[0001] The present invention concerns a process and corresponding device for the continuous
preparation of slabs, pa nels and the likes, based on hydraulic or water-settable
binders, containing incorporated in them net-shaped structures as a reinforcement.
[0002] From Spanish Patent n° 460.292 there are known manufac tured articles of cement concrete,
also in the form of slabs, containing as a reinforcement layers of oriented, synthetic
polymer films, fribrilled and spread open to form sort of a net. Such manufactured
articles display a rather high mecha nical resistance to bending, pulling, impact,
fatigues, to gellification and to permeability to water; wherefore, said articles
are considered very interesting for applications in the building field.
[0003] The incorporation into the binder of one or more of the net-like structures of the
mentioned kind, each formed, in general, by a plurality of superimposed. fibrilled
polymeric films, hardly leads to a uniform and capillary diffusion of the binder in
the net-like structure, there be ing, above all, the risk of the formation of air
bubbles the and of portions of/nimpregnated reinforcing structure, es pecially in
a panufacturing process running at industrially competitive output rates.
[0004] The process of this invention allows to carry put this preparation in a continuous
way, at acceptable industrial production speeds, and without the above mentioned drawbacks,
even when using reinforcing structures of a very high num ber of superimposed layers.
[0005] Such a process is characterized in that it comprises at least one full series of
the following operations from
(a) to (f):
(a) continuous deposition of a layer of a cement mix on a horizontal moving ribbon
or band, or a porous surface;
(b) continuous feeding of an open-mesh net-like structure, consisting of one fibrilled
film, or of several super imposed fibrilled films, on that layer, in the direction
and sense in which moves said porous surface;
(c) deposition of the net-like structure on the surface of said layer;
(d) deposition of a layer of cement concrete (mix) on such a net-like struture;
(e) compacting the whole, consisting of the layers of ce- . ment mix and of the net+like
structure by means of vi bration carried out at least in the vertical sense;
(f) compression of the whole assembly or slab, with the consequential reduction of
its content in water to values comprised between 25% and 35% of the weight of the
solids present in it.
[0006] The process of this invention may consist of one sin gle series of operations from
(a) to (f), or it maycompri se any wanted number of such operational series, in succes
sion,one after the other, with the formation of slabs con taining any wanted number
of net-like structures alternated to layers of cement mix.
[0007] By "cement mix" one must intend a mixture entirely consisting or mainly consisting
of one or more hydraulic or water-settable binders such as e.g.: cement, chalk, mortar
and the likes, with water and, in particular the mixtures having a volumetric ratio
water/binder comprised between 30-50/100.
[0008] To the mix there may be added different types of ad ditives for various purposes,
such as for instance:
- inert materials such as e.g.: quartzy sand, with the pur pose of improving the dimensional
stability and duration of the finished manufactured article;
- fluidizing chemical agents, known products that in general act in the way to reduce
the water requirements of the cement mix or concrete;
- well known chemical agents acting as hardening, accelerating or retarding agents;
- chemical agents well known as water-repellents which act to reduce the absqbtion of water by the hardened cement and improve the performance of the finished
slab;
- coloured pigments, to be used in connection with white cement, for the production
of coloured slabs;
- water-emulsified synthetic resins that polymerize inside the cement structure, thereby
improving the resistance and elasticity characteristics of the finished slab, according
to already known techniques;
- short surface-reinforcing fibres, such as: asbestos, cel lulose fibres and derivatives
therefrom, alkalino-resis tant glass fibres, short polyolefine fibres, steel fibres,
etc., and in general all the products or materials susceptible to be mixed with the
cement.
[0009] In fact, a characteristic of the process of this invention is that of allowing, by
means of a differential do sing or metering of each layer, the differentiating of
the type of'mix in the various layers, depending on the particular characteristics
one wishes to impart to the slab, with a wide range of possibilities of variation
and with the pos sibility to save in production costs.
[0010] For instance, it is possible to use high-resistance ce ment, which is more expensive,
only in the two outer layers, or there may be carried out impermeabilizations with
water--repellent agents, or reinforcing treatments with either emulsified synthetic
resins or with reinforcing fibres, only in above mentioned layers, with an evident
saving on the cost of raw materials.Analogously, the production of coloured slabs
may be carried out by using white cement and/or pigments only in the outer layers.
[0011] Furthermore, inert fillers may be added only to the innermost layers of the laminate
on correspondence with the neutral deformation axis, thereby achieving a saving on
the cost of cement and of reinforcement.
[0012] The distribution of the flows relating to the deposi tion of the cement mix layers
before and after the deposi tion of each net-like structure, is made so as to ensure
both the complete covering up.of the net as well as a uni form presence of the nets
in the cement of the intermediate layers.
[0013] In the case the slab is prepared using nets of a small number of fibrilled films,
which therefore are more easily penetrated by the cement, it is sufficient to have
only one dosing or metering device for each net position, unless one desires to obtain
slabs of alternate layers of net and cement, in which case at the beginning of the
first and of the last series of operations from (a) to (f), there must always be a
free metering device or doser forming the initial and the last superficial layers.
[0014] : The net-like structures, used as reinforcement in the process of this invention,
may be of any kind of synthetic polymer capable of forming fibrillable films.
[0015] Said net-like structures may be obtained starting from synthetic polymer films, by
using known fibrillating methods, capable of imparting to the film by a successive
cross-wise spreading an open-mesh net-like structure.
[0016] A method suited for preparing such structures is de - scribed, for instance, in English
Patent n°1.073.741. The net-like structure used in the process of this invention may
consist of either just one single fibrilled film or of a plu rality of superimposed
fibrilled films, possibly welded together.
[0017] A method of preparation for composite, net-like structures, consisting of a plurality
of superimposed fibrilled films and utiliz#able in the process of this invention,
is described, for instance, in Italian Patent n
022.800 A/79, filed in the name of the same Applicant.
[0018] The compacting operation (e) is carried out by means of devices that transmit a vibratnon,in
an at least vertical sense, to the cement mix and that preferably hit the nets bedded
in the cement layers contemporaneously downwards and with a high frequency, without,
however, creating points of stopping of the advancing net.
[0019] The vertical vibratory action may also be combined with horizontal vibrations imparted
to the surface of the conveyor belt or porous surface.
[0020] The compacting operation causes the penetration of the pasty matrix into the net-like
reinforcement, acting un der pressure against the porous surface, and at the same
time bringing about an intimate and uniform contact between matrix and reinforcement,
eliminating air bubbles and zones of non-impregnation. The compacting,in general causes
a slight loss of water through the porous surface. This water may be allowed to flow
freely downward or be gathered, for instance, by means of suction systems with a very
slight depression.
[0021] Lastly, the compacting may be carried out in combination with vibrating high-frequency
movements, imparted to the conveyor belt itself, in the impregnation zones, by electrical
or mechanical vibrators, according to known cement vibration techniques.
[0022] The compression operation (f) aims at regulating or ad justing the thickness of the
slab, at compressing the cement and to eliminate the air as well as the water in excess
with respect to the content, considered,necessary, of 25-35% by weight on the global
weight of nets and cement, and moreover to smoothen its surface.
[0023] Before this operation the slab may, however, be subjected to a preliminary dehydration
operation by suction under vacuum of the water. Likewise after the compression operation
(f), the slab may be subjected to an additional vacuum suction treatment, with the
purpose of further redu cing the content in water down to the value necessary to confer
to it a consistency sufficient for possible succes sive processing operations such
as, for instance, lateral (side) trimming, cutting, undulation., etc., before the
fi nal hardening sets in.
[0024] The device, which forms the further object of this in vention, is characterized in
that it comprises one or more operational units arranged in series, each of which
consists:
(a') a net-like open-mesh structure feeder, the structure consisting of one or more
superimposed fibrilled films;
(b') a horizontal porous surface in motion;
(c') a device for guiding the net-like structure over the moving porous surface;
(d') at least one feeding-dosing device for the deposition of the cement mix on said
surface or on said net-like structure; at least
(el) a vibrator, vibrating/inthe vertical sense, to be used for compacting the cement
mix;
(f') a compressor for compressing the cement mix.
[0025] The feeder (a') may be represented by a standard reel--unwinder, reels on which the
net-like open-mesh structures are wound up, and works maintaining the tension of said
struc ture low and constant.
[0026] The device (c'), acting as a guide for the net-like structure, may consist of a system
of either smooth or fly ted or grooved rollers, or it may consist of rotating, freewheeling
or motor-driven bushes, and will serve to approach the net-like structure to the horizontal
porous surface and/ /or to deposit it onto the layer of cement mix deposited on said
horizontal porous surface.
[0027] The porous surface (b
l), acting as conveyor belt, may consist of a heavy fabric, of the type of paper-mill
felts or for cement-asbestos mixes.
[0028] Such a surface may have either a levelled or profiled cross-section, with any profile
it is wished to impart to the slab, and may moreover, be provided with reliefs, gas
kets or side blades, in order to ensure the lateral contain ment of the cement mixes.
[0029] That surface moves in the same direction and sense of the net-like structure feeder.
[0030] The feeder-doser (d') must be such as to ensure cha racteristics of constancy and
uniformity of flow of the cement mix on the porous surface and/or on the net-like
structure
[0031] This device may may consist of various devices of dif ferent types, such as for instance:
- a horizontal over-flow (surge) tank fitted with an inter nal stirrer, in order to
avoid the hardening of the mix, and suitably fed according to the already known techniques,
by a volumetric pump;
- a vat provided with a horizontal dosing screw which ensures both the metering by
discharg from one side of the vat as well as the advancement of the mix in the vat
itself;
- surge pipeline in which, by means of a pump, there is made to circulate a batch
of cement mix that is muchgreaterthan the metered quantity. The dosing or metering,
in such a case, is carried out by a volumetric pump which provides to integrate into
the circuit the quantity that had flown court of the a gauged and adjustable slot
placed on the surge pipipeline, or through a series of spray-nozzles with gauged bore.
[0032] In general, the metering device will have to allow the easy emptying and washing
of the installation during the stops of the machine, while it will also have to avoid
flow variations due to clogging or to crystalline deposits on the part of the cement.
[0033] Each dosing or metering system, moreover, must be fed by a volumetric pump which
shall allow to vary the flows from layer to layer, and more particularly the flow
of the last layer which, if a good superficial finish of the slab and a sure covering
of the net-like reinforcement are wi shed, must be dosed in quantities much greater
than that of the other layers.
[0034] The compacting vibrator (e
l) may take various forms, one of which is represented by element (8) (vertically ac
ting vibrator) illustrated in figure L, (A) and (B), consis ting of a rotating rollers
supporting frame (15), the rol lers being driven positively and being provided withneliefs,
for instance blades arranged radially to the rollers and having a peripheral speed
equal to or slightly greater than the sliding speed of the net/cement assembly on
band (7).
[0035] The roller-carrying frame is connected elastically with a vibrator (16), for instance
an electro-magnetical one, carried by an upper supporting frame.
[0036] Moreover, the distance between the edges of the blades and the band (
7) is adjustable so that the blades be in contact with or draw in the surface of the
slab being formed, so as to be able to hit it and set it into vibration.
[0037] The slab under formation receives, thus, mechanical stresses of a high frequency
by the revolving blades, with out however their causing any stoppage of the movement
of the slab itself. The compacting device may be achieved also with rigid vertical
elements having at their ends sliding elements such as, for instance, idling rollers,
spheres, small plates oriented in the sense of motion of the nets, etc.. Or it may
be achieved by rows of rotating elements turning in the sense of the net-like structure,
for instance wheels, and prompted by the vibrations, to hit ra pidly the surface of
the nets and of the cement mix.
[0038] The vibratory motion which acts vertically, may be obtained,according to known methods,
by means of electro--mechanical or pneumatic apparatuses, while the frequency of the
vibrations, depending on the speed of the motion of the nets, on the type of nets
and on the matrix and the thicknessof the slab, may vary within a very wide range,
that is, from just a few cycles/second to several hundred cycles/second.
[0039] Compressor (f) may consist of a pair of rollers of which, for instance, the lower
one is driven by a motor, and between which it is possible to carry out a distance
ad justment and to pass the composite slab onto the conveyor belt; or it may consist
of a doctor blade system with a smoothenmng and thickness-regulating blade.
[0040] In order to avoid the adherence or dragging of the cement and/or of the net by the
rollers, these latter may be covered or coated with anti-adhesive sunstances, for
in stance silicon resins, and they may, moreover, be fitted with scraping blades or
with nozzles for air jets, in order to favour the detachment (separation) of the slab.
[0041] Before and/or after compressor (f
l) there may be pre sent, in a succession, suction systems for the removal of the excess
of water present in the slab.
[0042] In figure I is represented in a side view (A) and in a plan view (B), an operational
unit of the device of this invention, with the accessory elements suited for its wor
king. In said figure there will be noted:
A feeding device (1) for the feeding of the net-like struc ture (2); the net-guide
(3) (which may be a roller or a ro tating brush) which serves to approach said net-like
struc ture to the porous surface (7)in motion in the sense in which the arrow points;
the porous surface supporting the drilled plate (9);the dosing devices(4), fed by volumetric pump (5) through valves (6); a vibrator (8); a compressor (10)
consisting of rollers (19) and (20), of which roller (20) is driven by a motor (13);
gaskets (17), placed Ion gitudinally on the porous surface, for retaining the cement
mix spread on said surface, and for avoiding losses of the mix following lateral spilling
of the mix itself.
[0043] In fig. I,(C) represents a doctor-blade compression system, with blade (21) for the
scraping and regulation of the thickness of the cement slab.
[0044] In fig.II there is represented a type of device ac three cording to this invention,
consisting of/operational units arranged in series, where, additionally, there are
represented: the suction systems (14) placed under the vibrators (8); a further suction
system (11); a conveyor belt (18) for gathering the final plate or slab; a washing
device (12) for the porous carrying surface; rotating blades (19) for the trimming
of the slab and the moving cutting lance (20) for the cutting of the slab into crop-ends.
[0045] Still in figure II, (B) represents a schematical view of the production steps for
a composite slab consisting of three nets (2) alternated with three layers of cement
mixes (21).
[0046] Referring to fig. I, the carrying out of the operations in the process of preparation
through an operatio nal unit, is the following one:
The net-like structure (2) is unwound from the reel by means of the unwinder (1),
guided by the net-guiding system (3) on the porous band (7) moving horizontally, and
is placed on the cement layer pre-existing on the said conveyor belt, where it will
be covered up with a layer of cement coming from the successive doser (4). The assembly
of cement/net/ /cement is then conveyed to the vibrator-compacter (8), then to the
compression or lamination system (10) and from there it is conveyed towards the successive
operational unit, where it suffers the superimposition of a new net-like structure
followed by that of another layer of cement.
[0047] Passing from one operational unit to the successive one, in a device consisting of
various different operational units arranged in series, like the one represented in
fig.II, the single laminated elements are superimposed naturally on one another, they
combine with each other and compact them selves forming the final humid slab which
comes out of the last pressing position.
[0048] In order to obtain a good union or joint of the single elementary layer with each
other, it is however necessary that the percentage of residual water in each layer
and the state of compacteness be such as to allow the diffused fil tration of the
successive overlying layers. Thus, the pres- surees in the compressor (10) (and the
possible suction in the suction systems (14)), will have gradually growing values,
growing from the first to the last operational unit and will have to be adjusted (regulated)
in such a way that the residual water in each intermediate layer be comprised, as
a general indication, to be verified,for each type of plant and each cement/nets composition,
within about 0.25 to 0.35 of the water/solids relationship.
[0049] In the last operational unit, the final composite slab, after compacting of the last
cement/net layer, is prefera bly subjected to a vacuum phase with the purpose of removing
the water in excess with respect to the final level of water/solid relationship of
about 0.20-0.25, wherein the slab displays sufficient consistency for the successive
processing stages.
[0050] The removal of the excess of water may also be obtai ned in the course of the last
compression or lamination phase in the last operational unit which, having to bring
the slab to the finally desided thickness, necessarily cre ates a considerable superficial
pressure and increases the contact between the reinforcement and the matrix, eliminating
the water in excess or possible air bubbles.
[0051] The process according to this invention permits also to produce slabs with different
profiles, undualted etc., either by the known undulation or profiling systems on the
trimmed and cut slabs, both by the use of a porous surface already having the desired
profile, for instance an undula ted profile, and of all the organs of the machine
and in particular the net-guides, the compactors, the vacuum boxes, the compre ssion
or pressure rollers, as well as all the motion, transmission and belt-cleaning rollers
having the same profile of the belt itself, so as to maintain the ne vessary adherence.
EXAMPLE 1 :
[0052] Using a device, consisting of 5 operational units ar ranged in series, each of the
type illustrated in fig. I, there were produced flat slabs of cement reinforced with
about 8% by volume of net, obtained from a fibrilled poly propylene film.
[0053] The slabs showed a finished size after trimming, of: 100 x 200 cm and 7 mm thickness.
[0054] The rough width, before trimming amounted to 106 cm. The net of polypropylene showed
a weight of
10
7 g/cc, had open meshes and was 106 cm wide, being formed of 12 layers of polypropylene
films each 75 micron thick, fibrilled by longitudinal slitting and subsequently spread
open transversally with a 9-fold expansion of its original width, wherefore it suffered
a longitudinal shrinkage or contraction of 0.85.
[0055] The layers in the net showed the unfibrilled slanting bands arranged approximately
at ± 12° and ±25° with respect to the direction or sense of the slitting or fibrillation.
[0056] The preparation of the slabs was carried out by suces- sively impregnating with a
cement mix 5 nets whose total weight amounted to 535 g/linear meter.
[0057] The cement mix was of the following composition:
- Portland 325 cement = 100 parts b.w.
- water = 39 parts b.w.
- superfluidizing agent at 20% concentration= 1 part b.w.
[0058] The density of the mix was equal to 1.90 g/cu.cm
[0059] The feeding rate of each of the five nets, and the speed of the porous surface, were
both 12 mt/minute.
[0060] The peripheric (peripheral) speed of the rollers forming the compressor (10), is
greater by about 2% than the speed of the porous surface, so as to maintain the slab
always in traction (tension).
[0061] The dosing of the mix, by means of the volumetric pumps, is adjusted in each operational
unit as follows:

[0062] The porous surface (or conveyor belt) consisted of a felt of polypropylene fibres,
needle-point treated, with a specific weight of 1500 g/sq.mt.
[0063] The elimination of the excess water in each unit was regula ted as follows:
in the first units from 1 to 4 = free discharge, in the 5th unit: = 350 mmHg of vacuum
applied immediately after the 5th compacting device.
[0064] The compression rollers were regulated as follows:

[0065] The compacting system consisted of a frame carrying 4 (four) rollers, each carrying
32 blades, and having a diameter of 120 mm, said compacting system being operated
by an elec tromagnetic vibrator producing vertically directed vibration, at a frequency
of 3000 cycles/minute.
[0066] The slab at the outlet of the last compression position showed a content in water,
measured by drying in an oven at 105° ÷ 110°C, of 22.7% on the total weight of solids.
[0067] The slabs were trimmed at the edges to 100 cm width and then cut to a length of 200
cm.
[0068] After staying/the slabs in water for 28 days and ensuing dry ing in the air for 48
hours, there were measured the unitary resistances at break under bending stresses,
by method UNI 3948, thereby obtaining the following results:
- Resistance, in longitudinal direction = 388 Kg/sq.cm
- Resistance in a transversal direction = 137 Kg/sq.cm The thickness of the sample
slab amounted to 6.9 mm,as the mean value of 10 measurements at different points.
EXAMPLE 2 :
[0069] With the same machine of the preceding example, with the same type of polypropylene
nets and with the same procedures of combination, there were prepared slabs of the
following net size: 100 x 200 cm x 7 mm of thickness, using white cement coloured
with mineral pigments:
The cement mix was of the general composition:
- white Portland (cement, type 425: 100 parts b.w .
- water 39 " "
- superfluidizing agent at 20% concentr.: 1 " " "
[0070] The dosing or metering device n°1 and n°10, which give place to the formation of
the two outside (external) layers of the finished slab, were fed with the above indicated
mix additioned with 3.5% b.w. of red iron oxide, while the inter mediate metering
devices were fed with the general mix.
[0071] The process conditions were the same as those used in ,
example 1.
[0072] After staying in water and drying in the air, the slabs which on the surface showed
a uniform light red tinge, were measured as to their bending resistance with UNI 3948
method, obtaining the following results:
