properties not equalled by
conventionally cut singlet stones of whatever origin or detailed chemical composition.
[0028] The principles by which the pleochroic doublet functions can be illustrated using
the alexandrite example by reference to the polarized absorption curves shown in FIG.
1 and the schematic doublet shown in FIG. 2. If one considers, for example, a "c"
axis plate of alexandrite viewed in transmission parallel to the "c" direction (i.e.,
at right angles to the plate), the unpolarized light passing through the plate will
be resolved by the crystal into two orthogonally polarized beams, one with E|| a and
the other E||b. Viewed separately (as with a polarizer), the E||b beam appears deep
blue-green by virtue of the relatively strong absorption of this polarization in the
yellow-orange spectral region (X = 0.6-0.65 µm). The E||a beam, viewed separately,
appears yellow-orange by virtue of the relatively low absorption in this spectral
region combined with the peak in human visual spectral response, which occurs near
the same spectral region. One notes that both polarizations transmit with little absorption
in the far red spectral region (λ> 0.65 µm). Upon leaving the plate, the two beams
recombine and, in thin sections, the color sensation produced is green. As the section
thickness (or dopant concentration) is increased, however, the composite color becomes
increasingly orangish, due, for the most part, to orange light (
X = 0.6-0.65 pm) transmitted by the E||a beam with an absorption coefficient, a, lower
than that for either beam in the blue-green transmission band centered near λ= 0.5
µm.
[0029] The intensity of the transmitted light depends exponentially on the product of the
absorption coefficient and the section thickness; that is, I/I = e -αX, where I
o is the incident intensity, I is the transmitted intensity, a is the absorption coefficient
and "x" is the section thickness. Thus, the ratio of green to orange light transmitted
also varies exponentially with the thickness section "x". If a second "c" axis plate
is now placed parallel to the first and oriented with both "a" (or "b") directions
parallel, the effect is that of a simple increase in section thickness. If, however,
the second plate is rotated by 90° relative to first plate around the "c" axis, as
shown in FIG. 2, the polarizations of the two transmitted beams are now interchanged
as they pass from one plate into the other. That is, the E a beam in the first plate,
which was transmitted with relatively low absorption in the orange spectral region,
becomes the E b beam in the second plate, and as such experiences strong absorption
of its orange spectral components. Since neither polarization experiences strong absorption
in the blue-green transmission band centered near X= 0.5 µm or in the far red (X>0.65pm),
these colors now dominate the composite transmitted spectra, and the stone appears
either green under illuminations such as skylight or fluorescent light, which are
rich in green, or red under illuminations such as candlelight or incandescent light,
which are rich in the red and poor in the green-blue spectral regions. Thus, the classical
alexandrite illumination-dependent color change effect is somewhat flawed by the relatively
low absorption coefficients of E||c and E||a polarizations in the spectral region
of X = 0.6-0.65 µm (orange to red) which causes the effect to become obscured in thick
sections or deeply colored stones. This flaw is corrected by the method of the present
invention by the controlled total or partial absorption of this E||a transmission
by rotational transformation of this beam to a different polarization.
[0030] We have found, in the course of a detailed study of rotated doublet effects in pleochroic
minerals, that a number of desirable color modifications similar in origin to those
described above in alexandrite can be effected by the method of the present invention.
[0031] One such case involves doublets constructed by cementing together one plate of "c"
or "a" axis alexandrite with another plate of tourmaline cut so that the tourmaline
"c" axis lies in the plane of the plate. Certain varieties of tourmaline, which exhibit
an undesirable yellowish-green color alone can be made to change to a deep pure emerald
green color by varying the angle of rotation of the tourmaline-alexandrite doublet,
the strongest effect occurring when the tourmaline "c" axis lies parallel to the alexandrite
"b" axis.
[0032] Similarly, certain other tourmaline varieties, known collectively as watermelon tourmaline
because they contain regions of both red and green color in the same crystal, can
be combined in the doublet configuration with the "a" or "c" axis alexandrite plates
in such a way as to increase the depth and contrast of their unique coloration. This
is particularly useful in the case of lightly colored
[0033] material which is otherwise of good quality but appears pale and low in color contrast.
Again, the effect is maximized when the tourmaline "c" axis lies parallel to the alexandrite
"b" axis.
[0034] The color tint of certain varieties of aquamarine, morganite, beryl and ruby canrbe
adjusted by combining them with dichroic plates of tourmaline or cordierite in doublet
configurations as described above, with the rotation angle being adjusted to produce
the desired color.
2. Triplet Gem Stones
[0035] Triplet-gem stones accomplishing the effects discussed above for pleochroic doublets
can bo produced using the variation of the present invention as described below. This
variation relies on the known optical rotatory power or optical activity of a-quartz
(and certain other compounds of the same crystal structure, such as berlinite) to
rotationally transform the polarization directions of light beams traveling in the
pleochroic multiplet gem stone. A beam of linearally polarized light traveling parallel
to the "c" axis in a crystal of a-quartz will suffer a progressive rotation of its
plane of polarization, depending on the distance traveled and the wavelength of the
light. In general, due to the so-called rotatory dispersion, light of shorter wavelength
will suffer more rotation in a given path length than light of a longer wavelength.
[0036] The example of the alexandrite-quartz-alexandrite triplet will be used to illustrate
this aspect of the present invention. It will be recalled that the alexandrite doublet
functions by transformation of the E||a beam in one element into the E||b beam in
the other element through appropriate relative orientation of the pleochroic doublet
components and the consequent absorption of light in the X = 0.6-0.65 m spectral region
which would otherwise be transmitted by single sections. In the present variation,
the rotational transformation is accomplished by the use of a quartz "c" axis plate
interposed between two plates of similarly oriented alexandrite. The thickness of
the quartz plate is adjusted so as to produce a rotation of approximately 90° in the
spectral region of X= 0.6-0.65 µm. The rotatory power in this region is about 20°
per mm, so the required thickness for a full 90° of rotation is about 4.5 mm. In practice,
we have found that thinner quartz plates (0.5 mm and up) can also be used if the balance
of the rotation required is made up by physical rotation of the alexandrite elements
of the triplet. As a practical matter, the maximum thickness for a quartz plate employed
in triplet gem stones is about 10 mm. The preferred position of the quartz plate in
the finished gem is generally near the girdle, and the chromium concentration ranges
and ratios discussed above in connection with alexandrite doublets also apply.
[0037] In addition to effecting the color variations produced by doublets, we find that
striking interference effects are produced by pleochroic material-quartz triplets
such that the color of the stone changes rapidly with slight shifts in viewing angle.
EXAMPLES
Example 1
[0038] An alexandrite doublet gem was constructed as follows. Two polished "c" axis plates
of synthetic alexandrite, 'one containing 0.3 atomic percent chromium and the other.containing
0.1 atomic percent chromium, were cemented together using epoxy glue (formula), with
a 90° relative rotation such that the "a" axis in one plate lay parallel to the "b"
axis in the other plate. After allowing adequate time for the epoxy glue to cure,
the composite was formed into a standard brilliant-cut gem by conventional lapidary
di.amond grinding and polishing techniques. Using the traditional crown and pavillion
angles for chrysoberyl or alexandrite, the upper or crown plate, containing 0.3 atomic
percent Cr
3+, had a final thickness in the finished gem of 1.53 mm, and the pavillion or back
plate, containing 0.1 atomic percent Cr
3+, had a final maximum thickness (at the culet or point) of 4.58 mm. The glue joint
in the finished gem was placed parallel to the table or top facet and at the level
of the girdle or widest diameter of the gem. The finished gem had a girdle diameter
of 9.8 mm, a total height, from table to culet, of 6.1 mm and a weight of approximately
4 carats (0.8 g). The color of the finished gem was deep green by daylight or fluorescent
light and deep raspberry red when illuminated by an incandescent bulb or candlelight.
Example 2
[0039] Two standard emerald cut alexandrite gems were produced following the general procedures
outlined in Example 1. In this case, both the crown and pavillion elements were "c"
axis synthetic alexandrite plates containing 0.05 atomic percent Cr
3+. Both stone nad final width and length dimensions of 10 and 12 mm, respectively.
In the first stone (stone A), the "a" axis of the pavillion or bottom plate was parallel
to the width dimension of the finished gem, as was the "b" axis of the crown plate..
In the second stone (stone B), the "b" axis of the pavillion element and the "a" axis
of the crown element were both parallel to the width dimension, i.e., the reverse
of stone A. Both stones appeared raspberry red under incandescent light or candlelight
and green in daylight. The daylight tint of stone A, however, was decidedly bluish-green,
while that of stone B was more of a pure green.
Example 3
[0040] In this example, a doublet combining two pleochroic materials to produce a unique
effect is described. Two elements, one of a dichroic natural andalusite crystal and
one of a crystal of the blue, strongly pleochroic variety of cordierite (also known
as iolite or dichroite) were placed together such that the surface perpendicular to
the orange-appearing direction in the andalusite crystal (containing the optical X
direction) contacted the surface perpendicular to the blue-appearing direction in
the cordierite crystal (also containing the optical X direction). (The optical X direction
is the polarization direction of light with the smallest index of refraction.) Rotation
of the elements such that the optical X directions of both crystals were parallel
produced a violet color by daylight illumination, which changed to red under incandescent
light. Thus, an illumination color change effect was produced.
[0041] A standard emerald-cut gem stone measuring 6 x 5 mm is produced using the general
procedures outlined in Example 1. The crown plate is formed from the andalusite crystal
with the polished surface perpendicular to the orange-appearing direction in the crystal
so that the polished surface contains the optical X direction. The pavillion plate
is formed from the cordierite crystal in such a way that the optical X direction of
the crystal again lies in the plane of the plate. The plates are cemented together
so that the optical X directions of both crystals lie parallel in the finished gem
and along the long dimension. The finished gem is a pleasing violet color by daylight
illumination, which changes to red under incandescent light.
Examplè 4
[0042] In this example, a quartz rotator plate is used to accomplish a part of the rotational
transformation of polarizations in an alexandrite-quartz-alexandrite triplet. Two
cubes of alexandrite, 8 mm on edge, with edges oriented parallel to the "a", "b" and
"c" directions, were placed on either side of a 4 mm thick "c" axis a-quartz plate
such that the surface perpendicular to the "c" axes of the cubes contacted the surface
perpendicular to the "c" axis of the plate. Alignment of the cubes such that their
"a" axes were parallel produced the characteristic green color under daylight illumination
and the characteristic raspberry red color under incandescent illumination, when viewed
along the "c" axis. When viewed at angles slightly off the "c" axis, color fringes
appeared, and the color changed to reddish-orange under daylight illumination.
[0043] A standard brilliant-cut gem stone is prepared as follows. A crown plate of "c" axis
synthetic alexandrite containing 0.15 atomic percent chromium is cemented to one side
of a 2 mm thick "c" axis a-quartz plate. To the other side of.the quartz plate is
cemented a pavillion plate of "c" axis synthetic alexandrite containing 0.05 atomic
percent chromium and oriented with its "a" axis rotated 45° from the "a" axis of the
crown plate in a direction producing the characteristic color change (the direction
of rotation required will depend on whether right or left-handed rotating quartz is
used). The composite so produced is then fabricated into a 15 mm diameter brilliant-cut
gem stone, with the quartz plate parallel to the table facet and lying at a depth
such that it is centered at the girdle plane.
[0044] The resulting gem appears the characteristic green color in daylight when viewed
at right angles to the table facet, but changes to reddish-orange if rotate by a slight
angle. Under incandescent illumination, there is a decided color change to the characteristic
raspberry red color.
1. A multiple element transparent optical display object comprising a gem stone having
at least two optically oriented elements of at least one pleochroic material, said
oriented elements being either physically rotated with respect to each other over
a range of about 20° to 1600 or separated by an optically active rotator material.
2. A multiple element transparent display object comprising at least two optically
oriented elements of at least one pleochroic material, said oriented elements being
either fixedly mounted with respect to each other such that one element is rotated
with respect to the other by an angle ranging from about 20° to 1600 or disposed in continuously variable rotational configuration with respect to each
other.
3. A display object according to either of claims and 2, in which said at least one
pleochroic element is selected from alexandrite, andalusite, axinite, beryl, chrysoberyl,
cordierite, dichroite, emerald, epidot, kyanite, peridot, ruby, sinhalite, spodumene,
tourmaline or zoisite.
4. A display object according to any one of claims 1 to 3, comprising two elements
of at least one pleochroic material physically rotated with respect to each other.
5. A display object according to claim 4, in which said two elements comprise alexandrite,
each element containing chromium in the concentration range of about 0.005 to 1.0
atom percent substitution for aluminum, said elements being oriented substantially
parallel to crystal planes which contain the "b" crystal direction and rotated with
respect to each other over a range of about 20° to 1600.
6. A display object according to claim 4, in which one element comprises tourmaline
oriented at right angles to the "c" plane and the second element comprises either
"a" axis or "c" axis alexandrite.
7. A gem stone according to either of claims 1 and 3 comprising three elements, two
of which comprise at least one pleochroic material and the third an optically active
rotator material interposed between said two elements.
8. A display object according to claim 2, additionally comprising an optically active
rotator material disposed between said at least two elements.
9. A gem stone according to either of claims7 and 8, in which said rotator material
comprises a-quartz.