(19)
(11) EP 0 020 275 A1

(12) EUROPEAN PATENT APPLICATION

(43) Date of publication:
10.12.1980 Bulletin 1980/25

(21) Application number: 80400775.5

(22) Date of filing: 30.05.1980
(51) International Patent Classification (IPC)3B03D 1/02, C10L 9/00
(84) Designated Contracting States:
AT BE CH DE FR GB IT LI LU NL SE

(30) Priority: 01.06.1979 US 44736

(71) Applicant: CALGON CORPORATION
Robinson Township Pennsylvania 15205 (US)

(72) Inventors:
  • Snow, Glen F.
    Birmingham Alabama 35209 (US)
  • Bell, Hugh L.
    Toronto Ontario (CA)

(74) Representative: Corre, Jacques Denis Paul et al
Cabinet Regimbeau 26, Avenue Kléber
75116 Paris
75116 Paris (FR)


(56) References cited: : 
   
       


    (54) Process for improving the recovery of clean coal from flotation circuits


    (57) Adding an effective amount of a water soluble, partially hydrolyzed polyacrylamide to the coal being processed to decrease the amount of the clay being floated and removed from the cells with the fine coal.


    Description

    Background of the Invention



    [0001] Flotation processes have been used for some time in the coal industry to recover coal fines from previously discarded aqueous streams generated by processing raw coal. Generally, the flotation feed consists of fine coal and clay which results from prior coarse separation steps such as baths, jigs, dewatering screens, sieve bends and cyclones. The feed is normally 28 x 0 mesh and contains 4 to 12 percent solids.

    [0002] The flotation circuit consists of four to eight cells in a single bank with the number of banks proportional to the total tonnage to be processed. The concentrate produced in the flotation cells goes to a vacuum filter where it is concentrated to approximately 75 to 80 percent solids. The tailings from the flotation process are discharged to a waste pond or a refuse vacuum filter. During the flotation process, the very fine clay that is in the circuit often becomes entrapped in and/or adsorbed on the coal being floated and increases the amount of ash in the final product.

    [0003] Accordingly, it is an object of this invention to improve the operation of the coal flotation circuit by improving the overall yield of coal.

    [0004] It is another object of this invention to improve the operation of the coal flotation circuit by improving the overall yield of coal.

    [0005] It is another object of this invention to improve the operation of the coal flotation circuit by decreasing the ash content of the coal.

    [0006] These and other objects of this invention are accomplished by the addition of the partially hydrolyzed polyacrylamides to coal flotation circuits.

    Detailed Description of the Invention



    [0007] The polymer may be added to the feed to the flotation circuit or to the individual cells by conventional feeding means and it is believed that it functions by flocculating the fine coal fraction. The polymer may be used in dosages of between 0.025 and 1 pound per ton, preferably at least 0.05 pounds per ton, based on the weight of the dry flotation feed.

    [0008] Suitable polymers which may be used in accordance with the teachings of this invention are water soluble, partially hydrolyzed polyacrylamides having a degree of hydrolysis of from 1 percent to 50 percent and a molecular weight of at least 50,000, and preferably at least 1,000,000.

    [0009] The following examples will illustrate this invention.

    Example 1



    [0010] A series of flotation tests were conducted. The objectives of the tests were to reduce the ash in the clean coal, increase the percent recovery of the coal and reduce the amount of fuel oil being used in the flotation circuit. The results of these tests are set forth in Table I.




    Example 2



    [0011] A similar series of flotation tests were conducted and the results of these tests are set forth in Table II.






    Claims

    1. A process for improving the recovery of clean coal from flotation circuits which comprises adding an effective amount of a water soluble, partially hydrolyzed polyacrylamide to the coal being processed to decrease the amount of the clay being floated and removed from the cells with the fine coal.
     





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