(19)
(11) EP 0 024 198 A1

(12) EUROPEAN PATENT APPLICATION

(43) Date of publication:
25.02.1981 Bulletin 1981/08

(21) Application number: 80302786.1

(22) Date of filing: 13.08.1980
(51) International Patent Classification (IPC)3D02G 3/22
(84) Designated Contracting States:
DE FR GB IT NL

(30) Priority: 13.08.1979 US 66216

(71) Applicant: CELANESE CORPORATION
New York New York 10036 (US)

(72) Inventor:
  • Sawyer, Linda C.
    Chatham New Jersey (US)

(74) Representative: Beton, John Lonsdale et al
Intellectual Property Department ICI Materials P.O. Box 90
Wilton Cleveland TS90 8JE
Wilton Cleveland TS90 8JE (GB)


(56) References cited: : 
   
       


    (54) Mixed fiber length yarn


    (57) A novel synthetic yarn disclosed which comprises fibers of different lengths (as specified). At least three groups of synthetic fibers are present in the yarn, with the synthetic fibers within each group being substantially uniform in length. The substantially uniform length of each group of synthetic fibers present in the yarn differs from the substantially uniform length of the synthetic fibers in the other groups. The use of such mixtures of fiber lengths in a synthetic yarn enables the yarn to exhibit physical characteristics such as high bulk which more closely resemble the characteristics of natural fiber-containing yarns. Fabrics having improved physical characteristics may also be produced from , the novel synthetic yarns disclosed.


    Description


    [0001] The present invention relates to yarns containing synthetic fibers, especially novel yarns comprised of synthetic fibers having different lengths. For many years natural fibers such as cotton and wool have been replaced, either wholly or in a part, by synthetic fibers in the manufacture of yarns and fabrics. Significant improvements in the strength and processability of textile yarns have thus been achieved. Synthetic fiber-containing yarns and fabrics do not, however, typically possess the appearance and physical characteristics of cotton or wool yarns and fabrics. Synthetic fiber-containing fabrics also do not generally attain the same level of comfort as natural fiber-containing fabrics.

    [0002] Attempts have thus been made to improve the physical characteristics of synthetic fiber-containing yarns and fabrics. For example, US Patent 3 350 872 describes a textile yarn comprised of synthetic fibers whose physical characteristics are intended to simulate those of a wool fabric, which yarn consists of a crimped and uncrimped acrylic fiber. US Patent No 3 965 664 describes a yarn which is formed from a mixture of synthetic fibers including fibers having at least three different deniers and which is intended to have the feel of a natural fiber-containing yarn. US Patent 3 188 790 discloses yarns comprised of a blend of synthetic fibers (eg nylon or polyethylene terephthalate) and cotton fibers, with the synthetic fibers being both crimped and uncrimped. US Patents 3 587 220 and 3 686 850 disclose yarns comprised of synthetic fibers having high and low shrinkage characteristics. US Patent 2 271 184 describes a blend of fibers having both regular and irregular deniers. Differential fiber length is also a criterion taken into account in US Patents 3 157 021; 3 371 475; and 3 335 466 in order to produce a bulky, high strength synthetic yarn. A synthetic fiber-containing yarn has not been produced, however, which adequately exhibits the advantageous physical characteristics (eg, bulkiness and appearance) of natural fiber-containing yarns while retaining the strength and durability of synthetic fiber-containing yarns.

    [0003] In one aspect of the present invention there is provided an improved synthetic fiber-containing yarn comprised of a blend of synthetic fibers of different lengths wherein the synthetic fibers present in the yarn comprise at least about 50 percent by weight of the fibers within said yarn and consist of a mixture of at least three groups of synthetic fibers, each group consisting of fibers of a substantially uniform length which differs from the substantially uniform length of the synthetic fibers in the other groups, and wherein the fibers contained within said at least three groups of synthetic fibers are distributed among each of the following ranges based upon the weight of the fibers in the at least three groups: .

    (a) up to about 75 percent by weight of fibers having a length of about X, wherein X represents the length of the longest synthetic fiber in said groups;

    (b) up to about 75 percent by weight of fibers having a length greater than about 1/2X up to but not including said length of about X; and

    (c) up to about 35 percent by weight of fibers having a length less than or equal to said length of about 1/2X.



    [0004] In. another aspect of the present invention, there is provided an improved fabric containing such synthetic fiber-containing yarn.

    [0005] A preferred distribution of synthetic fibers within the above ranges consists of between about 25 and about 50 percent by weight of synthetic fibers having a length of about X, between about 25 and about 50 percent by weight of synthetic fibers having a length greater than about 1/2X up to but not including said length of about X, and up to about 30 percent by weight of synthetic fibers having a length less than or equal to said length of about 1/2X. Most preferably the yarn contains less than about 20 percent by weight of synthetic fibers having a length less than or equal to said length of about 1/2X.

    [0006] It has been found that yarns which contain synthetic fibers in these lengths and proportions possess characteristics closely paralleling those of natural fiber-containing yarns (eg, cotton or wool yarns). These characteristics relate to aesthetic factors as well as to the thermal and tactile comfort of fabrics containing such yarns.

    [0007] Fabrics containing yarns comprised of natural fibers such as cotton generally exhibit "comfort" characteristics which are superior to those exhibited by fabrics which contain conventional synthetic fiber-containing yarns. Generally, natural fiber-containing yarns exhibit a greater bulk than synthetic yarns (ie the yarns consist of loosely packed fibers). Natural fiber-containing yarns consist of a mixture of fibers of differing length, thus providing a yarn having a multitude of protruding ends along the longitudinal axis of the yarn.

    [0008] 'The high bulk of natural fiber-containing yarns enables fabrics to be produced which exhibit low air permeability and satisfactory covering characteristics. The high degree of fiber end protrudence also enhances the comfort of the fabric.

    [0009] The significant degree of protrudence of fiber ends from the yarn in such fabrics provides for greater tactile comfort in comparison to conventional synthetic yarn-containing fabrics. Conventional synthetic yarns typically consist of fibers having a uniform length, therefore providing a lessened amount of protruding ends resulting in a smoother tactile sensation, high degree of air permeability, and low bulk.

    [0010] The novel synthetic fiber-containing yarns and fabrics of the present invention'more nearly simulate natural fiber-' containing yarns and fabrics, while additionally exhibiting the advantageous characteristics of synthetic fiber-containing yarns.

    [0011] The yarns of this invention contain at least three groups of synthetic fibers with the synthetic fibers within each group being of substantially the same length. It is recognized that the fiber lengths within each group will normally not be exactly the same due to the lack of precision which exists when large amounts of such fibers are cut, but the fiber lengths within each group will generally only differ by a factor of about 5 percent or less. For example, if the longest length X of the synthetic fibers in the groups is intended to be 3 inches, the group of fibers which is cut to that length will generally contain synthetic fibers differing from the desired 3 inch length by a factor of about plus or minus 5 percent or less. This group of fibers will, for purposes of the invention, be deemed to contain fibers of about 3 inches in length (ie a length of about X). Similarly, the phrase "about 1/2X" is intended to include lengths of 1/2X plus or mums about 5 percent. That is,' if the longest length X of the synthetic fibers in the groups is intended to be 3 inches, then fibers having a length of about 1/2X will differ from a length of 1 1/2 inches by only about plus or minus 5 percent.

    [0012] The substantially uniform length of the synthetic fibers of each of the groups present in the yarn will also differ from the substantially uniform length of the synthetic fibers in the other groups present in the yarn. Generally it will be advantageous to employ groups of synthetic fibers whose substantially uniform lengths differ from the substantially uniform lengths of the synthetic fibers in the other groups by at least about 15 percent and preferably between about 15 percent and about 30 percent in order to provide a uniform and high degree of fiber end protrudence along the longitudinal axis of the yarn. It should be noted, however, that less significant differences between the substantially uniform lengths of the groups of synthetic fibers within the yarn will also provide desired results,although the advantages of employing groups of synthetic fibers of differing lengths clearly diminish as the lengths of the synthetic fibers within the yarn become more nearly equal. Generally, the substantially uniform length of the synthetic fibers of each group should differ from the substantially uniform length of the synthetic fibers of the other groups by a factor of at least about 5 percent in order to ensure that the fiber lengths differ significantly enough to provide the desired results.

    [0013] The synthetic fibers within the yarn must consist of a minimum of three groups of synthetic fibers in order to obtain the desired characteristics. More than three groups of synthetic fibers may be present as long as the lengths of all of the fibers present in the yarn are distributed in the required proportions. Generally, the actual lengths of the synthetic fibers are considered to be less important than the ratio of the lengths of the individual fibers to each other. However, yarn production considerations (eg, the problems which arise from handling multiple lengths of fibers) discourage the use of an excessive number of groups of synthetic fibers of differing lengths. The advantages of the present invention may generally be achieved by employing anywhere from three to six groups of synthetic fibers of such lengths and in such proportions consistent with the required distribution of the synthetic fibers within the yarns of this invention. However, it may be desirable to have a wide distribution of lengths of fibers within each group.

    [0014] In order to attain the full benefit of the yarn of the present invention, each of the groups of synthetic fibers contained in the yarn should be present in a significant amount. That is, each group should preferably comprise at least about 5 percent by weight of the total weight of the synthetic fibers contained within said groups. However, the percentage of synthetic fibres in any group may be less than about 5 percent by weight in certain instances, such as when more than three groups of synthetic fibers are present in the yarn. For example one polyester yarn made according to the invention contained six groups of fibers of different lengths ranging from about 1-1/2 inches to about 1/4 inch as follows:-



    [0015] The different fiber lengths to be used within the groups present in the yarn can vary greatly depending upon the desired yarn characteristics as well as the intended use of the yarn. For example, textile fabrics whose primary use is in shirts and similar wearing apparel typically will be comprised of a yarn which contains synthetic fibers having a longest length of about 1 1/2 inches. Yarns which are to be used in the prodiction of sweaters, however, will typically contain synthetic fibers having a longest length of about 3 to 6 inches. The determination of the longest length to be used in a yarn which is intended for a specific use is well within the skill of the artisan.

    [0016] Thus, in accordance with the required fiber distribution of the present invention, a yarn whose primary use lies in the shirting field could contain up to about 75 percent by weight of synthetic fibers of about 1 1/2 inches in length, up to about 75 percent by weight of synthetic fibers having a length greater than about 3/4 of an inch up to but not including said length of about 1 1/2 inches, and up to about 35 percent by weight of synthetic fibers having a length less than or equal to said length of about 3/4 of an inch, based upon the weight of the fibers in those three groups.

    [0017] The synthetic fibers in each of the above ranges may be provided by more than one group of fibers, with the substantially uniform length of the synthetic fibers of one group differing from the substantially uniform length of the synthetic fibers of the other group. However, the total weight percentage of the synthetic fibers in the group must not exceed the allowable proportion for fibers of those lengths.

    [0018] For example, in a yarn which contains 50 percent by weight of synthetic fibers of about 1 1/2 inches in length, 40 percent by weight of synthetic fibers having a length greater than about 3/4 of an inch and up to but not including said length of about 1 1/2 inches, and 10 percent by weight of synthetic fibers having a length less than or equal to said length of about 3/4 of an inch (based upon the weight of the fibers in those groups), the synthetic fibers having a length of between about 3/4 and about 1 1/2 inches could be evenly distributed between fibers 1 inch in length and fibers 1 1/4 inches in length (ie, 20 percent by weight of each based on the total weight of the synthetic fibers present).

    [0019] It should be understood that the length of the longest synthetic fibers to be used in the groups contained within the novel yarn of this invention may be much greater than 1 1/2 inches, and may indeed be 3 or 6 inches or greater in length. Generally the length of the longest synthetic fiber will range between about 1 and 6 inches for conventional textile applications. However, the minimum length of the fibers present will necessarily be more closely controlled, since it may become very impractical to incorporate any fiber length of less than about 1/4 inch in length into the yarn during the production sequence. The shortest length of any synthetic fibers present will thus generally be at least 1/2 inch.

    [0020] The production of a synthetic fiber-containing yarn which contains synthetic fibers of lengths which vary over a wide range may also present problems during the production of the yarn. It is thus also advantageous to employ groups of synthetic fibers which have significantly differing lengths but which lengths do not differ too greatly. For example, a yarn containing synthetic fibers having lengths of about 3 inches, about 1 3/4 inches, and about 3/4 of an inch would be acceptable both with respect to length differential among the groups as well as the minimum length present.

    [0021] A preferred distribution of synthetic fibers within a yarn includes about 20 percent by weight of synthetic fibers of about 1 1/4 inches in length, about 40 percent by weight of synthetic fibers having a length ranging from about 1 up to but not including said length of about 1 1/4 inches, about 25 percent by weight of synthetic fibers having a length ranging from about 3/4 up to but not including said length of about 1 inch, and about 15 percent by weight of synthetic fibers having a length less than said length of about 3/4 inch (eg about 1/2 inch or less), based upon the weight of synthetic fibers present in the different groups.

    [0022] A most preferred distribution of synthetic fibers within a yarn contains about 20 percent by weight of synthetic fibers of about 1 1/4 inches in length, about 40 percent by weight of synthetic fibers having a length of about 1 inch, about 25 percent by weight of synthetic fibers having a length of about 3/4 of an inch and about 15 percent by weight of synthetic fibers having a length of about 1/2 of an inch.

    [0023] Other physical characteristics of the synthetic fibers used in the novel yarns of this invention may be varied in order to further increase the overall bulk of the yarn. For example, at least a portion of the synthetic fibers may be crimped prior to being incorporated into the yarn. Mixtures of shrinkable and non-shrinkable synthetic fibers may also be used to increase yarn bulk. At least a portion of the synthetic fibers may also have an irregularly- shaped or non-circular cross-section. Fibers of mixed deniers may also be used with the yarns of the present invention,

    [0024] The synthetic fibers used in the novel yarns and fabrics of this invention may consist of any suitable conventional polymeric material. Suitable polymeric materials include cellulose acetate, rayon, polyamides -(eg aramids), polyesters, acrylics, and polyolefins. Nylon 66 (eg, poly(hexamethylene adipamide)), linear terephthalate polyesters (eg, polyethylene terephthalate), polyacrylonitrile, polypropylene, and poly(met- aphenylene isothalamide) are exemplary materials. Mixtures of the above materials may also be employed in the yarns of the present invention. Polyethylene terephthalate and cellulose acetate are preferred polymeric materials.

    [0025] The synthetic fibers present in the yarn comprise at least about 50 percent by weight of the total fibers present in the yarn and consist of a mixture of at least three groups of synthetic fibers of substantially uniform length, with the synthetic fibers contained within the at least three groups being present in the required proportions in order to ensure that the benefits of the present invention are attained. Preferably, the synthetic fibers contained within the at least three groups are present in the yarn in amounts ranging from about 65 to 100 percent by weight based on the total weight of the fibers present in the yarn.

    [0026] The yarns of this invention may also contain natural fibers such as cotton or wool fibers in conventional weight ratios which typically range from about 50:50 to 90:10 synthetic fiber/natural fiber, with preferred ratios being 65:35 and 80:20. It should be noted, however, that when the yarn contains both synthetic and natural fibers, the natural fibers need not be present in the required number of groups of the specified ranges set forth for the synthetic fibers. In addition, the yarn of this invention may also contain other synthetic fibers such as rayon or nylon instead of or in mixture with the natural fibers. Thus, for example, the yarn could comprise 65% mixed length polyester and 35% rayon or nylon.

    [0027] The novel synthetic fiber-containing yarns of this invention may be formed into novel fabrics which exhibit improved comfort characteristics as compared to conventional synthetic fiber-containing fabrics. The fabrics may be produced by conventional processes (eg by knitting or weaving). Due to the increased bulk and protruding end count of the novel yarns of this invention, fabrics produced therefrom will exhibit improved covering characteristics as well as an improved tactile sensation. Such fabrics will therefore more closely possess the "look and feel" of natural fiber-containing fabrics, such as cotton and wool fabrics.

    [0028] Fabrics may also be prepared which comprise a mixture of the novel synthetic fiber-containing yarns of the present invention and conventional natural fiber-containing yarns or synthetic fiber-containing yarns. The novel yarns of this invention may be blended with such natural or synthetic fiber-containing yarns in conventional weight ratios.

    [0029] The yarns of this invention may be produced in any conventional manner. Any desired blending, carding, drafting and spinning sequence may be used to produce the yarns. When it is initially determined what distribution of synthetic fiber lengths is desired in the yarn to be produced, groups of synthetic fibers are cut on a cutting wheel set to the appropriate lengths. The cut fibers are then blended and carded whereupon the various lengths become randomly distributed. The yarn which is then spun from the mixture of fibers will contain the specified lengths of synthetic fibers in the required proportions. The fibers of each of the groups become randomly distributed and dispersed throughout the yarn during the yarn production process and are not actually grouped or segregated as to fiber lengths within the yarn which is produced.

    [0030] The following experiments illustrate but do not limit the invention. Four yarns were prepared as set forth in Table I.



    [0031] Fabrics prepared from each of the yarns A, B, C and D were tested using a Mitex Bending Tester to determine the bending rigidity of the yarns from which they were prepared. The bending rigidity of a yarn is indicative of how a fabric or garment containing that yarn will drape or hang from a person. The relative softness of a fabric is related to the bending rigidity of the yarn within the fabric, with a high value for bending rigidity being indicative of a high degree of fiber end protrudence within the yarn since the presence of protruding ends provides frictional resistence to bending.

    [0032] Table II sets forth the bending rigidity for the various yarns identified above.



    [0033] As may be seen from the above data, the cotton yarn exhibits the highest bending rigidity of the yarns tested. However, the mixed fiber length yarn which falls within the scope of the present invention (yarn D) exhibits a bending rigidity which is greater than that exhibited by any of the yarns except the cotton yarn. It is noted that the bending rigidity of the mixed fiber length yarn is significantly greater than the bending rigidity of the conventional polyethylene terephthalate yarn (ie yarn A).

    [0034] The fabrics prepared from yarns A, B, C and D were further tested to determine certain other of their characteristics as set forth below:



    [0035] The above data shows that a fabric produced from a synthetic mixed fiber length PET yarn of the present invention (ie yarn D) exhibits a bulk area (ie a measure of yarn bulk including loops and hairs) which is greater than the bulk area of a cotton fabric produced from a conventional cotton yarn (ie yarn B). The bulk area measurements of Table III were made on a Quantimet 720 Image Analyzing Computer and consitute the average of over fifty measurements. The bulk area of the fabric produced from the mixed fiber length yarn of the present invention is significantly greater than the bulk area of the fabric produced from a conventional PET yarn (ie yarn A). Therefore, the fabric produced from yarn D, while having a thickness and weight that are not excessive, exhibits a significant increase in bulk area which is highly desirable since the bulk area of a fabric is directly related to the coverage to be afforded by that fabric per unit weight. That is, an increase in the bulk area of a fabric will result in an increase in the covering characteristics of the fabric.

    [0036] In addition, fabrics produced from the mixed fiber length yarns of the present invention exhibit a water vapor transmission rate (WVTR) which is significantly lower than that exhibited by conventional synthetic fabrics while also approaching the values for cotton fabrics. The water vapor transmission rate is defined in accordance with ASTM test E96-66 and is indicative of the amount of water vapor which passes through a unit area of fabric per unit time at a vapor pressure difference of about 6.6 mm Hg at 70°F and 65 percent relative humidity.



    [0037] The water vapor transmission rate of a fabric is indicative of the relative porosity and the covering characteristics of the fabric. That is, a fabric comprised of a yarn having a large number of protruding ends will necessarily be less porous than a fabric comprised of a yarn having a lesser number of protruding ends.


    Claims

    1. A yarn comprising a blend of synthetic fibers of different lengths, characterised in that the synthetic fibers present in the yarn comprise at least about 50 percent by weight of the fibers within said yarn and consist of a mixture of at least three groups of synthetic fibers, each group consisting of synthetic fibers of a substantially uniform length which differs from the substantially uniform length of the synthetic fibers in the other groups, and wherein the synthetic fibers contained within said at least three groups of synthetic fibers are distributed among each of the following ranges based upon the weight of the fibers present in said at least three groups:

    (a) up to about 75 percent by weight of fibers having a length of about X, wherein X represents the length of the longest synthetic fiber in said groups;

    (b) up to about 75 percent by weight of fibers having a length greater than about 1/2X up to but not including said length of about X; and

    (c) up to about 35 percent by weight of fibers having a length less than or equal to said length of about 1/2X.


     
    2. A yarn according to claim 1 wherein the synthetic fibers within said at least three groups are comprised of polymeric material selected from the group consisting of linear terephthalate polyesters, cellulose acetate, acrylics, and polyamides.
     
    3. A yarn according to claim 1 wherein the synthetic fibers within said at least three groups are distributed among each of the following ranges:

    (a) between about 25 and about 50 percent by weight of fibers having a length of about X;

    (b) between about 25 and about 50 percent by weight of fibers having a length greater than about 1/2X up to but not including said length of about X; and

    (c) between about 5 percent and 30 percent by weight of fibers having a length less than or equal to said length of about 1/2X.


     
    4. The yarn of claim 1 wherein the substantially uniform length of the synthetic fibers within each of the at least three groups present in the yarn differs from the substantially uniform length of the synthetic fibers in the other groups by a factor of between about 15 percent and about 30 percent.
     
    5. A fabric containing the yarn of claim 1.
     





    Search report